Electrochemical Micromachining of Micro Hole Using Micro Dri
Electrochemical Micromachining of Micro Hole Using Micro Dri
A R T I C L E I N F O A B S T R A C T
Keywords: The stray current corrosion brings negative effects on the machining quality and accuracy in electrochemical
Electrochemical micromachining (EMM) micromachining (EMM) of micro hole, limiting the industrial application of EMM. This paper proposes the
Micro hole electrochemical micromachining of micro hole using micro drill with non-conductive mask on the machined
Non-conductive mask
surface. In this method, non-conductive mask was coated on the workpiece surface first. Then, the mask was
Micro drill
Stray current
drilled precisely by micro drill to expose the workpiece surface, which was a mask through-hole. Thirdly, on the
Stray corrosion location of this mask through-hole, the same micro drill was used as a cathode electrode to fabricate micro hole
through EMM. Lastly, the redundant mask was removed through a chemical method without damaging the
original surface of workpiece. The simulation results show that the mask coated on the workpiece surface can
reduce the stray current significantly, thereby decreasing the stray corrosion effectively. The cyanoacrylate was
chosen as an ideal mask material because of its excellent properties, such as low cost, easy operation, etc.
Through the above method, micro hole with high quality and accuracy was fabricated successfully, demon
strating that using micro drill with non-conductive mask coated on the workpiece surface can not only effectively
protect the workpiece surface from corrosion, but also improve the machining quality and accuracy of micro hole
in EMM.
* Corresponding author at: School of Mechanical Engineering, Shandong University, Jinan, 250061, China.
E-mail address: [email protected] (X. Yue).
https://doi.org/10.1016/j.jmapro.2020.09.077
Received 15 June 2020; Received in revised form 24 August 2020; Accepted 30 September 2020
Available online 10 October 2020
1526-6125/© 2020 The Society of Manufacturing Engineers. Published by Elsevier Ltd. All rights reserved.
H. Zou et al. Journal of Manufacturing Processes 59 (2020) 366–377
Fig. 1. Schematics of the experimental setup used to fabricate micro hole by EMM.
traditional ECM, has been applied in the machining of micro holes [7,8]. difficult in the ECM with the ultrasonic vibration, limiting its wide ap
However, EMM also faces many challenges in the machining of micro plications in the EMM of micro hole. In recent years, ultra-short pulse
holes with high quality and precision, such as the stray corrosion [9], with tens of nanosecond duration is used in EMM to improve the
poor machining accuracy and process stability. As a result, traditional machining precision and quality [17–19]. However, the machining ef
EMM technology cannot satisfy the usage requirements of micro holes ficiency of ultra-short-pulse EMM is extremely low, which limits its wide
with high precision and surface quality. Thus, many researchers [10–12] applications.
have been focusing on improving the machining quality and precision of To protect the machining surface from corrosion by the stray current
micro holes in ECM. Some researchers designed or optimized the shapes from the bare micro electrode and improve the machining accuracy, this
of micro electrode to achieve better electrical density distribution and paper proposes another new method which is the electrochemical
thus improve machining accuracy. However, the stray current coming micromachining of micro holes using micro drill with non-conductive
from the side wall of bare microelectrode is unavoidable. On the other mask on the machined surface. In this method, non-conductive mask
hand, some researchers [13–15] applied the insulated layer on the sur is coated on the workpiece surface first. Then, this non-conductive mask
face of the cathode electrode to avoid the influence of the stray current is drilled precisely by a micro drill. Finally, on the location of this mask
on the machining precision and quality of holes in ECM. But, it is very hole, a micro hole on the metal workpiece can be machined through
hard and expensive to prepare the insulated layer on the surface of micro EMM by using the same micro drill as the cathode electrode. The
electrode whose diameter is just tens of micrometers, thus, this method simulation and experimental results demonstrate that this method pro
is limited in the practical application of EMM process. Wang et al. posed in this study can effectively improve the machining accuracy and
demonstrates that the ultrasonic vibration in ECM can improve the quality of micro hole in EMM. Furthermore, the preparation of non-
surface quality of machined workpiece and decease the radial overcut conductive mask on the surface of workpiece doesn’t rely on the com
and hole taper [16]. However, the rotation of the tool electrode is plex technological process and expensive equipment, such as the
367
H. Zou et al. Journal of Manufacturing Processes 59 (2020) 366–377
Fig. 3. Comparison diagram of the cylindrical electrode and micro drill in transferring the electrolysis products.
