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SOLVED PAPER - 2022| H.S. 2ND
YEAR
BY MANTU PANDIT Mantu Pandit 11:33 PM

AHSEC| CLASS 12| CHEMISTRY|

SOLVED PAPER - 2022| H.S. 2ND
YEAR
2022
CHEMISTRY
(Theory)
Full Marks: 70
Pass Marks: 21
Time: Three hours
The figures in the margin indicate full marks for the
questions.

1. A metal crystallies in a body-centred cubic structure.

If ‘a’ is the edge length of its unit cell, ‘r’ is the radius of
the sphere, what is the relationship between ‘r’ and
‘a’? 1

2. Arrange the following compounds in the increasing

order of their boiling points: CH3 -CHO, CH3 -CH2 -OH,
CH3 -CH2 -CH3 1

3. Write down the formula of

Tetraamineaquachloridocobalt(III) chloride. 1

Ans:- [CQ(NH3)4(H2O)CI]CI2

4. Write the IUPAC name of the following compound:

1

Ans:- Benzylic propeneol.

5. What will be the impact on Kf when the molality of a

solution is doubled? 1

Ans:- When the molality of a solution is doubled, the

effect on Kf will remain unchanged.

6. Which is a stronger oxidizing agent- 1

Ans:- Bi.

7. pKb of aniline is more than that of methylamine.

Why? 1

Ans:- In aniline, the lone pair of electrons on the N-atom

delocalizes over the benzenering. As a result, the electron
density on nitrogen decreases. On the other hand, in
CH3NH2,+l effect of CH3 group increases the electron
density on the N-atom. Hence aniline is less basic than
methylamine. Therefore, the Kb value of aniline is less
than that of methylamine.

8. Which of the following compounds can undergo Hell-

Volhard-Zelinsky reaction? 1

(i) Benzoic acid (ii) Propanoic acid

Ans:- (ii) Propanoic acid.

9. The freezing point depression constant for water is

1.860Cm-1. If 5.0g of Na2So4 is dissolved in 45g of water,
then freezing point is charged by 3.800C. Calculate the
Van’t Hoff factor for Na2So4. 2

Or

State Henry’s law. Why do gases nearly always tend

to be less soluble in liquids as the temperature is
raised? 2

Ans:- Henry's law states that at a constant

temperature the mass of a gas dissolved per unit volume
of solvent is directly proportional to the pressure of the
gas in equilibrium with the solution.

If m is the mass of the gas dissolved in unit volume

of the solvent and p is the pressure of the gas in
equilibrium with the solution, then

m p

Or m = k.p.

Where is the constant of proportionality.

The solubility of gases in liquids decreases with

increase in temperature. Because solution is an
exothermic process.

10. Calculate the pH at which the potential of hydrogen

electrode will be 0.059V. 2

Ans:- Given, 2H+ + 2e-1 –>H2

Ecell = E0cell – 0.059log 1/H+ Ecell = E0cell –

0.059PH

0.059 = 0.0 – 0.059PH PH = -1

Or

The Chemistry of corrosion of iron is essentially an

electrochemical phenomenon. Explain the reaction
occurring during the corrosion of iron in the
atmosphere. 2

11. Why H2 and O2 do not react at room temperature?

Write the rate equation for the reaction A2+B2 -->2C, if
the overall order of the reaction is zero. 1+1=2

Ans:- H2 and O2 do not react at room temperature

because the activation energy for that reaction is high
which is not provided at room temperature.

Since, the overall order of the reaction is zero, hence

the rate equation for the reaction A2 + 3B2 –> 2C, is Rate,
= K[A]0[B]0

Or

A first order reaction has a rate constant of 0.0051

min-1. If we begin with 0.10M concentration of the
reactant, what concentration of reactant will remain in
solution after 3 hours? 2

12. Answerer any two:

(a) Write the mathematical expression for the

Freundlich absorption isotherm and draw the graph log
x/y vs log P. 2

Ans:- The plot of the extent of adsorption (x/m)

against the pressure of a gas (P) at a constant
temperature (T) is called an adsorption isotherm.

Freundlich adsorption isotherm for the adsorption of

gases on solids:

x/m = K P1/n

It can also be written as

Log x/m = log k+1/n log P

Where x = mass of adsorbate

M = mass of adsorbent

P = Pressure of the gas

N = Constant and is greater than 1.

(b) How do emulsifiers stabilize emulsion? Name two

emulsifiers. 2

Ans:- Emulsifiers stabilize an emulsion by reducing the

interfacial tension between the two liquids that make up
the emulsion. glue, soap etc.

(c) Define shape-selective catalysis. Give an

example. 1+1=2

Ans:- The catalytic reaction which depends on the

pore structure and pore structure of the catalyst or the
size of the catalyst and reactant and product molecules is
called size-selective catalysis.

13. Why is it that only sulphide ores are concentrated by

froth floatation processes? What is the role of
depressants in the froth floatation process of dressing
of ores? 1+1=2

Ans:- Since the sulphide particles are preferentially

wetted with oil and further processing by gangue coaters
is selected depending on the concentration of the
sulphide ore.

A depressant suppresses the formation of scum with

a particular compound in the froth flotation process by
chemically reacting with it. Thus, it helps in the
separation of two metal sulphides viz: ZnS and PbS In
case of ore containing, NaCN is used as a depressant. It
forms a layer of Zn complex, Na2 [Zn(CN)4] with ZnS on
the surface of ZnS and hence prevents it from foaming.

ZnS + 4NaCN –> Na2 [Zn(CN)4] + Na2S

14. Answer any two:

(a) Ti4+ compounds are colourless in aqueous

solution but Ti3+ compounds are violet coloured.
Explain. 2

Ans:- If Ti4+ has no electron in the d-orbital, no d-d

transition is possible and hence it is colourless. But in Ti3+
one electron is in d-orbital. So, it's coloured.

(b) What is meant by ‘disproportionation’ of an

oxidation state? Give an example. 2

Ans:- 'Disproportionation', is a redox reaction in which

a compound in an intermediate oxidation state is
converted into two compounds, one in a higher and one in
a lower oxidation state.

(c) Actinoid contraction is greater than lanthanoid

contraction. Why? 2

Ans:- The actinides in general exhibit a greater range

of oxidation states than the cap of the lanthanides. This is
due to the fact that in the case of actinides the 5f, 6d and
7s levels are of comparable energy.

15. (i) Write the IUPAC name of the following

compound: 1

[Pt(NO2)(NH3)BrCI]

Ans:- Triamminebromochloronitroplatinum (iv)

chloride.

(ii) How many geometrical isomers will be possible

for [Pt(Py)(NH3)BrCI] compound? 1

Ans:- 3 no. of geometrical isomers will be possible.

Or

Write the hybridization state of central atom of the

following co-ordination complexes along with their
magnetic properties. 2

[Cu(NH3)4]2+ and [Ni(CO)4]

Ans:- Hybridization state of the central atom of -

[Cu(NH3)4]2+ = dsp2 , [N1(CO)4] = Sp3

***

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