Outokumpu Corrosion Management News Acom 3 Edition 2006
Outokumpu Corrosion Management News Acom 3 Edition 2006
Yours sincerely
Jan Olsson
Technical editor of Acom
www.outokumpu.com
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Abstract
Stainless steel is today more and more used as an engineering material in architecture- and
building constructions. It is a material with high aesthetic attraction, good weldability
and formability and also high strength when needed. A further aspect is durability of
the material and no need for protective coatings against corrosion or fire. Austenitic
stainless steels are the most used stainless steels in building applications. The trend
today however is an increased use of high strength duplex stainless steels.
Typical stainless properties are discussed in the paper such as formability, increased
strength by cold deformation, corrosion resistance and especially weldability. Different
applications today and future possibilities are shown as well as different design criteria.
For stainless steels the most used joining technique is arc welding. The paper will
highlight specific questions such as how should a weld look like to fulfil mechanical
properties, fatigue, removal of weld oxides, corrosion, and aesthetic appearance, prestigious
material. To reach sufficient corrosion resistance and mechanical properties correct filler
material must be used as well as a qualified welding procedure and welding operator.
Fig. 1 From the left: Chrysler Building (New York), One Canada Square in Canary Wharf (London) and Petronas Towers
(Kuala Lumpur).
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renovated because of water leakage in some parts of the upper floors. During the renovation
the quality of the stainless steel plates was controlled and they were considered still to
be in perfect condition after more than 80 years of service in harsh weather conditions,
exposed to a combination of urban/industrial and marine environments.
There are good reasons for starting to look at stainless steel as a construction material.
Stainless steels are amongst the most corrosion resistant materials that exist. Stainless
steel has self-healing properties in case of small damages on the surface. The covering
oxide layer is replaced quite fast after the damage. With the right choice of grade for the
purpose and appropriate manufacturing methods, stainless will be unaffected by the
environment even in the most aggressive industrial sites including marine atmospheres.
More than 90 percent of all building applications today can be constructed using
a small number of stainless steels. The most common ones are ferritic and austenitic
steels. The common steel grades in building applications today are: EN 1.4301 (304),
EN 1.4307 (304L), EN 1.4401 (316), EN 1.4404 (316 L), EN 1.4571 (316Ti),
EN 1.4510 (439) and EN 1.4016 (430). Fast development of duplex stainless grades has
influenced that these steels are considered as the future construction materials in the
building and construction industry. Examples of such duplex steels are: EN 1.4362
(SAF 2304), EN 1.4462 (2205) and a new low nickel alternative EN 1.4162 (LDX 2101).
[1]. Two ferritic grades are used in load carrying constructions EN 1.4113 (434) and
EN 1.4003 (410S). Common for both these grades is the high proof strength of a mean
value of 370 MPa. EN 1.4113 is also used for architectural exteriors trims and profiles.
Also decorative profiles and metallic finishing for building are typical applications.
EN 1.4113 has a higher Cr content of than EN 1.4003 and about 1% Mo content.
This leads to a significant improvement in pitting corrosion resistance.
Normally the austenitic grades EN 1.4301, EN 1.4306, EN 1.4541, EN 1.4571,
EN 1.4318 are available in different product forms including hollow sections. For
these grades the mechanical strength and fire resistance properties vary to some degree.
The information about the behaviour of the different materials has become available
through continuous research. The duplex grades are also used in building and construction
applications when high mechanical strength is needed in aggressive environments, like
bridge structures.
Today stainless steel is used in many other areas than in facades and roof covers,
which were the first applications back in the twenties. Other important aspects are life
cycle costs and the ideal of sustainable development. Even if the initial material costs for
stainless steel can be higher than for carbon steel, stainless steel requires no painting
and surface treatment. This, together with the savings in maintenance, compensates
more than well the higher material costs. Stainless steel is 100% recyclable after the
product life cycle and there is no limitation for the recyclable scrap that can be used for
new production of stainless steel. [2]
for construction. The largest differences in physical and mechanical properties between
stainless steel and carbon steel are that the stainless steel has:
A sample of typical strength values for some common stainless steels. The guaranteed
values according to European standard are also shown in the table. Table 1
Fig. 2 Typical stress-strain curves for stainless steel and carbon steel
(for longitudinal tension) [1]
O
N/mm2
600
E 1.4462
O 0,2
400
Carbon steel (grade S355)
O 0,2 1.4301/1.4401
200
E
0
0,002 0,005 0,010 0,015 3
(O0,2 is the 0,2% proof strength)
The strength of austenitic and duplex materials is increased through cold working. The
50% increase of proof strength (0.2%) can be considered as typical for cold-formed corner
in a profiled plate. This effect on strength is very local and the increase in the components
load bearing capacity is depending on where the higher strength corner is situated in the
component or its cross section. The increase in the material strength compensates well
the effect of local thinning of the material because of the forming process.
