Residual Risk

S Risk Rating Action

Hazard Risk Who is at Risk Necessary Control Measures Rating
R By
S L Rating S L Rating

RRNHR-2070
Risk Assessment Oxy Acetylene Welding Cutting Serial # 13
compressed  Serious or fatal Welding  Assign competent person for task.
Oxygen/Acetylene injury. Crew  Adequate supervision.
cylinders can  Property Site
 Task Supervisor to conduct prestart meeting with his
explode violently Damage. workers.
crew and discuss about all potential hazard and
corrective action to be taken.
 Assign skilled personnel to perform hot work.
 Assign trained fire watch with fire extinguisher.
1.  Strict comply with no smoking policy.
4 4 16  Provision of flash back arrestors.
HSEM 2 2 04
 Pressure gauges and regulators in good and working
condition
 Remove all combustible & flammable material from
below and surrounding welding area.
 Combustible & flammable material shall be covered
with fire blanket which cannot be removed?
 Assign stand by man for 30 minute during any break
and after completion of welding cutting work.
Enrichment of the  Fire can cause  Welding  Maintain Oxygen pressure at 50 PSI.
air caused by injuries like Crew  Check for leakage of cylinder.
2. oxygen leaks burns from
minor to 3rd
 Site
Workers.
4 3 12  Check pressure gauge in good and working condition. HSEM 2 1 02
degree.
Fire and explosion  Skin burns  Welding  Provide proper ventilation in welding/cutting area.
caused by gas leak,  Internal crew 4  Check for gas leak.
backfires and injuries  Site  Maintain Acetylene pressure at 15 PSI and Oxygen at
flashback.  Infected lungs workers 50 PSI.
3.  Cell and tissue
damages
 Nearby
contracto
5 20  Do not allow to keep the gas cylinder in the confined
space.
3 1 03
 r  Keep out the welding torch and hoses from the
 Nearby confined space during break and end of the shift.
public  Provide flash back arrestor to avoid the back fire.
 Residual Risk
S Risk Rating Action
Hazard Risk Who is at Risk Necessary Control Measures Rating
R By
S L Rating S L Rating

 Improper Cylinder  Might causing  Cylinder shall be kept in upright position, chained and
Storage damage to cap shall be provided to valves.
valves and  Oxygen and acetylene cylinders shall be stored
leading to gas separately at least 6.6 meter or 20 feet apart from each
leak. other or separated by a fire proof, 1.6 meters (5 feet)
 Infected lungs,
high partition.
 Burns due to fire
 Empty and full cylinders shall be stored separately with
CM/H
4. 4 4 16 empty cylinders plainly marked as such, to avoid SEM
3 1 03
confusion.
 Storage area shall be well-ventilated, shaded and 20
meters away from any temporary structure.
 Cylinders shall be stored below 54 oC (130 oF).
 Area shall also be marked for flammable and restricted
smoking zone.
 DCP fire extinguishers shall be provided.
Mishandling &  Serious or Fatal  Welders,  Strict comply with No Smoking policy. Provision of fire
Transportation. Injury Storekeeper extinguisher.
 Crushing injuries s  Deriver / operator must be aware about the potential
 Impact injuries  Workers,
hazards of the load and emergency procedure.
Supervisors,
Foremen.  Transport must have load spaces which separated from
driver cabin. Cylinder must be firmly secured and in
upright position. Cylinders must be closed, Valve outlet
must be capped and no leakage to be occurred. CM/H
5. 4 5 20  Cylinder shall not be dropped, thrown, dragged and SEM
2 2 04
rolled. Approved trolley shall be used for movement.
 Cylinder shall not be allowed to lift from valves or to lift
by using the slings. Approved lifting Cage or specially
designed bottle holder with lifting eyes shall be provided
for lifting purpose. Where a trolley is to be used for
slinging. Its base should be strong enough to take the
weight of the cylinders.
Accidental Release  Burns  Welders  Display of emergency numbers.
 Infected lungs  Workers  Provision of first aid facilities and emergency vehicle, on
6  Infected
Respiratory tract


Supervisors
Foremen
4 4 16 call. HSEM 3 2 06
 Evacuate the area.
 Suffocation  Storekeeper
 Residual Risk
S Risk Rating Action
Hazard Risk Who is at Risk Necessary Control Measures Rating
R By
S L Rating S L Rating

s  Inform emergency contact num.

