Question Paper [CODE - 28585]

BRAHMASTRA_Full Syllabus Test-02_Advanced Paper -1

12th+13th JEE (M+A)
KOTA

Date: 08-May-2025 Duration: 3 Hours Max Marks: 180

Page No. 1
 SYLLABUS
Maths
Full Syllabus

Physics
rinkesh.gupta

Chemistry
Full Syllabus

Page No. 2
 MATHS

1. If S =
1
2
+ 2
2
+ 2
3
+. .. Further S1 is the sum of first (n – 1) terms of the given series
2 2
1+n 2 +n 3 +n

and S2 is the sum of (n – 1) terms but starts from the 2nd term of the given series; n
2
(i. e. )
2 2
2 +n

∈ N (set of natural numbers). Then which of the following is/are correct?

(A) S1 >
1

2
ln 2 (B) S2 <
1

2
ln 2 (C) S2 >
1

2
ln 2 (D) S1 <
1

2
ln 2

2. f : [0, 2] → R is continuous on [0, 2] and twice derivable in (0, 2). If f(0) = 0; f(1) = 1 and f(2) =
1, then
(A) f '(c) = 1
for atleast one c ∈ (0, 2) (B) 2f '(c) + 2c = 3 for atleast one c ∈ (0, 1)
3

(C) 2f '(c) + 2c = 3 for atleast one c ∈ (1, 2) (D) f ''(c) = – 1 for atleast one c ∈ (0, 2).

3. Major and minor axis of an ellipse are 8 and 6 respectively. Initially it touches positive x and y axis
and line joining the two focii is parallel to x-axis. It then rotates in anti-clockwise sense, always
touching both the positive co-ordinate axes, and the rotation stops when the line joining their focii
is vertical for the first time. C is centre of ellipse and O is origin, then
(A) Locus of C is the complete portion of x2 + y2 = 25 lying in Ist quadrant
(B) Locus of C is part of the circle x2 + y2 = 100

(C) Total distance covered by C is 5 tan–1

7
( )
24

(D) Initial and final positions of C lies on the curve xy = 12

Page No. 3
 MATHS

4. P is a point and P M, P N are perpendiculars from P to the Z X and X Y planes respectively. If

O P makes angles θ, α, β, γ , with the plane O M N and the X Y, Y Z, Z X planes respectively,

then ) is equal to
2 2 2 2
sin θ(cosec α + cosec β + cosec γ

(A) 1 (B) 3

(C) 5 (D) 7

5. t+1
Let f (x) = e
(p+1)x
− e
x
for real p > 0 and g(t) = ∫
t
f (x)e
t−x
dx . If f(x) is minimum at x = xp
and g(t) is minimum at t = tp then
ln(p+1)
(A) xp =
p

p
(p+1)(e −1)
(B)
1
tp = ln ( )
p p

(C) lim (xp − tp ) =

1

+
2
p→0

(D) lim (xp − tp ) = 2

+
p→0

6. 3+√5
If and are the first three consecutive terms
2 2 π
√ , sgn(x − 3x + 4) 2{[ ]+ sin }, x ∈ R
2
2 3+x 10

of G.P. and sum of its infinite terms is , then the value of is.
λ
λ
3

(√5−1)

[Note: [k], {k} and sgn (k) denote greatest integer function, fractional part function and signum
function of k respectively.]
(A) 8 (B) 12

(C) 16 (D) 20

7. If the value of 404

C −
4
C ⋅
303
C + C
4
⋅
202
C − C
4
⋅
101
C is ab where a ∈ N and b is an even
4 1 4 2 4 3 4