Corrosion resistance
When using stainless steel as a construction material it is important to remember that
stainless steel can corrode in some circumstances. It is therefore important that the designer
make the correct choice of steel, filler material, welding procedure and post weld cleaning
for a certain exposure environment to avoid later corrosion problems. The most frequent
stainless steel corrosion types occurring in constructions are pitting and crevice corrosion
although the discussion will also cover galvanic corrosion of carbon steel.
Pitting is often localized to the weld area due to weld tint, spatter, unintentional
arcing and coarse grinding, Figure 3a. Crevice corrosion might occur in overlap joins,
flanges, root weld defects and under deposits.
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Galvanic corrosion of carbon steel can take place if it is welded to stainless steel and
if both materials are immersed in a corrosive environment, e.g. water. To avoid this the
carbon steel surface should be coated, e.g. painted, and so also the stainless steel surface
to a distance of about 10–20 cm from the joint.
Another common phenomenon is extraneous corrosion, i.e. corrosion of carbon steel,
which has contaminated the stainless steel surface. Reasons can be that tools or lifting
devices have been used for the handling of both carbon steel and stainless steel or just
carbon steel dust in a workshop without separation of the two materials, Figure 3b.
a b
Stress corrosion cracking (SCC) is normally not a problem within the building and
construction industry, but one such problem should still be emphasised, SCC in load
bearing structures in swimming pool buildings. Volatile compounds, mainly chloramines,
can precipitate on cold metal surfaces and cause a special type of SCC, occurring at
ambient temperatures.
Fig. 4 Stainless steel bridge in Menorca, Spain. The material is EN 1.4462 (2205)
duplex stainless steel.
When designing tanks containing liquids the high strength of duplex stainless steels
can be utilized, Figure 5. Proof strengths of 400 – 500 MPa for duplex stainless steels
make it possible to reduce the plate thickness of the walls and in thus spare money by
using duplex steel EN 1.4462 (2205) instead of the ‘standard’ stainless EN 1.4401 (316).
The same goes for many other load bearing structures, e.g. bridge components, see Fig. 6
where the high strength, good weldability and good ductility of duplex stainless steels can
be utilized.
Several accidents due to failures in load bearing structures in swimming pools buildings
show that the risk of SCC makes the normal austenitic grades such as 1.4306 and 1.4404
unsuitable for several such applications in certain environments. Test results show that grades
EN 1.4547, EN 1.4529 and EN 1.4565 are suitable for critical load-bearing components
in pool hall atmospheres that are not washed or cleaned frequently. This is in agreement
with the requirements of the German building code. As a result of their microstructure,
duplex grades are more resistant to SCC than the standard austenitic grades. There are
some recent examples in the UK of flumes being suspended with super duplex grade
EN1.4507 stranded wire. There are also examples of duplex grade 1.4462 (2205) giving
satisfactory performance in safety critical, load-bearing swimming pool applications. [5].
Stainless steels are on their way to be used in car components as well. Automotive vehicle
structural crashworthiness is defined as the capability of an automotive structure to provide
adequate protection for the vehicle and its passengers in the event of a crash. The vehicle
structure and the occupant restraint system interact to protect vehicle occupants. The
structure needs to maintain enough space inside the vehicle so that the occupant restraints
can operate effectively. One very potential component for stainless steel is front bumper
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support, which requires very good energy absorbing capability. In a Swedish project one has
succeeded in creating a stainless steel bumper support construction that is 26% lighter
than the existing structure keeping the costs the same and having the same energy absorbing
capacity. The material is HyTens from Outokumpu.
Mixed joints with carbon steel are possible in most cases. However, use of over alloyed
filler material is then often required. In case of heavy gauges in austenitic grades a small risk
for hot cracking does exist. This is quite typical welding defect for austenitic stainless steels.
It can be avoided by using a filler material, which gives 2 – 10% ferrite in the weld metal.
In EN 1011-3 some other overall recommendations are given for handling and welding
of stainless steel.
