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O Level Chemistry Paper Solving Week 1 (June 2022, V2)

The document is a Cambridge O Level Chemistry worksheet for Paper 1 Multiple Choice, detailing exam instructions, necessary materials, and a series of chemistry questions. It includes information on the exam format, scoring, and specific experimental setups for various chemical reactions. The document serves as a preparatory tool for students taking the exam in June and November series of 2022 and beyond.

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Ashik Ahmed Nayeem

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0% found this document useful (0 votes)

88 views72 pages

O Level Chemistry Paper Solving Week 1 (June 2022, V2)

Uploaded by

Ashik Ahmed Nayeem

We take content rights seriously. If you suspect this is your content, claim it here.

Available Formats

Download as PDF, TXT or read online on Scribd

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Name of Candidate:

Worksheet
Cambridge O Level
Chemistry 5070
Paper solving
s for exams inweek
2023, 20241and
(June
2025. 2022, V2)
Exams are available in the June and November series.

Nayeem Sir, 01581499263

Version 1
Please check the syllabus page at www.cambridgeinternational.org/5070
to see if this syllabus is available in your administrative zone.
Homework: June 2022/P1/V1
Cambridge O Level

CHEMISTRY 5070/12
Paper 1 Multiple Choice May/June 2022
1 hour

You must answer on the multiple choice answer sheet.

*9091136550*

You will need: Multiple choice answer sheet

Soft clean eraser
Soft pencil (type B or HB is recommended)

INSTRUCTIONS
 There are forty questions on this paper. Answer all questions.
 For each question there are four possible answers A, B, C and D. Choose the one you consider correct
and record your choice in soft pencil on the multiple choice answer sheet.
 Follow the instructions on the multiple choice answer sheet.
 Write in soft pencil.
 Write your name, centre number and candidate number on the multiple choice answer sheet in the
spaces provided unless this has been done for you.
 Do not use correction fluid.
 Do not write on any bar codes.
 You may use a calculator.

INFORMATION
 The total mark for this paper is 40.
 Each correct answer will score one mark.
 Any rough working should be done on this question paper.
 The Periodic Table is printed in the question paper.

This document has 16 pages.

IB22 06_5070_12/4RP R
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1 A student investigates the rate of reaction between calcium carbonate and hydrochloric acid.

Investigation of rate of reaction:

Stopwatch is a must to record time

different concentrations of HCl:

Measure different volumes of HCl and water.
Measuring cylinder is needed.

Keep mass of Calcium carbonate constant:

Mass balance is needed.

calcium hydrochloric acid

carbonate

The volume of gas in the syringe is recorded after one minute.

The experiment is repeated using different concentrations of hydrochloric acid.

Which additional pieces of apparatus are essential for the investigation?

1 balance
2 measuring cylinder
3 stop-clock

A 1 and 2 only B 1 and 3 only C 2 and 3 only D 1, 2 and 3

2 Which statement is correct?

A A mixture of liquids with boiling points which differ by 35 C can be separated by distillation.
B Locating agents are needed to identify the colours present in ink.
C The desalination of sea water to produce pure water is achieved by fractional distillation.
D The Rf value of a dye in a chromatogram can be calculated using the formula:

distance moved by solvent

Rf 
distance moved by spot

Locating agent is needed to locate the position of colourless spots in chromatography

Desalination is a type of distillation

Rf value formula is opposite way round

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3 Some reactions of an aqueous solution of compound X are given.

 When a few drops of aqueous sodium hydroxide are added, a white precipitate is
formed. [contains either aluminium, zinc, Magnesium or calcium]

 When dilute nitric acid is added and the mixture is warmed, a gas is formed. The
gas decolourises acidified potassium manganate(VII). A gas produced with KMnO4, is SO2,
this confirms the presence of SO3 ion
 When dilute nitric acid and aqueous barium nitrate are added, no visible reaction
occurs. Barium nitrate or barium chloride forms white precipitate of BaSO4 if SO4 is present.

What can be deduced about the identity of X?

A X contains only aluminium sulfate, Al 2(SO4)3.

B X contains only calcium sulfite, CaSO3.
C X must contain aluminium sulfite, Al 2(SO3)3, or zinc sulfite, ZnSO3.
D X must contain aluminium sulfite, Al 2(SO3)3, calcium sulfite, CaSO3, or zinc sulfite, ZnSO3.

4 Which set of changes to the conditions increases the volume of a gas?

pressure temperature
Pressure and volume are inversely proportional
A decreases increases Pressure is proportional to temperature

B increases decreases
Volume is also proportional to temperature
C increases unchanged
D unchanged decreases

5 Ethylamine gas, C2H5NH2, and hydrogen chloride gas, HCl, react together to form a white solid,
ethylamine hydrochloride.

At which position in the tube would a ring of solid white ethylamine hydrochloride form?

A B C D

cotton wool soaked cotton wool soaked

in ethylamine solution in hydrochloric acid

White solid is formed after gases diffuse and meet. Rate of diffusion is less if RFM of particle is more and vice versa.
Ethylamine has a higher RFM, so it travels short distance and HCl travels longer distance.

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4

6 Element X can be represented by the symbol 14

6 X.

Which statements about an atom of element X are correct?

In a neutral atom,
1 It has 6 electrons. Number of protons = Number of electrons
proton = 6, and so electron = 6

2 It has 8 protons. Mass number or RFM = sum of proton and neutron number
In this case, RFM = 14
3 It is an isotope of carbon. Proton number identifies and element.

4 It is an isotope of nitrogen. Isotopes are atoms of same element but different RFM.

A 1, 2 and 3 B 1 and 2 only C 1 and 3 only D 2 and 4

7 Two isotopes of chlorine are 35Cl and 37Cl.

Using these isotopes and 12C and 1H, how many different relative molecular masses are possible
for the compound with molecular formula C2H3Cl 3?
RFM of chlorine would vary:
So, possibilities are:
A 2 B 3 C 4 D 5 all 3 atoms are Cl-35
or, 2 atoms of Cl-35 and 1 atom of Cl-37
or, 1 atom of Cl-35 and 2 atoms of Cl-37
or, 3 atoms of Cl-37
8 Which row is correct?

elements compounds mixtures

A graphite, iron methane, water air, copper Simple Fact

B graphite, iron sand, water air, brass

C iron, water methane, graphite air, brass
D water, methane air, graphite iron, brass

9 Which statement about ionic compounds is correct?

Ions attract each other by strong electrostatic force of
A They are all solids at room temperature. attraction. This force is very strong and needs a lot of
energy to break. Thus ions are able to move if the attractive
force is broken by heating or dissolving it in water.
B They all conduct electricity at room temperature.
C They are all soluble in water.
D They all have strong intermolecular forces.

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10 A molecule of tetrafluorosilane, SiF4, is shown in the dot-and-cross diagram. Only the outer shell
electrons are shown.

This is a simple molecular covalent

compound as the number of atoms
F can be counted. Such molecules attract
each other by WEAK INTERMOLECULAR
FORCE OF ATTRACTION and thus have
a low melting point.

F Si F

Which statement is correct?

A Each molecule of SiF4 has exactly 16 pairs of electrons.

B In SiF4 both the silicon and the fluorine have the same electronic configuration as neon.
C Molten SiF4 will conduct electricity.
D SiF4 has a low melting point.

11 The table describes two properties associated with metals. In metals, there are layers of positive ions
surrounded by sea of delocalised electrons.
The layers of metals can slide over each other.
Which row shows a correct reason for the stated property? Electrons can move freely due to heat or voltage.

property reason

A malleable the layers of metal anions can slide over each other
B malleable the layers of metal cations can slide over each other
C conduct electricity metallic structures contain mobile anions
D conduct electricity metallic structures contain mobile cations

12 Aqueous silver nitrate, AgNO3, reacts with aqueous potassium chromate(VI), K2CrO4, to give a
yellow precipitate.
Ionic reaction for precipitation contains the ions of precipitate only.

What is the ionic equation for this reaction?

