Sri Chaitanya IIT Academy.,India.
A.P T.S KARNATAKA TAMILNADU MAHARASTRA DELHI RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Sr.Super60, Elite,Target & LIIT BT's Paper -2(Adv-2023-P2-Model) Date: 16-04-2025
Time: 02.00Pm to 05.00Pm GTA-27 Max. Marks: 180$
KEY SHEET
MATHEMATICS
1 C 2 A 3 A 4 C 5 ABCD 6 BC
7 BC 8 9 9 22 10 0 11 5 12 2
13 8 14 4.5 15 4 16 0.6 17 16
PHYSICS
18 A 19 B 20 B 21 B 22 BC 23 BD
24 B 25 3 26 2 27 3 28 7 29 5
30 4 31 4 32 7.2 33 6 34 20
CHEMISTRY
35 C 36 B 37 A 38 D 39 AC 40 ABC
41 AD 42 4 43 2 44 6 45 80 46 12
0.97- 0.16-
47 108 48 49 50 5 51 1
0.99 0.18
Sri Chaitanya IIT Academy 16-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2023 –P2)_GTA-27_Key& Sol’s
SOLUTIONS
MATHEMATICS
1. Volume = 2b c,3c a, 4a b 18
2
24 abc 18 abc
3
2
1 sin cos sin 2
2 2 4
Now, ab c sin cos sin 2
3 3 3
2 2 4
sin cos sin 2
3 3 3
Applying R1 R1 R2 R3 we get after simplification,
a bc cos3 1
2.
Z1. Z 2 Z 3 Z 1 Z 2 Z 3 0
2 2 2 2
Z1 Z 2 Z1.Z 2 Z 1.Z 2 Z1 Z3 Z1.Z 3 4
Z1 Z 2 . Z 1 Z 2 Z1 Z3 . Z 1 Z 3 4 22
Z1
Z3
Z2
Hence Z 2 , Z 3 are diametrically end points. Z 2 Z3 0 Z1 Z 2 Z3 1
1 0 0 0 21 22 2 n
2
0 0 0 0 0 0
3. A
3 0 0 0 0 0 0
n 0 0 0 0 0 0
1 0 0 0 2 1 22 2 n 1 0 0 0 21 22 2 n
2 2 0 0 0 0 0 0 2 0 0 0 0 0 0
A
3 0 0 0 0 0 0 3 0 0 0 0 0 0
n 0 0 0 0 0 0 n 0 0 0 0 0 0
Sec: Sr.Super60, Elite,Target & LIIT BT's Page 2
Sri Chaitanya IIT Academy 16-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2023 –P2)_GTA-27_Key& Sol’s
1 0 0 0 i.2i 0 0 0 21 22 2 n
2 2 0 0 0 2 0 0 0 0 0 0
A i.2i. A
3 0 0 0 3 0 0 0 0 0 0
n 0 0 0 n 0 0 0 0 0 0
ni n
A2 A. i.2i An i 2i A tr An i.2i
1/ n 1 2 3
tr An i.2i 2
2 4 8
4. 3 16 I F where 0 F 1
Let 3 1 G where 0 G 1 I F G 3 1 3 1
6 6 6
2 6 C0 3 6 C2 3 6 C4 3 6 C6
6 4 2
2 1.27 15.9 15.3 1 416
or I 416 F G 415 (AS O < F + G < 2)
5. tan 2
. tan 1 3 1 .1 2
since , are integers possible values can be
(i) 1 2, 1 1
5
1, 2 tan 2 1 ,
4 4
(ii) 1 2, 1 1 3, 0
3 7
tan 2 1 ,
4 4
Total 4 possible values of .
6.
As SP 6 3t 2 3 t 1 P 3,6
Tangent at P : 6y = 6 (x + 3) x y30
T 0,3 ST 3 2 also Q = (–3, 0) QS = 6
Sec: Sr.Super60, Elite,Target & LIIT BT's Page 3
Sri Chaitanya IIT Academy 16-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2023 –P2)_GTA-27_Key& Sol’s
As given SR = 6 R (9, 0)
As we know if tangent and normal at any point P cuts axis at Q & R then SP = SQ = SR
According. to figure PR is normal
Now Area of PRST = Area of PQR –Area of TQS .
1 1 1 1
PS QR OT .QS 6 12 3 6 27 .
2 2 2 2
Also as we know if tangent at P & M meet at point N, then SN SP.SM
2
25 7 7
25 6 SM SM 3t 2 3 t 2 t
6 18 3 2
7
ordinate of M 2at 2.3.