368
H. Zou et al. Journal of Manufacturing Processes 59 (2020) 366–377
Fig. 4. Top surface of workpiece before and after drilling micro hole.
369
H. Zou et al. Journal of Manufacturing Processes 59 (2020) 366–377
Fig. 6. Schematics of working principle of non-conductive mask cooperating with micro drill to fabricate micro hole in EMM.
machining conditions of low concentration electrolyte and pulse power electrolyte due to the stray corrosion, as shown in Fig. 4.
were used in the fabrication of micro hole on the spring steel workpiece Some researchers used an insulated through-hole mask to cover the
through EMM, the machining quality and accuracy of micro hole were workpiece surface. The machined area of workpiece is exposed by these
still extremely low under the condition of jetting electrolyte. Next, a new through-holes on the mask while the other area can be protected by the
method would be proposed to solve the above problem. mask effectively [22]. Through the design of through-hole array,
different kinds of complex micro-dimple array on the workpiece surface
3. Propose of non-conductive mask cooperating with micro drill can be fabricated easily by ECM. Inspired by this method, we propose
to fabricate micro hole the electrochemical micromachining of micro hole using micro drill with
non-conductive mask on the machined surface. In this method,
3.1. Principle of non-conductive mask cooperating with micro drill to non-conductive mask is coated on the workpiece surface first. Then, this
fabricate micro hole non-conductive mask is drilled precisely by a micro drill, as shown in
Fig. 6(a). The micro drill and the workpiece are connected to the outputs
Traditionally, in the fabrication of hole by ECM, to reduce the of the contact perception of the machine tool. In the drilling process of
negative effect of the stray corrosion on the machining accuracy and the mask hole, every 1 μm the micro drill moves towards the workpiece
quality, the outer surface of the cathode electrode is coated with non- surface, the machine tool will detect the voltage between the micro drill
conductive mask [13–15]. However, in the EMM of micro hole, the and workpiece. When the micro drill touches the workpiece surface, the
above method faces new problems. On one hand, it is quite expensive or voltage between the micro drill and workpiece becomes zero and the
difficult to coat non-conductive mask on the outer surface of micro movement of the micro drill is stopped by the machine tool immediately.
cathode electrode whose diameter is just tens of micrometers. On the Through the above method, the relative position between the micro drill
other hand, in the EMM of micro hole, along with the decrease of the and workpiece can be determined preciously. Finally, on the location of
diameter of cathode electrode, the fabrication of hollow electrode is this mask hole, micro hole on the anode workpiece can be machined
becoming more and more difficult. As a result, flushing the electrolyte through EMM by using the same micro drill as the cathode electrode, as
from the inside of the cathode electrode is becoming impossible. Thus, to shown in Fig. 6(b). During the machining process, it is guessed that
guarantee the flow and renewal of the electrolyte in the micro hole non-conductive mask coated on the workpiece surface can protect the
during the EMM, flushing the electrolyte from the outside of the cathode non-machining area of the workpiece surface from being corroded by
electrode is extensively adopted. However, the machining experiment the stray current, thereby improving the machining quality and accu
has demonstrated that as for some materials that are easy to be corroded, racy. Next, a simulation will be implemented to verify this method
the workpiece surface can be destroyed seriously by the flushing theoretically.
370
H. Zou et al. Journal of Manufacturing Processes 59 (2020) 366–377
Table 2 bubbles generated in EMM, were neglected, and the electrolyte con
Simulation conditions. ductivity k was assumed to be constant.
Electrolytic conductivity k 1.7 S/m Based on the theory of the static electric field, the potential distri
Machined voltage U 10 V bution ϕ in the electrolyte follows the Laplace’s equation, as shown in
Feeding speed v 40 μm/s Eq. (1).
∂2 ϕ ∂2 ϕ
∇2 ϕ = + =0 (1)
∂x2 ∂y2
→
The current density J n is given by Eq. (2).