A 2AgNO3(aq) + K2CrO4(aq)  Ag2CrO4(s) + 2KNO3(aq)

B 2Ag+(aq) + 2NO3–(aq) + 2K+(aq) + CrO42–(aq)  Ag2CrO4(s) + 2NO3–(aq) + 2K+(aq)

C 2Ag+(aq) + CrO42–(aq)  Ag2CrO4(s)

D Ag+(aq) + CrO4–(aq)  AgCrO4(s)

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6

13 What is the relative formula mass of anhydrous sodium carbonate? Add the atomic masses of atoms.

A 51 B 83 C 106 D 124

14 What contains the greatest mass of solute?

Greatest mass must has the greatest mole.
A 100 cm3 of 1.00 mol / dm3 sodium hydroxide, NaOH For complete analysis, find moles of each of
them and multiply them by their RFM.
3 3
B 500 cm of 0.05 mol / dm sulfuric acid, H2SO4
C 1.00 dm3 of 0.10 mol / dm3 potassium hydroxide, KOH
D 2.00 dm3 of 0.01 mol / dm3 hydrochloric acid, HCl

15 How many tonnes of aluminium oxide, Al 2O3, are required to produce 27 tonnes of aluminium?

A 27 B 51 C 54 D 102 Simple mol calculation

16 Dilute sulfuric acid is electrolysed. Hydrogen gas and oxygen gas are produced.
Dilute sulfuric acid has:
Which row correctly describes what happens? H+ ions, SO4 (2-) ions and OH(-) ions.
OH(-) goes to anode and H+ goes to cathode.

oxygen produced at the hydrogen produced at the concentration of acid

A anode cathode decreases

B anode cathode increases
C cathode anode decreases
D cathode anode increases

17 Aluminium can be extracted by the electrolysis of aluminium oxide dissolved in molten cryolite.

Which reactions take place during the electrolysis?

Al (3+) goes to cathode,
O (2-) goes to anode.
reaction at the anode reaction at the cathode

A Al + + e–  Al O2– + 2e–  O
B Al 3+ + 3e–  Al 2O2– + 4e–  O2
C O2– – 2e–  O 3Al + + 3e–  3Al
D 2O2– – 4e–  O2 Al 3+ + 3e–  Al

18 Which reaction is exothermic?

A combustion of methane (release energy)

B cracking of hydrocarbons (needs energy to break alkane)

C decomposition of water into hydrogen and oxygen by electrolysis (needs energy to break water)

D photosynthesis in plants (light energy is absorbed)

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19 What is the correct balanced equation and enthalpy change, H, for the complete combustion of
butanol, C4H9OH? All combustion reactions release heat energy and so are exothermic.

A C4H9OH(l) + 5O2(g)  4CO2(g) + 5H2O(g) H = –2676 kJ / mol

B C4H9OH(l) + 5O2(g)  4CO2(g) + 5H2O(g) H = +2676 kJ / mol

C C4H9OH(l) + 6O2(g)  4CO2(g) + 5H2O(g) H = –2676 kJ / mol

D C4H9OH(l) + 6O2(g)  4CO2(g) + 5H2O(g) H = +2676 kJ / mol

20 Bromate, bromide and hydrogen ions react according to the equation shown.

BrO3–(aq) + 5Br –(aq) + 6H+(aq)  3Br2(aq) + 3H2O(l)

Some apparatus for measuring how the rate of this reaction varies over time is suggested.

1 gas syringe
2 balance concentration / amount of H+ ions decreases with time.
amount of H+ or OH- can be monitored by pH meter.

3 pH meter

Which apparatus is suitable to measure the rate of this reaction?

A 1 and 2 B 1 only C 2 and 3 D 3 only

21 25 cm3 of 1.0 mol / dm3 hydrochloric acid reacts with 10 g of a solid to produce a gas. The solid is
in excess. The graph labelled first experiment shows the volume of gas produced over time.
Graphs P and Q show the volume of gas produced under different conditions.

Graphical analysis: P
Rate of reaction = Gradient or steepness

Final amount of product or reactant

= Levelling off of the graph. first experiment
volume of
gas / cm3

0
0 time / s

Which changes in conditions produce graphs P and Q, if all other conditions are kept the same?

A P uses a catalyst and Q has a lower temperature.

B P uses 25 cm3 of more concentrated acid and Q uses smaller pieces of solid.
C P uses a higher temperature and Q uses 25 cm3 of more dilute acid.
D P uses smaller pieces of solid and Q uses larger pieces of solid.

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8

22 Nitrogen dioxide, NO2, is a dark brown gas that decomposes as shown in the equation.

2NO2(g) 2NO(g) + O2(g)

dark brown colourless

The diagram shows a glass flask containing a mixture of the three gases. The mixture is pale
brown.

inlet for gas

NO2, NO, O2
mixture

More oxygen is forced into the flask.

Increasing concentration shifts the equilibrium away
so that its concentration would decrease.
Which colour change is seen in the mixture? Increasing amount of oxygen would shift the equilibrium
position to the left so that amount of NO2 would increase
and the mixture becomes dark brown.
A It becomes a darker brown.
B It becomes a paler brown.
C It turns colourless.
D There is no change.

23 What is an observation of an oxidation process? Some oxidation reactions:

Electrolysis, electroplating, displacements,
A blue copper sulfate crystals turning to white powder when heated
B copper being deposited on the cathode during electrolysis
C green gas being produced at the anode when sodium chloride is electrolysed
D white precipitate forming when aqueous silver ions react with aqueous chloride ions

24 An excess of aqueous iodide ions is added to acidified aqueous potassium manganate(VII).

Which row is correct?

colour of
iodide ions
final solution potassium manganate (VII) is an oxidising agent.
So it would oxidise I- to I2 (red/brown/orange).
This is an oxidation reaction as oxidation number of
A oxidised colourless iodine is increasing.

B oxidised brown
C reduced colourless
D reduced brown

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25 When ammonia gas is dissolved in water a reversible reaction takes place.

NH3(g) + H2O(l) NH4+(aq) + OH–(aq)

Which statements are correct? Follow the first two lines of the explanation of Question 22.

1 Ammonia is an alkali because it produces hydroxide ions in solution.

2 The pH of this solution is 7. (This is not true as solution contains OH-. So pH is more than 7)

3 Adding hydroxide ions to the mixture at equilibrium produces more ammonia.

A 1, 2 and 3 B 1 and 3 only C 1 only D 2 and 3 only

26 Three dilute solutions of acid, each with a concentration of 0.01 mol / dm3, are reacted separately
with excess calcium carbonate until there is no further reaction. The same volume of acid is used
each time.

The carbon dioxide produced is collected and its volume measured. All measurements are
at room temperature and pressure.

volume of carbon
acid pH dioxide formed Acid 3 is a weak acid. Organic acids are
/ cm3 weak acids (-anoic acids/carboxylic acids).
So, it has high pH but still <7
Sulfuric acid is one of the strongest
1 2.0 20 laboratory acids. So it must have a lowest
pH.
2 1.7 40
3 3.4 20

What are the possible identities of the acids?

acid 1 acid 2 acid 3

A hydrochloric sulfuric ethanoic

B hydrochloric nitric ethanoic
C nitric sulfuric hydrochloric
D sulfuric hydrochloric nitric

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10

27 The steps for the preparation of a pure sample of sodium nitrate are listed.

1 Titrate with dilute nitric acid until the end-point is seen.

2 Evaporate to concentrate the solution.
3 Rinse out the conical flask.
Simple experimental Fact
4 Add indicator.
5 Pipette a known volume of aqueous sodium hydroxide into a conical flask.
6 Cool and filter to remove crystals.
7 Repeat using the same volumes of aqueous sodium hydroxide and dilute nitric acid
but no indicator.

Which order of steps is correct?

A 1754263

B 3571246

C 4135267

D 5413726

28 A white compound is insoluble in water. Any compound with

> group 1 metal
Which cations and anions could be present in the compound? >ammonium (NH4)
> nitrate (NO3)
are entirely soluble. They have nothing insoluble.

sodium calcium carbonate nitrate

A key
B = present
C = absent
D

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29 The flow chart describes the preparation of ammonium sulfate.

air element 1 element 2 air

Haber Contact
element 3 element 4
process process

From air, we can obtain:

N2 and O2 through fractional distillation.
ammonium sulfate Haber process makes NH3 (ammonia).
Contact process makes H2SO4
Ammonia being basic and H2SO4 being
What are elements 1– 4? acidic, makes ammonium sulfate (salt)

1 2 3 4

A nitrogen oxygen hydrogen sulfur

B nitrogen oxygen hydrogen oxygen
C oxygen nitrogen hydrogen sulfur
D oxygen nitrogen sulfur hydrogen

30 Which row correctly shows the possible uses of sulfur dioxide and sulfuric acid?

sulfur dioxide sulfuric acid

Simple fact.
A as a bleach as battery acid SO2 is used as food preservative
(kill food microbes)
B killing bacteria in food as a bleach H2SO4 is used for cleaning,
battery making and fertilisers.
C making detergents as battery acid
D making fertilisers making fertilisers

From left to right of periodic table:

31 Selenium is in Group VI and gallium is in Group III. Metallic character decrease
Non-metallic character increase.
Which prediction can be made from this information? Shell number = period numebr
Number of valence shell electrons = group number
A A gallium atom has three more protons than a selenium atom.
B Gallium is more likely to form negative ions than selenium.
C Selenium atoms have fewer valence electrons than gallium atoms.
D Selenium has more non-metallic character than gallium.