3 2
14
Sum of squares = 14 + 14 = 28
7.
As BCA BOA 90 90 180 A, O , B, C are concyclic
COB CAB
2
5 5
tan cot
2 12 12
y 12
Locus of C (x, y) =
x 5
Also using ptolemy’s theorem :
5. OA + 12. OB = 13.OC
5 12 5 12
OA OB OC p , q
13 13 13 13
8.
Divide given differential equation by x y y 2 x 2 .
y y 2 2 x2 .dx x. 2 y2 x2 .dy 0 y 2 x2 x2
.dx
y2 y2 x2
.dy 0
x y y2 x2 x y y 2 x2
x. y 2 x 2
y. y 2 x 2
Sec: Sr.Super60, Elite,Target & LIIT BT's Page 4
Sri Chaitanya IIT Academy 16-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2023 –P2)_GTA-27_Key& Sol’s
dx x.dx y dy dy dx dy ydy xdx
2 0 2 0
x y x2 y 2 x2 y x y y x2
1
nx ny n y 2 x 2 K
2
x 2. y 2. y 2 x2 C
g 3 g
f x x 2 , g y y 2 2.25
f 2 4
9. As plane pass through a common line, their normals will be coplanar.
1 sin sin
sin 1 sin 0
sin sin 1
sin 2 sin 2 sin 2 2sin .sin .sin 1
Now P1 P 2 is parallel to given line
i j k
P1 P 2 1 sin sin i sin .sin sin j sin sin sin k
sin 1 sin
1 sin 2
sin .sin sin sin sin .sin 1 sin 2
cos
cos cos cos
sin cos ,sin cos 2n
2
5 g
possible values will be , ,
2 2 2
10. From given matrix,
1
f f 1 x 2 f x f 1 ........... i
x
1
1 1
f 2 f x 2 1 4 f 2 ........... ii
x x x
1 1 1
f x f f 1 2 ............. iii
x x x
1 1 f 1
f 1 f x 2 f ............... iv
x x
From (ii), x = 1 2 f 1 0 f 1 0
Sec: Sr.Super60, Elite,Target & LIIT BT's Page 5
Sri Chaitanya IIT Academy 16-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2023 –P2)_GTA-27_Key& Sol’s
1
Equation i , x 2 f x f ...........*
x
1/ x
1
Now, f t dt I Replace t
t
x
x 1/ x
1 1 1 1
I f 2 dt
x t f 2 dt
t t
1/ x x
1/ x
1
2I f t t 2 f t dt 0 from (*)
x
i.e., I = 0 = f (1).
7
11. C6 .8 C7 (only Rani) 8 C6 .8 C7 (only Radha) 8 C6 .8 C8 (neither Rani nor Radha)
1 2
12. Use graph of f (x) = y and y = e x
e e
2
x 2
2
13. x 4 7 x 2 4 x 20 x 2 4
2
x 4 9 x 2 16 x 2 4 x2
Take the curve y x 2 . Both square roots can be interpreted as distances.
14. f (2) = 4 _______(1)
f 2 2 h a 2 ab 2 a b h
2
a 2 ab b _______(2)
f 2 0 a 2 ab 2 a b .1 h
a 2 ab 2 a b _______(3)
from (1) and (2)
a 2 ab a b 6 0
ab4 (using – 4)
from (4) a (a + b) + 2 = 0
1 g
4a + 2 = 0 a b
2 2
15.
f 2 f 2 f 2
a 2 ab 6 a 2 ab 2 a b 2a 2 2 ab a b 8 0 for a R D 0
Sec: Sr.Super60, Elite,Target & LIIT BT's Page 6
Sri Chaitanya IIT Academy 16-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2023 –P2)_GTA-27_Key& Sol’s
2b 1 2 4.2.8 b 0 4b 2 4b 63 0
smallest positive value of b = 4
8
f ' x
16. Consider .dx I by substituting f (x) = t, we get
4 f x
2
8
1 1 1
I 2 4 2
f x 4 f 8 f 4
2 2
8 8 f 1 x 8 8
f x 1
f 1 x 2
Now, consider J 2 K 4 dx 2 K dx K dx
4 f x 4 f x 4 f 2 x 4
J 1 2 K 2 K . 8 4
2
1 4K 4K 2
8 2 8 1 2
f 1 x f x 1
K dx 2 K 1
2
2 2 dx 0
4 f x 4 f x 2
f 1 x 1 f 1 x 1
Integrand , must be 0. 2 (always)
f x 2
2
f x 2
1 x
Integrating both sides w.r. t x C
f x 2
1 4
putting x = 4 C 4 2 C C 6
f 4 2
2 2 1 1 3
f x f 6 value of 0.6
12 x 12 6 3 5. f 6 5
1 11 11
2
17. Given integral can be written as I 12 x r . . dx
0 r 4 r 4 12 x r
1 11 11
2
12 r x . . dx
r 4 12 r x
0 r 4
1
1 1 1
2 x 8 x 7 x 1 . . dx
x8 x7 x 1
0
here integrand is exact derivative of (x + 1) . (x + 2) ----------- (x + 8)
1
I 2 x 1 . x 2 x 8 2. 2.3.4. .9 1.2.3. 8
0
16 8!
