Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Sr.Super60 & All Streams Paper -1(NewModel-P1-Model) Date: 22-12-2024
Time: 09.00Am to 12.00Pm GTA-11 Max. Marks: 198

KEY SHEET
MATHEMATICS
1 BC 2 AD 3 ABCD 4 BC 5 AB
6 AC 7 722 8 3 9 5 10 6
11 2 12 1 13 1 14 5 15 2
16 7 17 81 18 7 19 28 20 14

PHYSICS
21 B 22 AC 23 ABD 24 AC 25 AC
26 ABC 27 0.60 28 2.88 29 781.25 30 1200

31 4 32 4 33 5 34 5 35 6

36 0 37 1250 38 1050 39 20 40 10

CHEMISTRY
41 ABC 42 AC 43 AC 44 ABCD 45 ABD
46 AB 47 500 48 5 49 12 50 7
51 3 52 5 53 6 54 7 55 6
56 80 57 19.15 58 2 59 6 60 6
 Sri Chaitanya IIT Academy 22-12-24_ Sr.Super60 & All Streams _Jee-Adv(NewModel-P1)_GTA-11_Key& Sol’s
SOLUTIONS
MATHEMATICS
1. Mean deviation calculation about mean
xi fi fixi xi 15 fi x i  15
3 8 24 12 96
9 10 90 6 60
17 12 204 2 24
23 9 207 8 72
27 5 135 12 60
N   fi  44  f i x i  660  fi x i  15  312
1 660
Mean= X 
N
  fi x i  
44
 15
1 312
Mean deviation = M.D.   fi x i  15   7.09
N 44
2. The number of sequences under consideration is equal to 12-element combinations with
61
C12
repetition of elements of set{1, 2 3 …., 50}. Probability =
 50 12
n
n r  1   n  1!
3. S  n  1    1 1  
 r  1  r! n  1  r !
r 0
 n r 
n
n  rn 1
n
 n  1!n  2  1
   1 Cr    1
 r  1! n  1  r ! n  2
r 0 r 0
n
1 n n r n  2 1   1
1 
n  2 r 0
 1 C n 1 r  1 
n2
393 n  5
4. n 2  5  2n  5    n 2  25
5
 73.6  n  83.6 , n = 80 is only possible value
x 
   
x 2 x
5. f  x 
2 1  2 2

 1 2
  
2 x
 
x
2 1  2 2

x 
  

1  2  
 f  x    f  4  x   f  x  is symmetrical about ( 2, 0)
1
 a1  2 and a2 
2
  2   2  2   2      1
6. a  b  b  c  c  a  3 a  c  b  0, a  c  b  a c  
2
        
So, a  b  c  2 b  2 , a  2b  3c  3a  5c  19

Sec : )Sr.Super60 & All Streams Page 2

 Sri Chaitanya IIT Academy 22-12-24_ Sr.Super60 & All Streams _Jee-Adv(NewModel-P1)_GTA-11_Key& Sol’s

   
5 n
7. P 2 3 , where 0  f , f '  1, Also f '  2  3

   2  3
n n
Now I  f  f '  2  3 =even integer  f  f ' is an integer
But 0  f  f '  f  f '  1
2

 
n
2 1  2  3 
f2 f 2 1  f '  n 2

   
  n
Now ,     1  2  3   2  3
 
1 f f ' f' n  
2 3
n 2
2  3        
n 2n n n
1  2  3 2 2 3  2 3  2 3 2
 
Not put n = 5, 2  C0  2  C2  2  3  5 C 4  21  9  1
5 5 5 3
 
2 32  10.8.3  5.2.9  1  2 32  240  90  1  722
8. Let Hi = the event of getting a head on ith coin
H=getting odd number of heads on throwing n coins once
Coin number: 1 2 3 4……..m ……n
1 1 1 1 1 1
P  Hi  ..... .......1
3 5 7 9  2m  1  2n  1
 
