NEET-Ultimate Crash Course

CHEMISTRY
Equilibrium

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L AJ
BA

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

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L AJ
BA

Important Points to Remember

 SOLUBILITY PRODUCT (Ksp)
The constant Kspis known as solubility product. It is equalto the product of the concentration of ions in
saturatedsolution.

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

 For general electrolyte AxBy
x y
Ksp =  A  y   B x 
 Factors Affecting Equilibrium Concentrations: Temperature
• An increase in temperature for exothermic reactions decreases the concentration of products at
Equilibrium and vice-versa.
• An increase in temperature for endothermic reactions increases the concentration of products
at equilibrium and vice-versa.
Pressure
• An increase in pressure to an equilibrium favours the reaction where number of moles show a
decrease and vice-versa.
Effect or pressure (or volume)

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

 
D 1 x
d 1
x 
Dd 
d 
 D
AJ
The density of one mole of gas is given by D 

1 

moles 
MP
RT
Consider dissociation of PCl5. Let x be degree of dissociation

Where D is the theoretical vapour density and d is observed vapour density at temperature t °C.
1
D  Molecular mass
2
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If nx moles of products are formed, then total number ofmoles after dissociation
1 – x + nx = 1 + x (n – 1)
D 1  x  n  1 Dd
  x 
d 1 d  n  1
BA

 Calculation of pH Value of Buffers

Acidic buffer pH  pK a  log
salt 
acid 
This is known as Henderson's equation

Basic buffer pOH  pK b  log

salt 
 base
A buffer has maximum buffer capacity when
salt  or salt   1
acid   base
 Variation of equilibrium constant with variation of the reaction equation (K = equilibrium constant for
originalreaction) is given as below:

Moles of acid or a base added to 1 litre of buffer

 Buffer capacity =
Change in pH
 Calculation of Degree of Dissociation
Let us consider the following reaction:

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

 PCl5  g  PCl3  g   Cl 2  g 
Initial pressure and temperature are P1and T1. At equilibrium, pressure and temperature are P2and T2,
Respectively. The volume of vessel is constant, equal to ‘V’.

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Alternate Method:

Topic name/ year

T1: Law of Mass Action,

2014

1
2015

2
AJ
Topic-wise analysis of NEET 2014-2021
2016 2017

3
2018 2019 2019
(Orissa)
2020 2020
(covid-19)
2021

(Kc and Equilibrium

Constant Kp) and its
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Applications
T2: Relation between 1 1 1 1 1
K,Q,G and Factors
Affecting Equilibrium
T3: Theories of Acids and 1 2 2
Bases, Ionic Product of
BA

Water and pH Scale

T4: Ionization of Weak 1
Acids and Bases and
Relation between Ka and
Kb
T5: Common Ion Effect, 2 1 1 1 1 1 1 1 2 1
Salt Hydrolysis Buffer
Solutions and Solubility
Product

NEET 8 Years at a Glance

1. Which one of the following conditions will favour maximumformation of the product in the reaction,
A2(g) + B2(g) X2(g) r H = –X kJ : [2018]
1) Low temperature and high pressure 2) Low temperature and low pressure
3) High temperature and low pressure 4) High temperature and high pressure
–3 –1
2. The solubility of BaSO4in water is 2.42 × 10 gL at 298 K.The value of its solubility product (Ksp) will
be (Given molarmass of BaSO4= 233 g mol–1) [2018]
–10 2 –2 –12 2 –2
1) 1.08 × 10 mol L 2) 1.08 × 10 mol L
3) 1.08 × 10–8mol2L–2 4) 1.08 × 10–14mol2L–2
3. Following solutions were prepared by mixing different volumes of NaOH and HCl of different
concentrations : [2018]

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

 M M M M
1. 60mL HCl  40mL NaOH 2) 55mL HCl  45mL NaOH
10 10 10 10
M M M M
3) 75mL HCl  25mL NaOH 4) 100mL HCl  100mL NaOH
5 5 10 10
pH of which one of them will be equal to 1?
1) 2 2) 1 3) 3 4) 4
4. The equilibrium constant of the following are : [2017]
N2  3H2 2NH3 K1
N2  O2 2NO K2
1
H 2  O2  H 2O K3
2
The equilibrium constant (K) of the reaction:
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2NH3  O 2 2NO  3H 2O, will be;
K

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1) K 2 K 33 / K1 2) K 2 K 3 / K1 3) K 32 K 3 / K1 4) K1K 33 / K 2
5. Concentration of the Ag+ ions in a saturated solution of Ag2C2O4 is 2.2 104 mol L1 . Solubility
product of Ag2C2O4 is [2017]

6.
1) 2.66 1012
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2) 4.5 1011
Which one of the following statements is not correct?
3) 5.3 1012 4) 2.42 108

1) The value of equilibrium constant is changed in thepresence of a catalyst in the reaction at

equilibrium
2) Enzymes catalyse mainly bio-chemical reactions
3) Coenzymes increase the catalytic activity of enzyme
4) Catalyst does not initiate any reaction
[2017]

7. A 20 litre container at 400 K contains CO2(g) at pressure 0.4atm and an excess of SrO (neglect the
volume of solid SrO).The volume of the container is now decreased by movingthe movable piston fitted
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in the container. The maximum volume of the container, when pressure of CO2 attains its
maximum value, will be : [2017]
(Given that : SrCO3  s  SrO  s   CO 2  g  , K p  1.6atm )
1) 10 litre 2) 4 litre 3) 2 litre 4) 5 litre
BA

8. MY and NY3, two nearly insoluble salts, have the same Kspvalues of 6.2 × 10–13at room temperature.
Which statementwould be true in regard to MY and NY3? [2016]
1) The molar solubilities of MY and NY3in water areidentical.
2) The molar solubility of MY in water is less than that ofNY3
3) The salts MY and NY3are more soluble in 0.5 M KYthan in pure water.
4) The addition of the salt of KY to solution of MY andNY3will have no effect on their solubilities.
9. Consider the nitration of benzene using mixed conc of H2SO4and HNO3. If a large amount of KHSO4is
added to themixture, the rate of nitration will be [2016]
1) faster 2) slower 3) unchanged 4) doubled
10. The Kspof Ag2CrO4, AgCl, AgBr and AgI are respectively,1.1 × 10–12, 1.8 × 10–10, 5.0 × 10–13, 8.3 ×
10–17. Which one ofthe following salts will precipitate last if AgNO3solution isadded to the solution
containing equal moles of NaCl, NaBr,NaI and Na2CrO4? [2015]
1) AgCl 2)AgBr 3) Ag2CrO4 4)AgI
11. If the value of an equilibrium constant for a particular reactionis 1.6 × 1012, then at equilibrium the
system will contain :- [2015]
1) mostly reactants 2) mostly products
3) similar amounts of reactants and products 4) all reactants
12. Which of the following statements is correct for a reversibleprocess in a state of equilibrium? [2015]
1)  G = 2.30 RT log K 2)  Gº = –2.30 RT log K
3)  Gº = 2.30 RT log K 4)  G = –2.30 RT log K
13. Which of the following salts will give highest pH in water? [2014]
1)KCl 2) NaCl 3) Na2CO3 4) CuSO4

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

14. Using the Gibbs energy change,  G° = + 63.3kJ, for the following reaction, [2014]
Ag 2 CO3  2Ag  aq   CO3  aq  the K sp of Ag 2 CO3  s  in water at 25 C is:  R  8.314JK mol 1 
 2 0 1

1) 3.2 1026 2) 8.0 1012 3) 2.9 103 4) 7.9 102

15. For the reversible reaction, N 2  g   3H 2  g  2NH 3  g   heat
The equilibrium shifts in forward direction [2014]
1) By increasing the concentration of NH3(g) 2) By decreasing the pressure
3) By decreasing concentration of N2(g) and H2(g)
4) By increasing pressure and decreasing temperature.
16. For a given exothermic reaction, Kp and K 'p are the equilibrium constants at temperatures T1 and T2,
respectively. Assuming that heat of reaction is constant in temperature range between T1 and T2, it is
readily observed that: [2014]
1) K p  K p
'
2) AgBr 3) Ag2CrO4 4) AgI
17. pH of a saturated solution of Ca(OH)2 is 9. The solubility product (Ksp) of Ca(OH)2 is [NEET-2019]
–15 –10 –15 –10
(1) 0.5 × 10 (2) 0.25 × 10 (3) 0.125 × 10 (4) 0.5 × 10

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18. Conjugate base for Bronsted acids H2O and HF are:- [NEET-2019]
– + + –
(1) OH and H2F respectively (2) H3O and F , respectively
(3) OH– and F–, respectively (4) H3O+ and H2F+, respectively
19.

