(0999DJA161103230020) Test Pattern

DISTANCE LEARNING PROGRAMME JEE (Advanced)

MAJOR TEST
(Academic Session : 2023 - 2024)
25-02-2024

JEE(Main + Advanced) : LEADER TEST SERIES / JOINT PACKAGE COURSE

Test Type : Full Syllabus
ANSWER KEY
PART-1 : PHYSICS
Q. 1 2 3 4
SECTION-I (i)
A. D B D D
Q. 5 6 7
SECTION-I (ii)
A. B A,C,D B,C
Q. 8 9 10 11
SECTION-I (iii)
A. C A B A
Q. 1 2 3 4 5 6
SECTION-II
A. 3 3 5 6 5 6

PART-2 : CHEMISTRY
Q. 1 2 3 4
SECTION-I (i)
A. C B B A
Q. 5 6 7
SECTION-I (ii)
A. A,B,C,D A,B,C A,C
Q. 8 9 10 11
SECTION-I (iii)
A. B C D C
Q. 1 2 3 4 5 6
SECTION-II
A. 30 3 390 10 741 108

PART-3 : MATHEMATICS
Q. 1 2 3 4
SECTION-I (i)
A. A D A D
Q. 5 6 7
SECTION-I (ii)
A. A,B B,C A,B,D
Q. 8 9 10 11
SECTION-I (iii)
A. C A B C
Q. 1 2 3 4 5 6
SECTION-II
A. 2 2 0 7 1540 3

HINT – SHEET
PART-1 : PHYSICS
SECTION-I (i)
1. Ans ( D )
mv2
mg – N =
r

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2. Ans ( B ) PART-1 : PHYSICS
SECTION-I (ii)
5. Ans ( B )

→a 1 = GM1 M2 /M1
R2

→a 2 = − GM1 M2 /M2
R2
→ → →
acceleation of M1 w.r.t. M2 →vCM = m1 u1 + m2 u2
m1 + m2
→a rel. = →a 1 − →a 2 u1 & u2 have same sign so
G(M1 + M2 ) GM
= = . vCOM will never be zero.
R2 R2
3. Ans ( D ) 6. Ans ( A,C,D )
h Percentage error in
λ=
p dh 0.3
h= × 100 = × 100 = 0.6%
h 46.2
λp pe mv
λe
=
pp
= e e
mp v p
Percentage error in t = 0.1 × 100 = 6.25%
1.6

m ve
Percentage error in
2= e ( )
mp 4ve
g = (% error in h) + 2× (% error in t)
me dg
∴ mp = = 13.1 %
8 g
g = 36 ± 5 ft/s2
4. Ans ( D )
7. Ans ( B,C )
ϕ = (0.4t) ( π (0.2)2
For siphon to work,
dϕ
Σ= = π(0.2)2 (0.4) V 1 2 1
dt P0 + ρg(0) + ρv = P + ρg(5 + H) + ρv2
2 2
Σ π(0.2)2 (0.4) 2
i= = = 0.4π = πA P = P0 − ρg(5 + H) ⩾ 0
R 0.04 5
P0 − ρg(5) 105 − 0.5 × 105
ring will be in compressive stress. H⩽ = m
ρg 104
H ⩽ 5m
1 1
P0 + ρg(5) + ρ(0)2 = P0 + ρg(0) + ρv2
2 2
v = √2g(5) = 10 m/s (Only if fluid is able to flow)

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PART-1 : PHYSICS 10. Ans ( B )
SECTION-I (iii)
8. Ans ( C )
⇒ For option (P) temperature is minimum
λD
hence λ m will be maximum β = ⇒β will
d
also be maximum
⇒ For option (Q) T = 3000 E −E
−3
On solving by KVP we get i1 = i2 =
b 2.9 × 10 R R
λm = =
T 30000 and i3 = E
2.9 R
λm = × 10−6 i1 – i3 = 0
3
= 0.96 × 10 – 6 i1 − i2 =
2E
= 966.6 nm R
E 4
Reading of ammeter A1 is =
P3000 = 6A (3000)4 R 3
2E 8
P6000 = 6A (6000)4 Reading of ammeter A2 is =
4 R 3
P3000 1
=( ) =
1 Reading of ammeter S3 is 0
P6000 2 16 and Δ VAB = 4V
1
P3000 = P6000 11. Ans ( A )
16
Q–4 2u2 sin 53∘ cos 53∘
(P) Range =
⇒ For (R) T = 5000 K g