 Isolate the area.
 Eliminate ignition sources.
 Ensure adequate ventilation.
 Use breathing apparatus.
 Post warning notices.
Welding fumes  Inhalation of  Welders,  Provide adequate ventilation by using Exhaust/Vent
during flame Cutting welding fumes Workers, fans. CM/H
7 Work  Dizziness
 Reddening of
Supervisor,
Foreman,
4 4 16 SEM
2 2 04
eyes

PM – Project Manager Risk Matrix Severity

Project: RRNHR-2070 CM – Construction Manager 1 2 3 4 5
HSEM – HSE Manager 1 1 2 3 4 5
Assessment 2 2 4 6 8 10
Carried out by: Umer Farooq Likelihood of 3 3 6 9 12 15
Harm 4 4 8 12 16 20
Assessment Date: April 03, 2024 5 5
S = Severity
10 15
15 to 25 High
20 25

L = Likelihood 8 to 12 Medium High

Key
Rating = S X L 4 to 6 Medium Low
Approved By: Waleed Tei 2 to 3
1
Low
Insignificant
 Page Number
MATERIAL SAFETY DATA SHEET 1/5
Date: 28/10/2018

MSDS V1.1 Acetylene DG008G

Label 2.1: flammable F+ : Extremely NFPA RATINGS

gas. flammable

1 IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING

Trade Name : Acetylene
Chemical Formula : C2H2
Chemical Family : Alkyne
MSDS No : DG008G
Company Identification : Aldakheel Industrial Gases Plant (DIGAS)
Emergency Phone Number : 04-8455-101

2 COMPOSITION / INFORMATION ON INGREDIENTS

COMPONENT CAS NUMBER CONCENTRATION

Acetylene 74-86-2 >99%*
*The symbol > means "greater than"
3 HAZARDS IDENTIFICATION

Emergency Overview : Danger! Flammable gas under pressure. Can form explosive mixtures with air. Fusible plugs
in top, bottom, or valve melt at 98-107°C (208-224°F). Do not discharge at pressures above
15 psig (103 kPa). pressures above 15 psig (103 kPa). Self-contained breathing apparatus
may be required by rescue workers.
Inhalation: : Asphyxiant. Effects are due to lack of oxygen. Moderate concentrations may cause
headache, drowsiness, dizziness, excitation, excess salivation, nausea, vomiting, and
unconciousness. The vapor from a liquid release may also cause in-coordination, abdominal
pain. Effects may be delayed.Lack of oxygen can kill.
Skin Contact : No harm expected from vapor. Liquid (acetone) may cause frostbite..
Swallowing : An unlikely route of exposure, but frostbite of the lips and mouth may result from contact with
the liquid. If swallowed, the liquid may cause nausea.
Eye Contact : Vapour containing acetone may cause irritation. Liquid (acetone) may cause irritation and
frosbite.
Effects of Repeated (Chronic) : NOTE: Acetylene cylinders are filled with a porous material containg acetone into which the
Overexposure acetylene is dissolved. ACGIH has established a TLV-TWA of 500 ppm for acetone and a
STEL of 750 ppm.
WORKING WITH WELDING AND CUTTING MAY CREATE ADDITIONAL HEALTH
HAZARDS. FUMES AND GASES can be dangerous to your health and may cause serious
lung disease.* Keep your head out of the fumes. Do not breathe fumes and gases caused by
the process. Use enough ventilation, local exhaust, or both to keep fumes and gases from
your breathing zone and the general area. The type and amount of fumes and gases depend
on the equipment and supplies used. Possibly dangerous materials may be found in fluxes,
coatings, gases, metals etc. Obtain a Material Safety Data Sheet (MSDS) for each material
used. Air samples can be used to find out what respiratory protection is needed. Short term
overexposure to fumes may result in discomfort such as dizziness, nausea, or dryness or
irritation of nose, throat, or eyes.
Other Effects of Overexposure : None known.
Medical Conditions Aggravated by
Overexposure : Repeated or prolonged exposure is not known to aggravate medical condition.

Potential Environmental Effects : None expected.

Aldakheel Industrial Gases Plants (DI GAS )

Medina K.S.A.
 Page Number
MATERIAL SAFETY DATA SHEET 1/5
Date: 28/10/2018

MSDS V1.1 Acetylene DG008G

4 FIRST AID MEASURES

Inhalation : Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
qualified personnel may give oxygen. Get medical attention immediately.
Skin Contact : Incase of contact, immediately flush skin with plenty of water. Remove contaminated
clothing and shoes. Cold water may be used. Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention.
Swallowing : If liquid is swallowed, immediately give two glasses of water and induce vomiting if victim is
conscious. Call a physician.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately flush eyes with
plenty of water for at least 15 minutes. Cold water may be used. See a physician, preferably
an ophthalmologist, immediately.
Notes to Physician : Aspirated acetone may cause severe lung damage. If a large quantity of material has been
swallowed, stomach contents should be evacuated quickly in a manner that avoids
aspiration. Otherwise, there is no specific antidote. Treatment of overexposure should be
directed at the control of symptoms and the clinical condition of the patient.