20.

21.
Which will make basic buffer?
AJ
(1) 50 mL of 0.1 M NaOH + 25 mL of 0.1 M CH3COOH
(2) 100 mL of 0.1 M CH3COOH + 100 mL of 0.1M NaOH
(3) 100 mL of 0.1 M HCl + 200 mL of 0.1 M NH4OH
(4) 100 mL of 0.1 M HCl + 100 mL of 0.1 M NaOH
The pH of 0.01 M NaOH (aq) solution will be
(1) 7.01 (2) 2 (3) 12 (4) 9
[NEET-2019]

[NEET-2019 ODISSA]

Which of the following cannot act both as Bronsted acid and as Bronsted base?[NEET-2019 ODISSA]
(1) HCO 3 (2) NH3 (3) HCl (4) HSO 4
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22. The molar solubility of CaF2 (Ksp = 5.3 × 10–11) in 0.1 M solution of NaF will be[NEET-2019 ODISSA]
(1) 5.3 × 10–11 mol L–1 (2) 5.3 × 10–8 mol L–1 (3) 5.3 × 10–9 mol L–1 (4) 5.3 × 10–10 mol L–1
23. Which among the following salt solutions is basic in nature ? [NEET-2020 COVID]
(1) Ammonium chloride(2) Ammonium sulphate (3) Ammonium nitrate (4) Sodium acetate
–8
24. The solubility product for a salt of the type AB is 4 × 10 . What is the molarity of its standard solution?
BA

[NEET-2020 COVID]
–4 –16 –16
(1) 2 × 10 mol/L (2) 16 × 10 mol/L (3) 2 × 10 mol/L (4) 4 × 10–4mol/L
25. Hydrolysis of sucrose is given by the following reaction [NEET-2020]
Sucrose + H 2O Glu cos e  Fructose
If the equilibrium constant  K C  is 2 1013 at 300K , the value of r GO at the same temperature will be
1. 8.314 J mol 1 K 1  300 K  ln  4 1013  2. 8.314 J mol 1 K 1  300 K  ln  2 1013 
3. 8.314 J mol 1 K 1  300 K  ln  2 1013  4. 8.314 J mol 1 K 1  300 K  ln  3 1013 
26. Find out the solubility of Ni  OH 2 in 0.1M NaOH . Given that the ionic product of Ni  OH 2 is
2 1015. [NEET-2020]
13 8 13
1) 110 M
8
2) 2 10 M 3) 2 10 M 4) 110 M
27 The pK b of dimethylamine and pK a of acetic acid are 3.27 and 4.77 respectively at T (K). The correct
option for the pH of dimethylammonium acetate solution is : [NEET-2021]
1) 5.50 2) 7.75 3) 6.25 4) 8.50

LEVEL-1
TOPIC 1: Law of Mass Action, Equilibrium Constant (Kcand Kp) and its Applications

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

1. A cylinder fitted with a movable piston contains liquid waterin equilibrium with water vapour at 25 °C.
Which operationresult in a decrease in the equilibrium vapour pressure?
1) Moving the piston downward a short distance2) Removing a small amount of vapour
3) Removing a small amount of the liquid water 4) Dissolving salt in the water
2. The reaction CaCO3  s  CaO  s   CO 2  g  goes to completion in lime kiln because
1)Of the high temperature. 2)CaO is more stable than CaCO3.
3)CaO is not dissociated. 4) CO2escapes continuously.
3. Which of the following conditions represents an equilibrium?
1) Freezing of ice in an open vessel, temperature of ice isconstant.
2) Few drops of water is present along with air in a balloon, temperature of balloon is constant.
3) Water is boiling in an open vessel over stove,temperature of water is constant.
4) All the statements 1), 2) and 3) are correct for theequilibrium.
4. Which of the following statement(s) is/are correct regardingchemical equilibrium?
(i) Equilibrium is maintained rapidly.
(ii) The concentration of reactants and products becomesame at equilibrium.

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(iii) The concentration of reactants and products areconstant but different.
(iv) Both forward and backward reactions occur at all timeswith same speed.
1) (i) and (iii) 2) (i), (ii) and (iii) 3) (iii) and (iv) 4) (ii), (iii) and (iv)
5. At the triple point of water there exists an equilibriumbetween

6.

7.
1)Ice and water
3)Ice, water and vapours

1) 0.53
AJ
2) 0.267
2) ice and vapours
4) none of the above.
Two moles of PCl5were heated in a closed vessel of 2 L. Atequilibrium 40% of PCl5is dissociated into
PCl3and Cl2.The value of equilibrium constant is
3) 2.63
1
4) 5.3
For the following reaction in gaseous phase CO  g   O2  g   CO2  g  , K p / K c is
2
1)  RT  2)  RT  3)  RT  4)  RT 
1/ 2 1/ 2 1

PCl3  Cl2 is 2.4 × 10–3. At

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8. At a given temperature the equilibrium constant for the reaction of PCl5
the same temperature, the equilibriumconstant for the reaction PCl3  g   Cl2  g  PCl5  g  is
1) 2.4 103 2) 2.4 103 3) 4.2 102 4) 4.8 102
9. Which of the following is correct for the reaction?
BA

N 2  g   3H 2  g  2NH 3  g 
1) K p  K c 2) K p  K c 3) K p  K c 4) Pressure is required to predict the correlation
10. Boiling point of the liquid depends on the atmosphericpressure. It depends on the altitude of the place;
at highaltitude the boiling point…………..
1) increases 2) decreases 3) either decreases or increases 4) remains same
11. 5 mole of NH4HS (s) start to decompose at a particulartemperature in a closed vessel. If pressure of
NH3(g) in thevessel is 2 atm, then Kpfor the reaction,
NH 4 HS  s  NH 3  g   H 2S  g  , will be
1) 2 2)4 3)0.4 4)0.8
12. A reaction is said to be in equilibrium when
1) the rate of transformation of reactant to products isequal to the rate of transformation of products to
thereactants.
2) 50% of the reactants are converted to products.
3) the reaction is near completion and all the reactantsare converted to products.
4) the volume of reactants is just equal to the volume ofthe products.
13. If the Kpfor the equilibrium, M.5H 2 O  s  M.3H 2 O  s   2H 2 O  g  is110 4 . Then M.5H 2 O  s  will
show efflorescence when it is exposed to anatmosphere where vapour pressure of water is
1) more than 10–2atm 2) below 10–2atm3) more than 10–4atm 4) below 10–4atm

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

14. For the reaction : 2NO 2  g  2NO  g   O 2  g  ,  K c  1.8 106 at 1840 C and R  0.0831kJ / mol K 
When Kp and Kc are compared at 1840C, it is found that
1)Whether Kpis greater than, less than or equal to Kcdepends upon the total gas pressure
2)Kp= Kc 3)Kpis less than Kc 4)Kpis greater than Kc
15. The equilibrium constant for the reversible reaction N2  3H2 2NH3 is K and for reaction
1 3
N2  H2 NH3 , the equilibrium constant is K’
2 2
The K and K’ will be related as:
1) K  K'  1 2) K  K ' 3) K  K 4) K  K '
'

16. For the reaction CO  2H2 CH3OH at 427o C , the partial pressure of CH3OH, CO and H2 at
equilibrium are 2,1 and 0.1atm. respectively. The value of Kp for the decomposition of CH3OH to CO
and H2 is
1) 5 103 atm2 2) 2 102 atm2 3) 5 102 atm2 4) 2 101 atm2
17. In A  B C . The unit of equilibrium constant is

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–1
1) Litre mol 2) Mol litre 3) Mol litre–1 4) No unit
18. A reaction is A + B C + D. Initially we start with equalconcentrations of A and B. At equilibrium we
find that themoles of C is two times of A. What is the equilibrium constantof the reaction?