prime number, then sum of the digits of ' a ' is

(A) 3 (B) 2

(C) 4 (D) 5

Page No. 4
 MATHS

8. If α, β are two roots of the equation 1! + 2! + 3! + … . (x − 1)! + x! = k , k ∈

2
I+, where α < β
2 2 2
x − ( α+3α+5α ) x −3β

and if α1 , α2 , α3 , α4 are roots of equation (a + √b) +(a − √b) = 2a , where

| α1 +α2 +α3 +α4 +α1 α2 α3 α4 |
a
2
− b = 1 , then the value of 10
is equal to

9. If ω is imaginary root of z28 = 1 and such that |ω + 1| is maximum and x =

1
∣ω −
∣
1
∣
∣ , then |8x4
2 ω

+ 4x3 – 8x2 – 3x – 5| is equal to ______

10. Let f (x) be a differentiable function defined for all x > 0 and Lim f (x)= 0 . Also f (x) satisfies
+
x→0

(i) f (xy)= xf(y)+ yf(x)∀x,y ∈ R

+

2 2
x f (x ) −x
(ii) ∫
0
f (x)dx =
4

If the area enclosed by lying in the fourth quadrant is S, then is equal to

9
y = f (x) log ( )
√6 S

11. Let f and g are real valued functions such that f (x + 2) = f (x − 1) , for each x ∈ R and
2
4x +13
, for each , where [.] represents the greatest
−1
g(x +[ ])= g(x − 2π − sin (sin 7)) x ∈ R
2
x +3

integer function, then the fundamental period of the function h(x) = f (x) + g(x) is P, then P

11

equals

12. If the locus of the middle points of all such chords of the parabola y
2
= 8x which has length of
(m+n)
, has the equation where , Find the value of
4 2
2 units y + ℓy (2 − x)= mx − n ℓ, m, n ∈ N
9ℓ

13. Let a ∈ (1, 4) and ∫

a
[x]dx = ∫
[a]
xdx , where [.] denotes the greatest integer function. If sum of
0 0

all possible values of a is N, then value of [N] is

Page No. 5
 MATHS

14. Match the following

Column – I Column – II
1 3 2
⎡ ⎤

If [1 x 1] ⎢ 2 5 1⎥
⎣ ⎦
15 3 2
(A) (P) 3
1
⎡ ⎤

⎢ 2 ⎥= 0, then a value of 1 – x is
⎣ ⎦
x

3 − x 2 2
⎡ ⎤

Let A = ⎢ 2 4 − x 1 ⎥ ,
(B) ⎣ ⎦ (Q) 0
−2 −4 −1 − x

then a value of x for which A–1 does

not exist
Area of the region bounded by the
(C) x2 + y2 – 2x ≤ 0, x + y ≤ 1, y > 0
π
(R) 6

is
π/2
sinx−cosx π
(D) ∫
2
dx (S) 8
(sinx+cosx)
0

(A) A − P; B − Q R; C − R; D − Q; (B) A − R; B − P, S; C − P; D − S;
(C) A − Q; B − Q, R; C − Q; D − P; (D) A − P; B − P, Q; C − S; D − Q;

Page No. 6
15. Match the following Column-I with Column-II
Column - I Column - II
Two circles with radii r1 and r2
intersect each other at point A and
(A) BC be the direct common tangent to (P) 16
10−π

circles of length ℓ such that

r r
∠BAC = 45º then is equal to
1 2

2
ℓ

The absolute value of minimum of

(B) (x + y − 24x − 24y + 3), if
2 2 1
(Q) 2

x
2
+ y
2
− 6x − 8y = 0 is
ABCD and CDEF are two squares of
equal area. The ratio of the shaded
area to the area of rectangle ABFE

(C) (R) 25

In the given figure ABCD and PQRS

are two square, then
(Area of square ABCD)
can be
(Area of square PQRS)

(D) (S) 115 + 10√145

(T) 5
(A) (A) – (Q); (B) – (S), (C) – (P); (D) – (R) (B) (A) – (R); (B) – (S), (C) – (P); (D) – (Q)
(C) (A) – (S); (B) – (Q), (C) – (R); (D) – (P) (D) (A) – (P); (B) – (Q), (C) – (R); (D) – (S)

16. Column
Column - I
- II
Let P(x, x2) be a point on the parabola y
= x2. If f(x) = –
2 2
2
√(x − 3) + (x − 2)
(P) (1) 6
and maximum value of
2
2 2
√x + (x − 1)

f(x) is √N, then N is

Number of divisors of 25.32.53 which are
(Q) divisible by 2 but not divisible by 6 and 8 (2) 7
is
Let f(n) = nC0 nC1 + nC1 nC2 + ...... +
(R) nCn–1 nCn If 4f(n + 1) = 15 f(n), then sum (3) 8
of all possible values of n is
The number of solutions of the equation
(S) (sinθ + cosθ)tanθ=√sec2 θ − 1 in (4) 10
[−3π, 3π] is ​

