NEET

Ummeed NEET 2025

Organic Chemistry
Hydrocarbon

DPP : 01

Q1 Catalytic hydrogenation of benzene at high Reason R: Van der Waals forces decrease with
temperature and pressure forms; increase in molecular weight.
(A) xylene (B) cyclohexane In the light of the above statements, choose the
(C) benzoic acid (D) toluene correct answer from the options given below:
(A) A is true but R is false.
Q2 Consider the statements given below for the
(B) A is false but R is true.
conversion of 2-Bromopentane to form pent-2-
(C) Both A and R are true and R is the correct
ene and pent-1-ene.
explanation of A.
A. Pent-2-ene is the major product
(D) Both A and R are true but R is NOT the
B. It is dehydrohalogenation reaction
correct explanation of A.
C. It is dehydration reaction
The correct statement(s) is/are; Q7 Sodium salt of benzoic acid on heating with
(A) A, B and C (B) A and B sodalime gives;
(C) A and C (D) B and C (A) Cyclohexanol (B) Benzoic acid
(C) Benzene (D) Benzaldehyde
Q3 Which one of the following is not prepared by
Wurtz reaction? Q8 Addition of hydrogen halides to alkene is an
(A) C2H6 (B) C4H10 example of;
(C) CH4 (D) C6H14 (A) Electrophilic addition reaction
(B) Nucleophilic addition reaction
Q4 In which of the following, anti-Markovnikov
(C) Electrophilic substitution reaction
addition of HBr is not observed?
(D) Nucleophilic substitution reaction
(A) Propene (B) But-1-ene
(C) But-2-ene (D) Pent-2-ene Q9 Which of the following reaction forms propane?
(A) Ni

Q5 Higher alkanes can be converted to a mixture of CH3 − CH = CH2 + H2 →

(B)
+
Zn,H
lower alkanes by; CH3 Cl + H2 −−→

(A) hydrolysis (C) CaO,Δ

CH3 COONa + NaOH −−−→

(B) oxidation
(D) conc. H2 SO4 ,Δ

(C) pyrolysis CH3 CH2 OH −−−−−−−−→

(D) distillation under reduced pressure

Q10
Q6 Given below are two statements: one is labelled on reductive ozonolysis gives;
as Assertion A and the other is labelled as (A)
Reason R
Assertion A: Boiling point of alkanes increases (B)
with increase in molecular weight.

Android App | iOS App | PW Website

 NEET

(C) Choose the correct answer from the options

given below:
(D) CH3 CH2 CH2 CH2 CHO (A) A-III, B-I, C-II, D-IV
(B) A-III, B-II, C-IV, D-I
Q11 Given below are two statements: one is labelled (C) A-III, B-IV, C-II, D-I
as Assertion A and the other is labelled as (D) A-II, B-III, C-IV, D-I
Reason R
Assertion A: Sodium acetate on Kolbe’s Q14 Ethene reacts with cold, dilute and aqueous
electrolysis gives methane. solution of KMnO4 to form;
Reason R: Methyl free radical is formed at anode. (A) Ethane-1,2-diol
In the light of the above statements, choose the (B) Ethanol
correct answer from the options given below: (C) Ethanal
(A) A is true but R is false. (D) Ethanoic acid
(B) A is false but R is true.
Q15 Which of the following does not belong to
(C) Both A and R are true and R is the correct
alkanes homologous series?
explanation of A.
(A) CH4 (B) C2H6
(D) Both A and R are true but R is NOT the
(C) C3H8 (D) C4H8
correct explanation of A.
Q16 Calcium carbide when treated with water gives;
Q12 The major product formed during the hydration
(A) ethene (B) methane
(C) ethyne (D) ethane
of in the presence of
Q17 A and B respectively are;
H2SO4/HgSO4 is; Lindlar ' sCatalyst

(A) A ←−−−−−−−−− CH3 − C ≡ C − CH3

H2

Na /liq⋅NH3

−−−−−−→ B.
(B) (A) cis-But-2-ene and trans-But-2-ene
(B) trans-But-2-ene and Butane
(C) trans-But-2-ene and cis-But-2-ene
(C)
(D) cis-But-2-ene and Butane

Q18
(D)

Product ‘A’ in the given reaction is;

Q13 Match List-I with List-II (A)
List-I List-II
(Reagents) (Process)
(A) H2/Ni (I) Ozonolysis
(B) R-X + AICI3 (II) Dehalogenation (B)
(C) Zn (III) Hydrogenation
(i) O3
(D) (ii) Zn - H2O (IV) Friedel-Crafts reaction

Android App | iOS App | PW Website

 NEET

(C) (B)

(D) (C)

(D)