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12

32 Which statement about some metals and their compounds is correct? A more reactive metal:
>Reacts faster with more vigour.
>Form compounds that decomposes
A Calcium reacts with cold water but not with steam. at higher temperatures.

B Lead carbonate decomposes at a higher temperature than zinc carbonate.

C Magnesium can be extracted from its oxide by heating strongly with carbon.
D Pure aluminium reacts with cold, dilute hydrochloric acid.

33 The diagram shows an experiment to determine the percentage of oxygen in air.

bell jar

Burning consumes the amount of

lit candle oxygen in air. So only 20% of the
volume of air would decrease.

water

Which diagram shows the correct level of water after the candle stops burning?

A B C D

34 The addition reaction between a hydrocarbon X and bromine forms only one product.
Alkenes carry out addition reaction. Straight alkenes have general formula CnH2n
Which compound is X?

A CH4 B C2H4 C C2H6 D CH3OH

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35 A series of reactions producing propanol from the naphtha fraction of petroleum (crude oil) is
shown.

H H H H OH H
X Y
naphtha H C C C H C C C H

H H H H H

What are processes X and Y? Alkenes can be obtained by cracking alkanes.

Alkene adds steam (H2O) to form alcohol.

X Y

A cracking reaction with steam

B cracking fermentation
C fractional distillation reaction with steam
D fractional distillation fermentation

36 The structures of four alcohols are shown.

1 2 3 4
H H H H H H H H H H

H C H H C C H H C C C H H C C C C H

OH H OH H OH H H H H OH

Which statement is correct?

A Alcohol 1 can be made by the addition of steam to an alkene.

B Alcohol 2 can be made from glucose. Alkenes have at least two carbon atoms. So
we can form an alcohol with 2C atoms or more.
C Alcohol 3 is a renewable energy source. Ethanol (2C alcohol), can also be made by
fermentation of glucose.
D Alcohol 4 has only one other isomer. A 4C alcohol has more than two isomers.

37 Which compounds have the molecular formula C3H6O2?

1 methyl ethanoate Ethanoate (CH3COO), Methanoate (HCOO)

methyl (CH3), Ethyl (C2H5)
Propanoic acid (CH3COOH)
2 ethyl methanoate
3 propanoic acid

A 1 and 2 only B 1 and 3 only C 2 and 3 only D 1, 2 and 3

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14

38 An organic compound has the empirical formula CH2O.

Which row shows a possible correct name and structure for this compound?

name structure

Determine molecular formula

and find empirical formula.
A methanol Empirical formula is the simplest mathematical
whole number ratio.

B methanoic acid

C ethanol

D ethanoic acid

39 Which statement is correct? Polyamides or polypeptides (CO-NH linkage): Protein, Nylon,

Polyesters (COO linkage): Starch, Terylene, PET

A Complex carbohydrates, such as starch, are hydrolysed to give simple sugars.

B Fats have the same amide linkages as Terylene.
C Proteins and nylon are polymers formed from the same monomers but with different
linkages.
D Proteins are natural polymers and are also called polysaccharides.

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40 The repeat unit of a polymer is shown.

CH3 Cl

C C
Monomer of an addition polymer has the repeating
H Br unit with a double bond between C atoms.

Which monomer would produce this polymer?

A B C D
H Cl CH3 H CH3 H Cl CH3

C C C C C C C C

CH3 Br Cl Br Br Cl H Br

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.

To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge
Assessment International Education Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download
at www.cambridgeinternational.org after the live examination series.

Cambridge Assessment International Education is part of Cambridge Assessment. Cambridge Assessment is the brand name of the University of Cambridge
Local Examinations Syndicate (UCLES), which is a department of the University of Cambridge.

© UCLES 2022 5070/12/M/J/22

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The Periodic Table of Elements
Group

Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
7 9 relative atomic mass 11 12 14 16 19 20
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
16

85 88 89 91 93 96 – 101 103 106 108 112 115 119 122 128 127 131
55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86

5070/12/M/J/22
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
133 137 178 181 184 186 190 192 195 197 201 204 207 209 – – –
87 88 89–103 104 105 106 107 108 109 110 111 112 114 116
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium
– – – – – – – – – – – – –

57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139 140 141 144 – 150 152 157 159 163 165 167 169 173 175
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232 231 238 – – – – – – – – – – –

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).

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Cambridge O Level

CHEMISTRY 5070/12
Paper 1 Multiple Choice May/June 2022
MARK SCHEME
Maximum Mark: 40

Published

This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of the
examination.

Mark schemes should be read in conjunction with the question paper and the Principal Examiner Report for
Teachers.

Cambridge International will not enter into discussions about these mark schemes.

Cambridge International is publishing the mark schemes for the May/June 2022 series for most
Cambridge IGCSE, Cambridge International A and AS Level and Cambridge Pre-U components, and some
Cambridge O Level components.

This document consists of 3 printed pages.

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5070/12 Cambridge O Level – Mark Scheme May/June 2022
PUBLISHED

Question Answer Marks

1 D 1

2 A 1

3 D 1

4 A 1

5 A 1

6 C 1

7 C 1

8 B 1

9 A 1

10 D 1

11 B 1

12 C 1

13 C 1

14 C 1

15 B 1

16 B 1

17 D 1

18 A 1

19 C 1

20 D 1

21 C 1

22 A 1

23 C 1

24 B 1

25 B 1

26 A 1

27 D 1

28 C 1

© UCLES 2022 Page 2 of 3

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5070/12 Cambridge O Level – Mark Scheme May/June 2022
PUBLISHED

Question Answer Marks

29 A 1

30 A 1

31 D 1

32 D 1

33 C 1

34 B 1

35 A 1

36 B 1

37 D 1

38 D 1

39 A 1

40 A 1

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Cambridge O Level
* 0 1 1 8 9 9 5 4 0 5 *

CHEMISTRY 5070/22
Paper 2 Theory May/June 2022

1 hour 30 minutes

You must answer on the question paper.

No additional materials are needed.

INSTRUCTIONS
● Section A: answer all questions.
● Section B: answer three questions.
● Use a black or dark blue pen. You may use an HB pencil for any diagrams or graphs.
● Write your name, centre number and candidate number in the boxes at the top of the page.
● Write your answer to each question in the space provided.
● Do not use an erasable pen or correction fluid.
● Do not write on any bar codes.
● You may use a calculator.
● You should show all your working and use appropriate units.

INFORMATION
● The total mark for this paper is 75.
● The number of marks for each question or part question is shown in brackets [ ].
● The Periodic Table is printed in the question paper.

This document has 20 pages. Any blank pages are indicated.

DC (RW/CGW) 303624/2
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BLANK PAGE

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Section A

Answer all the questions in this section in the spaces provided.

The total mark for this section is 45.

1 Choose from the following compounds to answer the questions.

**All silver salts except AgNO3 are insoluble. **Can form BaSO4 which is a white precipitate
Thus AgCl is insoluble and has to be formed
by precipitation reaction. AgCl formation AgCl
also identifies presence of Cl- **Used to identify oxidising agents.
Ba(NO3)2 This itself is a reducing agent.
It colour shifts between colourless and brown/Red.
Contains SO3, Follow explanation of KI
MCQ no. 3
KMnO4 ** It is used to identify reducing agent.
** Has NO3 This itself is an oxidising agent.
Would react with Aluminium foil and Its colour changes from purple to colourless.
sodium hydroxide followed by heating to K2SO3 It also has iodide ion that can be identified
produce NH3 (gas that turns damp red by forming AgI which is a pale white ppt.
litmus paper blue) Mg(NO3)2
Na2CO3
Has NH4, NH4 reacts with alkalis to from NH3 Has CO3 (2-) that can react with acids to form
(gas that turns damp red litmus paper blue) CO2 gas and CO2 gas turns limewater milky.
Na3N This strategy also identifies presence of CO3.

NH4Cl Has Zn ion. Adding NaOH until it is excess would

first produce white ppt and then it would dissolve.
ZnSO4 Same is the observation for Al ions.

Each compound may be used once, more than once or not at all.