(A) (P)–1; (Q)–2; (R)–3; (S)–4 (B) (P)–4; (Q)–2; (R)–1; (S)–3
(C) (P)–4; (Q)–3; (R)–1; (S)–2 (D) (P)–4; (Q)–3; (R)–2; (S)–1

Page No. 7
17. List -
List - I
II
If f is a differentiable function satisfying f(x
(P) + y) = f(x) + f(y) + 2xy – 4, ∀x, y∈R and f (1) 0
'(0) = – 2, the minimum value of f(x) is
3
2 4
− ( x +x )
x

(Q) If f(x) = e +1 + , the maximum

e 2

2x
x +1
4 (2) 1
value of f(x) is
The number of solutions(s) of the equation x
(R) (3) 2
– tan–1 x = – 1 + e–x is (are)
−x 2 −2x 3 −3x
xe +x e +x e +...∞
The value of lim ( ) is
(S) x→∞ ( ln ( 1+x ) )
−1
(4) 3
equal to
P Q R S P Q R S
(A) (B)
1 2 3 4 4 3 2 1

P Q R S P Q R S
(C) (D)
1 3 2 4 2 1 4 3

Page No. 8
 PHYSICS

1. A long cylindrical conductor of radius ‘a’ has two cylindrical cavities of diameter ‘a’ through its
entire length as shown in cross-section in figure. A current I is directed out of the page and is
uniform throughout the cross-section of the conductor. Then the magnetic field in terms of μ0, I, r
and a is :

2 2
μ0 I 2r −a
(A) at the point P2, πr
(
2 2
)
4r −a

2 2
μ0 I 2r −a
(B) at the point P1, πr
( 2 2
)
4r −a

2 2
μ0 I 2r +a
(C) at the point P2, πr
( 2 2
)
4r +a

2 2
μ0 I 2r +a
(D) at the point P1, πr
( 2 2
)
4r −a

Page No. 9
2. A triangular block ABC of mass m and sides 2a lie on a smooth horizontal plane as shown. Three
point masses of mass m each simultaneously strike the block at A, B and C with speeds v as
shown. After the collision the three particles come to rest. Select the correct alternative(s)

(A) the centre of mass of ABC remains stationary after collision

(B) the centre of mass of ABC moves with velocity v along the x-axis after collision
2 mva
(C) the triangular block rotates with an angular velocity ω = ( 1 + √3)about its centre of mass
√ I 3
(here, I is the moment of inertia of triangular block about its centroid axis perpendicular to its
plane)
(D) None of these

3. A battery of emf ε is connected with a small circular wire loop of radius r and resistance R.
Suddenly due to some reason battery get short circuited internally at t = 0. For t > 0 (consider
uniform magnetic field in the loop due to current which is equal to field at centre)

(A) the current in the loop become zero instantly.

(B) the current in the loop as a function of time is given by

ε −2 Rt /μ0 πr
e
R

–3
(C) The time in which current in loop decreases to 10 (from t = 0) for R = 100Ω and r = 5 cm
ε

R
2

is given by s
3π ℓn10
10
10

(D) The time in which current in loop decreases to 10–3 R (from t = 0) for R = 100Ω​and r = 5 cm
ε

is given by
3π
6
s
10

Page No. 10
 PHYSICS

4. Consider a sphere of radius R with a power source inside it. The power of source is P at its centre.
In steady state temperature of surface of the sphere is T0. The sphere is now covered with a
spherical shell of radius 2R (Assume that no radiations are incident from outside & all surfaces are
black body). Select the correct alternatives.

(A) Power of the source is

4 2
4πσT R
0
T0
(B) Temperature of inner sphere after covering is
√2

T0
(C) Temperature of outer spherical shell in steady state is 2
T0
(D) Temperature of inner sphere after covering is 1/4
2

5. A disc of radius R is spun to an angular speed ω0 about its axis and then imparted a horizontal
ω0 R
velocity of magnitude 4
(at t = 0) with its plane remaining vertical. The coefficient of friction
between the disc and the plane is sufficient to allow pure rolling, once it starts. The sense of
rotation and direction of its linear speed are shown in the figure. Choose the correct statement.