19.

20.
1) 1

1) 1 × 10 –2
AJ
2) 3

2NO2is
2) 2 × 10–3
3) 4

3) 1 × 10–5
4) 2
The decomposition of N2O4to NO2is carried out at 280 K inchloroform. When equilibrium has been
established, 0.2 moleof N2O4and 2×10-3mole of NO2are present in a 2L solution.The equilibrium
constant for the reaction, N2O4
4) 2 × 10–5
For the reaction H2(g) + I2(g) 2HI (g) at 721 K, thevalue of equilibrium constant is 50, when
equilibriumconcentration of both is 5M. Value of Kpunder the sameconditions will be
1) 0.02 2) 0.2 3) 50 4) 50 RT
21. The rate constant for forward and backward reaction ofhydrolysis of ester are 1.1  10–2and 1.5  10–
L
3
per minuterespectively. Equilibrium constant for the reaction
CH3COOC2H5+H+ CH3COOH+ C2H5OH is
1) 4.33 2) 5.33 3) 6.33 4) 7.33
22. Consider the following graph and mark the correct statement.
BA

1) Chemical equilibrium in the reaction, H2+ I2 ƒ2HIcan be attained from either directions.
2) Equilibrium can be detained when H2and I2are mixedin an open vessel.
3) The concentrations of H2and I2keep decreasing whileconcentration of HI keeps increasing with time.
4) We can find out equilibrium concentration of H2and I2from the given graph.
23. Steam reacts with iron at high temperature to give hydrogengas and Fe3O4(s). The correct expression for
the equilibriumconstant is
P   P   Fe O   Fe3O4 
4 4
PH22 H2 H2 3 4
1) 2) 3) 4)
P2
H2O P  4
H2O  P  4  Fe
H2O  Fe
24. For a reaction the free energy change. G   RT ln K p  RT ln Q p where Kp = equilibrium constant.
Q p  reaction quotient. For the reaction to be in equilibrium state
Qp Qp Qp
1) 1 2) 1 3) 1 4) Q p K p  1
Kp Kp Kp

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

 TOPIC 2: Relation between K, Q, G and Factors Affecting Equilibrium
25. What is the effect of halving the pressure by doubling the volume on the following system at 500 °C?
H 2  g   I2  g  2HI  g 
1) Shift to reactant side 2) Shift to product side
3) Liquefaction of HI 4) No effect
26. The equilibrium constant for a reaction, N 2  g   O 2  g  2NO  g  is 4 104 at 2000 K. In the
presence of catalyst, the equilibrium is attained 10 timesfaster. The equilibrium constant in presence of
catalyst at2000 K is:
1) 10 × 10–4 2) 4 × 10–2 3) 4 × 10–4 4) 40 × 10–4

27. The formation of SO3takes place according to the followingreaction:

2SO2  O2 2SO3 ; H  45.2kcal
The formation of SO3is favoured by
1)Increase in temperature 2) removal of oxygen

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3)Increase of volume 4) increase of pressure
28. According to Le-chatelier’s principle, adding heat to asolid ƒliquid equilibrium will cause the
1)Temperature to increase 2) temperature to decrease
3)Amount of liquid to decrease 4) amount of solid to decrease
29. Consider the reaction
AJ
2SO2(g) +O2(g) 2SO3(g) for whichKc= 278 M–1. 0.001 mole of each of the reagents SO2(g),
O2(g) and SO3(g) are mixed in a 1.0 L flask. Determine thereaction quotient of the system and the
spontaneousdirection of the system:
1) Qc= 1000; the equilibrium shifts to the right
2) Qc= 1000; the equilibrium shifts to the left
3) Qc= 0.001; the equilibrium shifts to the left
4) Qc= 0.001; the equilibrium shifts to the right
30. For the reaction XCO3(s) ƒXO(s) +CO2(g),Kp= 1.642 atm at 727°C. If 4 moles of XCO3(s) was put
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intoa 50 litre container and heated to 727°C. What mole percentof the XCO3remains unreacted at
equilibrium?
1) 20 2) 25 3) 50 4) None of these
BA

31. Which one of the following information can be obtained onthe basis of Le Chatelier principle?
1) Dissociation constant of a weak acid 2) Entropy change in a reaction
3) Equilibrium constant of a chemical reaction
4) Shift in equilibrium position on changing value of aconstraint
32. The equilibrium constant Kpfor a homogeneous gaseousreaction is 10–8. The standard Gibbs free energy
change  G° for the reaction (using R = 2 cal K–1mol–1) is
1) 10.98 kcal 2) –1.8 kcal 3) –4.1454 kcal 4) +4.1454 kcal
33. For the reaction NH4HS(g) NH3(g) + H2S(g) in a closedflask, the equilibrium pressure is P atm. The
standard freeenergy of the reaction would be:
1) – RT ln p 2) – RT (ln p – ln 2) 3) – 2 RT ln p 4) – 2 RT (ln p – ln 2)
TOPIC 3: Theories of Acids and Bases, Ionic Product of Water and pH Scale
34. In HS–, I–, RNH2 and NH3, order of proton acceptingtendency will be
1) I–> NH3> RNH2> HS– 2) HS–> RNH2> NH3> I–
3) RNH2> NH3> HS–> I– 4) NH3> RNH2> HS–> I–
35. Which one of the following compounds is not a protonicacid?
1)SO2 (OH)2 2) B(OH)3 3) PO(OH)3 4) SO(OH)2
36. Which of the following molecules acts as a Lewis acid?
1) (CH3)2O 2) (CH3)3P 3) (CH3)3N 4) (CH3)3B
37. Which one of the following is the correct statement?
1) HCO 3 is the conjugate base of CO32  2) NH2 is the conjugate acid of NH3.
3) H2SO4is the conjugate acid of HSO 4 4) NH3is the conjugate base of NH2

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

38. Which of the following has highest pH?
M M M M
1) KOH 2) NaOH 3) NH 4OH 4) Ca  OH 2
4 4 4 4
–3
39. The pH of a 10 M HCl solution at 25 °C if it is diluted 1000times, will be –
1) 3 2) zero 3) 5.98 4) 6.02
40. What will be the pH of a solution formed by mixing 50 mL of0.5 M HCl solution and 150 mL of 0.5 M
NaOH solution and300 mL H2O?
1) 13 2) 12.7 3) 7 4) 11
41. Water is well known amphoprotic solvent. In which chemical reaction water is behaving as a base?
1) H 2SO 4  H 2 O  H 3O   HSO 4 2) H 2 O  H 2 O  H 3O   OH 
3) H 2 O  NH 2  NH 3  OH  4) H 2 O  NH 3  NH 4  OH 

42. The value of ionic product of water at 393 K is

1)Less than 1 × 10–14 2) greater than 1 × 10–14 3)Equal to 1 × 10–14 4) equal to 1 × 10–7
43. Three reactions involving H2 PO4 are given below:

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1) H 3PO 4  H 2 O  H 3O   H 2 PO 4 2) H 2 PO 4  H 2 O  HPO 42  H 3O 
3) H 2 PO 4  OH   H 3PO 4  O 2
In which of the above does H2 PO4 act as an acid?