State which compound:

(a) is purple in colour

............................................................................................................................................. [1]

(b) reacts with aqueous sodium sulfate to form a white precipitate

............................................................................................................................................. [1]

(c) reacts with aqueous chlorine to give a brown solution

............................................................................................................................................. [1]

(d) is prepared using a precipitation reaction

............................................................................................................................................. [1]

(e) contains an anion with a charge of –3

............................................................................................................................................. [1]

(f) is used to test for a reducing agent.

............................................................................................................................................. [1]

[Total: 6]

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4

2 The table shows some information about elements in Group VI.

electronic melting point density in

element
configuration / °C g / cm3
oxygen 2, 6 –218 0.0013

sulfur 113 2.1

selenium 2, 8, 18, 6 217 4.8

tellurium 2, 8, 18, 18, 6 450 6.3

polonium 2, 8, 18, 32, 18, 6 254

(a) State the electronic configuration for sulfur.

............................................................................................................................................. [1]

(b) Predict the density of polonium.

............................................... g / cm3 [1]

(c) Sulfur has a boiling point of 445 °C.

Temperature between MP and BP gives liquid state

Predict the physical state of sulfur at 200 °C. Temperature below MP gives solid state

Temperature above boiling point gives gaseous state

Explain your answer.

physical state ............................................................................................................................

explanation ...............................................................................................................................

...................................................................................................................................................
[1]

(d) Oxygen exists as a diatomic molecule, O2.

(i) Draw the dot-and-cross diagram for a molecule of oxygen.

Show only the outer shell electrons.

[1]

(ii) Explain, in terms of structure and bonding, why oxygen has a low melting point.
Follow explanation of MCQ 10
...........................................................................................................................................

..................................................................................................................................... [1]

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(e) Selenium, Se, is a non-metal.

(i) Deduce the formula of selenium(IV) oxide.

..................................................................................................................................... [1]

(ii) A small sample of selenium(IV) oxide is dissolved in water.

Two drops of universal indicator are added to this aqueous solution.

Predict the colour of the universal indicator in this solution.

Non-metal oxides are acidic in nature.
Explain your answer.

colour ................................................................................................................................

explanation ........................................................................................................................

...........................................................................................................................................
[1]

(f) Calculate the volume, in dm3, of 30.2 g of oxygen at room temperature and pressure.

Give your answer to two significant figures.

Use:
mass/RFM = V/24

volume .................................................. dm3 [3]

[Total: 10]

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6

3 The diagram shows some reactions of butanoic acid.

gas A and salt B salt B, gas C and liquid D

Mg MgCO3

H H H O MA=SH
(Metal + acid = Salt + H2 gas)
H C C C C Metal carbonate + acid
= Carbondioxide + water + salt

H H H O H Carboxylic acid + alcohol

= Ester + water

heat with
ethanol

liquid D and organic liquid E

(a) A, B, C and D are different substances.

Identify by name A, B, C and D.

A ...............................................................................................................................................

B ...............................................................................................................................................

C ...............................................................................................................................................

D ...............................................................................................................................................
[4]

(b) Name and draw the structure of E.

name .........................................................................................................................................
Alcohol gives alkyl (ethanol gives ethyl),
structure Carboxylic acid (-anoic acid) gives anoate
(butanoic acid gives butanoate)

So the ester is ethyl butanoate

Reaction: Remove OH from acid, and H from

alcohol, combine the rest to form ester.

[2]

State what is meant by the term weak in weak acid.

...................................................................................................................................................

............................................................................................................................................. [1]

[Total: 7]
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4 The table shows information about some particles.

number of
particle
protons neutrons electrons
79 Br 35 44 35
35
79 Br – 35 44
35
40 Ca 20 20 20
20
40 Ca2+ 20 20 18
20

(a) State the nucleon number for 79

35 Br.

............................... [1]

35 Br .
(b) State the number of electrons in 79 –

............................... [1]

(c) 40 Ca is the full symbol for one isotope of calcium.

Write the full symbol for one other isotope of calcium.

............................................................................................................................................. [1]

(d) Describe how a calcium ion, Ca2+, is formed from a calcium atom, Ca.

...................................................................................................................................................

............................................................................................................................................. [1]

(e) Calcium bromide is an ionic compound. Follow explanation of MCQ 9.

Calcium bromide conducts electricity when molten but not when solid.

(i) Explain why calcium bromide conducts electricity when molten but not when solid.

...........................................................................................................................................

..................................................................................................................................... [2]

(ii) Predict two other physical properties of calcium bromide.

1. .......................................................................................................................................

2. .......................................................................................................................................
[2]

[Total: 8]

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8

5 Ethanol is manufactured by the reaction between ethene and steam.

The conditions used are 300 °C, a high pressure and a phosphoric acid catalyst.
Exothermic reaction increases temperature
(a) The reaction between ethene and steam is reversible. of mixture
Endothermic reaction decreases temperature
of mixture.
The forward reaction is exothermic. Equilibrium shifts to reverse the change imposed.

C2H4(g) + H2O(g) C2H5OH(g)

An equilibrium mixture is formed when the reversible reaction happens in a closed system.

(i) Predict what happens to the amount of ethanol in the equilibrium mixture if the
temperature is decreased and the pressure remains constant.

Explain your answer.

prediction ...........................................................................................................................

explanation ........................................................................................................................

...........................................................................................................................................

...........................................................................................................................................
[2]

(ii) Predict what happens to the amount of ethanol in the equilibrium mixture if the pressure
is decreased and the temperature remains constant.
Gas molecules exert pressure. More the gas
molecules, more is the gas pressure and vice
Explain your answer. versa.
Equilibrium shifts to reverse the change imposed.

prediction ...........................................................................................................................

explanation ........................................................................................................................

...........................................................................................................................................

...........................................................................................................................................
[2]

(b) Describe the manufacture of aqueous ethanol by the fermentation of glucose. This has to be
memorised. Also see
MCQ no. 36
Include the equation and the essential conditions needed for this fermentation.

...................................................................................................................................................

............................................................................................................................................. [3]

[Total: 7]

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6 A sample of an alloy containing aluminium and copper is added to hot dilute sulfuric acid.

Only the aluminium reacts with the dilute sulfuric acid. The products of the reaction are hydrogen
and aqueous aluminium sulfate.

(a) Construct the ionic equation, with state symbols, for the reaction of aluminium with dilute
sulfuric acid.

............................................................................................................................................. [2]
Adding NaOH until it is excess would
first produce white ppt and then it would dissolve.
(b) Describe a chemical test for aluminium ions. Same is the observation for Al ions. (from question 1).
However, ppt of Al does not dissolve in aqueous NH3
but Zn does
...................................................................................................................................................

...................................................................................................................................................

............................................................................................................................................. [2]

The relative formula mass of hydrated aluminium sulfate is 666.

Calculate the value of x in the formula Al 2(SO4)3•xH2O.

Simple RFM equation.

x = ......................................................... [2]

(d) State what is meant by the term alloy.

...................................................................................................................................................

............................................................................................................................................. [1]

[Total: 7]

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10

Section B

Answer three questions from this section in the spaces provided.

The total mark for this section is 30.

7 Carbon dioxide and sulfur dioxide are pollutants formed at power stations that burn fossil fuels
such as coal.

(a) State one environmental problem caused by producing carbon dioxide as an atmospheric
pollutant.
Remember that
Non-metallic
(covalent) ............................................................................................................................................. [1]
oxides are
acidic in
nature (b) State one environmental problem caused by producing sulfur dioxide as an atmospheric
pollutant.

............................................................................................................................................. [1]

In flue gas desulfurisation, sulfur dioxide reacts with calcium carbonate.

CaCO3(s) + SO2(g) CaSO3(s) + CO2(g) Rate of reaction would be faster

if collision rate is higher.

The reaction needs to be fast to remove as much sulfur dioxide as possible.

(i) Explain, using ideas about particles, why the calcium carbonate needs to be a powder
instead of a single solid lump. Powders have a larger exposed surface
area compared to lumps.
...........................................................................................................................................

...........................................................................................................................................

..................................................................................................................................... [2]

(ii) Explain, using ideas about particles, why decreasing the temperature decreases the rate
of the reaction between calcium carbonate and sulfur dioxide. Particles move slowly meaning that
there will be less number of collisions
...........................................................................................................................................

...........................................................................................................................................

..................................................................................................................................... [2]

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(d) Sulfur dioxide reacts with oxygen as shown.

Use concept of oxidation numbers.
Overall charge = sum of oxidation numbers.
2SO2 + O2 2SO3 Find oxidation numbers of S in both SO2 and
SO3. Observe that oxidation numbers of S
has increased.
(i) Explain why sulfur dioxide is oxidised in this reaction. You may also use the fact that S has gained
oxygen.
...........................................................................................................................................