→
J n = − k∇ϕ (2)
371
H. Zou et al. Journal of Manufacturing Processes 59 (2020) 366–377
Fig. 10. Schematics of the 1st method for preparation and removal process of non-conductive mask on the workpiece surface.
that was larger than 105 A/m2 was only -70 μm/s ~ 70 μm/s. Fig. 9 The first method used the electrophoretic deposition (EPD) tech
shows the comparison of the surface morphology of the anode. From nology to prepare the mask on the workpiece surface. The EPD is a
Fig. 9(a), it can be found that due to a wide range of stray current on the process that colloidal particles suspended in a liquid medium migrate
anode surface without non-conductive mask, the anode material was under the influence of an electric field (electrophoresis) and are
removed on a large scale, generating a bell-mouth profile. But, from deposited onto an electrode. All colloidal particles that can be used to
Fig. 9(b), it can be found that due to the protection of non-conductive form stable suspensions and that can carry a charge can be used in
mask on the anode surface, the stray current only caused a small-scale electrophoretic deposition. This includes materials, such as polymers,
undercutting, generating a bowl-mouth profile. The simulation results pigments, dyes, ceramics and metals [25]. The mask preparation and
demonstrate that the non-conductive mask coated on the anode surface removal processes were shown in Fig. 10 as follow: i) The workpiece was
can decrease the stray current effectively, thereby improving the connected with the cathode and put into the liquid medium with the
machining accuracy and quality markedly. colloidal particles solution of epoxy resin; ii) The workpiece with the
epoxy resin mask was dried in a drying oven; iii) The workpiece was
4. EMM of micro holes with mask on the machined surface drilled by micro drilling and machined by EMM; iv) The workpiece was
soaked in the epoxy resin remover liquid for 30 min to remove the epoxy
4.1. Preparation of non-conductive mask on the workpiece surface resin mask; v) The workpiece was cleaned in the alcohol liquid. The
comparison photograph of workpiece surface without epoxy resin mask
The simulation results have demonstrated that non-conductive mask (upper) and with epoxy resin mask (lower) prepared through the above
coated on the workpiece surface can not only protect the workpiece method was shown in Fig. 12(a). The mask prepared by this method was
surface from corrosion, but also improve the machining accuracy. black and its thickness is 10~20 μm.
However, in the practical application, making a mask with excellent The mask preparation and removal process of the second method was
performances on the workpiece surface is the key to achieve the above shown in Fig. 11 as follows: i) The workpiece tilted at 45◦ and the
method successfully. Thus, the mask prepared on the workpiece surface cyanoacrylate liquid (CH2– – C(CN)− COO-C2H5) dropped from the
must have the following properties: (1) easy to be fabricated by micro burette onto the workpiece surface. Under the action of gravity, the
drilling. The drilling accuracy and quality have significant and direct cyanoacrylate glue can flow and cover the workpiece surface; ii) The
influences on the final fabrication of micro hole by EMM, which will be workpiece still tilted at 45◦ and the water dropped from the burette onto
discussed in the Section 4.2; (2) good combination with the workpiece the mask surface. The liquid cyanoacrylate mask can be solidified with
surface. If the mask and workpiece surface don’t combine strongly, the water; iii) The workpiece surface was dried in the air; iv) The workpiece
electrolyte can percolate through the gap between the mask and work was drilled by drilling and machined by EMM; v) The workpiece was
piece surface, causing the stray corrosion; (3) the mask must be easy to soaked in the acetone liquid for 10 min to remove the solidified
be removed from the surface workpiece after EMM; (4) mask prepara cyanoacrylate mask; vi) The workpiece was cleaned in the alcohol
tion with convenience and low cost. Through constant attempts with liquid. The comparison photograph of workpiece surface without
different mask materials and manufacturing processes, two kinds of cyanoacrylate mask (upper) and with epoxy resin mask (lower) prepared
methods are proposed and compared as follows. through the above method was shown in Fig. 12(b). The mask prepared
372
H. Zou et al. Journal of Manufacturing Processes 59 (2020) 366–377
Fig. 11. Schematics of the 2nd method for preparation and removal process of non-conductive mask on the workpiece surface.
373
H. Zou et al. Journal of Manufacturing Processes 59 (2020) 366–377
Fig. 13. Optical images of micro hole machined by EMM with the 1st method shown in Fig. 10.