5 FIRE-FIGHTING MEASURES

Flammable class : Extremely flammable.

Extinguishing media
Suitable extinguishing media : All known extinguishants can be used.
Hazardous combustion products : Incomplete combustion may form carbon monoxide.
Protection of firefighters : DANGER! Flammable gas under pressure. Evacuate all personnel from danger area.
Immediately cool cylinders with water spray from maximum distance, taking care not to
extinguish flames. If flames are accidentally extinguished, explosive re-ignition may occur.
Use self-contained reathing apparatus. Remove ignition sources if without risk. Stop flow of
gas if without risk while continuing cooling water spray. Remove all cylinders from area of fire
if without risk. Allow fire to burn out.
Specific physical and chemical hazards : Heat of fire can build pressure in cylinder and cause it to rupture. Acetylene cylinders are
provided with pressure relief devices designed to vent contents when exposed to elevated
temperature. No part of a cylinder should be subjected to a temperature higher than 52°C
(125°F). If venting or leaking acetylene catches fire, do not extinguish flames. Flammable
vapors may spread from leak, creating an explosive reignition hazard. Vapors can be ignited
by pilot lights, other flames, smoking, sparks, heaters, electrical equipment, static discharge,
or other ignition sources at locations distant from product handling point. Explosive
atmospheres may linger. Before entering area, especially confined areas, check atmosphere
with an approved explosion meter.
Protective equipment and precautions : Firefighters should wear self-contained breathing apparatus and full fire-fighting turnout gear.
for firefighters

6 ACCIDENTAL RELEASE MEASURES

Personal precautions : Evacuate area. Wear self-contained breathing apparatus when entering unless atmosphere
. is proved to be safe. Ensure adequate air ventilation.
Environmental precautions : Try to stop release. Eliminate ignition sources.
Clean up methods : Ventilate area.

7 HANDLING AND STORAGE

Precautions to be taken in handling : Keep away from heat, sparks, and open flame. Use only spark-proof tools and explosion-
proof equipment. Never use acetylene at pressures exceeding 15 psig (103.5 kPa). Can
cause rapid suffocation due to oxygen deficiency. Close valve after each use; keep closed
even when empty. Arcs and sparks can ignite combustible materials. Prevent fires.

Aldakheel Industrial Gases Plants (DI GAS )

Medina K.S.A.
 Page Number
MATERIAL SAFETY DATA SHEET 1/5
Date: 28/10/2018

MSDS V1.1 Acetylene DG008G

7 HANDLING AND STORAGE (Continued)

Precautions to be taken in storage & use : Acetylene storage in excess of 2,500 cu ft (70.79 m3) is prohibited in buildings with other
occupancies. Store and use with adequate ventilation. Separate acetylene cylinders from
oxygen and other oxidizers by at least 20 ft i(6.1 m), or use a barricade of noncombustible
material. This barricade should be at least 5ft (1.53 m) high and have a fire resistance rating
of at least ½ hour. Post “No Smoking or Open Flames” signs in storage and use areas.
There must be no sources of ignition. All electrical equipment in storage areas must be
explosion-proof. Storage areas must meet national electric codes for Class 1 hazardous
areas. Store only where temperature will not exceed 52°C(125°F).

8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering controls : Use a local exhaust system, if necessary, to prevent oxygen deficiency and to keep
Local exhaust hazardous fumes and gases in the worker’s breathing zone below all applicable exposure
limits.
Mechanical (General) : General exhaust ventilation may be acceptable if it can maintain an adequate supply of air
and keep hazardous fumes and gases in the worker’s breathing zone below all applicable
exposure limits.
Special : None.
Other : None.
Personal protective equipment
Skin Protection : Wear work gloves when handling cylinders; welding gloves for welding and cutting.
Eye/Face Protection : Wear goggles with filter lenses. Provide protective screens and goggles, if necessary, to
protect others.
Respiratory Protection : Use air-purifying or air-supplied respirators, as appropriate, where local or general exhaust
ventilation is inadequate. Adequate ventilation must keep worker exposure below all
applicable limits for fumes, gases, and other by-products of welding with acetylene.

Other Protective Equipment : As needed, wear hand, head, and body protection, which help to prevent injury from
radiation and sparks. At a minimum, this includes welder’s gloves and protective goggles,
and may include arm protectors, aprons, hats, and shoulder protection, as well as
substantial clothing. Regardless of protective equipment, never touch live electrical parts.