..................................................................................................................................... [1]

(ii) Explain, using ideas about bond breaking and bond forming, why the reaction is
exothermic. Bond breaking occurs after absorbing energy and bond formation while energy is released.

...........................................................................................................................................

..................................................................................................................................... [2]

(iii) Explain why the addition of a catalyst increases the rate of this reaction.
Catalyst weakens the bonds
...........................................................................................................................................

..................................................................................................................................... [1]

[Total: 10]

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12
A more reactive metal has greater power to lose
8 Zinc is a metal. electrons. Zn being more reactive than iron, provides
electrons to Fe and so Fe retains its metallic bonding and
Zn loses its own metallic bonding.
(a) Coating iron with zinc prevents iron from rusting.

Explain how a coating of zinc prevents iron from rusting when the coating is scratched.

...................................................................................................................................................

............................................................................................................................................. [2]

(b) Zinc has metallic bonding.

(i) Describe, with the aid of a labelled diagram, the metallic bonding in solid zinc.

...........................................................................................................................................

...........................................................................................................................................
[2]

(ii) Explain why zinc is a good conductor of electricity.

...........................................................................................................................................

..................................................................................................................................... [1]

(c) One of the stages in the extraction of zinc involves electrolysis.

At the cathode, zinc ions, Zn2+, are changed into zinc atoms.

At the anode, hydroxide ions, OH–, are changed into oxygen molecules and water molecules.

Write the ionic equations for the reactions at the cathode and at the anode.

cathode .....................................................................................................................................

anode ........................................................................................................................................
[2]
Equation for OH - ion: 4OH(-) - 4e(-) = O2 + 2H2O

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(d) A sample of 2.34 g of zinc is reacted with 50.0 cm3 of 2.00 mol / dm3 hydrochloric acid.

Zn(s) + 2HCl (aq) ZnCl 2(aq) + H2(g)

Show by calculation that the hydrochloric acid is in excess in this reaction.

Simple mole calculation:

Calculate the volume of HCl needed for this reaction and compare with the given volume of HCl.

[3]

[Total: 10]

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14

9 Alkanes are a homologous series of saturated hydrocarbons.

(a) Draw the structures of two different alkanes with the molecular formula C4H10.

Show all of the atoms and all of the bonds in each structure.

[2]

(b) State, using the general formula of alkanes, the molecular formula of an alkane which has
only 12 carbon atoms in its molecule. Straight alkane general formula: CnH2n+2

............................................................................................................................................. [1]

(c) Many alkanes are separated from petroleum (crude oil) by fractional distillation.
Vapourised oil is allowed to condense as it
rises up. HigH RFM gas loses KE faster.
Describe the fractional distillation of petroleum (crude oil). Low RFM gas loses KE slowly.

...................................................................................................................................................

............................................................................................................................................. [3]

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(d) Butane, C4H10, reacts with chlorine to give several products. To provide activation energy (break bonds)
in these reactions, UV light is needed.

(i) State the condition needed for this substitution reaction.

..................................................................................................................................... [1]

(ii) One of these products contains 37.8% carbon by mass, 6.30% hydrogen by mass and
55.9% chlorine by mass.

Calculate the empirical formula of the product.

Deduce the molecular formula of the product.

Considering the percentages as masses, find moles of all atoms. Then divide all the moles by the
smallest mole number among them. This gives empirical formula.

Now multiply (RFM of MF)/(RFM of EF) with EF to find MF.

empirical formula ...............................................................

molecular formula ...............................................................

[3]

[Total: 10]

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16

10 Nitric acid, HNO3, is used to make fertilisers.

(a) Nitric acid is manufactured from ammonia.

In the first step, ammonia reacts with oxygen.

Balance this equation.

............ NH3 + ............ O2 ............ NO + ............ H2O [1]

(b) Nitric acid is used to make the soluble salt potassium nitrate, KNO3. Metal part is obtained from
base or alkali
(i) Name the alkali that reacts with dilute nitric acid to make potassium nitrate.

..................................................................................................................................... [1]

(ii) Describe the experimental procedure used to make colourless aqueous potassium
nitrate from the alkali and dilute nitric acid. All group I salts must be formed by titration because
their bases are soluble.
...........................................................................................................................................

...........................................................................................................................................

..................................................................................................................................... [2]

(iii) Calculate the percentage by mass of nitrogen in potassium nitrate.

Total RAM of concerned atom

x 100%
Total RFM of the molecule

percentage = ......................................................... [2]

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(i) Name one other pollutant found in river water.

..................................................................................................................................... [1]

(ii) State three processes used in the purification of river water to produce drinking water.

...........................................................................................................................................

..................................................................................................................................... [3]

Sedimentation: to remove large insoluble particles [Total: 10]

Add settling agent (Aluminium Sulfate): to clump smaller particles and then filter.
Pass over charcoal: to remove taste and odours.
Add chlorine: to kill microbes.

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The Periodic Table of Elements
Group

H He
hydrogen helium
Key 1 4
3 4 atomic number 5 6 7 8 9 10

Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
7 9 relative atomic mass 11 12 14 16 19 20
11 12 13 14 15 16 17 18

Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36

K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54

Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
20

85 88 89 91 93 96 – 101 103 106 108 112 115 119 122 128 127 131
55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86

5070/22/M/J/22
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
133 137 178 181 184 186 190 192 195 197 201 204 207 209 – – –
87 88 89–103 104 105 106 107 108 109 110 111 112 114 116
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium
– – – – – – – – – – – – –

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).

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Cambridge O Level

CHEMISTRY 5070/22
Paper 2 Theory May/June 2022
MARK SCHEME
Maximum Mark: 40

Published

This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of the
examination. It shows the basis on which Examiners were instructed to award marks. It does not indicate the
details of the discussions that took place at an Examiners’ meeting before marking began, which would have
considered the acceptability of alternative answers.

Mark schemes should be read in conjunction with the question paper and the Principal Examiner Report for
Teachers.

Cambridge International will not enter into discussions about these mark schemes.

This document consists of 12 printed pages.

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5070/22 Cambridge O Level – Mark Scheme May/June 2022
PUBLISHED
Generic Marking Principles

These general marking principles must be applied by all examiners when marking candidate answers. They should be applied alongside the
specific content of the mark scheme or generic level descriptors for a question. Each question paper and mark scheme will also comply with these
marking principles.

GENERIC MARKING PRINCIPLE 1:

Marks must be awarded in line with:

 the specific content of the mark scheme or the generic level descriptors for the question
 the specific skills defined in the mark scheme or in the generic level descriptors for the question
 the standard of response required by a candidate as exemplified by the standardisation scripts.

GENERIC MARKING PRINCIPLE 2:

Marks awarded are always whole marks (not half marks, or other fractions).

GENERIC MARKING PRINCIPLE 3:

Marks must be awarded positively:

 marks are awarded for correct/valid answers, as defined in the mark scheme. However, credit is given for valid answers which go beyond the
scope of the syllabus and mark scheme, referring to your Team Leader as appropriate
 marks are awarded when candidates clearly demonstrate what they know and can do
 marks are not deducted for errors
 marks are not deducted for omissions
 answers should only be judged on the quality of spelling, punctuation and grammar when these features are specifically assessed by the
question as indicated by the mark scheme. The meaning, however, should be unambiguous.

GENERIC MARKING PRINCIPLE 4:

Rules must be applied consistently, e.g. in situations where candidates have not followed instructions or in the application of generic level
descriptors.

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5070/22 Cambridge O Level – Mark Scheme May/June 2022
PUBLISHED
GENERIC MARKING PRINCIPLE 5:

Marks should be awarded using the full range of marks defined in the mark scheme for the question (however; the use of the full mark range may
be limited according to the quality of the candidate responses seen).

GENERIC MARKING PRINCIPLE 6:

Marks awarded are based solely on the requirements as defined in the mark scheme. Marks should not be awarded with grade thresholds or
grade descriptors in mind.

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5070/22 Cambridge O Level – Mark Scheme May/June 2022
PUBLISHED
Science-Specific Marking Principles

1 Examiners should consider the context and scientific use of any keywords when awarding marks. Although keywords may be present, marks
should not be awarded if the keywords are used incorrectly.

2 The examiner should not choose between contradictory statements given in the same question part, and credit should not be awarded for any
correct statement that is contradicted within the same question part. Wrong science that is irrelevant to the question should be ignored.

3 Although spellings do not have to be correct, spellings of syllabus terms must allow for clear and unambiguous separation from other syllabus
terms with which they may be confused (e.g. ethane / ethene, glucagon / glycogen, refraction / reflection).

