Sri Chaitanya IIT Academy., India.
A.P T.S KARNATAKA TAMILNADU MAHARASTRA DELHI RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec:Sr.Super60, Elite, Target & LIIT BT's Paper -2(Adv-2024-P2-Model) Date: 27-04-2025
Time: 02.00Pm to 05.00Pm GTA-30 Max. Marks: 180
27-04-2025_Sr.Super60, Elite, Target & LIIT BT's_Jee-Adv(2024-P2)_GTA-30_Syllabus
MATHEMATICS : TOTAL SYLLABUS
PHYSICS : TOTAL SYLLABUS
CHEMISTRY : TOTAL SYLLABUS
Name of the Student: ___________________ H.T. NO:
Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60, Elite,Target & LIIT BT's _Jee-Adv(2024-P2)_GTA-30_Q.P
JEE-ADVANCED-2024-P2-Model
Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 4) Questions with Single Correct Choice +3 -1 4 12
Questions with Multiple Correct Choice
Sec – II(Q.N : 5 – 7) +4 -2 3 12
with partial mark$
Questions with NON-NEGATIVE INTEGER
Sec – III(Q.N : 8 – 13) +4 0 6 24
Answer Type
Sec – IV(Q.N : 14 – 17) Paragraph with NUMERICAL VALUE 3 0 4 12
Total 17 60
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 18 – 21) Questions with Single Correct Choice +3 -1 4 12
Questions with Multiple Correct Choice
Sec – II(Q.N : 22 – 24) +4 -2 3 12
with partial mark
Questions with NON-NEGATIVE INTEGER
Sec – III(Q.N : 25 – 30) +4 0 6 24
Answer Type
Sec – IV(Q.N : 31 – 34) Paragraph with NUMERICAL VALUE 3 0 4 12
Total 17 60
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 35 – 38) Questions with Single Correct Choice +3 -1 4 12
Questions with Multiple Correct Choice
Sec – II(Q.N : 39 – 41) +4 -2 3 12
with partial mark
Questions with NON-NEGATIVE INTEGER
Sec – III(Q.N : 42 – 47) +4 0 6 24
Answer Type
Sec – IV(Q.N : 48 – 51) Paragraph with NUMERICAL VALUE 3 0 4 12
Total 17 60
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Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60, Elite,Target & LIIT BT's _Jee-Adv(2024-P2)_GTA-30_Q.P
MATHEMATICS Max Marks: 60
SECTION–I
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
For each question, choose the option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
1. Let P be the foot of perpendicular drawn from a point Q. where Q lies on the line
x y 4 0 and P lies on the line 5 x y 0 . If P is the image of point R 12,0 about
the line x y 2 , then coordinates of Q is
14 26 11 23 16 28
A) , B) , C) , D) 6, 10
3 3 3 3 3 3
2. Area of region bounded by curve y x x x , y 0, x 0, x 6 is equal to (in sq.
units)
A) 6 B) 13 C) 19 D) 23
x 1 y 2 z 1
3. A line passing through origin cuts the lines and
1 1 2
x 1 3y 8 z 3
at A and B respectively, then the square of length of AB is equal to
1 6 1
A) 3 B) 6 C) 9 D) 12
4. Let S be the set of all possible 2 2 matrices A with integer entries such that AAT 2 I
1 0
where I , then number of such matrices in S such that det A I 1 (where
0 1
det A denotes the determinant of matrix A) is
A) 2 B) 4 C) 6 D) 8
Sec: Sr.Super60, Elite,Target & LIIT BT's Space for rough work Page 3
Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60, Elite,Target & LIIT BT's _Jee-Adv(2024-P2)_GTA-30_Q.P
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
For each question, choose the option(s) corresponding to (all) the correct answer(s).
Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get
+1 mark; choosing no option (i.e. the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.
2 1 3
5. Let A 1 1 2 and A1 A2 A I , then which of the following holds good?
3 1 1
A) 1 B) 3 10
C) 8 11 D) 8 3
3x5 2 x3 , x Rational
6. f x , then
0, x Irrational
A) f x is continuous exactly at one point
B) f x is discontinuous x R
C) f x is non-differentiable x R
D) f x is differentiable exactly at one point
z 1
7. If w , z 1, z, w C , then:
z2
7
A) | w 3 |min B) | w 3 |max 3
3
C) (Arg(w))max ( Arg (w) ) D) (Arg(w)) min 0( Arg(w) )
4
SECTION-III
(NON-NEGATIVE INTEGER)
• This section contains SIX (06) questions.