Fig. 15. Optical images of micro hole machined by EMM with the 2nd method shown in Fig. 10.
cyanoacrylate mask. During the removal process of the cyanoacrylate very promising mask material used to protect the workpiece surface.
mask, the acetone didn’t bring about any negative influence on the However, the solid cyanoacrylate was quite brittle, and its machining
workpiece surface, such as the corrosion. Moreover, the preparation performance should be investigated first.
process of the cyanoacrylate mask was quite simple and didn’t rely on Fig. 14 shows the mask hole drilled under 2000 r/min and 10,000 r/
complex operation and equipment. Thus, the cyanoacrylate mask was a min. From the figure, it can be found that the shape and dimensional
374
H. Zou et al. Journal of Manufacturing Processes 59 (2020) 366–377
rotating speed of micro drill. But, when the rotating speed exceeded
4000 r/min, the diameter of the mask hole didn’t change obviously.
Thereby, in the following machining experiment, 4000 r/min was used.
Figs. 17 and 18 show micro holes machined in EMM with the mask
and without the mask respectively under the machining conditions
shown in Table 1 with the rotating speed of spindle 4000 rpm, voltage
frequency 10 kHz and 100 kHz, feeding rate 1 μm/s. The thickness of
workpiece used was 100 μm. From Fig. 17, it can be seen that the
workpiece surface at the inlet of micro hole kept its original quality after
drilling micro hole due to the protection of the mask. But, Fig. 18 shows
that the workpiece surface around the inlet of micro hole was corroded
by the stray current after drilling micro hole without the mask. Due to
the limitation of figure dimension, the fan-shaped stray corrosion zone
caused by the electrolyte that flowed on the surface of workpiece was
not presented here, which has been shown and discussed in Fig. 4.
Fig. 16. Relationship between the diameter of micro hole and the rotation
Moreover, the shape and dimensional accuracy of the inlet of micro hole
speed of micro drill.
machined with mask were also improved markedly compared to the
micro hole machined without mask on the workpiece surface. From
accuracy of the mask hole drilled under 10,000 r/min were much better Fig. 17, it can be found that the inlet diameter and the outlet diameter of
than the mask hole drilled under 2000 r/min. Fig. 15 shows the influ micro hole were almost equal and the taper of micro hole was near 0◦ no
ence of the machining quality of the mask hole on the final machining matter under low or high frequency of machined voltage. But, without
quality of micro hole in EMM. In Fig. 15(a), a crack defect around the the mask on the workpiece surface, the inlet diameter of micro hole was
Inlet of micro hole occurred during the drilling process of the mask hole larger than the outlet diameter of micro hole, as shown in Fig. 18. The
by micro drill. As a result, the defective mask can’t protect the work bell mouth and taper of micro hole were obvious. It should be noted that
piece surface effectively, and the workpiece surface was corroded with the mask on the workpiece surface, the outlet diameter of micro
locally. The final shape of micro hole machined in EMM was not circular, hole was a little larger than the inlet diameter of micro hole, as shown in
as shown by Fig. 15(b). Thus, the drilling quality of the mask hole has a Fig. 17. This is because the workpiece surface at the outlet of micro hole
significant influence on the final shape of micro hole by EMM. Fig. 16 was not coated with the mask, as a result, the outlet of micro hole was
shows the influence of the rotating speed of micro drill on the machining corroded slightly by the stray corrosion when micro drill drilled through
quality of the mask hole. From the figure, it can be found that the micro hole.
diameter of the mask hole decreased along with the increase of the To further investigate the inside of micro hole, micro holes were
Fig. 17. SEM images of micro hole machined by EMM with the 2nd method shown in Fig. 10.
375
H. Zou et al. Journal of Manufacturing Processes 59 (2020) 366–377
376
H. Zou et al. Journal of Manufacturing Processes 59 (2020) 366–377
fabricated on the workpiece with the thickness of 300 μm and then cut References
through their middle section. Fig. 19(a) and (b) show the SEM images of
cross-section of micro holes with and without the mask, respectively. [1] Zhu D, Qu NS, Li HS, Zeng YB, Li DL, Qian SQ. Electrochemical micromachining of
microstructures of micro hole and dimple array. CIRP Ann-Manuf Technol 2009;58
The machining conditions were shown in Table 1 with the rotating speed (1):177–80. https://doi.org/10.1016/j.cirp.2009.03.004.
of spindle 4000 rpm, voltage frequency 10 kHz, feeding rate 0.5 μm/s. [2] Li CJ, Zhang BW, Li Y, Tong H, Ding SL, Wang ZQ, et al. Self-adjusting EDM/ECM
From Fig. 19(a), it can be found that with the mask, the taper of micro high speed drilling of film cooling holes. J Mater Process Technol 2018;262:
95–103. https://doi.org/10.1016/j.jmatprotec.2018.06.026.
was very small. But, without the mask, micro hole has a very obvious [3] Sen MH, Shan HS. A review of electrochemical macro- to micro-hole drilling
taper that was about 7◦ . Furthermore, the surface quality of micro hole processes. Int J Mach Tool Manuf 2005;45(2):137–52. https://doi.org/10.1016/j.
with the mask was much better than that without the mask. ijmachtools.2004.08.005.