4 The error carried forward (ecf) principle should be applied, where appropriate. If an incorrect answer is subsequently used in a scientifically
correct way, the candidate should be awarded these subsequent marking points. Further guidance will be included in the mark scheme where
necessary and any exceptions to this general principle will be noted.

5 ‘List rule’ guidance

For questions that require n responses (e.g. State two reasons …):

 The response should be read as continuous prose, even when numbered answer spaces are provided.
 Any response marked ignore in the mark scheme should not count towards n.
 Incorrect responses should not be awarded credit but will still count towards n.
 Read the entire response to check for any responses that contradict those that would otherwise be credited. Credit should not be
awarded for any responses that are contradicted within the rest of the response. Where two responses contradict one another, this
should be treated as a single incorrect response.
 Non-contradictory responses after the first n responses may be ignored even if they include incorrect science.

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5070/22 Cambridge O Level – Mark Scheme May/June 2022
PUBLISHED
6 Calculation specific guidance

Correct answers to calculations should be given full credit even if there is no working or incorrect working, unless the question states ‘show
your working’.

For questions in which the number of significant figures required is not stated, credit should be awarded for correct answers when rounded by
the examiner to the number of significant figures given in the mark scheme. This may not apply to measured values.

For answers given in standard form (e.g. a  10n) in which the convention of restricting the value of the coefficient (a) to a value between 1
and 10 is not followed, credit may still be awarded if the answer can be converted to the answer given in the mark scheme.

Unless a separate mark is given for a unit, a missing or incorrect unit will normally mean that the final calculation mark is not awarded.
Exceptions to this general principle will be noted in the mark scheme.

7 Guidance for chemical equations

Multiples / fractions of coefficients used in chemical equations are acceptable unless stated otherwise in the mark scheme.

State symbols given in an equation should be ignored unless asked for in the question or stated otherwise in the mark scheme.

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5070/22 Cambridge O Level – Mark Scheme May/June 2022
PUBLISHED
Question Answer Marks

1(a) KMnO4 1

1(b) Ba(NO3)2 1

1(c) KI 1

1(d) AgCl 1

1(e) Na3N 1

1(f) KMnO4 1

Question Answer Marks

2(a) 2, 8, 6 1

2(b) any value between 6.8 to 9.4 inclusive (g / cm3) 1

2(c) liquid 1
because
melting point is below 200 °C and boiling point is above 200 °C / 200 °C is between the melting point and the boiling point

2(d)(i) correct dot-and-cross diagram 1

2(d)(ii) weak intermolecular forces / intermolecular forces are easy to break or overcome 1

2(e)(i) SeO2 / O2Se 1

2(e)(ii) red / orange / yellow / yellow-green 1

because
non-metal oxides (are acidic)

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5070/22 Cambridge O Level – Mark Scheme May/June 2022
PUBLISHED
Question Answer Marks

2(f) moles of oxygen = 0.94375 OR 30.2 / 32 (1) 3

volume = 0.94375  24 OR 22.65 (1)

volume = 23 (dm3) (1)

Question Answer Marks

3(a) A hydrogen (1) 4

B magnesium butanoate (1)

C carbon dioxide (1)

D water (1)

3(b) ethyl butanoate (1) 2

CH3CH2CH2CO2CH2CH3 (1)

3(c) does not completely dissociate / partially dissociates 1

Question Answer Marks

4(a) 79 1

4(b) 36 1

4(c) 41 1
20 Ca

4(d) loses two electrons 1

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5070/22 Cambridge O Level – Mark Scheme May/June 2022
PUBLISHED
Question Answer Marks

4(e)(i) in solid ions cannot move / in solid ions are in a lattice / in solid ions are fixed (1) 2

in molten liquid ions can move (1)

4(e)(ii) high melting point / high boiling point (1) 2

dissolves in water (1)

Question Answer Marks

5(a)(i) more ethanol (1) 2

(equilibrium shifts to the right) to release energy / to release heat (1)

5(a)(ii) less ethanol (1) 2

(position of equilibrium shifts to the left) more of moles of gas on reactant side of equation / less moles of gas on product
side (1)

5(b) C6H12O6  2C2H5OH + 2CO2 (1) 3

and any two from:

presence of yeast / enzyme (1)

presence of water (1)
quoted temperature between 15 and 45 (oC) inclusive (1)
absence of oxygen (1)

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5070/22 Cambridge O Level – Mark Scheme May/June 2022
PUBLISHED
Question Answer Marks

6(a) 2Al(s) + 6H+(aq)  2Al3+(aq) + 3H2(g) 2

balancing (1)

correct state symbol dependent on formulae (1)

6(b) add (aqueous) sodium hydroxide (1) 2

white ppt that redissolves / white ppt. soluble in excess (1)
OR
add (aqueous) ammonia (1)
white precipitate (1)

6(c) Mr for aluminium sulfate is 342 (1) 2

x = 18 (1)

6(d) mixture of a metal with another element 1

Question Answer Marks

7(a) global warming / greenhouse effect / climate change 1

7(b) acid rain / damage to buildings / killing living things 1

7(c)(i) to increase the surface area (1) 2

more exposed particles / more collisions per second (1)

7(c)(ii) particles move slower / particles have less kinetic energy (1) 2

fewer successful collisions / fewer collisions above that of activation energy (1)

7(d)(i) (sulfur or sulfur dioxide) gains oxygen 1

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5070/22 Cambridge O Level – Mark Scheme May/June 2022
PUBLISHED
Question Answer Marks

7(d)(ii) bond making releases energy and bond breaking absorbs energy (1) 2

more energy released than absorbed (1)

7(d)(iii) lowers the activation energy 1

Question Answer Marks

8(a) zinc is more reactive than iron / zinc is above iron in the reactivity series (1) 2

zinc will react in preference to iron / zinc will oxidise instead of iron (1)

8(b)(i) 2

positive ion

delocalised electrons

diagram showing closely packed positive ions surrounded by delocalised electrons (1)

strong attraction between electrons and positive ions (1)

8(b)(ii) electrons can move / has mobile electrons 1

8(c) cathode: Zn2+ + 2e–  Zn (1) 2

anode: 4OH– – 4e–  O2 + 2H2O / 4OH-  O2 + 2H2O + 4e– (1)

© UCLES 2022 Page 10 of 12

Page 47 l Nayeem Sir

5070/22 Cambridge O Level – Mark Scheme May/June 2022
PUBLISHED
Question Answer Marks

8(d) moles of zinc = 0.036 (1) 3

moles of HCl = 0.100 (1)

0.1 mole of acid would react with 0.05 mol of zinc / 0.036 mole of zinc would need 0.072 moles of HCl (1)

Question Answer Marks

9(a) H 2
H H
H C
C
C H
H H H H
H
H H
H C C C C H C
H
H H H H (1) H (1)

9(b) C12H26 1

9(c) petroleum is heated / petroleum is vapourised / petroleum is at high temperature (1) 3

use of a (tall fractionating) column (1)

separation depends on boiling point / high boiling point exits from the bottom / low boiling point from the top (1)

9(d)(i) UV / sunlight 1

9(d)(ii) amount of C is 37.8 / 12 (mol), amount of H is 6.30 / 1 (mol) and of Cl is 55.9 / 35.5 3
OR
mole ratio C:H is 3.15 : 6.30 : 1.57 (1)

empirical formula is C2H4Cl (1)

molecular formula C4H8Cl2 (1)

Page 48 l Nayeem Sir

5070/22 Cambridge O Level – Mark Scheme May/June 2022
PUBLISHED
Question Answer Marks

10(a) 4 NH3 + 5 O2  4 NO + 6 H2O 1

10(b)(i) potassium hydroxide 1

10(b)(ii) idea of titrating acid and alkali together using an indicator to find the end-point (1) 2

repeat the procedure using the same volumes but without the indicator (1)

10(b)(iii) Mr is 101 (1) 2

% is 13.861 (1)

10(c)(i) pesticides / herbicides / heavy metal ions / detergents 1

10(c)(ii) chlorination (1) 3

filtration / sedimentation / screening (1)

use of carbon (1)

Page 49 l Nayeem Sir

Cambridge O Level
* 1 4 9 2 1 5 1 1 2 1 *

CHEMISTRY 5070/42
Paper 4 Alternative to Practical May/June 2022

1 hour

You must answer on the question paper.

No additional materials are needed.

