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Acid Radicals

The document outlines methods for detecting various acid radicals in salt analysis, including carbonate, chloride, nitrate, acetate, and sulfate. Each section describes specific tests and observations to confirm the presence of these radicals using dilute and concentrated sulfuric acid, as well as other reagents. The results indicate the successful identification of each radical through characteristic reactions and confirmatory tests.

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20 views5 pages

Acid Radicals

The document outlines methods for detecting various acid radicals in salt analysis, including carbonate, chloride, nitrate, acetate, and sulfate. Each section describes specific tests and observations to confirm the presence of these radicals using dilute and concentrated sulfuric acid, as well as other reagents. The results indicate the successful identification of each radical through characteristic reactions and confirmatory tests.

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aqsa393808
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CHEMISTRY SS ee PART Ill; SALT ANALYSIS + Detection of Acid Radicals Detection of the radicals of dilute acid group Dilute acid group (CO}-, HCO; ,SO}",8,07",NO; ,S*") Carbonate(CO}). i Dilute acid group Colourless, odourless (CO?, HCO; , SOF, Salt + dil H2SO, gas evolve with + NOr-s* effervescence S,03,NOz,8") Present Pass above gas through lime ; water Lime water tum milky | May be COS orHCO} Si May be soluble ‘Salt + distilled water Soluble CO? or HCOY O.S + MgSO, solution White ppt. in cold state | Soluble CO} indicated Confirmatory Test O.S + BaCl; solution White ppt. in cold state CO} confirmed O.S + CaCl; solution White ppt. in cold state CO} confirmed Result: Soluble carbonate (CO?) confirmed. cHEMISTRY a ———— Chloride (CI) 1 | Salt +dil HSO, No gas evolve ION OF THE RADICALS OF CONCENTRATED ACID GROUP Concentrated Acid Group. (CI",Br”,CH,COO",C,0? NO; ) Dilute acid group (CO?,HCO',SO;, s,07,NO},S*) Absent 2 | Salt + Conc. HaSO, Colourless gas evolve with Conc. H2SOx group (CI, Br ,I',CH,COO”, ee | Results Chloride (CI) confirmed, irritating smell a 1 C,0;,NO;) Present. Test the i ee ees White dense fumes of 3. | rod dipped in NH,;OH CI indicated ; NHAC solution 4 | Confirmatory Test whi ink : te ppt. soluble in Cr Confirmed OS +A; ut + AgNO; solution NH,OH x ; Sean ae Orange brown fumes of It + KxCr,07 + 1.0m] . cr chromyl chloride Confirmed H,S0, + Heat : COG) i —— Nitrate (NO5). Experiment 1 | Salt + dil HoSOs Observation Pore Dilute acid groy, (COF,HCOS, sop, S,03 ,NO},s*) Absent No gas evolve 2 | Salt +Conc. H2SO4 Conc. H2SO, (CY, Br ,T,CH,Cog White fumes with pungent C,OF ,NO}) Present smell evolve. conc. H2SO, along the wall of test tube. May be HNO, 3 | Add paper pallet to above | Reddish brown fumes May be NO; gas contents and heat : Pass the above gas .

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