Sec: Sr.Super60, Elite,Target & LIIT BT's Page 7
Sri Chaitanya IIT Academy 16-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2023 –P2)_GTA-27_Key& Sol’s
PHYSICS
0 N 2 A
18. Self induction of a solenoid is L
If x is the length of the wire used to make the solenoid with R as radius of the solenoid,
then x 2 RN , A R 2
x 2 R 2 4 L
L 0 x
4 2 R 2 0
19. w PdV
20. Normal to the mirror is along j
N N
Along normal to the mirror, V1 2VM V0 2 3j 2j 4j m / s
Parallel to the plane of mirror (X–Z plane), V V i 5
1 P k m/s
0 P
V1 V1 V1
N P
= 4j i 5k
= i 4j 5
k m/s
21. At y according to Kirchhoff’s junction law,
y x y x 100 y 50 y y 50
0
r r r r r
5 y 2 x 200 ………. (i)
2 50V2
50 50
2
2 R 2 2
X X 100
i 2 2 i
100V
50 x y x
Similarly at x, i ………. (ii)
r r
x 100 50 x 100 y
At x + 100, i ………. (iii)
r r
From Eqs. (ii) and (iii), we get
y – 2x = 50 ………. (iv)
From Eqs. (i) and (iv), y = 37.5V So, current through R is 37.5/18.75 = 2A
Sec: Sr.Super60, Elite,Target & LIIT BT's Page 8
Sri Chaitanya IIT Academy 16-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2023 –P2)_GTA-27_Key& Sol’s
22. B
0 q v
r
4 r 3
q
B0 j 0 v 5i
4 r 3
This equation becomes true only if v has k component or i and k components.
Hence options ‘B’ and ‘C’ are true.
23. The x–component of velocity, being parallel to magnetic field, shall remain unchanged.
The component of velocity perpendicular to x–axis will always have magnitude Voy , and
at any time t it shall make an angle t with y–axis as shown.
z
y
t
0
Voy
y–component of velocity is Voy cos t and z–component of velocity along negative
qB
z–direction at any time t is Voy sin t . Where .
m
dq
24. (a) i
dt
a
a 4 cua 4
i u dA u cr 2 2rdr 2cu
4 2
0
r
c r
2
2r dr
(b) EdA E 2r 0
0
c r3
E
40
0 cu r 4
(c) B 2r
2
cur 3
B 0
4
Sec: Sr.Super60, Elite,Target & LIIT BT's Page 9
Sri Chaitanya IIT Academy 16-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2023 –P2)_GTA-27_Key& Sol’s
25. Applying energy conservation
2 2
1 a 1 a 1 1
k 2k mv12 Mv22 ………. (i)
2 2 2 2 2 2
By law of conservation of momentum
mv1 Mv2 0
v1 4v2 ………. (ii)
1 a 2 ka 2 1 2 1
k v1 4v22
2 4 4 2 2
3ka 2
v22
80
v2 3 m / s
P x S2
3
S1
26.