• The answer to each question is a NON-NEGATIVE INTEGER..
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4If ONLY the correct integer is entered; Zero Marks : 0 In all other cases.
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Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60, Elite,Target & LIIT BT's _Jee-Adv(2024-P2)_GTA-30_Q.P
1 1 1
8. Let a, b, c 0 and 4
4
4
1 , then the minimum value of a 2b 2c 2 is k then
1 a 1 b 1 c
value of k 2 is
n
k k2
9. The value of 12 lim 1 2 3 1 is equal to
n
k 1 n n
10. Let z1 , z2 , z3 and z4 be the roots of the equation z 4 8iz 3 24 z 2 32iz 15 i 0 and
4
P z be a point on complex plane, then the minimum value of z zi is 2 x , then the
i 1
value of [ x ] is equal to (where [] represent the greatest integer function)
ab 3a c
11. The value of 270 is
a 1 b 1 c 1 4
abc
a b b c c a
12. Let n be a positive integer. If the number of integers in the domain of the function
f x ln 1 x x n is 2n 11, then cot 1 cot n is equal to k then value of [k ] is:
[Use 3.14 ] (where [] represent the greatest integer function)
13. From a fixed point A, three normal are drawn to the parabola y 2 4ax at the points P, Q
and R . Two circles C1 and C2 be drawn on AP and AQ as diameters. If the slope of the
common chord of circles C1 and C2 be m1 and the slope of the tangent to the parabola at
the point R be m2 , then 16m1m2 is equal to
SECTION-IV
(PARAGRAPH QUESTIONS)
This section contains TWO (02) questions stems.
There are TWO (02) questions corresponding to each question stem.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered at the designated place;
Zero Marks:0 in all other cases
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Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60, Elite,Target & LIIT BT's _Jee-Adv(2024-P2)_GTA-30_Q.P
PARAGRAPH-I
Let set A contain all the 3 3 matrices whose entries are 0,1 & 1. Two of these entries
are 1, two are 1 & five are 0.
On the basis of above information, answer the following questions:
14. Number of skew-symmetric matrix in set A is
15. Number of symmetric matrix in set A which is non-singular is
PARAGRAPH-II
Let f : R R and g : R R such that
f x max x , x 1 , x 2 ,.., x 2018
g x min x , x 1 , x 2 ,.., x 2018 then:
2018
16. The value of f x dx is k then value of 3k is equal to
0
2018
f x dx
17. The value of 0 is
2018
g x dx
0
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Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60, Elite,Target & LIIT BT's _Jee-Adv(2024-P2)_GTA-30_Q.P
PHYSICS Max Marks: 60
SECTION–I
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
For each question, choose the option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
18. A wooden block (mass M) is hung from a peg by a massless rope. A speeding bullet
(with mass m and initial speed v0 ) collides with the block at time t 0 and embeds in it.
Let S be the system consisting of the block and bullet. Which quantities are conserved
between t 10 s and t 10 s ?
A) The horizontal component of the linear momentum of S.
B) The mechanical energy of S.
C) The angular momentum of S as measured about a perpendicular axis through the peg.
D) None of the above are conserved.
19. Four objects are placed at rest at the top of an inclined plane and allowed to roll without
slipping to the bottom in the absence of rolling resistance and air resistance.
• Object A is a solid brass ball of diameter d.
• Object B is a solid brass ball of diameter 2d.
• Object C is a hollow brass sphere of diameter d.
• Object D is a solid aluminium ball of diameter d. (Aluminium is less dense than brass.)
The balls are placed so that their centres of mass all travel the same distance. In each
case, the time of motion T is measured. Which of the following statements is correct?
A) TB TC TA TD B) TA TB TC TD
C) TB TA TC TD D) TC TA TB TD
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Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60, Elite,Target & LIIT BT's _Jee-Adv(2024-P2)_GTA-30_Q.P
20. Two identical carts A and B each with mass m are connected via a spring with spring
constant k. Two additional springs, identical to the first, connect the carts to two fixed
points. The carts are free to oscillate under the effect of the springs in one dimensional
frictionless motion.
