Okay, I'll provide explanations that include the relevant parts of the questions for 46-75.

46. 260 g of an aqueous solution contains 60 g of urea (Molar mass = 60 g mol-1). The molality
of the solution is:
●​ A) 2m
●​ B) 3m
●​ C) 4m
●​ D) 5m
●​ E) 6mExplanation: Molality (m) = moles of solute / kg of solvent. Moles of urea = 60 g /
60 g/mol = 1 mol. Mass of water = 260 g (solution) - 60 g (urea) = 200 g = 0.2 kg. Molality
= 1 mol / 0.2 kg = 5 m.
47. Which of the following pair exhibits diagonal relationship?
●​ A) Li and Mg
●​ B) Li and Na
●​ C) Mg and Al
●​ D) B and P
●​ E) C and ClExplanation: Lithium (Li) and Magnesium (Mg) show a diagonal relationship.
48. The molecule which has see saw in structure is:
●​ A) NH3
●​ B) SF4
●​ C) CCl4
●​ D) SiCl4
●​ E) BrF5Explanation: SF4 has a see-saw structure due to one lone pair and four bond
pairs around the central sulfur atom.
49. The quantum number which determines the shape of the subshell is:
●​ A) Principal quantum number
●​ B) Magnetic quantum number
●​ C) Azimuthal quantum number
●​ D) Spin quantum number
●​ E) Principal and magnetic quantum numberExplanation: The azimuthal quantum number
(l) determines the shape of the subshell.
50. (Question and options not included in the provided text)
Explanation: Need the question to provide an explanation.
51. (Question and options not included in the provided text)
Explanation: Need the question to provide an explanation.
52. The limiting molar conductances of NaCl, HCl and CH3COONa at 300 K are 126.4, 425.9
and 91.0 S cm2 mol-1 respectively. The limiting molar conductance of acetic acid at 300 K is:
●​ A) 266 S cm2 mol-1
●​ B) 390.5 S cm2 mol-1
●​ C) 461.3 S cm2 mol-1
●​ D) 208 S cm2 mol-1
●​ E) 108 S cm2 mol-1Explanation: Λ°(CH3COOH) = Λ°(CH3COONa) + Λ°(HCl) - Λ°(NaCl)
= 91.0 + 425.9 - 126.4 = 390.5 S cm2 mol-1.
53. Which of the following liquid pair shows negative deviation from Raoult’s law?
●​ A) Phenol – Aniline
●​ B) Acetone - Carbon disulfide
●​ C) Benzene – Toluene
●​ D) n-hexane – n-heptane
●​ E) Bromoethane – ChloroethaneExplanation: Phenol-Aniline shows negative deviation
 due to hydrogen bonding.
54. The half-life period of a first-order reaction is 1000 seconds. Its rate constant is:
●​ A) 0.693 sec-1
●​ B) 6.93 x 10-2 sec-1
●​ C) 6.93 x 10-3 sec-1
●​ D) 6.93 x 10-4 sec-1
●​ E) 6.93 x 10-1 sec-1Explanation: For a first-order reaction, t1/2 = 0.693 / k, so k = 0.693 /
t1/2 = 0.693 / 1000 s = 6.93 x 10-4 s-1.
55. Which of the following material acts as a semiconductor at 298 K?
●​ A) Iron
●​ B) Copper oxide
●​ C) Sodium
●​ D) Graphite
●​ E) GlassExplanation: Copper oxide is a semiconductor.
56. The resistance of a conductivity cell filled with 0.02 M KCl solution is 520 ohm at 298 K. The
conductivity of the solution at 298 K is (Cell constant = 130 cm-1)
●​ A) 0.50 S cm-1
●​ B) 1.25 S cm-1
●​ C) 0.025 S cm-1
●​ D) 0.25 S cm-1
●​ E) 0.75 S cm-1Explanation: Conductivity = Cell constant / Resistance = 130 cm-1 / 520
ohm = 0.25 S cm-1.