(A) The disc will not return to its initial position.

(B) The disc will stop finally irrespective of value of v and ω0 .
(C) If v0 = ω0 R/2 then the disc will stop finally.
(D) The friction will act in rightward direction after the rolling (without slipping) starts.

6. Suppose two particles 1 and 2 are projected in a vertical plane on a horzontal ground
simultaneously. Their angles of projection are 30° and θ respectively with the horizontal as shown.
Suppose they collide after a time t in air. Then, select incorrect - [g = 10 m/s2]

(A) θ = sin–1 (4/5) and they will have same speed just before the collision
(B) θ = sin–1 (4/5) and they will have different speed just before the collision
(C) x < (1280 √3 – 960) m
(D) It is possible that the particle collide when both of them are at their highest point

Page No. 11
7. Two identical sources moving parallel to each other at separation 'd' are producing sounds of
frequency 'f' and are moving with constant velocity v0. A stationary observer 'O' is on the line of
motion of one of the sources. Then the variation of beat frequency heard by O with time is best
represented by: (they come from large distance and go to a large distance)

(A)

(B)

(C)

(D)

Page No. 12
 PHYSICS

8. Suppose a nucleus initially at rest undergoes α -decay according to equation,

225
X→ Y + α
92

At t = 0, the emitted α -particle enters in a region of space where a uniform magnetic field
→ →
B = B0 î and electric field E = E0 î exist. The α -particle enters in the region with velocity
→
from x = 0. At time t = × 107 qE sec, the particle was observed to have speed twice
m
V = v0 ĵ √3
0

the initial speed v0, and the initial velocity v0 of the α-particle is 10n m/s, then n is (Mass of α -
particle m = 2 × 10−26 kg, charge on α-particle q = 3.2 × 10–19 C)
3

9. A spherical shell of inner radius a and outer radius b is made of a material of resistivity ρ and
negligible dielectric activity. A single point charge q0 is located at the centre of the shell. At the
time t = 0, all of the material of the shell is electrically neutral, including both the inner and outer
surfaces. The total charge Q on the outer surface of the shell as a function of time for t > 0 is
nt

found to be : Q = q0 (1 − e
4∈
0
ρ
) . Find the integer n? Ignore any effects due to magnetism or
radiation ; do not assume that b – a is small)

10. A point source of light is hanging from a spring in equilibrium as shown. The point image of this
source is formed on ground below. The source is on the principal axis. If the source oscillates up
& down with amplitude A (in cm), the image on ground in extreme position is circular with ratio of
radius 1.5 : 1. Find the value of A.

11. Here shown a diagram which is part of a network in steady state. Here R = 1Ω, Potential
difference across capacitor C1 is Vc = 2 volt and Potential difference across capacitor C2 is VC =
1 2

I2
4 volt. If currents in the resistance R1 and R2 are I1 and I2 respectively, then find I1
.

Page No. 13
12. In a carburator of an engine, air is drawn from atmosphere through section A with a velocity of 10
m/s. The narrow section B is connected to a petrol tank at atmospheric pressure as shown. The
minimum ratio of area of cross section A to area of cross section B, so that the petrol can just
enter the carburettor tube is . Then the value of x is : (density of petrol = 1000 kg/m3,
66
√
x

density of air = 2 kg/m3, g = 10 m/s2, atmospheric pressure = 105 Pa and assume density of air
remain constant)

13.
A solid sphere of mass M of radius R is moving with speed√ in free space.
GM −1
= 100√10 ms
R

Due to application of external impulsive force, it breaks into eight spheres of same radius in such a
way that the total mechanical energy before breaking and after breaking of sphere remains same.
The speed of each sphere is V in m/s when separation between them is very large (assume at that
instant speed of each sphere is same). Find the value of 25 V
.