Under suitable initial conditions, the two carts will oscillate in phase according to
xA t x0sin1t xB t where xA and xB are the locations of carts A and B relative to
their respective equilibrium positions. Under other suitable initial conditions, the two
carts will oscillate exactly out of phase according to xA t x0sin2t xB t
Determine the ratio 2 / 1
A) 3 B) 2 C) 2 2 D) 3
21. Two streams of water flow through the U-shaped tubes shown. The tube on the left has
cross-sectional area A, and the speed of the water flowing through it is v; the tube on the
right has cross-sectional area A’ = A/2. If the net force on the tube assembly is zero, what
must be the speed v0 of the water flowing through the tube on the right? Neglect gravity,
and assume that the speed of the water in each tube is the same upon entry and exit.
A) 1 / 2v B) v C) 2v D) 2v
Sec: Sr.Super60, Elite,Target & LIIT BT's Space for rough work Page 8
Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60, Elite,Target & LIIT BT's _Jee-Adv(2024-P2)_GTA-30_Q.P
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
For each question, choose the option(s) corresponding to (all) the correct answer(s).
Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get
+1 mark; choosing no option (i.e. the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.
22. A particle of mass 2.00 kg moves under a force given by F (8.00 N/m)( xˆi yˆj)
where î and ĵ are unit vectors in the x and y directions. The particle is placed at the
origin with an initial velocity v 3.00 m / s ˆi 4.00 m / s ˆj .
A) particle first return to the origin at t 1.57 s
B) the maximum distance between the particle and the origin is 5.00 m
C) magnitude of maximum acceleration of particle is 10 m / s2
D) the maximum distance between the particle and the origin is 2.50 m
23. A straight conducting wire of infinite length lies perpendicular to the plane of the paper
and current of magnitude 'I' is flowing out to the paper as shown in figure. Then choose
the correct option(s).
I
A) The value of B dl 0 .
8
B) The value of B dl B dl .
P1P2 P1 P2 P2 P3
7 I
C) The value of B dl 2 B dl .D) The value of B dl 0 .
24
P3 P4 P4 P5 P1P2 P3 P4 P5
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Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60, Elite,Target & LIIT BT's _Jee-Adv(2024-P2)_GTA-30_Q.P
24. During a number of complete cycles, a reversible engine (shown by a circle) absorbs
1200 joule from reservoir at 400 K and performs 200 joule of mechanical work then:
A) The reservoir at temperature T2 , absorbs 200J of heat while the reservoir at
temperature T3 , loses 1200J of heat.
B) The reservoir at temperature T2 , absorbs 1200J of heat while the reservoir at
temperature T3 , loses 200J of heat.
C) Change in entropy of reservoir at temperature T2 , will be 4J/K
D) Change in entropy of reservoir at temperature T3 , will be -1J/K
SECTION-III
(NON-NEGATIVE INTEGER)
• This section contains SIX (06) questions.
• The answer to each question is a NON-NEGATIVE INTEGER..
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4If ONLY the correct integer is entered; Zero Marks : 0 In all other cases..
25. Two beads, each of mass m, are free to slide on a rigid, vertical hoop of mass mh . The
beads are threaded on the hoop so that they cannot fall off of the hoop. They are released
with negligible velocity at the top of the hoop and slide down to the bottom in opposite
directions. The hoop remains vertical at all times. The maximum value of the ratio m/mh
such that the hoop always remains in contact with the ground is x. fill the value of 6x.
(Neglect friction).
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Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60, Elite,Target & LIIT BT's _Jee-Adv(2024-P2)_GTA-30_Q.P
26. Two identical charged particles having charge 10C and mass 100 gm each are released
on a rough horizontal plane surface at a distance of 1 m from each other. Coefficient of
friction between the particles and horizontal plane surface is 0.1 and acceleration due to
gravity is 10 m/s 2 . Find Maximum speed (in SI unit) acquired by each particle.
27. A uniform cylinder of radius a originally has a weight of 80 N. After an off-axis cylinder
hole at 2a/5 was drilled through it, it weighs 65 N. The axes of the two cylinders are
parallel and their centres are at the same height.
A force T is applied to the top of the cylinder horizontally. In order to keep the cylinder
at rest, the magnitude of the force T is (in N):
28. A charged particle is moving with a velocity v iˆ ˆj kˆ and the electric field
produced by it at a distant point is E iˆ ˆj kˆ . The magnetic field produced at the
same point due to the same charged particle is K00 . Find the value of K . (All
2
quantities are in S.I. units, take 2 1.4 and 3 1.7 )
29. A cube having body diagonal of length L and density 4 (Mass 4M) is being slowly
lowered into a very wide pool containing two liquids with the help of a thread as shown.
