Plastic and Its History
Plastic and Its History
1. 🧪 What Is Plastic?
🔬 Definition:
Plastic is a synthetic or semi-synthetic material made from polymers — long
chains of repeating molecules derived mostly from petroleum or natural gas.
🔁 Key Properties:
● Lightweight
2. 🕰️ History of Plastic
Year Milestone
3. 🧱 Types of Plastics
🔁 Thermoplastics (can be melted and reshaped)
Plastic Abbreviatio Common Uses
n
Epoxy Adhesives,
electronics
Bakelite Electrical
insulators
Melamin Kitchenware,
e laminates
2. Cracking: Hydrocarbons are broken down into monomers like ethylene and
propylene.
6. 🌍 Environmental Impact
🗑️ Waste Crisis:
● Over 8.3 billion metric tons of plastic produced since the 1950s.
🐢 Plastic Pollution:
● Plastic does not biodegrade, it breaks into microplastics.
● Found in oceans, soil, air, and even human blood and breast milk.
♨️ Climate Change:
● Plastic production and incineration emit greenhouse gases.
🔄 Circular Solutions:
● Mechanical recycling: Melts and reshapes plastic.
8. 📜 Global Responses
🌐 International Agreements
● UN Global Plastic Treaty (in progress)
● Seaweed-based films
gas and petroleum, and a small fraction from renewable materials, with one such
[2]
material being polylactic acid.
Between 1950 and 2017, 9.2 billion metric tons of plastic are estimated to have
been made, with more than half of this amount being produced since 2004. In
2023 alone, preliminary figures indicate that over 400 million metric tons of
[3]
plastic were produced worldwide. If global trends in plastic demand continue, it
is projected that annual global plastic production will exceed 1.3 billion tons by
[3]
2060. The primary uses for plastic include packaging, which makes up about
40% of its usage, and building and construction, which makes up about 20% of its
[1]
usage.
The success and dominance of plastics since the early 20th century has had
major benefits for mankind, ranging from medical devices to light-weight
construction materials. The sewage systems in many countries relies on the
resiliency and adaptability of polyvinyl chloride. It is also true that plastics are the
[4]
basis of widespread environmental concerns, due to their slow decomposition
rate in natural ecosystems. Most plastic produced has not been reused. Some is
unsuitable for reuse. Much is captured in landfills or as plastic pollution.
Particular concern focuses on microplastics. Marine plastic pollution, for
example, creates garbage patches. Of all the plastic discarded so far, some 14%
[5]
has been incinerated and less than 10% has been recycled.
produced annually per person, with production doubling every ten years.
The world's first fully synthetic plastic was Bakelite, invented in New York in 1907,
[7] [8]
by Leo Baekeland, who coined the term "plastics". Dozens of different types
Etymology
The word plastic derives from the Ancient Greek πλαστικός (plastikos), meaning
"capable of being shaped or molded." In turn, this derives from πλαστός
[10]
(plastos), meaning "molded." As a noun, the word plastic most commonly
[11]
refers to the solid products of petrochemical-derived manufacturing.
Structure
See also: Polymer
[12]
Most plastics contain organic polymers. The vast majority of these polymers
are formed from chains of carbon atoms, with or without the attachment of
oxygen, nitrogen or sulfur atoms. These chains comprise many repeating units
formed from monomers. Each polymer chain consists of several thousand
repeating units. The backbone is the part of the chain that is on the main path,
linking together a large number of repeat units. To customize the properties of a
plastic, different molecular groups called side chains hang from this backbone;
they are usually attached to the monomers before the monomers themselves are
linked together to form the polymer chain. The structure of these side chains
influences the properties of the polymer.
Classifications
Plastics are usually classified by the chemical structure of the polymer's
backbone and side chains. Important groups classified in this way include the
acrylics, polyesters, silicones, polyurethanes, and halogenated plastics. Plastics
can be classified by the chemical process used in their synthesis, such as
[13]
condensation, polyaddition, and cross-linking. They can also be classified by
A plastic handle from a kitchen utensil, deformed by heat and partially melted
Thermosets, or thermosetting polymers, can melt and take shape only once: after
[16]
they have solidified, they stay solid and retain their shape permanently. If
Elastomers consist of
Thermosets consist
wide-meshed
of closely
cross-linked polymers. Thermoplastics consist of
cross-linked
The wide mesh allows non-crosslinked polymers,
polymers.
the material to stretch often with a semi-crystalline
Cross-links are
under tensile load. structure (shown in red).
shown as red dots in
the figure.
They have a glass transition
temperature and are fusible.