Stainless reinforcing steels, rebars, are inherently resistant to corrosion. The use of stainless
rebars significantly decrease the demand for inspection and maintenance, and consequently
also the cost, of structures facing a risk of rebar corrosion. Stainless steel rebars are also
resistant to high chloride ion contents in concrete and they do not need an extra coating for
corrosion protection. By using stainless steel rebars the maintenance, traffic problems and
reparations can be reduced. All this can lead to cost reductions [6].
a) b) c) d) e)
h)
f) g) i) j)
Typical fatigue crack initiation points are the contact areas between weld material and
base material, weld toe, Fig. 7. You can almost always find there a small initial crack or
crack like fault which starts to grow under fatigue loading. These structural details can
be classified according to standardized fatigue classes. From fatigue point of view the
best would be detail a), butt weld, and the worst one either h), load carrying fillet weld,
depending on the weld type and quality, or d), welded reinforcement.
The most used fatigue life estimation method is more or less similar in all modern
fatigue standards. The standards include tables for choosing the most correct welded
joint type, like those in Fig. 7. The welded joints are grouped to several fatigue classes
(FAT) and each class is represented by S-N-curve, like the one in Fig. 8, FAT 71, detail
c in Fig. 7. Examples of joint classification can be found e.g. in ENV 1993-1-1, Ch. 9.
After the classification of the joint S-N-curve parameters are given and the fatigue life
can be calculated. Instructions how to calculate fatigue strength of a component or a
detail in carbon steel constructions are valid also to stainless steel, see Chapter 9 in
ENV 1993-1-1, which is going to be replaced by EN 1993-1-9 .
By following good design practice a lot can be done to reduce the sensitivity for fatigue.
This is in the first hand a question of appropriate detail design, having a consecutive
design strategy of choosing a structural detail that has as good fatigue strength as possible.
The key to good fatigue design is to take fatigue into account early in the design process.
It still happens that fatigue is checked only after the other design criteria are fulfilled.
This can lead to inadequate design from fatigue point of view or costly re-design of the
structure.
It is also important to take the manufacturing and installation process into account.
A miss in e.g. welding the detail can lead to a defect that causes a potential fatigue crack
initiation/growth leading in the best case to unplanned and hence costly repair work.
These potential risky details must be pointed out for the manufacturer in order to get the
best possible result. This is especially important for details like lifting brackets or holes.
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Fatigue properties of duplex stainless steel are at least as good as for carbon steels.
Fig. 8 shows test results for a relatively new duplex stainless steel LDX 2101.
Fig. 8 Example of fatigue test results for the new duplex stainless steel LDX 2101.
Rd50%
Rd95%
100 Test Specimen
90
80
70
60 Welded, GMAW (MIG)
Load Carrying Cruciform Filler Joint
50
104 105 106 107
Endurance, cycles, N
It is possible to avoid fatigue problems and in worst case structural failure by concentrating
on construction details, their design and manufacturing, and by avoiding:
• Abrupt changes in cross sections leading to stress concentrations
• Angular misalignment and eccentricity in welded details
• Small discontinuities likes scratches and grinding marks,
especially perpendicular to principal stresses
• Unnecessary welding of lifting brackets
• Imperfect welding, fillet welds, tack welds, etc.
• Unintentional arcing
• Crater cracks at electrode ends
• Placing the welds at high stress areas like corners
• Too sharp weld toe angles
• Oversized welds.
It is recommended that a fabricator uses a quality system for the welding operation.
The new international QA system, ISO 3824 gives a good guideline for the fabricator.
In this standard procedures for qualifying welders, qualification of welding procedures as
well as quality requirements for different constructions are given. For fabrication of steel
constructions, a new standard is now almost ready for publication, prEN 1090-2. This
new standard can also be used for stainless steel structures. The standard contains technical
requirements for execution, fabrication, welding, erection and cleaning for different execution
classes.
It is important that welds in stainless steels as well as welds in other materials are
free of defects to secure mechanical strength. Stainless steel welds must also fulfil the
requirements for corrosion resistance.
This means that the surface of the steel or the weld area must be free from contamination
or surface defects, which otherwise might cause localised corrosion. Requirements are
given in for example EN 25817. Examples of surface defects are iron contamination, coarse
grinding, spatter and unintentional arcing as well as heat tint. It is often advantageous
that the design engineer specifies the as-welded profile and surface condition required.
This may influence the choice of welding process or post weld treatment.