2.9 × 10−3 & u = 25 m/s

λm = = 0.58 × 10−6
5 × 103 u2 sin2 θ
= 580 nm (Q) Hmax =
2g
Visible to human eyes 2
(25) (sin 53)
2
= = 20
R–2 2 × 10
⇒ For (S) T = 10,000 → maximum At 3 th of Hmax speed of particle is given by
4
Hence (3) is wrong as it has minimum ( λ m)
V2 = 400 – 2 × 10 × ( 3 × 20) = 100
9. Ans ( A ) 4

(P) Velocity of fish in air = 4 × 3 = 3 ↑ ­ V = 10 m/s

4
Velocity of fish w.r.t bird = 3 + 6 = 9 ↑ ­ 2V 2 × 10
Time difference = = = 2 sec
g 10
(Q) Velocity of image of fish after reflection
3 (R) T = u = 25 = 25
from mirror in air = 4 × = 3↓ g sin θ 10 × 4/5 8
4
w.r.t bird = –3+6=3↑
(R) Velocity of bird in water = 6 × 4 = 8 ↓
3
w.r.t fish = 8 + 4 = 12↓
(S) Velocity of bird in water after reflection
from mirror = 8 ↑
w.r.t fish = 8 – 4 = 4 ↑ (S) atangential = gsin37° = 6
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PART-1 : PHYSICS 5. Ans ( 5 )
SECTION-II
1. Ans ( 3 )
1mm m1 = 2kg ; m2 = 3kg
Least count = = 0.1 mm; Zero error
10
= – (10 – 6) × 0.1 = – 0.4 mm; k = 300 N/m
Reading = 6 + 5 × (0.1) – ( – 0.4) = 6.9 mm
Time period of oscillation of spring
2. Ans ( 3 )
μ m1 m2
21 ∈0 A T = 2π√ , where μ=
Ceq = × k m1 + m2
5 d
2×3 6 6
μ= = Kg. So T = 2μ√
2+3 5 5 × 300
6 × 10 2
T = 2√ =
5 × 300 5

So oscillations in one second = 5

2
3. Ans ( 5 )
for two second = 5 × 2 = 5
1 2 1 2
= (0.5) =
fL 25 25
6. Ans ( 6 )
1 1 2 2 2 x
dv v
= − = − ∫ P dx = ∫ mv dx = ∫ mv2 dv
(feq )m fm fL −25 25 0 dt 0
x
1 −4 mv3
= ∴∫ (6x2 + 4x)dx =
(feq )m 25 0 3

25 v = 6m/s
ℓ = 2|(feq)m| =
2
2ℓ
PART-2 : CHEMISTRY
=5
5 SECTION-I (i)

4. Ans ( 6 ) 1. Ans ( C )
(A) PCl3 + 3HOH → H3PO3 (Phophorous Acid) +
3HCl
(B) NCl3 + 3HOH → NH3(ammonia) +
1 1
KE = MVc2 + Ic ω2 3HOCl(hypochlorous acid)
2 2
1 1 2(6)
2
2
2 (C) SO2Cl2 + 2HOH → H2SO4 + 2HCl
= × 2 × 22 + ( )( )
2 2 2 6 (Sulphuric acid)
= 4 + 2 = 6 Joule (D) 2NF3 + 3HOH → N2O3 + 6HF
Answer would be (3) i.e. sulphuric acid.

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2. Ans ( B ) 7. Ans ( A,C )
∵ P ∝ T2
2
P1 T 1
=( 1) =
P2 T2 4
T2 P1
Δ S = nCpln( ) + nRln ( )
T1 P2
5 1
=1× Rln2 + 1 × R ln ( )
2 4
3. Ans ( B ) PART-2 : CHEMISTRY
SECTION-I (iii)
Br2 Sn/HCl 8. Ans ( B )
−−−−→ −−−−−→
F eBr3 (1) NH4OH + HCl → NH4Cl + H2O
0.1 0.1 – –
0 0 0.1M
KW × C 10−14
NaNO2 CuBr (H+) = √ =√ × 10−1 = 10−5
−−−−→ −−−→ Kb 10−5
HCl HBr (2) CH3COONa + HCl → CH3COOH + NaCl
0.1 0.1 – –