Polypropylene (PP)
Polystyrene (PS)
Beyond the six most widely recognized listed above, there are more commodity
plastics that are also mass-produced and commonly used, such as polyurethanes
(PURs). PURs are a class of plastics also designated as commodity plastics due
to their low cost, ease of manufacturing, and versatility. However, they lack RICs
because they encompass many chemically diverse formulations such as foams
and adhesives.
A huge number of plastics exist beyond the commodity plastics, with many
having exceptional properties.
Additives 25 6.1 - -
Engineering plastics
Engineering plastics are more robust and are used to manufacture products such
as vehicle parts, building and construction materials, and some machine parts. In
some cases, they are polymer blends formed by mixing different plastics together
(ABS, HIPS etc.). Engineering plastics can replace metals in vehicles, lowering
their weight and improving fuel efficiency by 6–8%. Roughly 50% of the volume of
modern cars is made of plastic, but this only accounts for 12–17% of the vehicle
[20]
weight.
● Aramids: best known for their use in the manufacture of body armor,
this class of heat-resistant and strong synthetic fibers also has
applications in aerospace and military and includes Kevlar, Nomex, and
Twaron.
● Ultra-high-molecular-weight polyethylenes (UHMWPE)
● Polyetheretherketone (PEEK): strong, chemical- and heat-resistant
thermoplastic; its biocompatibility allows for use in medical implant
applications and aerospace moldings. It is one of the most expensive
commercial polymers.
● Polyetherimide (PEI): a high-temperature, chemically stable polymer
that does not crystallize
● Polyimide: a high-temperature plastic used in materials such as Kapton
tape
● Polysulfone (PS): high-temperature melt-processable resin used in
membranes, filtration media, water heater dip tubes and other
high-temperature applications
● Polytetrafluoroethylene (PTFE): heat-resistant, low-friction coatings
used in non-stick surfaces for frying pans, plumber's tape, and water
slides
● Polyamide-imide (PAI): high-performance engineering plastic
extensively used in high-performance gears, switches, transmissions,
[21]
and other automotive components and aerospace parts
● Polyphenylene sulfide (PPS): extreme chemical resistance, flame
retardancy, and thermal stability (up to 428°F).
● Polyethersulfone (PES): best known for their clarity, high-temperature
resistance (up to 392°F), and biocompatibility. Commonly used in
medical devices, food-grade equipment, and aerospace lighting.
● Polyvinylidene fluoride (PVDF): a nonreactive thermoplastic
fluoropolymer known for extreme chemical resistance, ultraviolet
stability, and piezoelectric properties. Commonly used in semiconductor
tubing, lithium-ion battery binders, and architectural coatings.
● Liquid-crystal polymers (LCPs): a class of polymers combining the
properties of both liquids and crystals, known for extreme dimensional
stability, low thermal expansion, and high dielectric strength. Commonly
used in miniature electronics, fiber-optic cables, and surgical devices.
● Polyimides (PIs): a class of high-performance thermosets, able to
operate up to 572°F and best known for their excellent dielectric
properties and radiation resistance. Commonly used in flexible printed
circuits, space suit layers, and jet engine components.
● Polybenzimidazole (PBI): extremely high heat resistance (up to 752°F
short-term), low outgassing, and flame resistance. Commonly used in
firefighting gear, semiconductor tools, and aerospace thermal shields.
● Bismaleimide (BMI): known for its high glass transition temperature
(around 482°F) and low moisture absorption. Commonly used in
composite aircraft matrices and military radar systems.
● Cyanate esters: known for their low dielectric loss and space-grade
radiation resistance. Commonly used in satellite components and radar
antennas.
Conductive polymers
Main article: Conductive polymer
Biodegradable plastics are plastics that degrade (break down) upon exposure to
biological factors, such as sunlight, ultra-violet radiation, moisture, bacteria,
enzymes, or wind abrasion. Attacks by insects, such as waxworms and
mealworms, can also be considered forms of biodegradation. Aerobic
degradation requires the plastic to be exposed at the surface, whereas anaerobic
degradation would be effective in landfill or composting systems. Some
companies produce biodegradable additives to further promote biodegradation.
Although starch powder can be added as a filler to facilitate degradation of some
plastics, such treatment does not lead to complete breakdown. Some researchers
have genetically engineered bacteria to synthesize completely biodegradable
plastics, such as polyhydroxybutyrate (PHB); however, As of 2021, these were
[25]
still relatively expensive.
