Question No. 1 to 5 are based on the given text.
Read the text carefully
and answer the questions:
At 298 K, the vapour pressure of pure benzene, C6 H6 is 0.256 bar and the
vapour pressure of pure toluene C6H5CH3 is 0.0925 bar. Two mixtures were
prepared as follows:
i. 7.8 g of C6H6 + 9.2 g of toluene
ii. 3.9 g of C6H6 + 13.8 g of toluene
1. The total vapour pressure (bar) of solution I is:
a. 0.258
b. 0.198
c. 0.128
d. 0.17425
2. Which of the given solutions have higher vapour pressure?
a. Both have equal vapour pressure
b. II
c. I
d. Cannot be predicted
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3. Mole fraction of benzene in vapour phase in solution I is
a. 0.734
b. 0.128
c. 0.174
d. 0.266
4. Which of the following statements is/are correct?
I. Mole fraction of toluene in vapour phase is more in solution I.
II. Mole fraction of toluene in vapour phase is less in solution I.
III. Mole fraction of benzene in vapour phase is less in solution I.
a. II and III
b. Only I
c. Only II
d. I and III
5. Solution I is an example of a/an
a. non-ideal solution with negative deviation
b. non-ideal solution with positive deviation
c. ideal solution
d. can't be predicted.
6. Diagram X represents a system in which two aqueous sucrose solutions
are separated by a semi-permeable membrane. Which of the following
represents the system after a certain amount of time has passed?
a. Option (C)
b. Option (A)
c. Option (D)
d. Option (B)
7. Henry’s constant (in kbar) for four gases , , and in water a1298 K is
given below:
KH 50 2 2 10-5 0.5
8. (density of water = 103 kg m-3 at 298 K)
This table implies that:
a. The pressure of a 55.5 molal solution of is 1 bar
b. The pressure of a 55.5 molal solution of is 250 bar
c. solubility of at 308 K is lower than at 298 K
d. has the highest solubility in water at a given pressure
9. The pressure under which liquid and its vapour can coexist in
equilibrium is known as:
a. limiting vapour pressure
b. saturated vapour pressure
c. normal vapour pressure
d. real vapour pressure
10. Assertion (A): Ice melts faster at high altitudes.
Reason (R): At high altitudes atmospheric pressure is high.
a. Both A and R are true and R is the correct explanation of A.
b. Both A and R are true but R is not the correct explanation of A.
c. A is true but R is false.
d. A is false but R is true.
11.Assertion (A): Molarity of a solution in liquid state changes with
temperature.
Reason (R): The volume of a solution changes with a change in
temperature.
a. Both A and R are true and R is the correct explanation of A.
b. Both A and R are true but R is not the correct explanation of A.
c. A is true but R is false.
d. A is false but R is true.
12. State True or False:
i. A saturated solution will remain saturated at all the temperatures.
a. True
b. False
ii. Solutions having same osmotic pressures are called hypertonic
solutions.
a. True
b. False
13. Fill in the blanks:
a. The sum of mole fractions of solute and solvent of a solution is
________.
b. Ideal solutions obey ________.
14. Define the term colligative properties?
15. Why the boiling point of solution is higher than pure liquid?
16. Which colligative property is preferred for the molar mass
determination of macromolecules?
17. 10 ml of liquid A was mixed with 10 ml of liquid B. The volume of
the resulting solution was found to be 19.9 ml what do you conclude?
18. What type of mixtures of two liquids distill over at one temperature
and why?
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19.
i. A 10% solution (by mass) of sucrose in water has a freezing point
of 269.15 K. Calculate the freezing point of 10% glucose in water
if the freezing point of pure water is 273.15 K.
(Given, the molar mass of sucrose = 342 g mol-1 and molar mass
of glucose = 180 g mol-1)
ii. Define the following terms:
a. Molality (m)
b. Abnormal molar mass
