Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Jr.Super60(Incoming)_NUCLEUS BT JEE-ADV-2022_P1 Date: 20-04-2025
Time: 09.00Am to 12.00Pm WTA-02 Max. Marks: 180

KEY SHEET
MATHEMATICS
1 4 2 3 3 8 4 2 5 7 6 0

7 2 8 25 9 BD 10 AC 11 ABC 12 AB

13 ABC 14 BC 15 A 16 C 17 A 18 A

PHYSICS

19 120 20 24 21 9 22 100 23 60 24 3

25 1 26 118.5 27 CD 28 AB 29 AC 30 AC

31 BCD 32 AD 33 A 34 D 35 C 36 B

CHEMISTRY
0.09- 65.9-
37 38 24 39 3 40 90 41 3.24 42
0.1 67.1
43 0.5 44 80 45 AC 46 D 47 ABC 48 ABC

49 ABCD 50 ABCD 51 A 52 C 53 A 54 A
 Sri Chaitanya IIT Academy 20-04-2025_Jr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2022-P1)_WTA-02_Key & Sol’s

SOLUTIONS
MATHEMATICS
1. Conceptual
2. Conceptual
3. Let 2 x /4  t
 3t 2  7t  20  0
5
 t  4 or t   (rejected)
3
 x 8
4. Find critical points
x  1 and 2 x 1  0
 x  1 and x = 0
So critical points are x = 0 and x = –1
Consider following cases:
x  1 …… (i)


2    2 x   2 x 1  1
 x1

2    2 x  2 x  2
 x1

 2x1  2
 x  1  1
 x  2
As x  2 satisfies (i), one solution x  2
 1  x  0 …… (ii)


2 x1  2 x   2 x  1  1 
 2 x1  2
 x 11
 x0
As x = 0 satisfies (ii), second solution is x = 0
x0 …… (iii)


2 x1  2 x  2 x  1  1 
 2 x1  2 x1
 Identify in x, i.e., true for all x  R
5. Modulus property

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1
 
1/64
6. y 8  3y4  4 k 2
y
y  x 1
y  x 2  3x  2

x
0 1 2
1
7.
8. Rationalization
9. 4  x  2  3  4
 1  x  2  7
 7  x  2  7
 9  x  5
2
 x2 x 6 
10.  3  3   0

 x 2  x  6  x  2,3
11. (A) y  4

(B) z   x  2 y  3  2 y  2  4  4
2 2

2
(C) x  6 x  5  0  1  x  5; 1  x  5 or 5  x  1
1
(D) Positive values of a are 1 and
2
12. a  b  a  b  ab  0
10  4 x x 1

 8  2 x 1  x  2
13. f  x    4 2 x3

 2 x  2 3  x  4

4 x  10 x4
f  x  has minimum value 4 is [2, 3]
14. Conceptual
15. 
(A) x 1  x 2  x  1  x 2  x  1 
 x 1  1
 1  x 1  1

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 Sri Chaitanya IIT Academy 20-04-2025_Jr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2022-P1)_WTA-02_Key & Sol’s

 
2
(B) x 2 1  2 x 1
2

 
 x2  2 x  2  x2  2 x  0
 
(C)) x 1  x 2  x  1  1  x

Take cases x  1 and x  1

16. x 2  a x  1  0 --------

a  a 2  4
x
2
17. Conceptual
18. Conceptual
PHYSICS
19. As we know by vector addition law
  
A B  R

Here we have drawn right angle triangle, as it is mentioned, resultant is perpendicular to

smaller vector.
 
Also, Given if A  A , then B  2 A
 
Angle between A and B is  , a for calculating angle between vectors they should be
joined tail to tail or head to head.
Using pythagorous theorem in above triangle
R 2  A2  B 2
R 2  B 2  A2

Now by vector addition law.

R 2  A2  B 2  2 AB cos 
B 2  A2  A2  B 2  2 AB cos 

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 Sri Chaitanya IIT Academy 20-04-2025_Jr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2022-P1)_WTA-02_Key & Sol’s

2 A2  2 AB cos 
A
cos  
B
1
cos  
2
  120
20. We know,
        
 OA  OB  OC  OD  OE  OF  OG  OH  0
By triangle law of vector addition, we can write
     
AB  AO  OB ; AC  AO  OC
     
AD  AO  OD ; AE  AO  OE
     
AF  AO  OF ; AG  AO  OG
  
AH  AO  OH
Now,
      
AB  AC  AD  AE  AF  AG  AH
       
 
= 7 AO  OB  OC  OD  OE  OF  OG  OH
  
 
= 7 AO  0  OA
 

= 7AO  AO


= 8 AO  8 2i  3j  4
k 

21.
 Angle of velocity with shoreline is 60
 Component of v is u cos 

  
 18cos 60 
 

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 Sri Chaitanya IIT Academy 20-04-2025_Jr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2022-P1)_WTA-02_Key & Sol’s
1
 18  9 km / hr
2