Bioplastics
While most plastics are produced from petrochemicals, bioplastics are made
[26]
substantially from renewable plant materials like cellulose and starch. Due
both to the finite limits of fossil fuel reserves and to rising levels of greenhouse
gases caused primarily by the burning of those fuels, the development of
[27][28]
bioplastics is a growing field. Global production capacity for bio-based
Plastic industry
The plastic industry includes the global production, compounding, conversion
and sale of plastic products. Although the Middle East and Russia produce most
of the required petrochemical raw materials, the production of plastic is
concentrated in the global East and West. The plastic industry comprises a huge
number of companies and can be divided into several sectors:
Production
Between 1950 and 2017, 9.2 billion tonnes of plastic are estimated to have been
made, with more than half of this having been produced since 2004. Since the
birth of the plastic industry in the 1950s, global production has increased
enormously, reaching 400 million tonnes a year in 2021; this is up from 381
[5][17]
million metric tonnes in 2015 (excluding additives). From the 1950s, rapid
it is estimated that by 2050 annual global plastic production will exceed 1.1-billion
[5]
tonnes annually.
● Polypropylene plants
●
A Slovnaft facility in Bratislava, Slovakia
●
A SOCAR Polymer polypropylene plant in Sumgayit, Azerbaijan
Graphs are unavailable due to technical issues. Updates on
reimplementing the Graph extension, which will be known as the
Chart extension, can be found on Phabricator and on
MediaWiki.org.
[17]
Annual global plastic production 1950–2015. Vertical lines denote the 1973–1975
recession and the financial crisis of 2007–2008 which caused brief lowering of plastic
production.
Roughly half of all production takes place in East Asia, with China being the
largest single producer. Major international producers include:
Region Global
production
China 31%
Japan 3%
NAFTA 19%
Latin America 4%
Europe 16%
CIS 3%
● Dow Chemical
● LyondellBasell
● ExxonMobil
● SABIC
● BASF
● Sibur
● Shin-Etsu Chemical
● Indorama Ventures
● Sinopec
● Braskem
differences in the volume of plastics production are driven by user demand, the
price of fossil fuel feedstocks, and investments made in the petrochemical
industry. For example, since 2010 over US$200 billion has been invested in the
United States in new plastic and chemical plants, stimulated by the low cost of
raw materials. In the European Union (EU), too, heavy investments have been
made in the plastics industry, which employs over 1.6-million people with a
turnover of more than 360 billion euros per year. In China in 2016 there were over
15,000 plastic manufacturing companies, generating more than US$366 billion in
[5]
revenue.
In 2017, the global plastics market was dominated by thermoplastics– polymers
that can be melted and recast. Thermoplastics include polyethylene (PE),
polyethylene terephthalate (PET), polypropylene (PP), polyvinyl chloride (PVC),
polystyrene (PS) and synthetic fibers, which together represent 86% of all
[5]
plastics.
Compounding
Plastic is not sold as a pure unadulterated substance, but is instead mixed with
various chemicals and other materials, which are collectively known as additives.
These are added during the compounding stage and include substances such as
stabilizers, plasticizers and dyes, which are intended to improve the lifespan,
workability or appearance of the final item. In some cases, this can involve mixing
different types of plastic together to form a polymer blend, such as high impact
polystyrene. Large companies may do their own compounding prior to
production, but some producers have it done by a third party. Companies that
specialize in this work are known as Compounders.
The compounding of thermosetting plastic is relatively straightforward; as it
remains liquid until it is cured into its final form. For thermosoftening materials,
which are used to make the majority of products, it is necessary to melt the
plastic in order to mix-in the additives. This involves heating it to anywhere
between 150–320 °C (300–610 °F). Molten plastic is viscous and exhibits laminar
flow, leading to poor mixing. Compounding is therefore done using extrusion
equipment, which is able to supply the necessary heat and mixing to give a
properly dispersed product.
The concentrations of most additives are usually quite low, however high levels
can be added to create Masterbatch products. The additives in these are
concentrated but still properly dispersed in the host resin. Masterbatch granules
can be mixed with cheaper bulk polymer and will release their additives during
processing to give a homogeneous final product. This can be cheaper than
working with a fully compounded material and is particularly common for the
introduction of color.
Converting
For thermosetting materials, the process is slightly different, as the plastics are
liquid to begin with and but must be cured to give solid products, but much of the
equipment is broadly similar.
Plastic consumption differs among countries and communities, with some form
of plastic having made its way into most people's lives. North America (i.e. the
North American Free Trade Agreement or NAFTA region) accounts for 21% of
global plastic consumption, closely followed by China (20%) and Western Europe
(18%). In North America and Europe, there is high per capita plastic consumption
(94 kg and 85 kg/capita/year, respectively). In China, there is lower per capita
consumption (58 kg/capita/year), but high consumption nationally because of its
[5]
large population.