57. For the equilibrium at 500 K, N2 (g) + 3H2 (g) ⇌ 2NH3 (g), the equilibrium concentrations of
N2 (g), H2 (g) and NH3 (g) are respectively 4.0 M, 2.0 M and 2.0 M. The Kc for the formation of
NH3 at 500 K is:
●​ A) 1/16 mol-2 dm6
●​ B) 1/32 mol-2 dm6
●​ C) 1/8 mol-2 dm6
●​ D) 1/4 mol-2 dm6
●​ E) 1/2 mol-2 dm6Explanation: Kc = [NH3]^2 / ([N2] * [H2]^3) = (2.0)^2 / (4.0 * (2.0)^3) =
4.0 / 32.0 = 1/8 mol-2 dm6.
58. The molarity of a solution containing 8 g of NaOH (Molar mass = 40 g mol-1) in 250 mL
solution is:
●​ A) 0.8M
●​ B) 0.4M
●​ C) 0.2M
●​ D) 0.5M
●​ E) 0.6MExplanation: Molarity = (grams of solute / molar mass of solute) / liters of solution
= (8 g / 40 g/mol) / 0.250 L = 0.2 mol / 0.250 L = 0.8 M.
59. Which of the following are the conditions for a reaction spontaneous at all temperatures?
●​ A) ΔH > 0 and ΔS > 0
●​ B) ΔH < 0 and ΔS > 0
●​ C) ΔH < 0 and ΔS < 0
●​ D) ΔH > 0 and ΔS < 0
●​ E) ΔH = 0 and ΔS > 0Explanation: For a reaction to be spontaneous at all temperatures,
ΔG must be negative. ΔG = ΔH - TΔS. This is true when ΔH is negative and ΔS is
positive.
60. Transition elements act as catalyst because:
 ●​ A) their melting points are high
●​ B) their ionization potential values are high
●​ C) they have high density
●​ D) they show variable oxidation state
●​ E) they have high electronegativityExplanation: Transition elements exhibit variable
oxidation states, which is a key reason for their catalytic activity.
61. Lanthanides (Ln) burn in O2 to give:
●​ A) LnO
●​ B) Ln(OH)3
●​ C) Ln2O3
●​ D) LnO2
●​ E) LnO3Explanation: Lanthanides burn in oxygen to form Ln2O3.
62. The IUPAC name of the coordination compound Hg[Co(SCN)4] is:
●​ A) Mercury (I) tetrathiocyanato-S-cobaltate (III)
●​ B) Mercury (II) tetrathiocyanato-S-cobaltate(II)
●​ C) Mercury (I) tetrathiocyanato-S-cobaltate (IV)
●​ D) Mercury (II) tetraisocyanato-S-cobaltate (III)
●​ E) Mercury (I) tetraisocyanato-N-cobaltate (III)Explanation: Mercury (II)
tetrathiocyanato-S-cobaltate(II).
63. In a combustion reaction, heat change during the formation of 40 g of carbon dioxide from
carbon and dioxygen gas is (Enthalpy of combustion of carbon = -396 kJ mol-1)
●​ A) 320 kJ
●​ B) -320 kJ
●​ C) -360 kJ
●​ D) 360 kJ
●​ E) 240 kJExplanation: Moles of CO2 = 40 g / 44 g/mol = 0.909 mol. Heat change = 0.909
mol * -396 kJ/mol = -360 kJ.
64. Which of the following statement is incorrect?
●​ A) Hyperconjugation is a permanent effect.
●​ B) Tertiary carbocation is relatively more stable than a secondary carbocation.
●​ C) F has stronger -I effect than Cl.
●​ D) Inductive effect decreases with increasing distance.
●​ E) When inductive and electromeric effects operate in opposite directions, the inductive
effect predominates.Explanation: The incorrect statement is E. When inductive and
electromeric effects operate in opposite directions, the electromeric effect predominates.
65. Which of the following statement is incorrect with regard to ozonolysis?
●​ A) It involves addition of ozone on alkene.
●​ B) An unsymmetrical alkene gives two different carbonyl compounds.
●​ C) It is used to identify the number of double bonds in starting material.
●​ D) It cannot be used to detect the position of the double bonds.
●​ E) Ozonide will undergo cleavage by Zn-H2O.Explanation: The incorrect statement is D.