[4] Krotz H, Wegener K. Sparc assisted electrochemical machining: a novel possibility
Thus, the above comparison experiments demonstrated that non- for microdrilling into electrical conductive materials using the electrochemical
conductive mask on the machined surface can improve the machining discharge phenomenon. Int J Adv Manuf Technol 2015;79:1633–43. https://doi.
accuracy and quality in EMM of micro hole. Furthermore, the cyano org/10.1007/s00170-015-6913-9.
[5] Zhao YH, Kunieda M. Investigation on electrolyte jet machining of three-
acrylate mask not only protected the workpiece surface but also didn’t
dimensional freeform surfaces. Precis Eng 2019;60:42–53. https://doi.org/
cause any damage on the original surface of workpiece, demonstrating 10.1016/j.precisioneng.2019.06.009.
that the cyanoacrylate material was an ideal mask material. [6] Han W, Kunieda M. A novel method to switch machining mode between Micro-
With the increasing demand of machining quality and accuracy for ECM and micro-EDM using oxide film on surface of tungsten electrode. Precis Eng
2019;56:455–65. https://doi.org/10.1016/j.precisioneng.2019.02.002.
micro holes in various micro components, EMM was put forward much [7] Rahman Z, Das AK, Chattopadhyaya S. Microhole drilling through electrochemical
higher requirements for better machining performance. Based on the processes: a review. Mater Manuf Process 2018;33(13):1379–405. https://doi.org/
above simulation and experimental results, it can be concluded that 10.1080/10426914.2017.140172.
[8] Hourmand M, Sarhan AAD, Sayuti M. Micro-electrode fabrication processes for
using micro drill as cathode electrode in combining with non-conductive micro-EDM drilling and milling: a state-of-the-art review. Int J Adv Manuf Technol
mask coated on the workpiece surface in EMM was an effective and easy 2017;91(1–4):1023–56. https://doi.org/10.1007/s00170-016-9671-4.
method to protect the machining surface from corrosion and to fabricate [9] Wang XD, Qu NS, Fang XL. Reducing stray corrosion in jet electrochemical milling
by adjusting the jet shape. J Mater Process Technol 2019;264:240–8. https://doi.
micro hole with high accuracy and quality, thereby, further promoting org/10.1016/j.jmatprotec.2018.09.017.
the industrial application of EMM. [10] Liu Y, Zhu D, Zeng YB, Yu HB. Development of microelectrodes for electrochemical
micromachining. Int J Adv Manuf Technol 2011;55(1–4):195–203. https://doi.
org/10.1007/s00170-010-3035-2.
5. Conclusions [11] Ghoshal B, Bhattacharyya B. Shape control in micro borehole generation by EMM
with the assistance of vibration of tool. Precis Eng 2014;38(1):127–37. https://doi.
This paper proposes the electrochemical micromachining of micro org/10.1016/j.precisioneng.2013.08.004.
[12] Zhao JS, Zhang XL, Yang ZW, Lu YM, He YF. Experimental research on the
holes using micro drill with non-conductive mask coated on the work
optimization of precision electrochemical machining feed mode of diamond-hole
piece surface to improve the machining quality and accuracy of micro grille. Int J Adv Manuf Technol 2017;91(1–4):147–53. https://doi.org/10.1007/
hole in EMM. Based on the simulation and experimental results, some s00170-016-9740-8.
research findings were shown as follows: [13] Liu GD, Li Y, Kong QC, Tong H. Research on ECM process of micro holes with
internal features. Precis Eng 2017;47:508–15. https://doi.org/10.1016/j.
precisioneng.2016.10.006.