Q23 Hydrocarbon (A) reacts with bromine by

Q19 substitution to form an mono alkyl bromide
which by Wurtz reaction is converted to gaseous
hydrocarbon containing less than four carbon
atoms. Hydrocarbon (A) is;
Major product ‘A’ is;
(A) HC ≡ CH (B) H2 C = CH2
(A)
(C) CH3 − CH3 (D) CH4

Q24 The electrophile in the nitration of benzene is;

(B) (A) NO− (B) HNO3
3

(C) NO2 +
(D) NO−
2

Q25 Two jars A and B are filled with different

(C)
hydrocarbons. Br2 in CCl4 is added to these jars.
A does not decolourise the Br2 solution, but B
decolourises. A and B respectively can be;
(D) (A) Alkane and alkene
(B) Alkene and alkane
(C) Alkene and alkyne
(D) Alkyne and alkane
Q20 The product formed in the following reaction is;
− +
NaOH+CaO Q26 Given below are two statements:
CH3 CH2 COO Na −−−−−−→
Δ Statement I: But-1-ene on reaction with HBr in
(A) Hexane (B) Propane the presence of a peroxide produces 1-
(C) Ethane (D) Methane Bromobutane as major product.
Statement II: 1-Bromobutane is obtained in the
Q21 The compound having the lowest boiling point
above reaction by the formation of a more stable
among the following is;
primary carbocation.
(A) 2,2-Dimethylpropane
In the light of the above statements, choose the
(B) Hexane
correct answer from the options given below:
(C) 2-Methylbutane
(A) Statement I is correct but Statement II is
(D) Pentane
incorrect.
Q22 The reaction of C6H5CH = CHCH3 with HBr (B) Statement I is incorrect but Statement II is
produces the major product; correct.
(A) C6H5CH2CH2CH2Br (C) Both Statement I and Statement II are correct.

Android App | iOS App | PW Website

 NEET

(D) Both Statement I and Statement II are (A) aldehyde

incorrect. (B) ketone
(C) carboxylic acid
Q27 If benzene is obtained by heating phenol with 'X'
(D) alcohol
then X is;
(A) Zn dust Q32 Which branched chain isomers of the
(B) Soda lime hydrocarbon with molecular mass 72 u gives only
(C) Sodium hydroxide one isomer of monosubstituted alkyl halide?
(D) Na/dry ether (A) Neopentane (B) Isohexane
(C) Neohexane (D) n-Hexane
Q28 Given below are two statements: one is labelled
as Assertion A and the other is labelled as Q33 The order of reactivity of halogens in aliphatic
Reason R: substitution reaction is;
Assertion A: Treatment of bromine water with (A) Br2 > Cl2 > F2
propene yields 1-Bromopropan-2-ol. (B) Cl2 > Br2 > F2
Reason R: Attack of water on bromonium ion (C) F2 > Cl2 > Br2
follows Markovnikov rule and results in 1- (D) F2 > Br2 > Cl2
Bromopropan-2-ol.
Q34 To prepare a pure sample of n-hexane using
In the light of the above statements, choose the
sodium metal as (in the presence of dry ether)
correct answer from the options given below:
one reactant, the other will be;
(A) A is true but R is false.
(A) methyl chloride and n-butyl chloride
(B) A is false but R is true.
(B) Methyl chloride and n-hexyl bromide
(C) Both A and R are true and R is the correct
(C) Ethyl bromide and n-pentyl bromide
explanation of A.
(D) n-propyl bromide only
(D) Both A and R are true but R is NOT the
correct explanation of A. Q35 Match List-I with List-II
List-I List-II
Q29 In the following reaction,
Alkyl halide + Sodium
(A) in presence of dry (I) Aromatisation
Product A is; ether
(A) Aromatic (B) Anti-aromatic H2 SO4

Propanol −−−→
(C) Non-aromatic (D) Acyclic (B) Δ (II) Wurtz reaction
propene
Q30 The major product A obtained in the following V2 O 5

n-hexane −−→ Catalytic

reaction is; (C) 773 K (III)
hydrogenation
benzene
Alkene + Hydrogen in
(A) Butan-2-ol (B) Butan-2-one (D) (IV) Dehydration
presence of Ni
(C) Ethanoic acid (D) Butan-1-ol
Choose the correct answer from the options
Q31 The product obtained in the reaction given below given below:
has the functional group; (A) A-III, B-I, C-II, D-IV
(B) A-III, B-II, C-IV, D-I
(C) A-II, B-I, C-III, D-IV
(D) A-II, B-IV, C-I, D-III