Gallery
●
Water bottles made of PET
●
High density polythene (HDPE) is used for making sturdy containers;
transparent containers may be made of PET.
●
Disposable suits can be made from non-woven HDPE fabric.
●
Plastic mailing envelopes made of HDPE
●
Clear plastic bags (shown) are made of low density polythene (LDPE);
blown-film shopping bags with handles are now made of HDPE.
●
A Ziploc bag made of LDPE
●
Food wrap made of LDPE
●
●
Kinder Joy shell made of polypropylene
●
A polypropylene chair
●
Stools made of HDPE
●
Expanded polystyrene foam ("Thermocol")
●
Extruded polystyrene foam ("Styrofoam")
●
Thermocol take-away food container
●
Egg tray made of PETE
●
A piece of packaging foam made of LDPE
●
A kitchen sponge made of polyurethane foam
●
Non-stick cookware with Teflon coating
●
iPhone 5c, a smartphone with a polycarbonate "unibody" shell
●
To withstand the extreme water pressure, this 10-meter deep Monterey Bay
Aquarium tank has windows made of acrylic glass up to 33 cm thick.
●
PVC pipes
●
PVC blister pack
Applications
The largest application for plastics is as packaging materials, but they are used in
a wide range of other sectors, including: construction (pipes, gutters, door and
windows), textiles (stretchable fabrics, fleece), consumer goods (toys, tableware,
toothbrushes), transportation (headlights, bumpers, body panels, wing mirrors),
[17]
electronics (phones, computers, televisions) and as machine parts. In optics,
[33]
plastics are used to manufacture aspheric lenses.
Additives
Additives are chemicals blended into plastics to improved their performance or
[34][35]
appearance. Additives are therefore one of the reasons why plastic is used
[36]
so widely. Plastics are composed of chains of polymers. Many different
[37][5]
In the EU, over 400 additives are used in high volumes. In a global market
[38]
analysis, 5,500 additives were found. At a minimum, all plastic contains some
polymer stabilizers which permit them to be melt-processed (molded) without
suffering polymer degradation.Additives in polyvinyl chloride (PVC), used widely
[5]
for sanitary plumbing, can constitute up to 80% of the total volume.
[citation needed]
Unadulterated plastic (barefoot resin) is rarely sold.
Leaching
Additives may be weakly bound to the polymers or react in the polymer matrix.
Although additives are blended into plastic they remain chemically distinct from it
and can gradually leach back out during normal use, when in landfills, or
[39]
following improper disposal in the environment. Additives may also degrade to
form other compounds that could be more benign or more toxic. Plastic
fragmentation into microplastics and nanoplastics can allow chemical additives
to move in the environment far from the point of use. Once released, some
additives and derivatives may persist in the environment and bioaccumulate in
organisms. They can have adverse effects on human health and biota. A recent
review by the United States Environmental Protection Agency (US EPA) revealed
that out of 3,377 chemicals potentially associated with plastic packaging and 906
likely associated with it, 68 were ranked by ECHA as "highest for human health
[5]
hazards" and 68 as "highest for environmental hazards".
Recycling
Main article: Plastic recycling
Lack of transparency and reporting across the value chain often results in lack of
knowledge concerning the chemical profile of the final products. For example,
products containing brominated flame retardants have been incorporated into
new plastic products. Flame retardants are a group of chemicals used in
electronic and electrical equipment, textiles, furniture and construction materials
which should not be present in food packaging or child care products. A recent
study found brominated dioxins as unintentional contaminants in toys made from
recycled plastic electronic waste that contained brominated flame retardants.
Brominated dioxins have been found to exhibit toxicity similar to that of
chlorinated dioxins. They can have negative developmental effects and negative
effects on the nervous system and interfere with mechanisms of the endocrine
[5]
system.
Health effects
Plastics have proliferated in part because they are relatively benign. They are not
acutely toxic, in large part because they are insoluble and or indigestible owing to
their large molecular weight. Their degradation products also are rarely toxic. The
same cannot be said about some additives, which tend to be lower molecular
weight.
Poor countries
bisphenol A (BPA) in plastic baby bottles is banned in many parts of the world but
[5]
is not restricted in some low-income countries.
Animals
In 2023, plasticosis, a new disease caused by the ingestion of plastic waste, was
discovered in seabirds. Birds affected with this disease were found to have
scarred and inflamed digestive tracts, which can impair their ability to digest
[42]
food. "When birds ingest small pieces of plastic, they found, it inflames the
digestive tract. Over time, the persistent inflammation causes tissues to become
[43]
scarred and disfigured, affecting digestion, growth and survival."