SAFETY DATA SHEET
1. Identification
Product identifier Clean & Shine
Other means of identification
Product Code 1259
Recommended use Dressing
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Company name Malco Products, Inc.
Address 361 Fairview Ave
Barberton, OH 44203
United States
Telephone Phone 800-253-2526
Fax 330-753-2025
Website www.malcopro.com
E-mail [email protected]
Contact person Technical Department
Emergency phone number Phone 1-800-424-9300
2. Hazard(s) identification
Physical hazards Not classified.
Health hazards Acute toxicity, oral Category 4
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Sensitization, skin Category 1
Specific target organ toxicity, single exposure Category 3 respiratory tract irritation
Environmental hazards Not classified.
OSHA defined hazards Not classified.
Label elements
Signal word Warning
Hazard statement May be harmful if swallowed. Causes skin irritation. May cause an allergic skin reaction. Causes
serious eye irritation. May cause respiratory irritation.
Precautionary statement
Prevention Avoid breathing mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when
using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing
must not be allowed out of the workplace. Wear eye protection/face protection. Wear protective
gloves.
Response If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin: Wash with plenty of water. If
inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Call a poison center/doctor if you feel unwell. If skin irritation or rash occurs: Get
medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off
contaminated clothing and wash before reuse.
Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise None known.
classified (HNOC)
Material name: Clean & Shine SDS US
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Supplemental information 11.52% of the mixture consists of component(s) of unknown acute dermal toxicity. 11.52% of the
mixture consists of component(s) of unknown acute inhalation toxicity. 1.52% of the mixture
consists of component(s) of unknown acute hazards to the aquatic environment. 1.52% of the
mixture consists of component(s) of unknown long-term hazards to the aquatic environment.
3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
Siloxanes And Silicones, Di-me 63148-62-9 10 - < 20
N,N-dimethyldodecan-1-amine 1643-20-5 <1
oxide
sodium;hydroxide 1310-73-2 < 0.3
Other components below reportable levels 80 - < 90
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Skin contact Remove contaminated clothing immediately and wash skin with soap and water. In case of
eczema or other skin disorders: Seek medical attention and take along these instructions. Wash
contaminated clothing before reuse.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Get medical advice/attention if you feel unwell.
Most important Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
symptoms/effects, acute and vision. May cause respiratory irritation. Skin irritation. May cause redness and pain. May cause an
delayed allergic skin reaction. Dermatitis. Rash.
Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim
medical attention and special under observation. Symptoms may be delayed.
treatment needed
General information If you feel unwell, seek medical advice (show the label where possible). Ensure that medical
personnel are aware of the material(s) involved, and take precautions to protect themselves. Show
this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse.
5. Fire-fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting Move containers from fire area if you can do so without risk.
equipment/instructions
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
protective equipment and appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do
emergency procedures not touch damaged containers or spilled material unless wearing appropriate protective clothing.
Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be
contained.
Methods and materials for Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
containment and cleaning up possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.
Material name: Clean & Shine SDS US
1259 Version #: 08 Revision date: 11-21-2023 Issue date: 11-21-2023 2/7
7. Handling and storage
Precautions for safe handling Do not taste or swallow. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing.
Avoid prolonged exposure. When using, do not eat, drink or smoke. Provide adequate ventilation.
Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe
good industrial hygiene practices.
Conditions for safe storage, Store locked up. Store in original tightly closed container.
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.
At this time, the other constituents have no known exposure limits.
US. OSHA Table Z-1 Permissible Exposure Limits (PEL) for Air Contaminants (29 CFR 1910.1000)
Components Type Value
sodium;hydroxide (CAS PEL 2 mg/m3
1310-73-2)
US. ACGIH Threshold Limit Values (TLV)
Components Type Value
sodium;hydroxide (CAS Ceiling 2 mg/m3
1310-73-2)
NIOSH. Immediately Dangerous to Life or Health (IDLH) Values, as amended
Components Type Value
sodium;hydroxide (CAS IDLH 10 mg/m3
1310-73-2)
US. NIOSH: Pocket Guide to Chemical Hazards Recommended Exposure Limits (REL)
Components Type Value
sodium;hydroxide (CAS Ceiling 2 mg/m3
1310-73-2)
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Provide
eyewash station. Eye wash fountain and emergency showers are recommended.
Individual protection measures, such as personal protective equipment
Eye/face protection Face shield is recommended. Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection Wear appropriate chemical resistant gloves.
Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Chemical respirator with
organic vapor cartridge.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene Keep away from food and drink. Always observe good personal hygiene measures, such as
considerations washing after handling the material and before eating, drinking, and/or smoking. Routinely wash
work clothing and protective equipment to remove contaminants. Contaminated work clothing
should not be allowed out of the workplace.
9. Physical and chemical properties
Appearance Milky.
Physical state Liquid.
Form Liquid.
Color White.
Odor Lemon
Odor threshold Not available.
pH 12.5
Melting point/freezing point Not available.
Material name: Clean & Shine SDS US
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Initial boiling point and boiling 211.95 °F (99.97 °C) estimated
range
Flash point Not available.
Evaporation rate Not available.
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure Not available.
Vapor density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity 5 cP
Viscosity temperature 68 °F (20 °C)
Other information
Density 8.38
Explosive properties Not explosive.
Oxidizing properties Not oxidizing.
VOC 0 % w/w
10. Stability and reactivity
Reactivity Reacts violently with strong acids. This product may react with oxidizing agents.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Contact with incompatible materials. Do not mix with other chemicals.
Incompatible materials Acids. Oxidizing agents.
Hazardous decomposition No hazardous decomposition products are known.
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause irritation to the respiratory system. Prolonged inhalation may be harmful.
Skin contact Causes skin irritation. May cause an allergic skin reaction.
Eye contact Causes serious eye irritation.
Ingestion Harmful if swallowed.
Symptoms related to the Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
physical, chemical and vision. May cause respiratory irritation. Skin irritation. May cause redness and pain. May cause an
toxicological characteristics allergic skin reaction. Dermatitis. Rash.
Information on toxicological effects
Acute toxicity In high concentrations, vapors are anesthetic and may cause headache, fatigue, dizziness and
central nervous system effects. Harmful if swallowed.
Components Species Test Results
N,N-dimethyldodecan-1-amine oxide (CAS 1643-20-5)
Acute
Oral
LD50 Rat > 20 g/kg
Material name: Clean & Shine SDS US
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Components Species Test Results
sodium;hydroxide (CAS 1310-73-2)
Acute
Dermal
LD50 Rabbit 1350 mg/kg
Oral
LD50 Rat 140 - 340 mg/kg
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Causes serious eye irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization May cause an allergic skin reaction.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity Not classifiable as to carcinogenicity to humans.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - May cause respiratory irritation.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not an aspiration hazard.
Chronic effects Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Components Species Test Results
Siloxanes And Silicones, Di-me (CAS 63148-62-9)
Aquatic
Acute
Fish LC50 Channel catfish (Ictalurus punctatus) 2.36 - 4.15 mg/l, 96 hours
sodium;hydroxide (CAS 1310-73-2)
Aquatic
Acute
Crustacea EC50 Water flea (Ceriodaphnia dubia) 34.59 - 47.13 mg/l, 48 hours
Fish LC50 Western mosquitofish (Gambusia affinis) 125 mg/l, 96 hours
* Estimates for product may be based on additional component data not shown.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Partition coefficient n-octanol / water (log Kow)
N,N-dimethyldodecan-1-amine oxide 4.67
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
Material name: Clean & Shine SDS US
1259 Version #: 08 Revision date: 11-21-2023 Issue date: 11-21-2023 5/7
13. Disposal considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to Not established.
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
Toxic Substances Control Act (TSCA)
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
sodium;hydroxide (CAS 1310-73-2) Listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
Classified hazard Acute toxicity (any route of exposure)
categories Skin corrosion or irritation
Serious eye damage or eye irritation
Respiratory or skin sensitization
Specific target organ toxicity (single or repeated exposure)
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material
is not known to contain any chemicals currently listed as carcinogens or reproductive toxins.
Material name: Clean & Shine SDS US
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US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
subd. (a))
sodium;hydroxide (CAS 1310-73-2)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date 11-21-2023
Revision date 11-21-2023
Version # 08
Disclaimer Malco Products, Inc. cannot anticipate all conditions under which this information and its product,
or the products of other manufacturers in combination with its product, may be used. It is the
user’s responsibility to ensure safe conditions for handling, storage and disposal of the product,
and to assume liability for loss, injury, damage or expense due to improper use. The information
provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling,
use, processing, storage, transportation, disposal and release and is not to be considered a
warranty or quality specification. The information relates only to the specific material designated
and may not be valid for such material used in combination with any other materials or in any
process, unless specified in the text.
Revision information This document has undergone significant changes and should be reviewed in its entirety.
Material name: Clean & Shine SDS US
1259 Version #: 08 Revision date: 11-21-2023 Issue date: 11-21-2023 7/7