P Hi
2
3
4
5
6
7
8
9
2m
.....
2n
 2m  1  2n  1
....... 2 

Now, P(H)= sum of series which has each term consisting of product of an odd number
of terms from (1) and even number of terms from (2) such that total number of factors in
each term is n
Consider the product
 2 1  4 1  6 1   2n 1  1
       ......  
 3 3  5 5  7 7   2n  1 2n  1  2n  1
1
LHS  P  H   P  H  
2n  1
n
Also, P  H   P  H   1  P  H      1,   2,   1,       4
2n  1
9. Newton Leibnitz Rule
10. Centre of the given circle is O(4, -3)
The circumcircle of PAB will circumscribe the quadrilateral PBOS also, hence one of
the diameters must be OP.
Equation of circumcircle of PAB will be  x  2  x  4    y  3 y  3  0
 x 2  y 2  6x  1  0 ……………(1)
Director circle of given ellipse will be
 x  5  2   y  3 2  9  b 2
 x 2  y2  10x  6y  25  b 2  0 …………………(2)

Sec : )Sr.Super60 & All Streams Page 3

 Sri Chaitanya IIT Academy 22-12-24_ Sr.Super60 & All Streams _Jee-Adv(NewModel-P1)_GTA-11_Key& Sol’s
From (1) and (2) by applying condition of orthogonally, we get
2  3 5  0  3   1  25  b2  30  24  b 2

 b2 
b 2  54    is 6
 9 
 
11. Let the normal to the hyperbola be 3x cos   y cot   10 …………(i)
2 5
and tangent to the parabola be y  mx  ……………….(ii)
m
 m.sec  1 3 1
Comparing (i) & (ii)  tan    sec    and tan  
3 5m 5m 2 5m
9 1
Now, sec2   1  tan 2   1  5m 4  m 2  9  0
4 2
5m 5m
  181
m2  the two real values
10
12. Case-I:
a a
If a   0,1 , the curves intersect at  ,  and (a, a). The bounded region is contained in
3 3
1  1
the triangle with vertices (0, 0),  ,0  and (1, 1) with area =
2  4
1
Hence, area cannot exceed
4
Case-II:
If a  1,3 . In this case the bounded region is a quadrilateral with four vertices
a a a  a 2 4a 
 ,  ,  ,0  ,  ,  and (1,1). In this case area bounded
3 3 2   3 3 
2
1 a a 1  4  a  a  1  a  2 1
1      2     
2 3 2 2  3  2 3 6 3

x2  1
13. Here x > 0, log 2  3x 2  2x 3
x
x 2  1 3x 2  2x 3 1 2 3 1
 2  x   23x  2x  21 ( x   2 if x  0 )  3x 2  2x 3  1
x x x
2  1
Or  x  1  2x  1  0  x   ,   1 But x > 0 x = 1
 2
Sec : )Sr.Super60 & All Streams Page 4
 Sri Chaitanya IIT Academy 22-12-24_ Sr.Super60 & All Streams _Jee-Adv(NewModel-P1)_GTA-11_Key& Sol’s
14. Integrating F we get:
zi
F z  
zi
zi
i
Ff  z   z  i 
 z  i   i  z  i   z  i  zi  1   z  1 i  1
 i  z  i   i  z  i  z  i  zi  1  z  11  i 
zi
zi
 z  1 i  12  z  1 2i  z  1
   i
 z  1 1  i 
2 2  z  1 2  z  1

z 1 z 1
ii  1  z  1   z  1 2z
 
F F F z   z  1
z 1
 z 1
z 1

 z  1   z  1

2
z
ii 1
z 1 z 1
From this, it follows that z k  3  z k , for all k.
1
 2i
z 0  i 137
Thus z 2002  z3667 1  z1    1  274i
z0  i 1
137
Thus a  b  1  274  275
dy
15.  y  4xe  x sin 2x , Integrating factor = e x
dx

Equation becomes ye x  4  x sin 2xdx ,  ye x   sin 2x  2x cos 2x   c

f 0  0  c  0 y  f  x    sin 2x  2xco2x  e  x

f  k   e k  0  2k 1  f  k   2ke  k
n
2e 
lim 
 f  k   2 1  e  2e2  3e3  .... upto   
 
n  k 1 2
e  1
2 4 5
16. A   8 9 15
16 81 81
2 4 5
17. A   8 9 15
16 81 81
18 9 1
18.   7
3! 3 1
8
19. C2
20. 39  3  29  3  19
Sec : )Sr.Super60 & All Streams Page 5
 Sri Chaitanya IIT Academy 22-12-24_ Sr.Super60 & All Streams _Jee-Adv(NewModel-P1)_GTA-11_Key& Sol’s