Android App | iOS App | PW Website

 NEET

Q36 1,2-Dibromoethane on treatment with zinc metal Q41 The major product formed when 2-methylbutane
lose a molecule of ZnX2 to form; reacts with bromine in the presence of sunlight is;
(A) ethane (B) ethene (A) 1-bromo-3-methylbutane
(C) methane (D) butane (B) 2-bromo-3-methylbutane
(C) 2-bromo-2-methylbutane
Q37 Halogenation of an alkane with Cl2/hv takes
(D) 1-bromo-2-methylbutane
place through the intermediate;
(A) carbocation (B) carbanion Q42 Given below are two statements: one is labelled
(C) free radical (D) carbene as Assertion A and the other is labelled as
Reason R
Q38 Which is the most acidic among the following?
Assertion A: Sodium salt of butanoic acid on
(A) Methane (B) Ethyne
heating with soda lime gives butane.
(C) But-1-ene (D) Neopentane
Reason R: Decarboxylation reaction yields
Q39 Match List-I with List-II. alkanes having different number of carbon atoms
List-I List-II as that of the parent carboxylate ion.
In the light of the above statements, choose the
CH3 − CH = CH2 →
(A) (I) HBr correct answer from the options given below:
CH3 − CHBr − CH3
(A) A is true but R is false.
CH3 − CH = CH2 →
(B) (II) Zn (B) A is false but R is true.
CH3 − CH2 − CH2 Br
(C) Both A and R are true and R is the correct
CH2 Br − CH2 Br →
(C) (III) Br2/CCl4 explanation of A.
CH2 = CH2
(D) Both A and R are true but R is NOT the
CH3 − CH = CH2 → HBr +
(D) (IV) correct explanation of A.
CH3 − CHBr − CH2 Br peroxide
Choose the correct answer from the options Q43 CCl4

CH3 − CH = CH − CH2 − CH3 + Br2 −

−→
given below: Product of the above reaction is?
(A) A-II, B-I, C-III, D-IV (A)
(B) A-III, B-II, C-IV, D-I
(C) A-I, B-IV, C-II, D-III
(D) A-IV, B-III, C-I, D-II (B)

Q40 Which of the following are free radical reactions?

(C)
(A) CH3 CH = CH2 + HBr

peroxide

−−−−→ CH3 CH2 CH2 − Br

(B) CH3 CH = CH2 + HCl (D)

peroxide

−−−−→ CH3 CH(Cl) CH3

(C) Q44 Complete combustion of CH4 gives;

500°C

CH3 CH = CH2 + Cl2 −−→ Cl − CH2 CH (A) CO2 + H2O (B) CO2 + H2
= CH2 (C) COCI2 (D) CO + H2
hv

(D) CH3 CH3 + Cl2 → CH3 CH2 Cl

Q45 Aromatisation of n-hexane gives;
(A) D only (B) A and B (A) cyclohexane (B) benzene
(C) A, B and C (D) A, C and D (C) cycloheptane (D) toluene

Android App | iOS App | PW Website

 NEET

Q46 But-2-yne on reaction with excess Cl2 gives; (C)

(A) 1-chlorobutane
(B) 1,2-dichlorobutane
(C) 1,1,2, 2-tetrachlorobutane
(D) 2,2,3,3-tetrachlorobutane
(D)
Q47 Ethylene dibromide on heating with alc. KOH
followed by treatment with NaNH2 forms;
(A) Ethane (B) Ethylene
(C) Acetylene (D) Ethyl bromide
Q49 Ethene reacts with HOCI to form -
Q48 Which of the following compounds would have (A) Hydroxy ethene
slower rate of electrophilic bromination than (B) Chloro ethene
benzene? (C) Ethylene chlorohydrin
(A) (D) Ethanol

Q50 Identify 'A' in the given chemical reaction and

choose the correct option.

(B)

(A) Benzene
(B) Cyclohexane
(C) Methyl cyclohexane
(D) Toluene

Android App | iOS App | PW Website

 NEET

Answer Key
Q1 (B) Q26 (A)

Q2 (B) Q27 (A)

Q3 (C) Q28 (C)

Q4 (C) Q29 (A)

Q5 (C) Q30 (C)

Q6 (A) Q31 (B)

Q7 (C) Q32 (A)

Q8 (A) Q33 (C)

Q9 (A) Q34 (D)

Q10 (A) Q35 (D)

Q11 (B) Q36 (B)

Q12 (C) Q37 (C)

Q13 (C) Q38 (B)

Q14 (A) Q39 (C)

Q15 (D) Q40 (D)

Q16 (C) Q41 (C)

Q17 (A) Q42 (B)

Q18 (D) Q43 (C)

Q19 (C) Q44 (A)

Q20 (C) Q45 (B)

Q21 (A) Q46 (D)

Q22 (C) Q47 (C)

Q23 (D) Q48 (A)

Q24 (C) Q49 (C)

Q25 (A) Q50 (D)

Android App | iOS App | PW Website