22. F  4i  j  3
k


Displacement = 14  3i  13  2j  9  6
k 
= 11i  11j  15
k
 
Work done  F  d
 4 11  111  315  100J
   
  
23. a  2b  5a  4b  0 [given]
       
5a  a  10a  b  4a  b  8b  b  0
 
5a 2  6a  b  8b2  0
 
Given a  b  1
Unit vector
 a 2  b2  1
 
5  6a  b  8  0
 
6a  b  3
  3
ab 
6
3 1
a b cos   
6 2
1
cos  
2
  60
 
24. Let A i  j  k , B i  j  
k
 
A B
cos  
A B
 
A  B  11  11  11
 1

A  12  12  12

= 3
B 3

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 Sri Chaitanya IIT Academy 20-04-2025_Jr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2022-P1)_WTA-02_Key & Sol’s
1 1
cos   
 3 3 3

 1
  cos1 
 3 
 a a
25. r g  i   k
2 2
 a a
r H  j   k
2 2
  a
r H  r g  j i
2
 
   
26. A1  3 A2  5 A1  A2  5

   2  2  
A1  A2  A1  A2  2 A1 A2 cos 

5  9  25  2  3 5cos
9 3
cos    
2  3 5 10
   
 
2 A1  3 A2  3 A1  2 A2 
 2      2
= 6 A1  9 A1  A2  4 A1 A2  6 A2
 3
54  5  3 5   6  25
 10 
45
= 54 150   118.5
2
27. For equilibrium resultant of four forces should be zero.
(C) It is possible that two forces is one plane and other two forces is other plane but there
resultant can cancel out.
(D) If 3 are in one plane than 4th must be in same place otherwise 4th will not be cancelled
out by anyone.
28. We know that resultant lies between
     
A  B  AB  A  B
(A) Rmax  2  13  15
11  R  15
Rmin  13  2  11
(B) Rmax  5  16  21

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 Sri Chaitanya IIT Academy 20-04-2025_Jr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2022-P1)_WTA-02_Key & Sol’s
11  R  21
Rmin  16  5  11
(C) Rmax  8  7  15
1  R  15
Rmin  8  7  1
(D) Rmax  100  105  205
5  R  205

29.
30. Conceptual
 
31. A B  AB sin  and sin  lies between 1  sin   1
 
 A B  AB when   90
 
A B  AB when 1  sin   0
 
A B  0 when   0 and 

32. Since, the vector i  xj  3k is doubled in magnitude, then it becomes 4i  4 x  2 j  2k

2 i  xj  3k  4i  4 x  2 j  2k

2 1  x 2  9  16  4 x  22  4

40  4 x 2  20  4 x  22

3x 2  4 x  4  0
 x  23x  2  0
2
x  2, 
3
  
33. In PQR PQ  QR  PR
  
QR  PR  PQ
  
QR  B  A
   
 
Also PS  2 QR  2 B  2 A

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 Sri Chaitanya IIT Academy 20-04-2025_Jr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2022-P1)_WTA-02_Key & Sol’s
In PST we have
     
PS  ST  PT ST   AB   A
   
PT  2 B  2 A  A
  
PT  3 A  2 B
In PRS
  
PR  RS  PS
   
B  RS  2 B  2 A
  
RS  B  2 A
  
Also TS  AB  A

34.
We can write co–ordinates of all points.

(A) AF  ai aj  ak


A.i  A i cos 
a
cos  
3a
a
cos  
3
 1 
  cos1 
 3 

(B) DG  ai aj  ak

   
AF  DG  AG  DG cos 

a2  a2  a2   3a  
3a cos 
1
cos  
3

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 Sri Chaitanya IIT Academy 20-04-2025_Jr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2022-P1)_WTA-02_Key & Sol’s
1
  cos1 
 3 

(C) AE  aj  ak

AG  ai aj
   
AE  AG  AE  AG cos 

a2
cos  
 
2a  2a 
1
cos  
2
1
  cos1 
 2 

  60
35. Conceptual
36. Conceptual

CHEMISTRY
37. Let ‘x’ gas be the mass of methance after 16 min.
16 gms CH 4  4 gms of H
x x
x gm CH 4   4  g of H
16 4
x
 N H atoms.
4 A
6N A x
No. of H atoms left after 16 min   N
 2 8
4 A
46 3
x 
2  2  2 32
2 5