44.

45.
1) (ii) only

1) depends on volume of water

AJ
2) (i) and (ii)
The value of the ionic product of water

3) changes by adding acid or alkali

3) (iii) only 4) (i) only

2) depends on temperature
4) always remains constant
Which of the following increasing order of pH of 0.1 Msolution of the compounds 1) HCOONH4,
2) CH3COONH4, 3) CH3COONa and 4) NH4Cl is correct?
1) A < D < B < C 2) D < A < C < B 3) A < D < C < B 4) D < A < B < C
46. On increasing the temperature of pure water
L
1) both pH and pOH increase 2) both pH and pOH decrease
3) pH increases and pOH decreases 4) pH decreases and pOH increases
TOPIC 4: Ionization of Weak Acids and Bases and Relation between Kaand Kb
47. The dissociation constant of two acids HA1and HA2are3.14 × 10– 4and 1.96 × 10– 5respectively. The
relative strengthof the acids will be approximately
BA

1)1 : 4 2) 4 : 1 3) 1 : 16 4) 16 : 1
48. At 298K a 0.1 M CH3COOH solution is 1.34% ionized. Theionization constant Ka for acetic acid will
be
1) 1.82 × 10– 5 2) 18.2 × 10–5 3) 0.182 × 10–5 4) none of these
49. Ka1,Ka2and Ka3are the respective ionisation constantsfor the following reactions.
H2S H  HS
HS H  S2
H2S 2H  S2
The correct relationship between Ka1 , Ka 2 and Ka3 is
1) K a 3  K a1  K a 2 2) K a 3  K a1  K a 2 3) K a 3  K a1  K a 2 4) K a 3  K a1 / K a 2
50. A monobasic weak acid solution has a molarity of 0.005 andpH of 5. What is the percentage ionization
in this solution?
1) 2.0 2) 0.2 3) 0.5 4) 0.25
51. Which of the following will occur if 0.1 M solution of a weakacid is diluted to 0.01 M at constant
temperature?
1) [H+] will decrease to 0.01 M 2) pH will decrease
3)Percentage ionization will increase 4) Kawill increase
52. At a certain temperature the dissociation constantsof formic acid and acetic acid are 1.8 × 10–4and
1.8 × 10–6respectively. The concentration of acetic acidsolution in which the hydrogen ion has the
sameconcentration as in 0.001 M formic acid solution is equal to

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

 1) 0.001 M 2) 0.01 M 3) 0.1 M 4) 0.0001 M
53. The degree of dissociation of acetic acid in a 0.1 M solutionis 1.32 × 10–2. Find out the dissociation
constant of the acid.
1) 1.50 × 10–4 2) 1.80 × 10–16 3) 1.76 × 10–5 4) 1.2 × 10–3
TOPIC 5: Common Ion Effect, Salt Hydrolysis, Buffer Solutions and Solubility Product
54. Solubility of salt A2B3is 1 × 10–4, its solubility product is
1) 1.08 × 1020 2) 1.08 × 1018 3) 2.6 × 10–18 4) 1.08 × 10–18
55. Which of the following metal sulphides has maximumsolubility in water?
1)CdS (Ksp= 36 × 10–30) 2)FeS (Ksp= 11 × 10–20)
–54
3)HgS (Ksp= 32 × 10 ) 4) ZnS (Ksp= 11 × 10–22)
56. The Kspfor Cr(OH)3is 1.6 × 10–30. The solubility of thiscompound in water is :
1) 4 1.6  1030 2) 4 1.6 1030 / 27 3) 1.6 1030/ 27 4) 1.6  1030

57. Consider the following equilibrium

AgCl  2NH 3 [Ag  NH 3 2 ]

I
White precipitate of AgCl appears on adding which of thefollowing?
1) NH3 2) aqueous NaCl 3) aqueous HNO3 4) aqueous NH4Cl
2
58. A saturated solution of Ag2SO4is 2.5 10 M, the valueof its solubility product is :

59.

60.
1) 62.5 106
AJ
2) 6.25 104 3) 15.625 106
The solubility of AgI in NaI solution is less than that in purewater because
1) the temperature of the solution decreases.
2) solubility product of AgI is less than that of NaI.
3) of common ion effect. 4)AgI forms complex with NaI.
4) 3.125 106

A litre of solution is saturated with AgCl. To this solution if1.0 × 10–4mole of solid NaCl is added, what
will be the[Ag+], assuming no volume change?
1) More 2) Less 3) Equal 4) Zero
–12
L
61. The solubility product of a sparingly soluble salt BA2is4 × 10 . The solubility of BA2is
1) 4 × 10–4 2) 4 × 10–12 3) 4 × 10–3 4) 1 × 10–4
62. The pH of an acidic buffer mixture is
1)> 7 2) = 7 3)< 7 4) depends upon Kaof the acid
63. The pH of a weak mono acidic base, neutralized upto 80%with a strong acid in a dilute solution, is 7.40.
BA

The ionizationconstant of the base is

1) 1.0 × 10–5 2) 1.6 × 10–7 3) 1.0 × 10–6 4) None of these
64. When a buffer solution, sodium acetate and acetic acid isdiluted with water :
1) Acetate ion concentration increases 2) H+ion concentration increases
–
3) OH ion conc. Increases 4) H+ion concentration remains unaltered
65. A buffer solution is prepared by mixing 0.1 M ammonia and1.0 M ammonium chloride. At 298 K, the
pKbof NH4OH is5.0. The pH of the buffer is
1) 10.0 2) 9.0 3) 6.0 4) 8.0
66. The product of ionic concentration in a saturated solutionof an electrolyte at a given temperature is
constant and isknown as
1) Ionic product of the electrolyte 2) Solubility product
3) Ionization constant 4) Dissociation constant
67. What is the molar solubility of Fe(OH)3if Ksp= 1.0 ×10–38?
1) 3.16×10–10 2) 1.386×10–10 3) 1.45×10–9 4) 1.12×10–11
68. The correct order of increasing solubility of AgCl in 1)water, 2) 0.1 M NaCl, 3) 0.1 M, BaCl2, 4) 0.1 M
NH3is
1) D > A > B > C 2) D > C > B > A 3) B > A > D > C 4) A > D > B > C
69 . If s and S are respectively solubility and solubility productof a sparingly soluble binary electrolyte then
1) s = S 2) s = S2 3)s = S1/ 2 4) s 1/2 S
–14
70. Solubility product of M(OH)2is 10 . What should be theconcentration of M2+in 0.1 M solution of
NH4OH, if NH4OHgets 10% ionised ?
1) 10–10 2) 10–5 3) 10–12 4) 10–4

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

 LEVEL – 2
1. PCl5is dissociating 50% at 250 °C at a total pressure ofP atm. If equilibrium constant is Kp, then which
of thefollowing relation is numerically correct –
2K p 2P
1) K p  3P 2) P  3K p 3) P  4) K p 
3 3
2. K1, K2and K3are the equilibrium constants of the followingreactions (I), (II) and (III) respectively:
1
I) N2  2O2 2NO2 II) 2NO2 N2  2O2 III) NO 2 N 2  O2
2
The correct relation from the following is
1 1 1 1 1
1) K1   2) K1   3) K1  K 2  K 3 4) K1   K3
K 2 K3 K 2  K3  2
K2
3. 3.2 moles of hydrogen iodide were heated in a sealed bulb at444 °C till the equilibrium state was
reached. Its degree ofdissociation at this temperature was found to be 22%. Thenumber of moles of