PHYSICS
21. When the switch ‘S’ is opened,
  RC  1.5sec Voltage across the capacitor,

 
Vc  10 1  e t/1.5 for t<T The current, i 
dQ
dt
dV
C c
dt

200
3
 
 106 e t/1.5 for t<T
Voltage drop across 100 k  resister,
20
V  iR  e  t/1.5 for t < T
3
After t = T,   100k  10 F  1sec
   
22. Direction of electromagnetic wave is along E  B And BandE oscillate in same phase
23. Three will be no normal reaction between rod and ring. Because rod is massless. The
motion of ring will be free fall under gravity.
3 / 5

 4 / 5

4 8g
Velocity of ring when it leaves contact with rod  2  g  
5 5
3 8g 72g3
Angular momentum  m m
5 5 125
24. Conceptual
330 330
25. f  640   640  660 Hz
 330  10  320
  
26. q  q 0 sin  t   i  q 0 cos
 6 6
q 3 24
i 0  q0  8 3
2 2 3

 
2
q 02 1 4 3 1 2
Alternatively    2   6
2C 2 2
1 2 q 02
q0  8 3 Li0   i0  4 3
2 2C
Sec : )Sr.Super60 & All Streams Page 6
 Sri Chaitanya IIT Academy 22-12-24_ Sr.Super60 & All Streams _Jee-Adv(NewModel-P1)_GTA-11_Key& Sol’s
2v 2 2  2  0.9
27. A t  Ai   2  0.3  0.6
 v1  v 2  6
V2 V 2 48  48
28. P R   2.88 
4R 4P 4  200
r dB
29. E1  
2 dt
R 2 dB 3 25
E2     5  102   5  102
2r dt 2 2 6
25  25  3  104
  78.125  104  781.25  10 5
46
I q
30. V1  
40 x2  R2
9  109  10  109
V1   3000
3  102
9  109  109  10
V2   1800 V  1200V
5  102
31. OE=x
FG  2a  2y
From the property of rhombus, we can write
2 2
 a   a x
  y      a2
 2   2 2
Neglecting x 2 and y 2 , we have
Using COME, we can write
mv 2 k 2 4m
  x   E  cons tan t  T  
2 2 k

32. Let in time t, m mass of liquid collides with windshield. So

p  pi 0  mv mv
F f  
t t t
  density of liquid molecules in air so
m  Svt    Svt
Where S  surface area of the windshield
Sec : )Sr.Super60 & All Streams Page 7
 Sri Chaitanya IIT Academy 22-12-24_ Sr.Super60 & All Streams _Jee-Adv(NewModel-P1)_GTA-11_Key& Sol’s
F
F  Sv 2   Mean pressure   v 2 .....1
S
Now as we assumed that  is the density of liquid molecules of drops in air so in  time
US0 volume of liquid will strikes on the surface of earth so mass of liquid strikes on the
earth in time interval  will be
h
m 0  S0 u  S0h  S0 u   
u
Putting this value in equation (1), we have
hv 2 48
Mean pressure  
u 5
33. P2  g  h  x  , P1  gh V2  Ax V1  Ax 0
Using Boyle’s law we can write
g  h  x  Ax  gh  Ax 0 

2 h h2
 x  hx  hx 0  0  x    hx 0  x  10m,90m
2 4
x    length of pipe  So answer will be x=10m

hx

x x0

34. We can reverse the question. Let I behaves as object and O behaves as image, because
retracing the path will not alter the distances.
Consider first refraction at point N
1.5 1.0 1.5  1.0 1.5 1 1
      v  3R
v R R v 2R R
M N
  1.5 0  1.0
R
O x P2 C P1
0  1.0 R 3R

1.0 1.5 1.0  1.5 1 3 1 5

     
v 5R R v 10R 2R 10R
1 5 3 1
     v  5R  x  5R  k  5
v 10R 10R 5R
Consider second refraction at point M, for this I, will behaves as normal object so
 1  3E
35. According to Bohr’s model E  E0 1    E min  0
 n2  4
During inelastic collision, a part of kinetic energy of colliding particles is converted into
internal energy. The internal energy of the system of two hydrogen atoms, considered in
the problem cannot be changed less than E min . It means if the change in kinetic energy
Sec : )Sr.Super60 & All Streams Page 8
 Sri Chaitanya IIT Academy 22-12-24_ Sr.Super60 & All Streams _Jee-Adv(NewModel-P1)_GTA-11_Key& Sol’s
of system in grour frame is less than E min (or if the kinetic energy of colliding atoms
with respect to their centre mass is less than E min ), then collision must be an elastic
2
1 v  3E 3E 0
one. Hence considering the critical case m H  0   2  0  v0 
2  2  4 mH