4 40 / AX
38.   Atomic mass of X, AX  24
9 60 / 16
1.28
39. Moles of A-atoms =  0.02
64
3.0  10 23
Moles of B-atoms =  0.5
6.0  10 23
Moles of C-atoms = 0.04
From the given atomic ratio, A and C are L.R.
Maximum mass of AB6C3 formed = 1.28 + (0.02  6  9) + (0.04  16) = 3.0 g
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2 1021
3 10
21
40.  45   M Q  0.6  M Q  90
6 10 23
6 10 23
41. C8 H18  25 O2  8CO2  9H 2O
2
8  44 g 9  18 g
9  18
 7.04 g  7.04  3.24 g
8  44
42. On heating Na 2CO 3 and NaHCO 3 , Na 2CO 3 remains unchanged while NaHCO 3
changes into Na 2CO 3 , CO 2 and H 2O . The loss in mass is due to removal of CO 2 and
H 2 O which escape out on heating.
 Mass of Na 2CO 3 in the product  2.00  0.248  1.752g
Let the mass of Na 2CO 3 in the mixture be x g.
 Mass of NaHCO3   2.00  x  g
Since Na 2CO 3 in the products contains x g of unchanged reactant Na 2CO 3 and rest
produced from NaHCO3 ,
The mass of Na 2CO3 produced by NaHCO 3 only  1.752  x  g .
Now, we have,
NaHCO3  Na 2CO3   H 2O  CO 2  
 2.0  x  g 1.752  x  g
Applying Principle of conservation of atom for Na atoms,
Moles of Na in NaHCO 3 = moles of Na in Na 2CO 3
1  moles of NaHCO 3 = 2  moles of Na 2CO3

2.0  x 1.752  x  NaHCO3  84 

 2  
84 106  Na 2CO3  106 
82
x  1.328g
62
1.328
 % of Na 2CO3   100  66.4%
2.0
43. 2 KClO3  2 KCl  3O2
C4 H 8  6O2  4CO2  4 H 2O
2 mole of KClO3  3 mole of O2  0.5 mole of C4 H 8
20
44. 20 mL   100  80%
25
0.9
45. Mole of H-atoms in glucose =  12 = 0.06
180

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0.48
Mole of H-atoms in hydrazine =  4 = 0.06
32
0.17
3
Mole of H-atoms in ammonia = 17 = 0.03
0.30
Mole of H-atoms in ethane =  6 = 0.06
30
0.03
Mole of H-atoms in hydrogen = = 0.03
1
46. It is the sum of masses (in g) of all fundamental particles present in the atom
47. 2 NH 3  N 2  3H 2 .
2 moles of NH 3 produce 1 mole of N 2  3 moles of H 2  4 moles of gas.
Option A: Initial moles = 2, final moles = 4. At constant T, P  n (closed container, V
constant). Pressure doubles. Correct.
Option B: Moles increase from 2 to 4, factor of 2. Correct.
Option C: Initial molar mass of NH 3  17 g / mol . Final mixture: 1 mole N 2  28 g / mol  ,
3 moles H 2 (2 g/mol). Average molar mass = (1  28 + 3  2)/(1 + 3) = 34/4 = 8.5
g/mol. Decreases (17 to 8.5). Correct.
Option D: Volume  moles (same T, P). Total moles = 4, moles of N 2 = 1. Volume of
N 2 = 1/4 of total, not 1/3. Incorrect.
48. CH 4  2O2  CO2  2 H 2O
49. Reaction: MgCO3  2 HCl  MgCl2  CO2  H 2O .
Option A: 1 mole of MgCO3 produces 1 mole of CO2 . Volume of CO2  moles of
MgCO3  purity. Correct.
Option B: 1 mole of MgCO3 produces 1 mole of MgCl2 . Mass of MgCl2  mass of
MgCO3 . Correct.
Option C: No CO2 means no MgCO3 reacted (since inert impurity doesn’t produce
CO2 ). Correct.
Option D: Residue after reaction with HCl = inert impurity ( MgCl2 is soluble). Mass of
residue  % impurity. Correct.
50. Parallel: X  Y (70 % ), X  Z (30 % ). Sequential: Y  W (100 % ).
1 mole of X: Y = 0.7 moles, Z = 0.3 moles. Y → W: 0.7 moles of Y  0.7 moles of W.
Final mixture: W = 0.7 moles, Z = 0.3 moles (Y fully consumed).
Option A: Total moles = 0.7 (W) + 0.3 (Z) = 1. Mole fraction of W = 0.7/1 = 0.7.
Correct.
Option B: Total moles of products = 0.7 + 0.3 = 1 = moles of X. Correct.
Option C: 1 mole of X  0.3 moles of Z. Correct.

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 Sri Chaitanya IIT Academy 20-04-2025_Jr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2022-P1)_WTA-02_Key & Sol’s
Option D: Y  W has 100 % yield, so Y is completely consumed. Correct.


51. A) H 2O H : 50%1 H ,50% 2 H ; O :100%16 O : 
Average molar mass of H = 0.5  1 + 0.5  2 = 1.5 g/mol.
Molar mass of H₂O = 2  1.5 + 16 = 3 + 16 = 19 g/mol. Matches P.