4. Ans ( A ) 0 0 0.1M
Chromium (III) salt Cr2O3 Cr2O3 [H+] = √ Ka . C = √10−5 × 10−1 = 10−3
pH = 3
Borax B2O3 + NaBO2
2Cr2O3 + 6B2O3 → 4Cr(BO2)3 (3) pH = pKa2 + pKa3 = 6 + 10 = 8
2 2
(4) H2CO3 + NaOH → NaHCO3 + H2O
So correct answer is option(1)
A a/2 –
PART-2 : CHEMISTRY
a/2 0 a/2
SECTION-I (ii) pH = pka1 = 5
5. Ans ( A,B,C,D ) (5) Mg(OH)2(s) ⇌ Mg2+(aq.) + 2OH – (aq.)
1 (s) (s) 2s
Cell constant = , so it is independent of
A
solution. Ksp = 4s3
6. Ans ( A,B,C ) 5 × 10 – 16 = 4 s3
5
O−2 → Superoxide s3 = × 10−16 = (1.25 × 10−16 )
4
ligand ion = (125 × 10 – 18)1/3
(Predicted on the basis of given t2g6 configuration) = 5 × 10 – 6
(OH – ) = 2s = 10 – 5
pOH = 5
pH = 9
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10. Ans ( D ) 3. Ans ( 390 )
(P) Pinnacol – Pinnacol. The possible structure of ‘X’ and reaction
(Q) Diazonium salt – Rearrange.
with is given below :
(R) Pinnacol – Pinnacolone.
(S) Carbocation – Rearrange.
11. Ans ( C )
Theory based.
PART-2 : CHEMISTRY Molecular weight of CH3CO–group = 43.
SECTION-II Since ‘H’ is replaced by –COCH3, therefore,
1. Ans ( 30 ) increase in weight per COCH3 is 42.
h Molecular weight of glucose penta–acetate
mΔV =
λ
= 180 + 5 × 42
4 × 10−3 6.6 × 10−34
× ΔV =
6.01 × 1023 330 × 10−7 = 180 + 210 = 390 g mol–1.

ΔV ≅30 cm/ sec 4. Ans ( 10 )

2. Ans ( 3 )
BrF3 , XeF2 , CH3+

5. Ans ( 741 )
Δ H = Δ U + Δ ngRT
1 8.314
= – 742.24 + × × 298
2 1000
= – 741 kJ/mol
Hence answer is (741)

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6. Ans ( 108 ) 3. Ans ( A )
Given t2 = 54 min T1/2 = 18 min 2x2 + 6yx + 5y2 – 1 = 0
x∈R∴D≥0
A B 36y2 – 8(5y2 – 1) ≥ 0
8 – 4y2 ≥ 0
t = 0 'x' M t = 0 'x' M
y2 ≤ 2
⇒ To calculate : [At] = 16 × [Bt] ....(1) time = ? 4. Ans ( D )
A0 3 – 2k – 2 = 0
⇒ For I order kinetic : [At ] = for continuity for differentiability
(2)n
ƒ'(1 – ) = ƒ'(1+)
n → no of Half lives
1 = – 2k
1
⇒ Now from the relation (1) k=−
2
∴ No value of k.
[At] = 16 × [Bt]
x x
⇒ n1
= × 16
(2) (2)n2

⇒ (2)n2 = (2)n1 × (2)4

t t
⇒ n2 = n1 + 4 ⇒ = +4
( t1/2 )2 ( t1/2 )1 PART-3 : MATHEMATICS
1 1 4 × 18 × 54 SECTION-I (ii)
⇒ t( − ) = 4 ⇒ t =
18 54 36
5. Ans ( A,B )
⇒ t = 108 min x
2
x ∫ et dt
PART-3 : MATHEMATICS 0 0
(A) Let ℓ = Lim ( )
x→0 −(ex − x − 1) 0
SECTION-I (i) x x
2 2
x ∫ et dt ∫ et dt
1. Ans ( A ) 0 0 0
n
= Lim = −2 Lim ( )
x→0
−x2 ( ex −x−1 x→0 x 0
∵ ∑ n Cr (a)n−r (b)r = (a + b)n x2
)

r=0 2
ex
20
1
20−r
1
20 = −2 Lim = -2
∴ ∑
20
Cr ( + x) {− (x + 1)}r = { + x − (x + 1)} x→0 1
r=0
2 2

∴ The coefficient of x10 = 0 (B) 14x2 – 7xy + y2 = 2

2. Ans ( D ) dy 28x − 7y
= ....(1)
3 4 4 π dx 7x − 2y
(cot x) (cot x) = cot x = cot ( )>1
10
cot x + cot3 x tan x
–1 + tan−1 (
f(x) = π + tan (
1 − (cot x) (cot3 x)
)
1 − tan2 x
)