Magnitude of the work done by the tension in process from the moment the bottom
vertex of the cube is touching surface of the top liquid to the moment when the bottom
vertex just touches the bottom of lower liquid is xMgL. Fill the value of x.
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30. A light bulb has a solid cylindrical filament of length L and radius a, and consumes
power P. You are to design a new light bulb, using a cylindrical filament of the same
material, operating at the same voltage, and emitting the same spectrum of light, which
will consume power nP. The length ( L1 ) and radius ( a1 ) of the new filament are L1 n x L
and a1 n y a . Find y/x. Assume that the temperature of the filament is approximately
uniform across its cross-section; the filament doesn’t emit light from the ends; and energy
loss due to convection is negligible.
SECTION-IV
(PARAGRAPH QUESTIONS)
This section contains TWO (02) questions stems.
There are TWO (02) questions corresponding to each question stem.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered at the designated place;
Zero Marks:0 in all other cases
PARAGRAPH-I
Four square metal plates of area A are arranged at an even spacing d as shown in the
diagram. (Assume that A d 2 ).
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Plates 1 and 4 are first connected to a voltage source of magnitude V0 , with plate 1
positive; plates 2 and 3 are then connected together with a wire. The wire is subsequently
removed. Finally, the voltage source attached between plates 1 and 4 is replaced with a
wire. The steps are summarized in the diagrams below.
31. The resulting potential difference (V12 V1 V2 ) between plates 1 and 2 is xV0 . Fill the
value of x.
32. The resulting potential difference V23 between plates 2 and 3 is yV0 . Fill the value of y.
PARAGRAPH-II
One pair of ends of two long, parallel wires are connected by a resistor, R = 0.25 Ω, and a
fuse that will break instantaneously if 5 amperes of current pass through it. The other pair
of ends are unconnected. A conducting rod of mass m is free to slide along the wires
under the influence of gravity. The wires are separated by 30 cm, and the rod starts out 10
cm from the resistor and fuse. The whole system is placed in a uniform, constant
magnetic field of B = 1.2 T as shown in the figure. The resistance of the rod and the wires
is negligible. When the rod is released it falls under the influence of gravity, but never
loses contact with the long parallel wires.
(Take g 10 m/s 2 )
33. What is the smallest mass (in kg) needed to break the fuse?
34. How fast (in m/s) is the mass moving when the fuse breaks?
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Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60, Elite,Target & LIIT BT's _Jee-Adv(2024-P2)_GTA-30_Q.P
CHEMISTRY Max Marks: 60
SECTION–I
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
For each question, choose the option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
35. Which orbital overlaps among the following is not possible in ‘pentadiene’ molecule?
A) sp 3 sp 3 B) sp 2 sp 2 C) sp sp D) sp 2 sp 3
36. For the four covalent bonds; H-F, H-O, F-O and O=O, the following bond energies are
listed (in random order)
44 kcal/mole
111 kcal/mole
119 kcal/mole
135 kcal/mole
If the magnitude of ΔH for the reaction F2O(g) + H 2O(g) O 2 (g) 2HF(g) is 79 kcal,
identify the incorrect statement(s)
A) F-O bond will be the weakest of the lot
B) O=O bond will be the strongest of the lot
C) H-F bond will be stronger than H-O bond
D) the reaction mentioned above is exothermic
37. In a solution of 0.1M AgNO3 , sodium chloride salt is slowly added. The concentrations
of different ions (before the saturation point of strong electrolytes) can be represented as
(graph not according to scale and assume there is no change in volume during process)
Select the correct statement
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Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60, Elite,Target & LIIT BT's _Jee-Adv(2024-P2)_GTA-30_Q.P
A) XC represents the [Ag + ]
B) O’D represents the [Cl ] after the complete precipitation of AgCl
C) YA represents the [Na ]
D) YO’ represents the [NO3 ]
38. If clockwise spin were represented by the number 9 and anti clockwise spin by the
number 6, the 2p subshell of oxygen atom in ground state can attain a maximum
numerical value of (assume all rules of electron filling apply)
A) 6966 B) 9699 C) 9996 D) 9999
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
For each question, choose the option(s) corresponding to (all) the correct answer(s).
Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get
+1 mark; choosing no option (i.e. the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.