Page No. 14
 PHYSICS

14. Figure shows arrangement of three long parallel conducting wires, each carrying equal current
coming out of page. Four points A, B, C and D are also marked in the figure, showing distances
between points and wires. All points lie in the same plane which is perpendicular to the wires.

Column I Column II
At
magnitude of the magnetic field is maximum out of
(A) point (p)
given points
A,
At
magnitude of the magnetic field is neither maximum
(B) point (q)
nor minimum out of given points in magnitude
B,
At
magnitude of the magnetic field is minimum out of
(C) point (r)
given points
C,
At
direction of the magnetic field is along negative y
(D) point (s)
axis.
D,

(A) (A) s, q (B) s, q (C) r (D) p

(B) (A) s, r (B) s, q (C) p (D) r
(C) (A) r, q (B) p, q (C) r (D) p
(D) (A) p, q (B) p, r (C) s (D) p

Page No. 15
15. In a hydrogen atom, a0 = 0.529Å, E1 = –13.6 eV. Some modified situations are given. Compare
the energy of levels and radius of allowed orbits.
Column I Column II
An atom consists of positive charge 2e and mass
or
E 1

(A) m and an electron of mass m revolving around (p) 2

the centre of mass of the system 2E1
An atom consists of positron and electron 2a0 or
(B) (q) a
revolving around the centre of mass of system
0

An atom consists of a particle of mass double

E1 or
2

that of electron and charge same as that of

(C) (r) 9
9

electron revolving around a heavy nucleus of E1

2
charge 4e
An atom consists of a nucleus of infinite mass
(D) and an electron revolving around the nucleus of (s) a0 or 8a0
charge 2e
(t) 4E1
(A) (A) p,r,s; (B) p,q,s; (C) p,q,r,s; (D) q,s,t
(B) (A) q,r,p; (B) p,r,s; (C) r,p,s; (D) q,s,t
(C) (A) p,r,s; (B) q,s,p; (C) p,q,s; (D) q,s,t
(D) (A) r,p,q; (B) p,q,s; (C) t,q,s; (D) q,s,t

16. A solid block is floating in a liquid as shown in the figure. Distance h and l are shown in the figure.
The thermal coefficient of volume expansion of the liquid is α. Thermal expansion of the solid is
negligible.

Column I Column II
If the container is moved
Distance l
(A) upward with uniform (p)
decrease
acceleration
If the block is replaced by
another block of similar Distance h
(B) (q)
dimensions but lesser increase
density
If the liquid is replaced by
Distance h
(C) another liquid of equal (r)
decreases
volume but higher density
If the temperature of the
Buoyant force on
liquid is increase (assume
(D) (s) the block
that the block still floats in
increases
liquid)
Buoyant force on
(t) the block
remains constnt

(A) (A) p,r; (B) p,t; (C) p,s,t; (D) q,p

(B) (A) r; (B) p,s; (C) p,s,t; (D) q,t
(C) (A) s; (B) p,r; (C) p,r,t; (D) q,t
(D) (A) r,s; (B) p,s; (C) p,r,q; (D) p,t

Page No. 16
17. Match the statements in column I with the results in column II and indicate your answer by
darkening appropriate bubbles in the 4 × 4 matrix given in the OMR.
Column I Column II
Work done by ideal gas during free
(a) (P) zero
expansion
A wedge block system is as shown in
the fig. The wedge lying on horizontal
surface is accelerated to right by a
horizontal force F. All surfaces are
smooth. Work done by normal
non
(b) reaction exerted by wedge on block in (Q)
any time interval is zero

Two identical conducting spheres of

radius 'a' are separated by a distance
'b' (b >>a). Both spheres carry equal
(c) (R) negative
and opposite charge. Net electrostatic
potential energy of system of both
spheres is
A uniform cylinder lies over a rough
horizontal platform. The platform is
accelerated horizontally as shown with
acceleration a. The cylinder does not
slip over the platform. The work done
(d) by the force of friction on the cylinder (S) positive
w.r.t. ground in any time interval is

(A) (A) s (B) c,s (C) q,d (D) q,s

(B) (A) p (B) q,s (C) q,s (D) q,s
(C) (A) p (B) r,s (C) q (D) p,s
(D) (A) q (B) p,s (C) q,s (D) q,s

Page No. 17
 CHEMISTRY

1. Choose the correct statement(s).

(A) Stopping potential is independent of photo-intensity of incident radiation.
(B) Stopping potential is independent of frequency of incident radiation.
(C) Photocurrent is independent of photo-intensity of incident radiation.
(D) Photocurrent is independent of frequency of incident radiation.