3  2.18  1018
 39.1617  104  6.257  104 m / s  6.26  104 m / s
27
1.67  10
a  bc 6 26
 6
kn 3 4
36. In the time interval t=0 sec to t  t 0 sec , till the time. The relative velocity is not zero the

nature of friction will be kinetic. U AB  
 0iˆ  20iˆ  20m / sec ˆi 
 
N  100N  Fk  0.25  100  25N a A  4m / sec2  ˆi  ,a B  0m / sec2  ˆi 
      

a AB  a A  a B  4m / sec2 ˆi VAB  U AB  a AB t  o  t  5sec
N

F  15N
10 kg
Fk
10g
When the relative motion between block A and belt conveyor will be zero, the nature of
friction will be static and its magnitude will equal to magnitude of unbalance external
force acting on the block A and its direction will be I the opposite direction of unbalanced

external force.
 25N

 Fr  Frictionalforce  
 ˆi   kineticin nature
15N
  ˆi   Staticin nature
25N
5sec t
O
15N

37. In the time interval t=0 sec to t  t 0 sec , till the time. The relative velocity is not zero the

nature of friction will be kinetic. U AB  0iˆ  20iˆ  20m / sec ˆi   
 
N  100N  Fk  0.25  100  25N a A  4m / sec2 ˆi ,a B  0m / sec2 ˆi  
      

a AB  a A  a B  4m / sec2 ˆi VAB  U AB  a AB t  o  t  5sec
N

F  15N
10 kg
Fk
10g

Sec : )Sr.Super60 & All Streams Page 9

 Sri Chaitanya IIT Academy 22-12-24_ Sr.Super60 & All Streams _Jee-Adv(NewModel-P1)_GTA-11_Key& Sol’s
When the relative motion between block A and belt conveyor will be zero, the nature of
friction will be static and its magnitude will equal to magnitude of unbalance external
force acting on the block A and its direction will be I the opposite direction of unbalanced

external force.

 Fr  Frictionalforce  

25N ˆi  kineticin nature

 
15N ˆi  Staticin nature


25N
5sec t
O
15N

38. In the time interval t=0 sec to t  t 0 sec , till the time. The relative velocity is not zero the

nature of friction will be kinetic. U AB  
 0iˆ  20iˆ  20m / sec ˆi 
 
N  100N  Fk  0.25  100  25N a A  4m / sec2  ˆi  ,a B  0m / sec2  ˆi 
      

a AB  a A  a B  4m / sec2 ˆi VAB  U AB  a AB t  o  t  5sec
N

F  15N
10kg
Fk
10g
When the relative motion between block A and belt conveyor will be zero, the nature of
friction will be static and its magnitude will equal to magnitude of unbalance external
force acting on the block A and its direction will be I the opposite direction of unbalanced

external force.

 Fr  Frictionalforce  

25N ˆi  kineticin nature

 
15N ˆi  Staticin nature


25N
5sec t
O
15N
1 1 1 1 1 1 1
39.        f  20cm
f v u 30 60 f 20
1
Focal length of convex mirror f   30  10   10cm
2
1 1 1 1 1 1 1
40.        f  20cm
f v u 30 60 f 20
1
Focal length of convex mirror f   30  10   10cm s
2

Sec : )Sr.Super60 & All Streams Page 10

 Sri Chaitanya IIT Academy 22-12-24_ Sr.Super60 & All Streams _Jee-Adv(NewModel-P1)_GTA-11_Key& Sol’s
CHEMISTRY
41. Conceptual
42.
CH3 CH3 CH3
CH3
Br Br
Br

