TOP PYQ (2012-2024) - Contact Number: 9667591930 /

Equilibrium 8527521718

1 The values of Ksp of CaCO3 and CaC2O4 are 4.7 × 5 The following solutions were prepared by mixing
10–9 and 1.3 × 10–9 respectively at 25°C. If the mixture different volumes of NaOH and HCl of different
of these two is washed with water, what is the concentrations :
concentration of Ca2+ ions in the water? A) 60 mL H CI + 40 mL N aOH
M

10
M

10

1. 5.831 × 10–5 M B) M M
55 mL H CI + 45 mL N aOH
10 10

2. 6.856 × 10–5 M C) 75 mL
M

5
H CI + 25 mL
M

5
N aOH

3. 3.606 × 10–5 M D) 100 mL H CI + 100 mL N aOH M M

10 10

4. 7.746 × 10–5 M pH of which one of them will be equal to 1?

1. B
2 Consider the following reaction in a sealed vessel at 2. A
equilibrium with concentrations of 3. D
−3
N = 3.0 × 10 M, O = 4.2 × 10 M and
2 2
−3
4. C
NO = 2.8 × 10 −3

2NO
6 Equimolar solutions of the following substances
g ⇌N g
( ) 2( )
+ O
2 (g)
were prepared separately. Which one of these will record
If 0.1 mol L-1 of NO(g) is taken in a closed vessel, what the highest pH value?
will be the degree of dissociation (α) of NO(g) at 1. BaCl 2

equilibrium? 2. AlCl3

1. 0.0889 3. LiCl
2. 0.8889 4. BeCl2

3. 0.717
4. 0.00889 7 Buffer solutions have constant acidity and alkalinity
because:
3 The ratio of solubility of AgCl in 0.1 M KCl

solution to the solubility of AgCl in water is: these give unionized acid or base on reaction with
1.
(Given: Solubility product of AgCl = 10 ) −10
added acid or alkali.
1. 10
−4
2. 10
−6
acid and alkali in these solutions are shielded from
2.
3. 10
−9
4. 10
−5 attack by other ions
3. they have large excess of H+ or OH- ions
4 The Ksp of Ag2CrO4, AgCl, AgBr, and Agl are 4. they have fixed value of pH
respectively, 1.1 × 10–12, 1.8 × 10–10, 5.0 × 10–13,
At 100 °C the Kw of water is 55 times its value at
8.3 × 10–17. Which one of the following salts will 8
precipitate last if AgNO solution is added to the 25ºC. What will be the pH of a neutral solution?
3

solution containing equal moles of NaCl, NaBr, Nal, and (log 55 = 1.74)
Na2CrO4? 1. 7.00 2. 7.87
1. Agl 3. 5.13 4. 6.13
2. AgCl
3. AgBr 9 The concentration of Ag+ ions in a saturated
4. Ag2CrO4 solution of Ag2C2O4 is 2.2 × 10–4 mol L–1.
The solubility product of Ag2C2O4 is:
1. 2.66×10–12 2. 4.5×10–11
3. 5.3×10–12 4. 2.42×10–8

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 TOP PYQ (2012-2024) - Contact Number: 9667591930 /
Equilibrium 8527521718

15 The pH of the solution containing 50 mL each of

−3
10 For the reaction 2 A ⇌ B + C, K c = 4 × 10 . At
a given time, the composition of reaction mixture is : 0.10 M sodium acetate and 0.01 M acetic acid is:
[A] = [B] = [C] = 2 × 10
−3
M. [Given pKa of CH3COOH = 4.57]
In light of the above facts, which of the following is 1. 2.57
correct? 2. 5.57
Reaction has a tendency to go in the forward 3. 3.57
1. 4. 4.57
direction.
Reaction has a tendency to go in the backward
2. 16 pH of a saturated solution of Ca (OH) is 9. The
direction. 2

Reaction has gone to completion in the forward solubility product (K ) of Ca (OH) is:
sp 2
3. 1. 0. 5 × 10 −10
direction.
4. Reaction is at an equilibrium. 2. 0. 5 × 10 −15

3. 0. 25 × 10 −10

11 A 20-litre container at 400 K contains CO 2 (g) at 4. 0. 125 × 10 −15

pressure 0.4 atm and an excess of SrO (neglecting the

volume of solid SrO). The volume of the container is 17 The molar solubility of CaF (K = 5. 3 × 10
−11
2 sp )

now decreased by moving the movable piston fitted in in 0.1 M solution of NaF will be:
the container. 1. 5. 3 × 10 −11
mol L 2. 5. 3 × 10 mol L
−1 −8 −1

The maximum volume of the container, when the 3. 5. 3 × 10 mol L −9

4. 5. 3 × 10
−1
mol L
−10 −1

pressure of CO2 attains its maximum value will be:

(Given that: SrCO3(s) ⇋ SrO(s) + CO2(g) , Kp = 1.6 18 A Lewis base among the following is:
atm) 1. BF3 2. PF3
1. 10 litre 2. 2 litre
3. CF4 4. SiF4
3. 4 litre 4. 5 litre

12 The solubility of BaSO4 in water is 2. 42 × 10

−3
g/ 19 For a weak acid HA, the percentage of dissociation
is nearly 1% at equilibrium. If the concentration of acid
litre at 298 K. The value of the solubility product will
is 0.1 mol L-1, then the correct option for its Ka at the
be: (Molar mass of BaSO4 = 233 gmol–1)
same temperature will be:
1. 1.08 × 10–10 mol2 L–2 2. 1.08 × 10–12 mol2 L–2
1. 1 × 10
−4

3. 1.08 × 10–14 mol2 L–2 4. 1.08 × 10–8 mol2 L–2 2. 1 × 10

−6

3. 1 × 10
−5

13 The pKb of dimethylamine and pka of acetic acid 4. −3

1 × 10
are 3.27 and 4.77 respectively at T (K).
The correct option for the pH of dimethylammonium
acetate solution is: 20 At room temperature, MY and NY3, two nearly
1. 7.75 2. 6.25 insoluble salts, have the same Ksp values of 6.2 × 10-13.
3. 8.50 4. 5.50 The true statement regarding MY and NY3 is:
The molar solubility of MY in water is less than that
1. of NY .
14 Which composition will make the basic buffer? 3
1. 100 mL of 0.1 M HCl+100 mL of 0.1 M NaOH The salts MY and NY3 are more soluble in 0.5 M
2.
2. 50 mL of 0.1 M NaOH+25 mL of 0.1 M CH3COOH KY than in pure water.
100 mL of 0.1 M CH3COOH+100 mL of 0.1 M The addition of the salt of KY to a solution of MY
3. 3. and NY will have no effect on their solubilities.
NaOH 3
4. 100 mL of 0.1 M HCl+200 mL of 0.1 M NH4OH The molar solubilities of MY and NY3 in water are
4.
identical.

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 TOP PYQ (2012-2024) - Contact Number: 9667591930 /
Equilibrium 8527521718

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