2. Which of the following statements is incorrect regarding back bonding.

(A) Due to back bonding, bond angle always increases.
(B) Due to back bonding, bond length decreases.
(C) Due to back bonding, bond angle decreases.
(D) Due to back bonding hybridisation of central atom does not change always.

3. Compound A(C8H8O2) do not give FeCl3 test, but gives Lucas test and positive Fehling test.
B do not give NaHSO3 test.
1. HI / Red P 1. PCC

A−−−−−−−−→ B A−−−−−−−−→ C
2. Br2 /hν(1 eq) 2. Conc NaOH
+
3. aq KOH 3. H

4. Δ
4. Cu /300

Correct statements are

(A) A have 5 hydrogen deficiency (B) B gives positive iodoform test
(C) C have 3 stereoisomers (D) C have 4 stereoisomers

Page No. 18
 CHEMISTRY

4. 2O3 (g) ⇌ 3O2 (g)

The yield of O2 is given as at Temp T1

If temperature is increased upto T2 then the correct graph is

(A)

(B)

(C)

(D)

5. Statement-1 : Bond angle of HOF is lesser than HOCl.

Statement-2: Oxygen atom is more electronegative than chlorine.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-
1
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
statement-1.
(C) Statement-1 is true, statement-2 is false
(D) Statement-1 is false, statement-2 is true

Page No. 19
6. An organic compound (A), C4H9Cl on reacting with aqueous KOH gives B and on reaction with
alcoholic KOH gives (C) which is also formed on passing vapours of (B) over heated copper. The
compound (C) readily decolourises bromine water. Ozonolysis of (C) gives two compound (D) &
(E). compound (D) is ketone.
Which of the following statements is incorrect.
(A) Compound (D) Produces two products after reaction with NH2OH
(B) Compound (E) gives disproportionation reaction with NaOH
(C) (D) can also be prepared from propyne on treatment with H2O in presence of Hg++ & H2SO4.
(D) Compound (E) form urotropin on reaction with NH3.

7. heat

(X) + K2 CO3 + Air −

−→ (Y)

(Y) + Cl2 ⟶ (Z) Pink

Which of the following is correct?

(A) X = black, MnO2 ,Y = Blue, K2 CrO4 , Z = KMnO4

(B) X = green , Cr2 O3 ,Y = Yellow , K2 CrO4 , Z = K2 Cr2 O7

(C) X = black , MnO2 ,Y = green , K2 MnO4 , Z = KMnO4

(D) X = black ; Bi2 O3 ,Y = colourless KBiO2 , Z = KBiO3

Page No. 20
 CHEMISTRY

8. What is Δvap H(Kcal/mol) for substance whose vapor pressure is represented by diagram?
[R = 2 Cal/mol-K]

Where : P (Vapour pressure)

T (Temperature in Kelvin)

9. For the following reaction scheme, percentage yields are given along the arrow :

x g is mass of R
(Use : Molar mass (in g mol–1 ) of H, C and O as 1, 12 and 16, respectively)
The value of x×100 is_____.

10. Find the number of compounds having higher boiling point than water.
CH4, NH3, CO2, He, SiO2, NaCl, MgF2, ZnO, CF4, Br2, HF, HCl.

11.

If number of C-atoms, number of O-atoms & number of N-atoms in D are x, y & z respectively
then determine the value of x + y + z.

12. 1 ℓH2O2 solution having 1 M concentration was left open causing first order decay of H2O2 with
rate constant equal to 6.93 × 10–2 sec–1. If after 20 sec, the solution is reacted with excess of
I¯(aq) forming I2 (g) with water then calculate the amount of energy released in kJ.
[Assume no change in volume of H2O2 solution]
Given Data :
o
ΔH H2 O2 (aq) = −200 kJ/ mole
f
o
ΔH I2 ( g) = 60 kJ/ mole
f
o −
ΔH I (aq) = −60 kJ/mole
f
o
ΔH H2 O = −290 kJ
f

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13.