Br2
Fe 
Sn/HCl
 
NaNO2 /HCl
273 278K

NO2 NO2
NH2 N 2 Cl
P Q R
H 2O H3PO 2

COOH CH3

Br Br
KMnO 4
OH 

T   S
43. Conceptual
44. Conceptual
45. Pm 3  Ho 3  4
Sm 3  Dy 3  5
Eu 3  Tb 3  6
46. a) due to back bonding, dipole moment of R 3P   O  less than R 3N   O
b) PCl3F2  PCl2F3 - order of dipole moment
PCl3F2 - symmetrical TBP,   0
c) NH3  HF  H 2O -order of dipole moment
d) HF  HI  HBr  HCl -order of boiling point
1 dKE h
47. KE  mv2  dKE  mv dv  dv  and x 
2 mv 4mv
h hv 6.62  1034  2  106
 x   x   x   x  500A
dkE 4 dKE 6.62 21
4m 4   10
mv 
48. Mg  HCO3 2  2Ca  OH 2  Mg  OH 2  2CaCO3  2H 2O
49.

50. X = 4, Y=3

Sec : )Sr.Super60 & All Streams Page 11

 Sri Chaitanya IIT Academy 22-12-24_ Sr.Super60 & All Streams _Jee-Adv(NewModel-P1)_GTA-11_Key& Sol’s

Q=

R= H3C N CH3

CH3
2
51. Cu  NH3  
 4
 Cu 2  d9      one
2
 Ni  NH3  
 6
 Ni 2  d8      two
4
Co  NO2    Co 2  d 7  S.F  one
 6
 Fe  CO    Fe0  d6s2  S.F  d8  0
 5
3
Ti  H 2 O    Ti3  d1    one
 6
 Ni  CO    Ni0  d8s 2  S.F  d10  0
 4
3
Co  H 2 O    Co 3  d 6  S.F  0
 6
52. arachno boranes - Bn H n  6
53. (I, II, III, IV, V, VII)
54. Sugar of RNA is
OH-CH 2
O OH
H H
H
H
OH OH x=4
Sugar of DNA is
OH-CH 2
O OH
H H
H
H
OH H
Y=3
X+y=4+3=7
55. Molarity of weak acid = 0.2 M
Now, 10 mL of 0.2 M NaOH +25 mL of 0.2M HA
Salt formed millimoles  10  0.2  2
Acid reacted in millimoles  25  0.2  5
Remaining acid left in millimoles  5  2  3

 pH  pKa  log
salt   5.82  pKa  log  2 / v
 acidic buffer   Acid  3 / v 
 5.82  pKa  log 2  log 3  5.82  pKa  0.3  0.48  pKa  6

Sec : )Sr.Super60 & All Streams Page 12

 Sri Chaitanya IIT Academy 22-12-24_ Sr.Super60 & All Streams _Jee-Adv(NewModel-P1)_GTA-11_Key& Sol’s
E a E a  16
56.   E a  80 kJ / mol
500 400
H
57.  1  H  19.147 J / mol
2.303R
58. Given cell
 2H   2e , E  0V
Anode Half cell H 2 

Cathode Half cell Fe2  2e 

 Fe , E  0.44V

   
 E ocell  E ocathode  E oanode  0.44 V  Nernst equation
2.303RT
E cell  E ocell  log Q
nF
2
2.303   8.314    300   Fe   H 
 E cell  0.44  log
 2  96500   Fe2  P
  H2
 1 
 
2
 2  10 
 E cell  0.44   0.0297   103  
 4 
 
Because pH  0.699  1  0.3010
  log  H    1  0.3010   log  H    log 2  log10
   
  H    2  101  E cell  0.44   0.0297   log 10  E cell  0.4697
 
Now , G   nFE cell    2  96500  0.4697   90652 J mol1
 H  G
Now,  r G   r H  T r S  T r S  r
T
90000  90652
 = -2.17 J  rS  2 J
300
Clearly the cell is non spontaneous
59&60.

CrCl3  NaOH  Cr  OH 3 Cr  OH 3  NaOH  Cr  OH 4 
 exess 
 B  green ppt   C  green solution 

Cr  OH    H2O2 / OH  Na 2CrO4  Cr  6 
 4
 D  yellow solution 
Na 2CrO4  H 2O2  acid  CrO5
 E  deep blue solution 
Longstanding
CrO5 acidic medium
Cr 3  aq  green   O2  O 2  antibonding electrons  6 
A  F

Sec : )Sr.Super60 & All Streams Page 13