Weldability
Working/
Micro- Steel Welding Hydrogen Grain 475°C - Hot
Structure Type Filler Temperature Cracking Growth Embrittlem. Cracking
Austenitic 200 – 400°C Very
Martensitic 1.4021/420 No No No
(martensite.) (200 – 400°C) sensitive
Ferritic 200– 300°C
Ferritic 1.4016/430 Sensitive Yes Yes No
Austenitic RT
1.4401/316 Austenitic RT No No No Some
Austenitic 1.4539/904L “ RT No No No Some
1.4845/310S “ RT No No No Yes
Duplex 1.4462/2205 Duplex RT No Some Yes Small
RT to 150°C
Carbon
Steel Ferritic Dependent of Sensitive Yes No Some
thickn. and C-ekv.
C-Steel to Over
Mixed joint
Stainl. steel alloyed Some Small
Welding processes
The common used fusion methods can be used for welding of stainless steels. When
welding thin gauge materials GTAW, PAW and Laser are the most used methods. The
development of the GMAW equipments has now given the operators the possibility
to use this method down to 1.0 mm. This increases productivity when welding in the
field compared to GTAW. When welding heavier gauges on site the trend today is to use
flux-cored wires. They give the welder good weld pool control and a high productivity.
Thin walled constructions may be designed with an overlap joint. In such cases resistance
spot/seam welding are often used due to high productivity. The design engineer must
however be aware of the risk of crevice corrosion.
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Consumables
1. Duplex steels
Duplex steels should be welded with designed fillers. This optimizes microstructure,
mechanical properties and corrosion resistance. The following fillers are recommended.
2. Austenitic steels
The steels presented in this article have all very good weldability. They can be welded
autogenously or with the use of filler. Recommended fillers are shown below.
Parent material Filler: Avesta Welding
1.4310 308L/MVR
1.4301 (304) 308L/MVR
1.4404 (316L) 316L/SKR
1.4571 (316Ti) 316L/SKR
3. Ferritic steels
These steels do not have the same good weldability as the other presented.
The sensitivity to grain growth implicates the need to weld with very low heat input.
They are mostly welded with austenitic fillers to give a weldment as high ductility
as possible. They are also limited in thickness.
Welding distortion
In common with other metals, stainless steel suffers from distortion due to welding.
However, the distortion of stainless steel, particularly austenitic grades, is greater than
that of carbon steels due to a higher coefficient of thermal expansion and lower thermal
conductivity. Welding distortion can only be controlled, not eliminated. The designer and
fabricator can take some actions to reduce distortion. Few beads, small joints, symmetric
joint configuration, pre-setting of the plates, clamping jigs, back stepping and by using
a welding process that gives a narrow weld (e.g. Laser) are examples that can be used to
reduce weld distortion.
A deco or pattern rolled surface should not have exposed welds because they will normally
not be accepted from an aesthetic aspect after a cleaning operation. And the same philosophy
should be applied if the surface of the steel is cold rolled skin passed. Such a bright shiny
surface will after welding and cleaning mostly give a dull appearance of the weld area.
Summary
The important properties in stainless steel compared to carbon steel for constructional
use are:
• No specific yield point like carbon steels, Rp0.2 (or sometimes Rp1.0)
are used instead
• Stainless steel has generally better toughness than carbon steels
• Stainless steel deform hardens much more than carbon steel – especially
the austenitic ones
• Some specific design methods like using secant modulus instead of Young’s
modulus when calculating beam bending
• Detail design and fabrication is important for the fatigue properties
like it is for carbon steels
• Post weld cleaning is important for corrosion and aesthetical reasons
• Stainless steels are more sensitive to high heat inputs during welding
• To design and construct using stainless steel is not difficult, it is just
a bit different.
References
[1] Euro-Inox: Good Fabrication in Architectural Stainless Steel, 2002
[2] Bingen, M, http://www.stainlessbuilding.com/why/index.aspx
[3] Design manual for structural stainless steel, Euro Inox and The Steel Construction
Institute, 2002, ISBN 2-87997-037.
[4] Eurocode 3: Design of steel structures, prEN 1993-1-4, Part 1.4 : General rules
Supplementary Rules for Stainless steels.
[5] Baddoo, N & Cutler, P. Stainless Steel in indoor swimming pool buildings.
Downloadable at: http://www.euro-inox.org/
[6] http://www.stainless-rebar.org/appl.htm
[7] Payet-Gaspard P. Stainless Steel: A superb construction material. Presentation
in the conference “Stainless Steel for Architectural Visions”. Paris, 2001.
1278EN-GB. Graphic Concept. October 2006
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