I
hydrogen iodide present at equilibrium are
1) 2.496 2) 1.87 3) 2 4) 4
4. For the equilibrium reaction
2NOBr  g  2NO  g   Br2  g 

5.
If PBr 2 
1) 1/3
P
9
AJ
, Where P is total pressure at equilibrium. The ratio
2) 1/81 3) 1/9
Kp
P

A gaseous compound of molecular mass 82.1 dissociates on heating to 400 K as

X 2 Y4  g 
is equal to
4) 1/27

X 2  g   2Y2  g  The density of the equilibrium mixture at a pressure of 1 atm and

temperature of 400K is 2.0gL-1. The percentage dissociation of the compound is
1) 12.5% 2) 48.5% 3) 90.1% 4) 25.0%
L
6. In a reversible chemical reaction having two reactants inequilibrium, if the concentration of the
reactants are doubledthen the equilibrium constant will
1) Also be doubled 2) Be halved 3) Become one-fourth 4) Remain the same
7. Ammonium carbamate dissociates on heating as :
NH 2 COONH 4  g  2NH 3  g   CO 2  g  The equilibrium constant Kpfor the reaction, at some
BA

temperature is 3.2 105 atm3 Calculate the partial pressureof NH3in the equilibrium system at the same
temperature.
1) 2.0 × 10–2atm 2) 4.0 × 10–2atm 3) 3.2 × 10–2atm 4) 6.4 × 10–2atm
8. Consider the partial decomposition of A as 2A  g  2B  g   C  g  At equilibrium 700 mL gaseous
mixture contains 100 mL ofgas C at 10 atm and 300 K. What is the value of KPfor thereaction?
40 1 10 28
1) 2) 3) 4)
7 28 28 10
9. If Kcis in the range of ………………… appreciableconcentrations of both reactants and products are
present.
1) 10–4to 104 2) 10–3to 103 3) 103to 10– 3 4) 10–5to 103
10. For which one of the following systems at equilibrium, atconstant temperature will the doubling of the
volume causea shift to the right?
1) H 2  g   Cl 2  g  2HCl  g  2) 2CO  g   O 2  g  2CO 2  g 
3) N 2  g   3H 2  g  2NH 3  g  4) PCl5  g  PCl3  g   Cl 2  g 
11. The reactions
PCl5  g  PCl3  g   Cl 2  g  and COCl 2  g  CO  g   Cl 2  g 
are simultaneously in equilibrium in a vessel at constant volume. If some CO is introduced into the
vessel then at the new equilibrium
1) Cl2is greater. 2) PCl5is less. 3)PCl3remain unchanged. 4) PCl5is greater.

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

12. The element Bi melts at 271 °C and has density of 9.73 g/mLas a solid and 10.05 g/mL as a liquid at
this temperature. Forthe equilibrium Bi(s) Bi(l), the melting point is favouredin this endothermic
reaction either by
1)Increasing temperature, decreasing pressure 2)Decreasing temperature, decreasing pressure
3)Increasing temperature, increasing pressure 4) there is no effect of pressure on melting point
13. At 25 °C, the dissociation constant of a base, BOH, is1.0  10-12. The concentration of hydroxyl ions in
0.01 M aqueous solution of the base would be
1) 1.0  10-5mol L-1 2) 1.0  10-6mol L-1 3) 2.0  10-6mol L-1 4) 1.0  10-7mol L-1
14. On doubling P and V with constant temperature theequilibrium constant will
1) remain constant 2) become double 3) become one-fourth 4) None of these
15. K1and K2for oxalic acid are 6.5×10–2and 6.1×10–5respectively. What will be [HO–] in a 0.01 M solution
ofsodium oxalate ?
1) 9.6×10–6 2) 1.4×10–1 3) 1.3×10–6 4) 1.3×10–8

16. The exothermic formation of ClF3is represented by theequation:

I
Cl2(g) + 3F2(g) 2ClF3(g);  H = – 329 kJ
Which of the following will increase the quantity of ClF3inan equilibrium mixture of Cl2, F2and ClF3?
1) Adding F2 2) Increasing the volume of the container

17.

18.
3) Removing Cl2
6

3) HCN > HF > HCOOH

AJ 4) Increasing the temperature
Equimolar solutions of HF, HCOOH and HCN at 298 K havethe values of Kaas 6.8 × 10–4, 5.8 × 10–
and 4.8 ×10–9respectively. What is the observed trend of acid strength?
1) HF > HCN > HCOOH 2) HF > HCOOH > HCN
4) HCOOH > HCN > HF
Which of the following pKavalue represents the strongestacid ?
1) 10–4 2) 10–8 3) 10–5 4) 10–2
19. For preparing a buffer solution of pH 6 by mixing sodiumacetate and acetic acid, the ratio of the
concentration of saltand acid should be (Ka= 10–5)
L
(a) 1 : 10 2) 10 : 1 3) 100 : 1 4) 1 : 100
20. What will be the volume of 1 M NH3and 1 M HCl requiredto prepare 300 mL of a buffer of pH = 9.26
(pKa= 9.26 for NH4 )
1) 225 mL, 75 mL 2) 200 mL, 100 mL 3) 100 mL, 200 mL 4) 150 mL, 150 mL
21. The sum of pH and pKbfor a basic buffer solution is 13.The ratio of the concentration of the base to that
BA

of thesalt is
1) 10 2) 1 3) 0.05 4) 0.1
22. Solubilities of three sparingly soluble salts XY (Ksp), XY2(K'sp) and X2Y3(K''sp) are equal in water. What
will be thecorrect order of their solubility products –
1)Ksp<K'sp< K''sp 2)Ksp< K''sp<K'sp 3) K''sp<K'sp<Ksp 4) K''sp<Ksp<K'sp
23. Equal volumes of three acid solutions of pH 3, 4 and 5 aremixed in a vessel. What will be the H+ion
concentration inthe mixture ?
1) 1.11 × 10–4M 2) 3.7 × 10–4M 3) 3.7 × 10–3M 4) 1.11× 10–3M
24. Which of the following pairs constitutes a buffer?
1) NaOH and NaCl 2) HNO3and NH4NO3 3) HCl and KCl 4) HNO2and NaNO2
25. The 0.001M Solution of Mg (NO3)2is adjusted to pH 9, Kspof Mg(OH)2is 8.9 × 10–12. At this pH
1)Mg(OH)2will be precipitated. 2)Mg(OH)2is not precipitated.
3)Mg(OH)3will be precipitated. 4)Mg(OH)3is not precipitated.
26. In a saturated solution of the sparingly soluble strongelectrolyte AgIO3(molecular mass = 283) the
equilibriumwhich sets in is AgIO3(s) Ag+ (aq)+ IO3 (aq). If thesolubility product constant Kspof
AgIO3at a giventemperature is 1.0 × 10–8, what is the mass of AgIO3contained in 100 mL of its
saturated saolution?
1) 1.0 × 10– 4g 2) 28.3 × 10–2g 3) 2.83 × 10–3g 4) 1.0 × 10–7g.
27. The solubility of AgSCN in 0.002 M NH3is (KspforAgSCN = 1.0 × 10–12;Kdfor Ag(NH3) 2 = 1.0 × 10–8)
1) 3 × 10–5M 2) 4 × 10–4M 3) 4 × 10–5M 4) 2 × 10–5M