Ozonolysis can be used to detect the position of double bonds.
66. Which of the following statement is true?
●​ A) Dehydration of alcohol takes place in presence of HCl/ZnCl2.
●​ B) Formation of ethene from ethyl iodide occurs on heating with aqueous KOH.
●​ C) Hydrogenation of an unsymmetrical alkyne in presence of Pd/C gives cis- alkene.
●​ D) Hydrogenation of an unsymmetrical alkyne in presence of Na/liq.NH3 gives cis-alkene.
●​ E) The order of reactivity of hydrogen halides towards alkenes is HI < HBr <
 HCl.Explanation: Hydrogenation of an unsymmetrical alkyne in presence of Pd/C gives
cis-alkene is true.
67. An organic compound X (C6H6O) on reaction with zinc dust gives ‘Y’. The product ‘Y’ reacts
CH3COCl in presence of anhydrous AlCl3 to give ‘Z’ (C8H8O). The compounds X, Y and Z are
respectively:
●​ A) benzaldehyde, benzene, methyl phenyl ketone
●​ B) phenol, benzene, acetophenone
●​ C) phenol, naphthalene, acetophenone
●​ D) benzene, phenol, diphenyl ketone
●​ E) cyclohexanol, cyclohexane, benzophenoneExplanation: X is phenol, Y is benzene,
and Z is acetophenone.
68. The percentage amylose in starch is about:
●​ A) 40-50 %
●​ B) 80-85 %
●​ C) 60-80 %
●​ D) 50-60 %
●​ E) 15 – 20 %Explanation: The percentage of amylose in starch is about 15-20%.
69. Which of the following statement is correct?
●​ A) Bromination of phenol in CS2 at low temperature give 2,4,6-tribromophenol.
●​ B) Oxidation of phenol with chromic acid gives benzene.
●​ C) Conversion of phenol into tribromophenol by bromine water is a nucleophilic
substitution reaction.
●​ D) p-Nitrophenol is steam volatile due to intermolecular hydrogen bonding.
●​ E) The intermediate in Riemer-Tiemann reaction is substituted benzal
chloride.Explanation: The intermediate in the Reimer-Tiemann reaction is a substituted
benzal chloride is correct.
70. On heating an aldehyde with Fehling’s reagent, a reddish-brown precipitate is obtained due
to the formation of:
●​ A) cupric oxide
●​ B) cuprous oxide
●​ C) carboxylic acid
●​ D) silver
●​ E) copper acetateExplanation: Cuprous oxide (Cu2O) is formed.
71. The decreasing order of basic strength of amines in aqueous medium is: (The options are
not included in the provided text. )
Explanation: Need the options to provide a complete explanation, but generally, in aqueous
solution, the order is secondary amine > primary amine > tertiary amine > ammonia.
72. Which of the following statement is correct?
●​ A) Sucrose is laevorotatory.
●​ B) Fructose is a disaccharide.
●​ C) Sucrose on hydrolysis gives D(+)-glucose only.
●​ D) Sucrose is made up of a glycosidic linkage between C1 of α-D-glucose and C2 of
β-D-Fructose.
●​ E) Sucrose is a reducing sugar.Explanation: Sucrose is made up of a glycosidic linkage
between C1 of α-D-glucose and C2 of β-D-Fructose is correct.
73. The structure of MnO4- ion is:
●​ A) square planar
●​ B) octahedral
 ●​ C) trigonal pyramid
●​ D) pyramid
●​ E) tetrahedralExplanation: MnO4- ion has a tetrahedral structure.
74. When benzene diazonium fluoroborate is heated with aqueous sodium nitrite solution in the
presence of copper, the product formed is:
●​ A) fluorobenzene
●​ B) benzene
●​ C) aniline
●​ D) nitrobenzene
●​ E) phenolExplanation: Nitrobenzene is formed.
75. A fibrous protein present in muscles is:
●​ A) keratin
●​ B) albumin
●​ C) riboflavin
●​ D) insulin
●​ E) myosinExplanation: Myosin is a fibrous protein found in muscles.