9 PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Colorless gas.
Odor : Acetylene of 100% purity is odorless, but commercial acetylene has a distinctive, garlic-like
odor.
Odor Thresold : Not available.
Physical State : Gas at normal temperature and pressure
pH : Not applicable.
Melting Point at 10 psig (170 kPa abs) : -82.2°C (116°F)
Boiling Point at 10 psig (170 kPa abs) : -75.2°C (-103.4°F)
Evaporation Rate (Butyl Acetate = 1) : Not applicable.
Flammability : Flammable.
Flammable Limits In Air, % by volume: : Lower 2.5% Upper 100%
Vapor Pressure at 21.1°C (70°F) : 649.6 psia (4479 kPa abs)*
Vapor Density at 0°C (32°F) : 0.00117 g/ml
Specific Gravity (H2O = 1) : Not applicable.
Molecular Weight : 26.04 g/mole
Molecular Formula : C2H2

Aldakheel Industrial Gases Plants (DI GAS )

Medina K.S.A.
 Page Number
MATERIAL SAFETY DATA SHEET 1/5
Date: 28/10/2018

MSDS V1.1 Acetylene DG008G

10 RAW MATERIALS INFORMATION

COMMODITY SYNONYM FORMULA

Calcium Carbide CALCIUM CARBIDE CaC2
ITEM MEASUITE STANDARD RESULT
H2S % (v/v) 0.12< 0.08
PH3 % (v/v) 0.08< 0.06
Gas Yield L/KG 285-295 295
Size MM 25-50 25-50

11 STABILITY AND REACTIVITY

Chemical Stability : Unstable. Stable.

Acetylene is stable as shipped. Avoid use at pressures above 15 psig (103kPa).
Conditions to Avoid : Elevated temperature and pressure and/or the presence of a catalyst.
Incompatible Materials : Copper, silver, mercury, or their alloys; oxidizing agents; acids; halogens; moisture.
Hazardous Decomposition Products : Thermal decomposition or burning may produce CO/CO2H2. The welding and cutting
process may form reaction products such as CO and CO2. Other decomposition products of
normal operation originate from the volatilization, reaction, or oxidation of the material being
worked.
Possible Of Hazardous Reactions : May Occur. Will Not Occur.
Fire or explosion may result from use at elevated temperatures and pressures or from use
with incompatible materials.

12 TOXICOLOGICAL INFORMATION

Acute Dose Effect : No known effects from acetylene gas. The welding process may generate hazardous fumes
and gases.

13 ECOLOGICAL INFORMATION

Ecotoxicity : No adverse ecological effects expected.

Other Adverse Effects : None known. Acetylene does not contain any Class I or Class II ozone-depleting chemicals.

14 DISPOSAL CONSIDERATION

Waste Disposal Method : Do not attempt to dispose of residual or unused quantities. Return cylinder to DIGAS.
15 TRANSPORT INFORMATION

Transport Information : Avoid transport on vehicles where the load space is not separated from the driver's
: compartment.
Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in
the event
: Before of an accident
transporting or an
product emergency.
containers:
- Ensure that containers are firmly secured.
- Ensure cylinder valve is closed and not leaking.
- Ensure valve outlet cap nut or plug (where provided) is correctly fitted.
- Ensure valve protection device (where provided) is correctly fitted.
- Ensure there is adequate ventilation.
- Compliance with applicable regulations.

Aldakheel Industrial Gases Plants (DI GAS )

Medina K.S.A.
 Page Number
MATERIAL SAFETY DATA SHEET 1/5
Date: 28/10/2018

MSDS V1.1 Acetylene DG008G

16 OTHER INFORMATION

Ensure all national/local regulations are observed.

Ensure operators understand the flammability hazard.
The hazard of asphyxiation is often overlooked and must be stressed during operator training.

FUMES AND GASES can be dangerous to your health and may cause serious lung disease. Keep your head out of fumes. Do
not breathe fumes and gases. Use enough ventilation, local exhaust, or both to keep fumes and gases from your breathing zone
and the general area. Short-term overexposure to fumes may cause dizziness, nausea, and dryness or irritation of the nose,
throat, and eyes or may cause other similar discomfort.
HAZARD RATING SYSTEMS:

S: NFPA Ratings: HMIS Ratings:

Health =1 Health =2
Flammability =4 Flammability =4
Instability =3 Physical Hazard =2
Special = None

STANDARD VALVE CONNECTIONS:

THREADED : The CGA-300 connection is standard for cylinders.

PIN-INDEX YOKE : Not applicable

Use the proper CGA connections. DO NOT USE ADAPTERS.

This Material Safety Data Sheet has been established for the best knowledge of DIGAS.

Details given in this document are believed to be correct at the best of DIGAS knowledge. Whilst proper care has been taken in
the preparation of this document, no liability for injury or damage resulting from its use can be accepted.

End of Documents

Aldakheel Industrial Gases Plants (DI GAS )

Medina K.S.A.