= π + tan – 1 (
tan x
2
) + tan−1 (
tan x
)
tan x − 1 1 − tan2 x

= π

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6. Ans ( B,C )
if x = 1 then 14 – 7y + y2 = 2
(A) g'(x) = f(x) ...(1)
2
⇒y – 7y + 12 = 0
tangent to y = f(x) : y – f(x1) = f'(x1)(x – x1) ...(2)
⇒y=3 or 4
tangent to y = g(x) : y – g(x1) = g'(x1)(x – x1) ...(3)
hence L (1, 3) and M (1, 4)
28 − 21 for (2) and (3), at y = 0
slope of tangent at L = =7;
7−6
28 − 28 f(x1 ) f ′ (x1 )
slope of tangent at M = =0 = ′
7−8 g(x1 ) g (x1 )
f ′ (x) g ′ (x)
equation of tangent at L and M are ⇒ =
f(x) g(x)

y – 3 = 7(x – 1) ⇒ y = 7x – 4 ⇒ ℓ nf(x) = ℓ n(g(x)) + ℓ nc

f(x)
and y – 4 = 0(x – 1) ⇒ y = 4 ⇒ =c
g(x)
8 1
hence N = ( , 4) ⇒ (C) put x = 0, we get c =
7 4
(C) If n is odd then graph of f (x) is a3 is the g(x)
⇒ f(x) =
4
only point where g(x) x
g ′ (x) = ⇒ g(x) = 4e
4 4

⇒ f(x) = ex/4
1
x2 + 4
(B) I=∫ dx
4 + 4ex/4
−1
f (x) has its minimum value
Apply king,
If n is even then graph of f (x) is From a2 to a3 1
x2 + 4
I=∫ dx
at all values of x, f (x) is minimum. 4 + 4e−x/4
−1
1
x2 + 4
Add 2I = ∫ dx
4
−1
13
⇒I =
12
(D) f'(x) = 2px + q
(C) h(x) = f(x) – g(x)
f(x2 ) − f(x1 )
f ′ (c) =
x2 − x1 h(x) = ex/4 – 4ex/4
(px22 + qx2 + r) − (px21 + qx1 + r)
2pc + q = 1
x2 − x1 h′ (x) = ex/4 [ − 1] (–ve)
x2 + x1 4
2pc + q = p ( ) + q
2 ∴ h(x) is decreasing
x1 + x2
c=
4
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7. Ans ( A,B,D ) PART-3 : MATHEMATICS
∵ |z| = 1 SECTION-I (iii)
8. Ans ( C )
⇒ z lies on a circle whose centre is at origin 2
e1/x − 1
2
e1/x − 1
2
e1/x − 1
(P) x→∞
lim = =
2 ( π2 − tan−1 (x2 )) 2cot−1 (x2 ) 2tan−1 ( 1
)

and radius = 1 2 1
x2

( e1/x − 1) ( )
x2 1
2π lim
⇒ x→∞ =
and ∵ arg(z – 1) = 2( 1
tan−1 ( 1 2
3 x2
)
x2
)

3
⇒ z lies on a ray emanating 64sin x. cos x
(Q) f (x) = ⇒ 64sin3 xcos3 x
sec2 x
from (1, 0) making an angle of 2π
with ƒ(x) = 8sin32x
3 ∴ ƒ(x)max = 8 at sin 2x = 1
positive real axis. 2
2 3
(R) ∫ [ (x − 1) tan(x − 1) − (x − 1) + 1] dx
0
or put x – 1 = t
1 1
2 3
∫ ( t tan t − t + 1) dt = ∫ dt = 2
−1 −1
(S) curve x2 – 2x + 1 – 2y2 = 2
⇒ (x – 1)2 – 2y2 = 2
(x − 1)2 y2
2π ⇒ − =1
∵ ∠ PQX= 2 1
3
∴ Radius of director circle is (2 – 1) = 1
⇒ ∠ PQO = π
3 9. Ans ( A )
and OP = OQ 2πα
i
Let z1 = e 30 ; α = 0, 1, ..., 29
⇒ triangle OPQ is equilateral 2πβ
i
z2 = e 42 ; β = 0, 1, ..., 41
⇒ OP = OQ = PQ ⇒ |z| = |z – 1| = 1 2πγ
i
and z3 = e 70 ; γ = 1, 2, ..., 69
⇒ (D) is correct β
If z1 = z2 ⇒ α =
30 42
and amp(z) = 60° ⇒ 7 α = 5 β ⇒ α = 0, 5, ..., 25
⇒ n(A ∩ B) = 6
1 + i √3
⇒ a = cos60° + isin60° = = −ω2 β γ
2 If z2 = z3 ⇒ = ⇒ 5β = 3γ
42 70
⇒ (B) is correct ⇒ β = 3, 6, ..., 39
⇒ n(B ∩ C) = 13
⇒ (C) is correct γ
If z3 = z1 ⇒ α = ⇒ 7α = 3γ
30 70
Now z2 = ω 4 = ω ⇒ z2 + z4 = – 1 ⇒ α = 3, 6, ..., 27
If z1 = z2 = z3 ⇒ α is a multiple of 3 as well
⇒ amp(z2 + z4) = π ⇒ (A) is correct. as 5.
⇒ α = 15
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10. Ans ( B ) 11. Ans ( C )
dy dy
(P) y−x = y2 + Δ 1 = Δ by C3 → C3 + C1, then C2 → C2 – 2C3
dx dx
dx dy Δ 2 = Δ 2 {determinant of cofactors}
=
(1 + x) y(1 − y)
Integrate both sides Δ3 = Δ
log|1 + x| = log|y| – log|1 – y| + logc
Δ4 = 9Δ
log|(1 + x)(1 – y)|= logcy
(x + 1)(1 – y) = cy PART-3 : MATHEMATICS
(Q) (2x – 10y3) dy + y = 0 SECTION-II
dx
dy dy
2x – 10y3 + y = 0 1. Ans ( 2 )
dx dx 2021
2xdy – 10y3dy + ydx = 0 I=∫ ( f ′ (x) + f ′ (−x)) (
1
+
1
) dx
x −x
(2021) + 1 (2021) +1
y dx = 10y3 – 2x 2021
0