Note : I and G will give brown ppt. with Nesslar's reagent in alkaline medium.
What will be the value of xyz if the ratio of different atom in compound (F) according to the
increasing order of electronegativity is x : y : z

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 CHEMISTRY

14. Column-I Column-II

(A) (P) Carbocation

(B) (Q) Racemic mixture

(C) (R) Coupling reaction

(D) (S) Addition reaction

(T) Substitution reaction

Select the correct option
(A) (A)–PQRST; (B)–QR;(C)–PST; (D)–PQ (B) (A)–P; (B)–PQSR;(C)–PQT; (D)–PS
(C) (A)–PT; (B)–PQS;(C)–PT; (D)–PQR (D) (A)–PRT; (B)–Q,S;(C)–PQT; (D)–PQ

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15. At 25°C, the resistance of 0.1M - CH3COOH solution is 100 ohm. The cell constant of the
conductivity cell is 50 m–1 . The limiting molar conductivities of NaCl, CH4COONa and HCl are 9.65
× 10–3, 9.45 × 10–3 and 1.02 × 10–2 ohm–1 m2 mol–1, respectively. The ionic mobility of Cl– ion at
infinite dilution is 2 × 10–8 m2 V–1 s–1.
Column I Column II
Degree of dissociation of
(A) 0.05 (P)
0.1M-CH3COOH in water.
[H+] in 0.1 M - CH3COOH
(B) 0.8 (Q)
solution is
(C) 0.5 (R) Ka of CH3COOH is
The ionic mobility of Na+ ion
(D) 0.15 (S) in water is y × 10–7 m2V–1s–
1 . The value of 'y' is :
The osmotic pressure of 0.1
M-CH3COOH solution
(T)
at 298 K is (z × 0.0821 ×
298) atm. the value of 'z' is
(A) (A) QR (B) S (C) P (D) T (B) (A) QR (B) R (C) P (D) S
(C) (A) QP (B) R (C) P (D) S (D) (A) QT (B) T (C) P (D) S

16. Match column-I with column-II for reactions of type R(g) → P(g)

Column-I
Column-I
(Order of
(Characteristics)
reaction)
Zero order Time of completion
(A) (P)
reaction is not finite
Increase in
First order temperature
(B) (Q)
reaction decreases half life of
reaction
Value of rate
constant will be
Second dependent on
(C) order (R) whether pressure of
reaction reactant is used or
concentration is
used
Reaction must be a
(S)
complex reaction.

(A) (A) QRS (B) PQ (C) PQRS

(B) (A) QRS (B) PQR (C) PQRS
(C) (A) RS (B) PQ (C) PQRS
(D) (A) PQRS (B) PQ (C) QRS

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17. Column-I and Column-II contains four entries each. Entries of Column-I are to be not matched
with some entries of Column-II. One or more than one entries of Column-I may have the not
matching with the same entries of Column-II.
Column-I Column-II
[Ni (CO) ] and
Magetic
(A) (P)
4

K2 [Ni (CN) ]
4
moment
Oxidation
[Cu (NH3 ) ] SO4
no. of
(B) (Q)
4

and K3 [Cu (CN) ]

4
central
metal
K2 [NiCl4 ] and
(C) (R) Geometry
K4 [Ni (CN) ]
4

K2 [NiCl4 ] and EAN of

(D) (S) central
K2 [PtCl4 ]
metal
(A) (A) - (q, r, s) ; (B) - (p, q, r, s) ; (C) - (p, q, s) ; (D) - (p, r, s)
(B) (A) - (q, r, s) ; (B) - (p, q, r, s) ; (C) - (p, q, s) ; (D) - (p, r, d)
(C) (A) - (q, r, s) ; (B) - (p, q, r, s) ; (C) - (p, q, s) ; (D) - (p, r, p)
(D) (A) - (q, r, s) ; (B) - (p, q, r, s) ; (C) - (p, q, s) ; (D) - (p, r, r)

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