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(E) How bond length of diatomic molecules is determined TKN/KS/16/5858
with the help of rotational spectra ? 2½
(F) Explain selection rule for pure vibrational spectra. Bachelor of Science (B.Sc.) Semester–IV
Out of H2, O2, N2, HCl, NO and CH4 which will (C.B.S.) Examination
give pure vibrational spectra ? 2½
CHEMISTRY (Physical Chemistry)
5. Attempt any TEN of the following : Paper—II (CH-402)
(i) What do you mean by efficiency of a system ?
(ii) Define ‘‘Chemical Potential’’. Time—Three Hours] [Maximum Marks—50
(iii) Why Helmholtz’s free energy is now called Helmholtz’s N.B. :— (1) All FIVE questions are compulsory
work function ? and carry equal marks.
(iv) Define an electrochemical cell. (2) Draw diagrams wherever necessary.
(v) Why KCl is not used in the salt bridge in case of 1. (A) Derive an expression for the entropy change
Cu-Ag Cell ? accompanying the isothermal expansion of an ideal
(vi) How is an oxidation-reduction electrode set up ? gas. 5
(B) Derive Van’t-Hoff reaction isotherm. 5
(vii) Define ‘Nuclear fission’.
OR
(viii) Define ‘Dipple moment’. What is its SI unit ?
(C) Derive Gibb’s Helmoltz equation. 2½
(ix) Write the relation between dielectric constant and
dipole moment of a substance. (D) The free energy change for a reaction :
(x) What is zero point energy ? What does it indicate ? N2(g) + 3H2(g) 2(NH3)(g)
(xi) Define force constant. State its SI unit. is –33.20 kJ at 25ºC. Calculate the equilibrium
constant. 2½
(xii) Write Morse equation. 10×1=10
(E) Give any five statements of 2nd law of thermodynamics.
2½
(F) Calculate the total entropy change when 5 moles of
ice is converted into water at 0ºC. The latent heat
of fusion of ice is 80 cal gm–1 . 2½
MXP—M—3525 4 11050 MXP—M—3525 1 Contd.
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2. (A) How can you determine various thermodynamic (D) Calculate the binding energy per nucleon
quantities such as ∆ H, ∆G and ∆S accompanying in helium atom [ 42 He ] which has a mass of 4.0026
the cell reaction ? 5 amu. Calculated atomic mass is 4.03298 amu
(B) Derive Nernst equation of EMF of a cell. Calculate (1 amu = 931.5 MeV) 2½
the EMF of a cell at 25ºC :
Zn(s)/Zn++ (0.1 M) || Cu++ (0.01 M) Cu(s) (E) Explain Polarization of molecules in the electric field.
if Eº cell = 1.0993 V. 5 2½
OR (F) How is percentage of ionic character of a polar
covalent bond calculated with dipole moment ?
(C) Define ‘‘Liquid junction potential’’. How can it be 2½
eliminated ? 2½
4. (A) What do you understand by non-rigid rotor ? Explain
(D) How is pH of a solution calculated by using glass how its spectra differs from rigid rotor. Calculate
electrode ? 2½ rotational constant of HCl molecule. The H–Cl bond
(E) Derive an expression for emf of a concentration cell length is 136 ×10–12 m. The reduced mass of
with transference. 2½ molecule is 1.626 × 10–27 kg. (h = 6.626 × 10–34 JS,
(F) Discuss briefly reversible and irreversible cells. C = 3 ×108 ms–1). 5
2½ (B) What are harmonic and anharmonic oscillators ? Draw
3. (A) Discuss the liquid drop model of nucleus. What are their potential energy diagram. What is fundamental
the evidences in its favour and its limitations ? 5 band and overtones ? 5
(B) Explain the application of dipole moment in : OR
(i) Differentiating O, M and P-isomers and (C) The rotational constant of CO molecule is
166 m–1 . Calculate bond length if its reduced mass
(ii) Predicting the geometry of molecules. 5 is 1.24 ×10–26 kg. 2½
OR (D) Calculate number of modes of vibrations in NO
(C) Discuss applications of radioisotopes in : molecule and show them with vibrational frequency.
(i) Medical Science and 2½
(ii) Agriculture. 2½
MXP—M—3525 2 Contd. MXP—M—3525 3 Contd.
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