5
S1P S2 P
2
5
3 2 x 2 x
2
25 2 11 11
9 2 x 2 x 2 5 x x 40 108 2 107
4 20 20
K 2
27. The motion of the cylinder will be simple harmonic. In equilibrium, the block will float
with 1/4th of its length submerged. If further pushed by a distance x,
4
Sec: Sr.Super60, Elite,Target & LIIT BT's Page 10
Sri Chaitanya IIT Academy 16-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2023 –P2)_GTA-27_Key& Sol’s
a acc n ag x W 4g . At equilibrium Vmax W Amplitude
4
4 g 3 3
Vmax g 3m / s
4 2
28. dQ dU dW
dw pdv ps dx
Mg
dw P0 s dx
s
dW P0s Mg dx
V
dx
PVRT
3
dU RdT also PV RT pdv RdT psdx
2
3 Mg 3
dU P0 s dx P0 s Mg dx
2 s 2
5 2 dQ / dt
dQ P0s Mg dx v V 7 m / s
2 5 P0 S Mg
10 5
29. Power loss = 100 k 50 10 k
4 2
5
At 30 C PLoss k 30 10 20 50W
2
v
M M
u
30. u/
By momentum conservation Mu Mv Mu / u vu /
/ M 2
By angular momentum conservation M .u Mu . u u /
2 2 12 6
Sec: Sr.Super60, Elite,Target & LIIT BT's Page 11
Sri Chaitanya IIT Academy 16-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2023 –P2)_GTA-27_Key& Sol’s
2u 12u
For elastic collision v u / u On solving v ;
2 5 5
1M 2 1
Now KE of upper half part = Vcm . I cm . 2
2 2 2
M
2
.
1 M 2u 3u 1 2 2 12u
2 2
Mu 2
= .
2 2 5 5 2 12 5 25
31&32
1
P0 h1 1 g h2 2 g 2 v 2 P0
2
F a v2
33&34
1510
Ceff 6 F
25
q1 : q 2 2 :1
1
q 2 q total 20 C
3
CHEMISTRY
35. 1) We are given that the sum of the principal quantum numbers is 4: n1 + n2 = 4
2) And their difference is 2: n1 - n2 = 2
Solving these two equations simultaneously:
1) Adding the two equations gives 2n1 = 6, so n1 = 3
2) Substituting n1 = 3 into either equation gives n2 = 1
2) Apply the Rydberg formula for Hydrogen-like species:
The wave number v of the emitted radiation for a hydrogen-like species (like Li 2 ) is
given by: v R * Z 2 * 1 / n 22 1 / nl 2
Where:
1) R is the Rydberg constant.
2) Z is the atomic number (Z = 3 for Lithium).
3) n1 and n2 are the principal quantum numbers of the initial and final levels,
respectively.
Sec: Sr.Super60, Elite,Target & LIIT BT's Page 12
Sri Chaitanya IIT Academy 16-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2023 –P2)_GTA-27_Key& Sol’s
3. Substitute the values and calculate:
v R * 3 * 1 / 12 1 / 32 v 9 R * 1 1 / 9 v 9 R * 8 / 9 v 8 R
2
36. The sequence 5' -ATGCCTAA- 3' has the following base pairs:
1) A-T: 2 hydrogen bonds
2) T-A: 2 hydrogen bonds
3) G-C: 3 hydrogen bonds
4) C-G: 3 hydrogen bonds
5) C-G: 3 hydrogen bonds
6) T-A: 2 hydrogen bonds
7) A-T: 2 hydrogen bonds
Total hydrogen bonds = (2 * 2) + (3 * 3) + (2 * 2) = 4 + 9 + 4 = 17
37.
38. (a) Incorrect: The reaction is a halogen exchange (metathesis) reaction, not a free radical
reaction. Free radical mechanisms involve species with unpaired electrons, which are not
involved here.
(b) Incorrect: While small amounts of intermediate fluorinated species might form, the
reaction's primary and favored outcome is the formation of SF4 . It implies a significant
mixture of products, which isn't the case. The reaction is driven towards SF₄.
(c) Incorrect: While SF₄ and AgCl are the major products, the stoichiometry does matter.
You need enough AgF to replace all the Cl atoms in SCl4 . If you have insufficient AgF,
you'll likely have some partially fluorinated sulfur chlorides as well. The statement
"regardless of stoichiometry" is therefore not entirely accurate.
(d) Correct: This option correctly identifies the driving forces:
1) Stronger S-F bonds: Fluorine's higher electronegativity leads to stronger S-F bonds
compared to S-Cl bonds. This provides a thermodynamic driving force.
2) AgCl precipitation: The formation of insoluble AgCl removes products from the
reaction mixture, driving the equilibrium towards product formation according to Le
Chatelier's principle. This makes the reaction essentially irreversible.