dy
dx 2x f ′ (x) + f ′ (−x)) dx = (f (x) − f (−x))2021
= 10y 2
∫ (
+ 0
dy y 0
(R) sec2y dy + tany dx = dx
I = f (2021) − f (−2021)
sec2y dy = (1 – tany) dx
Let tany = t x
sec2y dt = dt f (x) = x100 − 2x98 + x54 + 3x28 + − 1000
2021
dt 2x
dx = f (x) − f (−x) =
1−t 2021
Integrate both sides
x = – log|1 – t| + logc' f (2021) − f (−2021) = 2 = I
|1 − t|
– x = log 2. Ans ( 2 )
c′
1−t
∴ e−x =
′
⇒ t = 1 – c'e – x Differentiate given function
c –x
∴ tany = 1 + ce 3ƒ2(x) . ƒ'(x) = x ƒ2(x)
dy
(S) siny = cosy(1 – xcosy) ƒ2(x) . [3ƒ'(x) – x] = 0
dx
tany secy dy – secy = – x ∵ ƒ2(x) > 0 ( ∵ ƒ(0) = 0 & ƒ is increasing)
dx x
put secy = v ∴ ƒ'(x) =
dy dv 3
∴ secy tany = ∴ ƒ'(6) = 2 Ans.
dx dx
dv
− v = −x ...(1) 3. Ans ( 0 )
dx
Here P = – 1 x2

∫ P dP = ∫ −1. dx = −x f ′ (x) = 2x ∫ f (t) dt + 2x3 f (x2 )

1
∴ I.F. = e – x
Multiplying (1) by I.F. we get f ′ (1) = 2f(1)
dv
e−x − e−x . v = −x. e−x f ′ (1) + f(1) = 3f(1) & f(1) = 0
dx
Integrating both sides
ve−x = ∫ −xe−x dx
v = 1 + x + cex
secy = x + 1 + cex
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4. Ans ( 7 ) 6. Ans ( 3 )
S : x2 + (y – 4)2 = 4 f(x) = log 5 2(sin x − cos x) + 3 we know
√ (√ )

x2 y2 that
E: + = 1.
A2 B2 – √2 ≤ sin x – cos x ≤ √2 , ∀ x ∈ R
[since − √
a2 + b2 ≤ a sin x + b cos x ≤ √a2 + b2 ]

⇒ −√2 ≤ (sin x – cos x) ≤ √ 2 ⇒ 1≤ √ 2

(sin x – cos x) + 3 ≤ 5
⇒ 0 ≤ log ( 2(sin x – cos x) + 3) ≤ 2.
√
5
√

Hence range is [0, 2]

√
A2 e2 + 16 + 2 = 7 ⇒ Ae = 3

2 – B = 1 ⇒ B = 1 ⇒ A2 = 10.
x2 y2
Hence, E : − =1
10 1
∴ A2 – 3B2 = 7

5. Ans ( 1540 )
ƒ(1) = 2 and ƒ(x + y) = ƒ(x) + ƒ(y) ⇒ ƒ(x) = 2x
100
10.11.21
∑ (2r)2 = 4 [ ] = 1540

r=1
6

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