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

28. When sulphur (in the form of S8) is heated at temperatureT, at equilibrium, the pressure of S8falls by
30% from1.0 atm, because S8(g) is partially converted into S2(g). Findthe value of KP for this reaction.
1) 2.96 2) 6.14 3) 204.8 4) None of these
29. Phosphorus pentachloride dissociates as follows, in a closed reaction vessel
PCl5  g  PCl3  g   Cl 2  g 
If total pressure at equilibrium of the reaction mixture is P and degree of dissociation of PCl5is x, the
partial pressure of PCl3will be
 x   x   x   2x 
1)  P 2)  P 3)  P 4)  P
 x 1   1 x   x 1  1 x 

30. If degree of dissociation of pure water at 100°C is1.8 × 10–8, then the dissociation constant of water will
be(density of H2O = 1 g/cc)
1) 1 × 10–12 2) 1 × 10–14 3) 1.8 × 10–12 4) 1.8 × 10–14

ANSWER KEY

I
NEET 8 Years at a Glance
1) 1 2) 1 3) 3 4) 1 5) 3 6) 1 7) 4 8) 2 9) 2 10) 3
11) 2
21) 3

1) 4
11) 2
21) 4
12) 2
22) 3

2) 4
12) 1
22) 1
13) 3
23) 4

3) 2
13) 2
23) 2
AJ
14) 2
24) 1

4) 3
14) 4
24) 3
15) 4
25) 2

5) 3
15) 3
25) 4
16) 1
26) 2
LEVEL – 1
6) 2
16) 1
26) 3
17) 1
27) 2

7) 2
17) 1
27) 4
18) 3

8) 3
18) 3
28) 4
19) 3

9) 2
19) 3
29) 2
20) 3

10) 2
20) 3
30) 4
31) 4 32) 1 33) 4 34) 3 35) 2 36) 4 37) 3 38) 4 39) 3 40) 1
41) 1 42) 2 43) 1 44) 2 45) 4 46) 2 47) 2 48) 1 49) 1 50) 2
L
51) 3 52) 2 53) 3 54) 4 55) 2 56) 2 57) 3 58) 1 59) 3 60) 2
61) 4 62) 4 63) 3 64) 4 65) 1 66) 2 67) 2 68) 1 69) 3 70) 1
LEVEL –II
1) 2 2) 2 3) 1 4) 2 5) 1 6) 4 7) 2 8) 3 9) 2 10) 4
BA

11) 2 12) 3 13) 4 14) 1 15) 3 16) 1 17) 2 18) 2 19) 2 20) 2
21) 4 22) 3 23) 2 24) 4 25) 2 26) 3 27) 4 28) 1 29) 3 30) 4
Hints and Solutions
NEET 8 Years at a Glance
1. 1) A 2  g   B2  g  X 2  g  ; H   xkJ
On increasing pressure equilibrium shifts in a directionwhere number of moles decreases i.e. forward
direction.On decreasing temperature, equilibrium shifts inexothermic direction i.e., forward direction.
So, high pressure and low temperature favoursmaximum formation of product.
2. 1)Solubility of BaSO4  2.42 103 gL1
2.42 103
s   1.038 105 mol L1
233
K sp  s 2  1.038 105   1.08 1010 mol2 L2
2

1
3. 3)Meq. Of HCI = 75  1  15
5
1
Meq. of NaOH = 25  1  5
5
Meq. of HCl in resulting solution = 10

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

 10 1
Molarity of [H+] in resulting mixture = 
100 10
1
pH =  log  H     log    1.0
10 
4. 1)

I
5. 3) Ag 2 C2 O 4  s 
2
K sp   Ag   [C 2 O 24 ]
 Ag    2.2 104 M
AJ
2Ag   aq   C2 O 42  aq 

Given that
 Concentration of C2O24 ions
L
2.2 104
[C2O42 ]  M  1.1104 M
2
 K sp   2.2 104  1.1104   5.324  1012
2
BA

 K  K 2  K 33 / K1
6. (1)A catalyst speeds up both forward and backward reaction with the same rate. So, equilibrium
constant is not affected by the presenceof a catalyst at any given temperature.
7. (4) Max. pressure of CO2= Pressure of CO2at equilibriumFor reaction, SrCO3  s  SrO  s   CO 2
K p  PCO2  1.6 atm  maximum pressure of CO2
Volume of container at this stage
V = nRT/P ……………………….(i)
Since container is sealed and reaction was not earlier at equilibrium
 n = constant
PV 0.4  20
n  ……………………..(ii)
RT RT
Put equation (ii) in equation (i)
 0.4  20  RT
V  5L
 RT  1.6
8. 2)

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

  molar solubility of NY3 is more than MY in water.

I
9. 2)The presence of large amount of KHSO4will decreaseionisation of H2SO4that result in lesser
ionisation ofnitric acid and lesser formation of nitronium [NO2+].Hence the rate of nitration will be
slower.
10. 3) Ag2CrO4
2
AJ
K sp   Ag   Cr2O 42   1.11012

 Ag   

AgCl
1.11012
[Cr2O 42

K sp   Ag   Cl   1.8 1010

1.8 1010
L
 Ag   
Cl 
AgBr
K sp   Ag    Br    5.0 1013
BA

5.3 1013
 Ag   
 Br  
AgI
K sp   Ag    I    8.3 1017
8.3 1017
 Ag   
 I  
If we take Cr2 O 42   Cl    Br     I    1 then maximum  Ag   will be required in case of Ag2 Cro4
11. 2)Equilibrium constant for reaction:

K  1.6 1012 
 Pr oduct  The value of K is very high so the system will contain mostly products at
 Re ac tan t 
equilibrium
12. 2) G0  2.30RT log K
Because at equilibrium G  0
13. 3) Na 2 CO 3 is a salt of strong base (NaOH) and weak acid(H2CO3). On hydrolysis this salt will produce
stronglybasic solution. i.e. pH will be highest (pH > 7) for thissotluion. Others are combination of
KCl = Strong acid + Strong base  neutral solution (pH  7)
NaCl = Strong acid + Strong base  neutral solution (pH  7)

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

 CuSO4= Strong acid + weak base  Acidic solution (pH  7)

14. 2) G  2.303log K here

2
K   Ag   CO3   K sp
 63.3  103  2.303  8.314  298log K sp
63.3 103
 log K sp    11.09
5705.8
 K sp  Anti log  11.09   8 10 12
15. (4) Given reaction is exothermic reaction. Hence according to Le-Chatelier's principle low temperature
favours the forward reaction and on increasing pressure equilibrium will shift, towards lesser number of
moles i.e. forward direction.
16. (1) In exothermic reactions on increasing temperature value of Kpdecreases
 K p  K 'p (Assuming T1< T2)

I
17.
L AJ
18. Conjugate base of H2O is OH–
Conjugate base of HF is F–
19.. Basic buffer is mixture of weak base and salt of weak base with strong acid
milli mole of HCl = 100 × 0.1 = 10 milli mole
BA

milli mole of NH4OH = 200 × 0.1 = 20 milli mole

HCl  NH 4OH  NH 4 Xl  H 2O
10 20  
 10 10
20.

21.

22

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

23. CH 3COONa  Salf of CH 3COOH  WA   NaOH  SB 

I
Solution of CH3COONa shows basic nature
24. K sp for AB  s2  4 108
 Molarity of solution = solubility = K sp

25.