39. Which of the following atoms are less electronegative than phosphorus:
A) Si B) Sn C) S D) Se
40. A hydrocarbon (W) has molecular formula C13H 24 . Upon hydrogenation of it's pi-bond it
converts to 4-Cyclopentyl-4-methylheptane. Which of the following can be a
characteristic for the possible structure of (W):
A) presence of chiral carbon outside the cyclic ring
B) absence of geometrical isomerism in the molecule
C) presence of chiral carbon upon the cyclic ring
D) simultaneous presence of chiral centre and geometrical isomerism in the molecule
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41. Bachmann and Ferguson calculated the migratory aptitude of various aryl groups (listed
on the left) and came up with certain numbers (listed on the right)
Aryl group Migratory aptitude
o-anisyl 0.3
p-anisyl 0.7
p-toluyl 1.95
m-toluyl 15.7
p-chlorophenyl 500
Due to typist’s mistake the numbers in the above chart have got rearranged such that only
one number written infront of its group is actually right. All these number are calculated
w.r.t. phenyl ring whose migratory aptitude is taken as 1.
Identify the correct matching(s)
A) p – toluyl : 15.7 B) m – toluyl : 0.7
C) p – anisyl : 500 D) o – anisyl : 0.3
SECTION-III
(NON-NEGATIVE INTEGER)
• This section contains SIX (06) questions.
• The answer to each question is a NON-NEGATIVE INTEGER..
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4If ONLY the correct integer is entered; Zero Marks : 0 In all other cases.
42. Solubility of Pb(OH)2 (s) in pure water is104 M . How many times the solubility of
Pb(OH)2 will increase in buffer of pH 10 ? [Consider Temperature = 25 C ]
43. Shown below is the structure of Vitamin-E having molar mass of 430 grams.
The number of carbon atoms in the alkyl chain is ___________
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44. A crystalline solid is made of ccp packing of ‘X’ atoms with O atoms occupying all the
edge centres and Y atoms occupying all the tetrahedral voids created by X atoms. The
formula of its unit cell is Xa YbOc . If all the atoms along any one C3 axis of symmetry are
removal from the unit cell; the simplest formula of the resulting solid is Xd YbOa .
Calculate the value of a + b +c +d.
45. Select all the compounds having higher rotational energy barrier across C C as
compared to the following molecule and report the sum of their serial number as your
response.
46. 2 moles C ( g ) and 4 moles D ( g ) are mixed together in a sealed 1 litre vessel and allowed
to attain equilibrium as A( g ) 2 B( g ) C ( g ) D( g ) . K c for the above equilibria is 108
lit/mole. If the equilibrium concentration for C ( g ) is found to be x y 10 z (x point y
into 10 raised to minus z), calculate the value of x y z .
47. For the decomposition reaction X Y, 50% reaction occurs in 10 min. and the next
75% reaction takes 1 hour to finish. Tabulate the order of the reaction.
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SECTION-IV
(PARAGRAPH QUESTIONS)
This section contains TWO (02) questions stems.
There are TWO (02) questions corresponding to each question stem.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered at the designated place;
Zero Marks:0 in all other cases
PARAGRAPH-I
Carefully study the given segment of the modern periodic table:
Symbols of a few elements are mentioned in the appropriate box while the rest are hidden
inside boxes numbered 1 to 15.
48. If the atomic number of each of the hidden elements were divided by their box number,
how many natural numbers would show up?
49. If the stable oxidation states of elements hidden inside boxes 4, 8 and 12 are X, Y and Z
respectively in their compound, find the value of X Y Z
PARAGRAPH-II
Proline was first isolated in 1900 by Richard Willstatter. In the year that followed, Emil
Fischer isolated proline from casein, a milk protein. The amino acid gets its name from
the heterocyclic pyrrolidine unit it contains. It is a conditionally essential amino acid that
helps build collagen and supports healthy blood pressure and arterial elasticity.
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50. If for proline, pKa1 2 and pKa 2 10.6 ; then at pH 7 proline will exists as:
1. overall neutral structure with no charge sites
2. overall positively charged entity
3. overall negativity charged entity
4. overall neutral structure with equal number of oppositely charged sites
Select the correct number code from above and multiply it by the molecular weight of N-
methylproline (molar mass) to arrive at the answer.
51. When Proline undergoes Ninhydrin test, what colour is seen?
Select the correct colour code from above and multiply it by the number of carbons atoms
present in the pyrrolidine heterocycle to arrive at the answer.
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