INSTRUCTIONS
● Answer all questions.
● Use a black or dark blue pen. You may use an HB pencil for any diagrams or graphs.
● Write your name, centre number and candidate number in the boxes at the top of the page.
● Write your answer to each question in the space provided.
● Do not use an erasable pen or correction fluid.
● Do not write on any bar codes.
● You may use a calculator.
● You should show all your working and use appropriate units.

INFORMATION
● The total mark for this paper is 60.
● The number of marks for each question or part question is shown in brackets [ ].

This document has 16 pages. Any blank pages are indicated.

Page 50 l Nayeem Sir

1 A student determines the concentration of aqueous potassium manganate(VII), KMnO4, by

titration with a solution of ethanedioic acid, H2C2O4.

An equation to represent this reaction is shown.

2KMnO4 + 5H2C2O4 + 6H+ 2Mn2+ + 10CO2 + 8H2O + 2K+

(a) Diagrams of some of the pieces of apparatus the student uses are shown.

A B C

Name the three pieces of apparatus.

A ...............................................................................................................................................

B ...............................................................................................................................................

C ...............................................................................................................................................
[3]

(b) The student:

• records the mass of a sample of solid ethanedioic acid

• dissolves the solid in distilled water and makes the solution up to 250 cm3

• uses apparatus B to transfer 25.0 cm3 of the solution of H2C2O4 into apparatus C

• adds 10.0 cm3 of dilute sulfuric acid to apparatus C

• fills apparatus A with the solution of KMnO4

• titrates the colourless solution of H2C2O4 with the solution of KMnO4 until the end-point
is reached

• repeats the titration three more times.

EDA(x gram) EDA (x gram in 250 cm3 water, conc = C)

25cm3 EDA taken (conc = C) and reacted with KMnO4

Page 51 l Nayeem Sir

(i) Suggest why sulfuric acid is added to apparatus C. See the reaction. It needs invovement of
H+ ions. So we must acidify the solution

...........................................................................................................................................

..................................................................................................................................... [1]

(ii) State the colour change at the end-point. Final colour will be due to solution from burette.

from ............................................................ to ............................................................ [1]

(iii) The diagrams show parts of apparatus A with the liquid levels at the beginning and the
end of titration 1.

titration 1

initial reading final reading

1.0 27.0

2.0 28.0

Record the values in the results table.

Complete the results table.

titration 1 2 3 4

final reading / cm3 24.8 25.9 24.9

initial reading / cm3 0.0 0.8

volume used / cm3 24.8 24.6

best titration results (✓)

Tick the results that are closest [3]

(iv) Tick (✓) the best titration results in the table.

Use the ticked values to calculate the average volume of KMnO4(aq) added in cm3.
Calculate Average from ticked results

average volume of KMnO4(aq) added .................................................. cm3 [1]

Page 52 l Nayeem Sir
4

This student uses 1.08 g of ethanedioic acid to make up the 250 cm3 solution of H2C2O4.

The student obtains an average titration volume of 24.55 cm3.

(i) Calculate the number of moles of ethanedioic acid in 25.0 cm3 of the H2C2O4(aq).

Show your working.

Find concentration of EDA (using mol = CV)
Then find moles in 24.55 cm3 (using Mole = CV)
[Mr: H2C2O4, 90] unitary method may also be followed.

.................................................... mol [2]

(ii) During the reaction, two moles of KMnO4 react with five moles of H2C2O4.

Calculate the number of moles of KMnO4 in 24.55 cm3 of the aqueous potassium
manganate(VII).
Use simple mole ratio style.

.................................................... mol [1]

(iii) Calculate the concentration, in mol / dm3, of the KMnO4(aq).

Use mole = CV

........................................... mol / dm3 [1]

(iv) Calculate the concentration, in g / dm3, of the KMnO4(aq).

Give your answer to three significant figures.

[Mr: KMnO4, 158]

Use mole = (mass)/(RFM)

............................................... g / dm3 [1]

[Total: 14]

Page 53 l Nayeem Sir

2 (a) A solution contains one cation and two different anions.

The table shows the tests a student does on this solution.

Complete the table.

Follow concepts of :

Name any gases formed. Paper 1 MCQ 3

Paper 2 question 1.

test observations conclusions

(i) To 1 cm depth of
the solution in a ..............................................
test-tube, add a
small volume of ..............................................
aqueous sodium
hydroxide. ..............................................

Then add more .............................................. The cation might be Al 3+.

aqueous sodium
hydroxide until it is ..............................................
in excess. The cation could also be
..............................................
................................... .
[4]
(ii) To 1 cm depth of the
solution in a boiling ..............................................
tube, add a small
volume of aqueous ..............................................
ammonia.
..............................................
Then add more
aqueous ammonia .............................................. The cation is Al 3+.
until it is in excess.
..............................................

[2]
(iii) To 1 cm depth of A gas is evolved that
the solution in a decolourises acidified The gas is
test-tube add nitric potassium manganate(VII)
acid and warm until solution. ................................... .
no further change is
seen. One of the anions is

................................... .
[2]
(iv) To the solution from A yellow precipitate forms.
(iii) add aqueous The other anion is
silver nitrate.
........................................ .

[1]

Page 54 l Nayeem Sir
7

(b) A mixture of solids contains barium sulfate and sodium chloride only.

Barium sulfate is insoluble in water. Sodium chloride is soluble in water.

Describe how to separate the mixture to obtain pure barium sulfate and pure crystals of
sodium chloride. First dissolve in water (BaSO4 remains undissolved). Separate BaSO4 by filtration.

...................................................................................................................................................

............................................................................................................................................. [6]

[Total: 15]

Page 55 l Nayeem Sir
8

3 A student measures the temperature change during the reaction between HCl(aq) and
aqueous sodium hydroxide, NaOH(aq).

NaOH(aq) + HCl(aq) NaCl(aq) + H2O(l)

(a) The student:

• uses a measuring cylinder to add 25 cm3 of 1.50 mol / dm3 NaOH(aq) to a glass beaker

• records the temperature of the NaOH(aq)

• adds 4.0 cm3 of the HCl(aq) to the beaker and records the highest temperature reached

• adds further 4.0 cm3 portions of the HCl(aq), and records the highest temperature
reached each time.

The student’s results are shown.

total volume of
0 4.0 8.0 12.0 16.0 20.0 24.0 28.0 32.0
HCl(aq) / cm3
temperature / °C 24.5 25.0 28.5 30.5 32.5 32.5 31.5 30.5 29.5

(i) Name the type of reaction that takes place between HCl(aq) and NaOH(aq).

..................................................................................................................................... [1]

(ii) Name a piece of apparatus that can improve the accuracy of the volume of NaOH(aq)
added to the beaker. For 10, 20 or 25 cm3, pipette is more accurate than measuring cylinders

..................................................................................................................................... [1]

(iii) Name the piece of apparatus used to add the 4.0 cm3 portions of HCl(aq).
For smaller volume, use dropping pipette.
..................................................................................................................................... [1]

(iv) Explain why the glass beaker is not the most suitable piece of apparatus for this
experiment. This experiment involves evolution of heat. So there is an issue involving loss of heat.
Improvement can be achieved using hard plastic beakers or by covering the glass beakers
with insulation and lid.
Suggest an improvement.

explanation ........................................................................................................................

...........................................................................................................................................

improvement .....................................................................................................................

...........................................................................................................................................
[2]

Page 56 l Nayeem Sir

(v) Plot the values of temperature against total volume of HCl(aq) on the grid.

temperature / °C
34

22
0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32
volume of HCl (aq) / cm3
[2]

(vi) Circle the anomalous point on the grid. [1]

(vii) Draw a straight line of best fit through the points from 0 to 16 cm3. [1]

(viii) Draw a straight line of best fit through the points from 20 to 32 cm3.

Extrapolate both lines so that they intersect. [2]

(ix) Use the intersection to determine the minimum volume of HCl(aq) needed to react with
all of the NaOH(aq).

volume of HCl(aq) .................................................. cm3 [1]

Page 57 l Nayeem Sir
10

(x) Use the intersection to determine the temperature change, ∆T, due to the reaction.

∆T ..................................................... °C [1]

(xi) The heat change during this reaction is calculated using the expression shown.

heat change = mass of solution × specific heat capacity × temperature change

1.0 cm3 of this solution has a mass of 1.0 g.

Determine the value used for the mass of solution in the calculation of this heat change.

mass ....................................................... g [1]

(b) The actual heat change of this reaction is much greater than the value calculated using the
expression in (a)(xi).

Suggest a reason for this difference.

...................................................................................................................................................

............................................................................................................................................. [1]

[Total: 15]

Page 58 l Nayeem Sir

4 The apparatus shown is used for the electrolysis of dilute sulfuric acid to produce hydrogen gas
and oxygen gas.

(a) The electrodes are made of platinum.