Sec: Sr.Super60, Elite,Target & LIIT BT's Page 13
Sri Chaitanya IIT Academy 16-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2023 –P2)_GTA-27_Key& Sol’s
39. A) G nFE 237.39 103 2 96500 Ecell
o o o
Ecell
o
1.23 V
C)
G 237.39 0.8306 or 83.06%
o
H 285.8
o
40. First step is dehalognation and followed by hydrogenation
41. It is likely sulphide salt
1 1 1
42. tav 4sec
Ea / RT
1.25 10 s e1610 /2400
3
8 1
k A.e
43. T f K f . m
1 / x 2 y
For AB2 solution: 2.55 = 5.1 1
20 / 1000
1 / x 4 y
For AB4 solution: 1.7 = 5.1 2
20 / 1000
Atomic mass of A = x = 50
Atomic mass of B = y = 25
44. ----------------------
45. 3A(g) 2B(g) + 2C(s)
t=0 6 atm 0 –
t = 20 min (6 – x) atm 2/3 x atm 0.05 atm
t= 0 4 atm 0.05 atm
But from question, P = 4.05 atm and hence, (4.05 – 4) = 0.05 atm is the vapour pressure
of C(s).
2
Now, P20 6 x x 0.05 5.05 x 2
3
t =20 min = t1/2
46. 1. Reaction with Ammonium Thiocyanate:
Iron(III) chloride FeCl3 reacts with ammonium thiocyanate NH 4 SCN to form a
blood-red complex, which is complex (P). The reaction can be represented (in simplified
form, ignoring the exact stoichiometry) as:
3 x
Fe3 SCN Fe SCN x (where x is the number of thiocyanate ligands bound
to the iron).
The complex (P) is a high-spin complex. Iron(III) has a d 5 configuration. In a high-spin
complex, all five d electrons are unpaired.
2. Spin-only Magnetic Moment of (P):
The spin-only magnetic moment is calculated using the formula:
n n 2 BM, where ' n ' is the number of unpaired electrons.
Sec: Sr.Super60, Elite,Target & LIIT BT's Page 14
Sri Chaitanya IIT Academy 16-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2023 –P2)_GTA-27_Key& Sol’s
For complex (P), n = 5 (five unpaired electrons).
P 5 5 2 35 5.92 BM . So, a 5.92
3. Reaction with Sodium Fluoride:
Adding excess sodium fluoride (NaF) to complex (P) results in the formation of a
colorless complex (Q). Fluoride is a strong field ligand and will replace the thiocyanate
ligands. It forms a complex like this:
3 x 3
Fe SCN
x
F excess FeF6
3
The complex (Q), FeF6 , is a high-spin comple
Q 5 5 2 35 5.92 BM . So, b 5.92
47. Benzaldehyde with formaldehyde gives cross Cannizaro product
48&49
1: Molar Ratio of Styrene to Isoprene
1. Assume 100g of copolymer: This makes the percentage calculations easier. We'd have
60g of styrene and 40g of isoprene.
2. Calculate moles of each monomer:
1) Moles of styrene = (60 g) / (104 g/mol) = 0.577 moles
2) Moles of isoprene = (40 g) / (68 g/mol) = 0.588 moles
3. Calculate the molar ratio:
1) Ratio of styrene to isoprene = (0.577 moles) / (0.588 moles) 0.98
Therefore, the chemist should use a molar ratio of approximately 0.98:1 (or very nearly
1:
1) styrene to isoprene in the initial feed.
2: Moles of CCl4 Moles of total monomer: From question 1, in our 100g example, we
had approximately 0.577 moles of styrene + 0.588 moles of isoprene 1.165 moles of
total monomer.
1. Number of polymer chains: Since one molecule of CCl4 terminates one chain, the
number of moles of CCl4 needed will be equal to the number of polymer chains we
want. We'll use the relationship between number average molecular weight (Mn), the
total mass of polymer, and the number of polymer chains (n): Mn = (Total Mass) / (n)
2. Calculate moles of chains:
1) n = (Total Mass) / Mn = (10000 g) / (50,000 g/mol) = 0.2 moles of chains.
3. Moles of CCl4 : Since each CCl4 molecule terminates one chain, we need 0.2 moles of
CCl4 .
4. Ratio of CCl4 to total monomer:
Sec: Sr.Super60, Elite,Target & LIIT BT's Page 15
Sri Chaitanya IIT Academy 16-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2023 –P2)_GTA-27_Key& Sol’s
(Moles of CCl4 ) / (Moles of total monomer) = (0.2 moles) / (1.165 moles) 0.18
Therefore, the chemist should add approximately 0.0017 moles of CCl4 per mole of total
monomer in the initial feed. This very small amount shows how effectively chain transfer
agents can control molecular weight.
50&51
A : NH 3 ; B : NO; C : NO2 ; D : N 2O3 ; E : HNO2 ; F : N 2 ; G : CaNCN .
Sec: Sr.Super60, Elite,Target & LIIT BT's Page 16