B) CO2 C : 50%12 C ,50%13 C ; O : 50%16 O,50%18 O : 
Average molar mass of C = 0.5  12 + 0.5  13 = 12.5 g/mol.
Average molar mass of O = 0.5  16 + 0.5  18 = 17 g/mol.
Molar mass of CO₂ = 12.5 + 2  17 = 12.5 + 34 = 46.5 g/mol. Not P.
Mass of O = 2  17 = 34 g. Q.


C) NH 3 N :100%14 N ; H :100% 2 H : 
Molar mass = 14 + 3  2 = 14 + 6 = 20 g/mol. Not P.
No O atoms. Not Q.
Total atoms = 1 + 3 = 4 per molecule, so 4  N a . Matches R.
Mass of H = 3 × 2 = 6 g. Matches S.
Matches: R, S.


D) CH 4 C :100%12 C ; H : 25%1 H ,75% 2 H : 
Average molar mass of H = 0.25  1 + 0.75  2 = 0.25 + 1.5 = 1.75 g/mol.
Molar mass of CH 4 = 12 + 4  1.75 = 12 + 7 = 19 g/mol. Matches P.
Total atoms = 1 + 4 = 5 per molecule, so 5  N a . Not R.
Mass of H = 4  1.75 = 7 g. Not S.
Matches: P.
52. Conceptual stoichiometry
53. A) A (100 % pure)  B (100 % )  C (50 % ):
100 g A = 1 mole. B = 1 mole. C = 1  0.5 = 0.5 moles.
Mass of C = 0.5  50 = 25 g. Matches P.
Moles of C = 0.5. Not R, not S.
Matches: P.
B) A (80 % pure)  B (50 % to C, 50 % to D)  C (100 % ):
Pure A = 0.8  100 g = 80 g = 0.8 moles. B = 0.8  0.5 = 0.4 moles. C = 0.4 moles.
Mass of C = 0.4  50 = 20 g. Matches Q.
Moles of C = 0.4. Not R, not S.
Matches: Q.
C) A (100 % pure)  B (60 % )  C (50 % to C, 50 % to E):
100 g A = 1 mole. B = 1  0.6 = 0.6 moles. C = 0.6  0.5 = 0.3 moles.

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 Sri Chaitanya IIT Academy 20-04-2025_Jr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2022-P1)_WTA-02_Key & Sol’s
Mass of C = 0.3  50 = 15 g. Not P, not Q.
Moles of C = 0.3. Matches R.
Matches: R.
D) A (50 % pure)  B (50 % )  C (80 % ):
Pure A = 0.5  100 g = 50 g = 0.5 moles. B = 0.5  0.5 = 0.25 moles. C = 0.25  0.8 =
0.2 moles.
Mass of C = 0.2  50 = 10 g. Not P, not Q.
Moles of C = 0.2. Matches S.
Matches: S.
54. CH 4 10mL  O2  30mL sparked, then KOH:
Reaction: CH 4  2O2  CO2  2 H 2O  l  .
Initial volume = 40 mL. 10 mL CH 4 reacts with 20 mL O2 , producing 10 mL CO2 ( H 2O
condenses).
After sparking: 10 mL CO2 + 10 mL excess O2 = 20 mL.
After KOH (absorbs CO2 ): 10 mL O2 remains. Matches P.
CO (20 mL) + O2 (20 mL) sparked, then KOH:
Reaction: 2CO + O2  2 CO2 .
Initial volume = 40 mL. 20 mL CO reacts with 10 mL O2 , producing 20 mL CO2 , 10 mL
O2 remains.
After sparking: 20 mL CO2 + 10 mL O2 = 30 mL.
After KOH: All CO2 absorbed, 10 mL O2 remains.
H 2 (15 mL) + CO2 (15 mL) + O2 (30 mL) sparked:
Reaction: 2 H 2  O2  2 H 2O  l  , CO2 inert.
Initial volume = 60 mL. 15 mL H 2 reacts with 7.5 mL O2 , leaving 22.5 mL O2 + 15 mL
CO2 .
After sparking: 15 mL CO2 + 22.5 mL O2 = 37.5 mL. No absorption specified, but
"sparking only" implies 15 mL H 2 consumed
C2 H 2 (10 mL) + O2 (40 mL) sparked, then KOH:
Reaction: 2C2 H 2  5O2  4CO2  2 H 2O  l  .
Initial volume = 50 mL. 10 mL C2 H 2 reacts with 25 mL O2 , producing 20 mL CO2 .
After sparking: 20 mL CO2 + 15 mL O2 = 35 mL.
After KOH: 20 mL CO2 absorbed, volume contracts by 20 mL, leaving 15 mL O2 .
Matches S.

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