1 Compared with the EMM of micro hole without non-conductive mask [14] Wang J, Chen W, Gao F, Han FZ. Ultrasonically assisted electrochemical micro
on the workpiece surface, the EMM of micro hole with non- drilling with sidewall-insulated electrode. Proc Inst Mech Eng B-J Eng 2016;230
(3):466–74. https://doi.org/10.1177/0954405414555740.
conductive mask coated on the workpiece surface can not only [15] Swain AK, Sundaram MM, Rajurkar KP. Use of coated microtools in advanced
effectively protect the workpiece surface from corrosion, but also manufacturing: an exploratory study in electrochemical machining (ECM) context.
improve the machining quality and accuracy of micro hole J Manuf Process 2013;14:150–9.
[16] Wang MH, Zhang YB, He ZW, Peng W. Deep micro-hole fabrication in EMM on
significantly. stainless steel using disk micro-tool assisted by ultrasonic vibration. J Mater
2 The simulation results indicate that the non-conductive mask coated Process Technol 2016;229:475–83. https://doi.org/10.1016/j.
on the workpiece surface can decrease the stray current and stray jmatprotec.2015.10.004.
[17] Ahn SH, Ryu SH, Choi DK, Chu CN. Electro-chemical micro drilling using ultra
corrosion significantly, generating a bowl-mouth profile. But, on the short pulses. Precis Eng 2004;28(2):129–34. https://doi.org/10.1016/j.
workpiece surface without non-conductive mask, due to a wide precisioneng.2003.07.004.
range of stray current, the anode material was removed on a large [18] Han W, Kunieda M. Fabrication of tungsten micro-rods by ECM using ultra-short-
pulse bipolar current. CIRP Ann-Manuf Technol 2017;66(1):193–6. https://doi.
scale, generating a bell-mouth profile.
org/10.1016/j.cirp.2017.04.131.
3 The experimental results demonstrate that the cyanoacrylate was a [19] Ryu SH. Eco-friendly ECM in citric acid electrolyte with microwire and microfoil
kind of excellent mask material with low cost and easy operation. electrodes. Int J Precis Eng Manuf Technol 2015;16:233–9. https://doi.org/
The machining quality and accuracy of micro hole in EMM was 10.1007/s12541-015-0031-3.
[20] Chen XL, Qu NS, Fang XL, Zhu D. Reduction of undercutting in electrochemical
influenced by the machining quality of mask hole which was influ micro-machining of micro-dimple arrays by utilizing oxygen produced at the
enced by the rotating speed of micro hole. The experimental results anode. Surf Coat Technol 2015;277:44–51. https://doi.org/10.1016/j.
show that the mask hole can be drilled well when the rotating speed surfcoat.2015.07.028.
[21] Zhang XF, Qu NS, Chen XL. Sandwich-like electrochemical micromachining of
of micro drill exceeded 4000 r/min. micro-dimples. Surf Coat Technol 2016;302:438–47. https://doi.org/10.1016/j.
surfcoat.2016.05.088.
Declaration of Competing Interest [22] Chen XL, Qu NS, Li HS, Xu ZY. Electrochemical micromachining of micro-dimple
arrays using a polydimethylsiloxane (PDMS) mask. J Mater Process Technol 2016;
229:102–10. https://doi.org/10.1016/j.jmatprotec.2015.09.008.
The authors report no declarations of interest. [23] Principle of material removal in electrochemical micromachining. In:
Bhattacharyya B, editor. Electrochemical micromachining for nanofabrication,
MEMS and nanotechnology. William Andrew Publishing; 2015. p. 53–67.
Acknowledgements [24] Haisch T, Mittemeijer E, Schultze JW. Electrochemical machining of the steel
100Cr6 in aqueous NaCl and NaNO3 solutions: microstructure of surface films
This paper is supported by National Natural Science Foundation of formed by carbides. Electrochim Acta 2001;47(1–2):235–41. https://doi.org/
10.1016/S0013-4686(01)00561-8.
China (Youth Program, Grant No. 51905311), Natural Science Foun
[25] Boccaccini AR, Dickerson JH. Electrophoretic deposition: fundamentals and
dation of Jiangsu Province (BK20190203), the Key Laboratory of High- applications. J Phys Chem B 2013;117. https://doi.org/10.1021/jp211212y. 1501-
efficiency and Clean Mechanical Manufacture at Shandong University 150.
(Ministry of Education), and China Postdoctoral Science Foundation
(2020M672052).
377