26.
 4 108  2 104 mol / L

2)
AJ
G 0  2.303RT log10 K   RT ln k  8.314 J .mol 1k 1  300k  ln  2 1013 

Ni  OH 2 N12  2OH 
L
S S 2S
 2S  0.1
in presence NaOH of 0.1M
BA

2
K sp   Ni 2  OH  

2 1015   S  2 S  0.1
2

2 1015   S  0.1  2 S  0.1

2

 S  2 1013

27. PH  7 
2

1 ka
P  P kb  ;

1 1
PH  7   4.77  3.27   7  1.5  7.75
2 2

LEVEL – 1
1. (4) Dissolution of salt lowers the V.P. It is also effected bytemperature.
2. (4) In lime kiln CO2escapes continuously so reactionproceeds in forward direction.
3. (2) Equilibrium can be achieved only in closed system.
4. (3)

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

5. (3) Triple point of a substance is the temperature andpressure at which the three phases (gas, liquid and
solid) of that substance coexist in thermodynamicequilibrium.
6. 2) PCl5 PCl3  Cl 2
a 1 x  ax ax

a = 2, x = 0.4, V = 2L
2 1  0.4 
 PCl5    0.6molL1
2
2  0.4
 PCl3   Cl2    0.4molL1
2
0.4  0.4
 Kc   0.267
0.6
2)For a gaseous phase reaction K p and K c are related as K p  K c  RT  g For the given reaction
n
7.
1
CO  g   O2  g   CO 2  g 
2

I
1
n g  1  1  0.5   0.5or 
2
1 K 1
 K p  K c  RT  2 or p   RT  2
 

8.

9.
1
3) K  ; K 
'

K
'

2) N 2  g   3H 2  g 
Kc
1
2.4 103
 4.2 102

2NH 3  g 
 n  n products  n readants  2  4  2
AJ
Kc
 K p  K c  RT 
2
or K p 
 RT 
2
L
Thus K p  K c
10. 2)
11. 2) PNH3  PH 2S  2atm
 K p  PNH3  PH 2S  4
BA

12. 1) A reaction is said to be in equilibrium when rate of forward reaction is equal to the rate of backward
reaction.
 
2
13. 2) K p  PH2O
PH 2O (at equilibrium) = K p  102
Forward reaction will occur if value of PH 2O is less than 102 atm.
14. 4)For the reaction ; 2NO 2  g  2NO  g   O 2  g 
Given K c  1.8 106 at1840 C
R  0.0831KJ / mol K
K p  K c  RT 
n g

K p  1.8 106  0.0831 457  6.836 10 5

 1840 C   273  184   457K, n   2  1, 1  1
Hence it is clear that K p  K c
15. 3) N2  3H2 2NH3
 K   NH 3  /  N 2  H 2  ………………….(i)
2 3

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

 1 3
N2  H2 NH3
2 2
 NH3  ............... ii
 K'   
 N2  H2 
1/ 2 3/ 2

Dividing equation (i) by equation (ii), we get

K'  K
PCH3OH 2
16. 1) K p  ; Kp   200 atm 2
PCO  p 1  0.1
2 2
H2

1
For reverse reaction, K p   5 103 atm 2
200
17. 1) For A  B C, n  1  2  1
n 1
 mol   mol 
Unit of K c     litre mol1
 litre  
 litre 

I
18. 3)
19. 3)
20. 3) H 2  g   I 2  g  2HI  g 

21.

22.
K p  K c  RT  ; n  2  2  0; K p  K c
n

Equilibrium constant (Kc) =

K f 1.1102

K b 1.5 103
AJ
4)Rate constant of forward reaction (Kf) = 1.1 × 10–2andrate constant of backward reaction
(Kb) = 1.5 × 10–3per minute.

 7.33

(1) Equilibrium can be attained by either side of thereactions of equilibrium.

23. 2) 3Fe  s   4H 2O  steam  Fe3O 4  s   4H 2  g 
L
 pH2 
4

Kp  only gaseous products and reactants

 p H2O 
4

24. 3)
4) H 2  g   I 2  g  2HI  g 
BA

25.
Since the reaction does not involve any change innumber of moles, the equilibrium state is not affected
by change of pressure.
26. 3) Catalyst only changes time to achieve equilibrium, it does not affect the value of equilibrium
constant.
27. 4)
28. 4) Solid Liquid
It is an endothermic process. So when temperature is raised, more liquid is formed. Hence adding heat
willshift the equilbrium in the forward direction.
SO3  g  
2

29. 2) QC   1000  K c i.e., reaction moves backward also if volume increases

SO2  g   O2  g  
2 1

pressure decreases  Q c 
1.642  50
30. 4)Moles of CO2 present at equilibrium =  1
0.08211000
1
Mole % of XCO3decomposed = 100  25%
4
Hence, 75% remains undecomposed
31. 4) According to Le-chatelier's principle whenever a constraint is applied to a system in equilibrium, the
system tends to readjust so as to nullify the effect of the constraint.

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

32. 1) G0  2.303 RT log K = 2.303  2  298log108 = 2.303  2  298   8  cal  10980cal  10.98kcal
P
33. 4) PNH3  PH2S  atm
2
2
P P2
K p  PNH3 PH2S   
2 4
2
p
G  RT ln K p  RT ln    2RT  ln p  ln 2
2
34. 3)Strong base has higher tendency to accept the proton.Increasing order of base and hence the order of
accepting tendency of proton is I   HS  NH 3  RNH 2
2) B  OH 3 does not provide H ions in water instead itaccepts OH ion and hence it is Lewis acid.
+ –
35.

B  OH 3  H 2 O  B  OH 4   H 
36. 4)  CH 3 3 B  is an electron deficient, thus behave as a lewis acid.

I
37. 3) HSO 4 accepts a proton to form H2SO4 .
Thus H2SO4 sis the conjugate acid of HSO 4

H
HSO 4   H SO

38.

39.
base
2 4

AJ
conjugate acid of HSO 4

4) Among M/4 KOH, M/4 NaOH, M/4 NH4OH and M/4 Ca(OH)2, Ca(OH)2 furnishes highest number
of OH– ions  Ca  OH 2  Ca 2  2OH   so pH of M / 4 Ca  OH 2 is highest.
3)on dilution  H    106 M  106 mol
Now dissociation of water cannot be neglected, total  H    106  107  11107
pH   log  H     log 11107   5.98
L
40. 1) Acid and base will neutralise each other. Since volume of NaOH is more (150 mL) in solution.
M V  M1V1 150  0.5  50  0.5 1
 OH    2 2   Now
V1  V2  V3 50  150  300 10
OH   OH    1014   H    1013 ; pH  13
BA

41. 1)Bronsted base is a substance which accepts proton. In option 1), H2O is accepting proton, i.e., acting
as a base.
42. (2) Kwincreases with temperature.
43. 1)

44. (2) The value of ionic product of water changes with the temperature.
45. (4) All the salts undergo hydrolysis in aqueous solution.The acids formed have their strength in the
order:HCl > HCOOH > CH3COOH
The strength of the bases formed follow the order :NaOH > NH4OH.
46. 2) On increasing T, Kw increases and so also  H 3O   and  OH  
1 K al 3.14 104
47. 2)    4 :1
2 K a2 1.96 105

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

 2
 1.34  5
48. 1) K  c 2  0.1    1.8 10
 100 
49. 1)
50. 2) HA  H  A
 H    A  
Ka  ,  H    10 pH   H    105 ; and at equilibrium  H     A  
 HA
105 105
 Ka   2 108
0.0015
Ka 2 108
   4 106  2 103
C 005
Percentage ionization = 0.2
51. 3) Ostwald's dilution law, dilution increases ionisation.
52. 2)  H    C  K a  0.0011.8 104 for formic acid

I
53. 3)
54. 4)
55. 2)Higher the Ksp, more soluble is that compound in H2O.
 K sp of FeS 111020  is highest