Give the name of each electrode.

positive electrode ......................................................................................................................

negative electrode ....................................................................................................................

[2]

(b) The equation for the reaction at the positive electrode is shown.

4OH− O2 + 2H2O + 4e−

(i) Give the equation for the reaction at the negative electrode.

..................................................................................................................................... [2]

Page 59 l Nayeem Sir

(ii) Describe tests used to identify the gases produced.

Remember that
oxygen O2 test: use glowing splint, glowing splint relights re-burns
H2 test: use burning splint, splint extinguish or goes off with pop sound.

test ....................................................................................................................................

observations ......................................................................................................................

...........................................................................................................................................

hydrogen

test ....................................................................................................................................

observations ......................................................................................................................
[4]

[Total: 8]

Page 60 l Nayeem Sir
14

5 A student uses the apparatus shown to investigate the rate of reaction between excess
copper(II) carbonate and dilute sulfuric acid.

CuCO3(s) + H2SO4(aq) CuSO4(aq) + CO2(g) + H2O(l)

bung

X
cotton thread

dilute sulfuric
acid
sample tube containing
copper(II) carbonate

(a) Identify the piece of apparatus labelled X.

............................................................................................................................................. [1]

(b) The student starts the reaction by tipping the sample tube so that the copper(II) carbonate
and acid come into contact.

Explain why this method is used instead of adding the copper(II) carbonate to the acid and
then replacing the bung.

...................................................................................................................................................

............................................................................................................................................. [1]

Page 61 l Nayeem Sir

The student plots a graph of the results.

(i) Give the labels for each axis of the graph.

horizontal axis ...................................................................................................................

vertical axis .......................................................................................................................

[1]

(ii) List three things the student sees happening in the flask during the reaction.

1 ........................................................................................................................................
Since gas is produced,
So fizzing is occurirng. 2 ........................................................................................................................................
Amount of solid is decreasing
Piston of syringe moves
3 ........................................................................................................................................
[3]

(iii) Use the graph to explain what happens to the rate of reaction during the reaction.
Follow MCQ 21, for explanation
...........................................................................................................................................

...........................................................................................................................................

..................................................................................................................................... [2]

Page 62 l Nayeem Sir

Cambridge O Level

CHEMISTRY 5070/42
Paper 4 Alternative to Practical May/June 2022
MARK SCHEME
Maximum Mark: 60

Published

Mark schemes should be read in conjunction with the question paper and the Principal Examiner Report for
Teachers.

Cambridge International will not enter into discussions about these mark schemes.

This document consists of 9 printed pages.

Page 63 l Nayeem Sir

5070/42 Cambridge O Level – Mark Scheme May/June 2022
PUBLISHED
Generic Marking Principles

GENERIC MARKING PRINCIPLE 1:

Marks must be awarded in line with:

GENERIC MARKING PRINCIPLE 2:

Marks awarded are always whole marks (not half marks, or other fractions).

GENERIC MARKING PRINCIPLE 3:

Marks must be awarded positively:

GENERIC MARKING PRINCIPLE 4:

Rules must be applied consistently, e.g. in situations where candidates have not followed instructions or in the application of generic level
descriptors.

Page 64 l Nayeem Sir

5070/42 Cambridge O Level – Mark Scheme May/June 2022
PUBLISHED
GENERIC MARKING PRINCIPLE 5:

GENERIC MARKING PRINCIPLE 6:

Marks awarded are based solely on the requirements as defined in the mark scheme. Marks should not be awarded with grade thresholds or
grade descriptors in mind.

Page 65 l Nayeem Sir

5070/42 Cambridge O Level – Mark Scheme May/June 2022
PUBLISHED
Science-Specific Marking Principles

1 Examiners should consider the context and scientific use of any keywords when awarding marks. Although keywords may be present, marks
should not be awarded if the keywords are used incorrectly.

5 ‘List rule’ guidance

For questions that require n responses (e.g. State two reasons …):

Page 66 l Nayeem Sir

5070/42 Cambridge O Level – Mark Scheme May/June 2022
PUBLISHED
6 Calculation specific guidance

Correct answers to calculations should be given full credit even if there is no working or incorrect working, unless the question states ‘show
your working’.

7 Guidance for chemical equations

Multiples / fractions of coefficients used in chemical equations are acceptable unless stated otherwise in the mark scheme.

State symbols given in an equation should be ignored unless asked for in the question or stated otherwise in the mark scheme.

Page 67 l Nayeem Sir

5070/42 Cambridge O Level – Mark Scheme May/June 2022
PUBLISHED

Question Answer Marks

1(a) A burette (1) 3

B pipette (1)
C conical flask / Erlenmeyer flask (1)

1(b)(i) provide H+ 1

1(b)(ii) (from) colourless (to) (pale) pink 1

1(b)(iii) 3
titration number 1 2 3 4

final reading / cm3 27.1

initial reading / cm3 1.7 0.3

volume used / cm3 25.4 25.1

best titration results ()  

M1 final and initial readings correct in column 1 (1)

M2 volume used correct in column 1 (1)
M3 25.1 and 0.3 in columns 3 and 4 (1)

1(b)(iv) 24.7 (cm3) 1

1(c)(i) M1 1.08/90 OR 0.012 (1) 2

M2 (0.012 ÷ 10 =) 0.0012/1.2  10–3 (1)

1(c)(ii) 0.00048 / 4.8  10–4 1

1(c)(iii) 0.0196 1

1(c)(iv) 3.09 / 3.10 1

Page 68 l Nayeem Sir

5070/42 Cambridge O Level – Mark Scheme May/June 2022
PUBLISHED
Question Answer Marks

2(a)(i) M1 white precipitate (1) 4

M2 dissolves/soluble (1)
M3 colourless solution (1)
M4 Zn2+ (1)

2(a)(ii) M1 white precipitate (1) 2

M2 insoluble (in excess) (1)

2(a)(iii) M1 sulfur dioxide / SO2 (1) 2

M2 sulfite / SO32– (1)

2(a)(iv) iodide / I– 1

2(b) M1 add water to the mixture (1) 6

M2 stir / heat / shake

(water and the mixture) (1)

M3 filter
(barium sulfate) (1)

M4 wash the residue

or wash barium sulfate with distilled water and dry e.g. between filter papers (1)

M5 heat the filtrate / heat aqueous sodium chloride / heat sodium chloride solution (1)

M6 until crystallisation point / saturation point / to dryness (1)

Question Answer Marks

3(a)(i) exothermic / neutralisation 1

3(a)(ii) pipette / burette 1

3(a)(iii) burette 1

Page 69 l Nayeem Sir

5070/42 Cambridge O Level – Mark Scheme May/June 2022
PUBLISHED
Question Answer Marks

3(a)(iv) M1 heat loss (1) 2

M2 use a polystyrene cup / plastic cup / insulate the beaker (1)

3(a)(v) M1 points at 0, 4, 8, 12 and 16 plotted correctly (first 5) (1) 2

M2 points at 20, 24, 28 and 32 plotted correctly (last 4) (1)

3(a)(vi) circle the second point 1

3(a)(vii) best fit line ignoring anomalous point 1

3(a)(viii) M1 second best fit line (1) 2

M2 lines extended to intersect (1)

3(a)(ix) 17.4 (cm3) 1

3(a)(x) (33.2 – 24.5) = 8.7 (°C) 1

3(a)(xi) (25 + 17.4 =) 42.4 (g) 1

3(b) heat loss 1

Page 70 l Nayeem Sir

5070/42 Cambridge O Level – Mark Scheme May/June 2022
PUBLISHED
Question Answer Marks

4(a) M1 anode (1) 2

M2 cathode (1)

4(b)(i) M1 H+ + e on LHS 2
M2 2H+ + 2e  H2 fully correct

4(b)(ii) oxygen 4
M1 glowing splint (1)
M2 relights (1)

hydrogen
M3 burning splint (1)
M4 pop (1)

Question Answer Marks

5(a) gas syringe 1

5(b) (avoids) loss of gas 1

5(c)(i) (horizontal) time / s 1

AND
(vertical) volume (of gas / carbon dioxide / CO2) / cm3

5(c)(ii) M1 solid disappears (1) 3

M2 effervescence / fizzing / bubbling (1)
M3 solution turns blue (1)

5(c)(iii) M1 rate decreases (1) 2

M2 as concentration of acid decreases or
as gradient decreases / becomes less steep (1)

Page 71 l Nayeem Sir

Cambridge O Level: Chemistry 5070/12
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