56.
So it is more soluble and has maximum solubility in H2O
2) Cr  OH 3  s 

 s  3s 
27s 4  K sp
3
Cr 3  aq   3OH   aq 

 K sp
s
AJ 3s

1/ 4 1/ 4
 K sp   1.6 1030 
s   
L
 27   27 

3) 2HNO3  aq    Ag  NH 3 2   Cl  AgCl  s   2NH 4  2NO3
  
57.
2
58. 1) Ag 2SO 4  2 Ag   SO
x 4 (moles after diss)
BA

2x

K sp   Ag  SO    2x   x  4x 3
 2 2 2
4

Given solubility = x  2.5 102 mole/litre

 K sp  4   2.5 102   4 15.6 106  62.5 106
3

59. (3) Solubility of weak electrolyte decreases in solventhaving common ion. So solubility of AgI in NaI
solutionis less than in pure water because of common ion effect.
60. (2) The dissociation of a weak electrolyte (AgCl) issuppressed on adding the strong electrolyte having a
common ion (Cl–), hence concentration of Ag+ion willbe less.
61. 4) BA 2  B 2A
x 2x

Solubiliity product =  x  2x   4x 3
2

4 1012
4 1012  4x 3 or x  3
4
 x  104
 salt 
62. 4) pH of acidic buffer =  log K a  log 
 acid 
 pH of acidic buffer depends upon value of K a
 salt  8 4
63. 3) At 80% neutralization,   
 base  2 1

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

  pOH  pK b  log
salt 
 base
14-7.4 = pK b  log 4 ; pK b  6.6  0.6 ; K b  10 6
64. 4) pH or  H   of a buffer does not change with dilution.
65. 1) The pOH of a buffer consisting of NH3(i.e. NH4OH)and salt NH4Cl (salt) is given by the equation
pOH  pK b  log  5.0  log
0.1  5.0  log10  5  1  4.0
1.0
pH  pOH  14 ; pH  14  4  10
66. 2) Solubility product is the product of ionic concentration in a saturated solution of an electrolyte at a
giventemperature.
67. 2) K sp   Fe3  . 3OH  
So molar solubility of Fe3  s and 3OH    3s
Fe  OH 3

I
3
Fe  3OH 
s  3s
1.0 1038
1.0 1038  s 3s   s 4  27 ; s 4  s   3.703 1040 
1/ 4
 3.703 1040 ;  1.386 1010
3

27
68.
A; Cl   0, B; Cl    0.1
C; Cl   0.2, D; Cl    0
[soluble compelx is formed [Ag(NH3)2Cl]
AB
s

A B
s

s
AJ
1) The solubility decreases by common ion effect

Hence, solubility product of AB

K sp   A    B  ; S  s s   s  S1/ 2
L
2 10 K sp 1014
70. 1) K sp   M 2  OH   ; OH     0.1  0.01 ; [M 2 ]    1010
0.01
2 2
100 OH 


LEVEL – 2
BA

1. 2) 2. 2)
3.20  22
3. 1) 2HI H2  I2 it is 22% decomposed ;  0.704
100
(3.2–0.704) is equal to HI present at equilibrium which is = 2.496
4. 2)
PM 1 82.1
5. 1) D    2.5gL1 ; d  2.0gL1  given 
RT 0.0821 400
Dd 2.5  2
   0.125  12.5%
d  n  1 2  3  1
6. 4)Equilibrium constant (K) is independent ofconcentrations of reactants and products.
7. 2) NH 2 COONH 4  s  2 N H3  g   C O2  g 
2p p

Kp  P  PCO2   2p   p  3.2 10 5 atm 3  p  2 10 2 atm; p NH3  2  2 10 2 atm

2 2
NH3

8. 3) Initially only A is present so at eqm. B and C should be present in 2 : 1

2A  g  2B  g   C  g 
At eqm. 400mL 200mL 100mL
For ideal gases volume %  mole%

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

 2
 200   100 
 10   10 
Kp       10
700 700
2
 400  28
 10 
 700 
9. (2)
10. (4) When volume is increased the conc. decreases and theequilibrium shifts in the direction where more
moles areformed.
11. (2) Introduction of CO will suppress the dissociation ofCOCl2and concentration of Cl2will decrease.
Thiswill favour the dissociation of PCl5.
12. (3) Since the process of melting is endothermic, increasein temperature will favour melting. Since
 M
density ofsolid is less  D   , the high pressure will reduce Vand increase D, hence favour more
 V
melting.
13. 4)

I
14.
AJ
1)Equilibrium constant is not effected by change inconditions like P and V. These changes can change
only the time required to attain equilibrium.
15. 3) The hydrolysis of C2O24 is as follows
L
K w 1.0 1014 x2
C2O42  H2O HC2O4  H ; K h    ;  x  1.3 106
K 2 6.0 105 0.01
16. 1) The reaction given is an exothermic reaction thus according to Le-chatalier’s principle lowering of
temperature, addition of F2and / or Cl2favour the forward direction and hence the production of ClF3
BA

17. 2)Acidic strength  K a

18. 2) pKa   log K a
Smaller the value of pK a , stronger will be acid
 Acid having pK a value of 10-8 is strongest acid
19. 2) 6   log105  log
salt   5  log salt 
acid  acid 
log
salt  must be 1.  salt   10 or10 :1
acid  acid  1
20. 2) Let volume of HCl required be V mL then volume of NH3  300  VmL

pH  pK a  log
salt  ; 9.26  9.26  log
V
; V  100mL
 base  300  V   V,
21. 4)
22. (3) Since for sparingly soluble salts, solubility will be lessthan one. Therefore as the powers of s
increases inKspexpression, magnitude of Kspwill become smaller.
2)  H 3O  for a solution having pH = 3 is given by  H 3O   1103 moles / litre
 
23.
 H 3O   10 pH 
 

NEET JEE ONLINE CLASSES ANKUR SIR 7983744732

 Similarly for solution having pH = 4,  H3O   1104 moles / litre and for pH  5


 H 3O 

 1105 moles / litre
Let the volume of each solution in mixture be IL, then
total volume of mixture solution L = (1 + 1 + 1) L = 3L
Total  H 3O  ion present in mixture solution = 103  104  105  moles then  H 3O  ion concentration
 

103  104  105 0.00111

of mixture solution  M M = 0.00037M  3.7 104 M
3 3
24. 4) HNO2 is a weak acid and NaNO2 is salt of that weak acid and strong base (NaOH)
2
25. 2) pH  9;  H    109 ; OH    10 5 ;  Mg 2   1103 ;  Mg 2  OH    11013
given Kspof Mg(OH)28.9  10-12which is more than 1 × 10–13. Hence Mg(OH)2will not precipitate
26. 3) Let s = solubility
 
AgIO3 Ag  IO
s 3

I
s

K sp   Ag    IO3   s  s  s 2 Given K sp  110 8

4 4
 s  K sp  1 108  1.0 10 mol / L  1.0 10  283g / L

27.
L 
4)
Molecular mass of AgIO3  283 
AJ 1.0 104  283 100
1000
g /100mL  2.83 10 3 g /100mL
BA

 4  0.3
4
PS4  g 
28. 1) K p  2
  2.96
PS8  g  0.70
29. 3) P C l5  g  P C l3  g   C l 2  g 
1 x x x
Total moles after dissociation 1 x  x  x  1 x
 x 
p PCl3  mole fraction of PCl3  total pressure =  P
 1 x 
wt. of solute per litre of solution
30. 4)As, molarity =
Mol.wt of solute
1000
Molarity of H 2 O   55.55mole / litre
18
c 2
 c 2 ; K a  55.55  1.8 108   1.8 1014
2
H 2O H   OH  Thus, K a 
c1  c c 1 

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