Sec: ISR.

IIT_*COSC(MODEL-A) CAT-27 Date: 27-04-25

Time: 3 Hrs 2018_P2 Max. Marks: 180
KEY SHEET
MATHEMATICS
1 ABD 2 ABCD 3 ACD 4 A 5 BCD
6 ABD 7 -12 8 12 9 5 10 12
11 15 12 9 13 4 14 6 15 B
16 C 17 C 18 A

PHYSICS
19 ABCD 20 ABC 21 AC 22 ABC 23 ACD

24
AD 25
1.94 to 26
4.00 27
50.00 28
25.00
1.96
29 9.20 30 4.00 31 30.00 32 6.25 33 B

34 A 35 B 36 A

CHEMISTRY
37 AD 38 ABC 39 ABC 40 AC 41 AB

BC 13.3 4.15 160.84 3.92

42 43 TO 44 TO 45 TO 46 TO
13.5 4.19 160.88 3.96
-2.04 1.27 7.00 5.00 A
47 TO 48 49 50 51
-2.03
52 C 53 D 54 A
Narayana IIT Academy 27-04-25_ISR.*CO-SC(MODEL-A)_JEE-ADV_CAT-27_KEY&SOL
SOLUTIONS
MATHEMATICS

1. Suppose ax  by  c  0 is normal to the curve xy  1 at  x1 , y1  . Differentiating

 dy  1
xy  1 with respect to x , we have    2
 dx  x1 , y1  x1
1
Slope of tangent at  x1 , y1  = 2
x1
Slope of normal at  x1 , y1  = x12 >0

log 2 1  5a  a 2 
0
5
1  5a  a 2  1
5a  a 2  0
a 2  5a  0
 a   0,5 
2. Let g ( x)  f ( x)  x, x   a, b 
Now, g  a  g  b    f  a   a   f  b   b 
g  a  g  b    b  a  a  b     a  b   0
2

 g  c   0, c   a, b  ( from IMVT )
Further, applying LMVT for f ( x) in  a, c  we get
f (c )  f  a 
 f 1  c1  ; c1   a, c 
ca
f (b)  f  c 
Similarly,  f 1  c2  ; c2   c, b 
bc
cb a c
So, f 1  c1  f 1  c2    1
ca bc
cb
Now, f 1  c1   1
ca
ac
And f 1  c2   1
bc
3. f 1  x  must be of least degree so take f 1  x   a  x  1 x  3
a
 f  x     x 3  2ax 2  3ax  c
3
Using f (1)  6 and f  3  2 we get a  3, c  2
 f  x   x3  6 x 2  9 x  2

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4. ln  f  x    0  f  x   1 x  R
 f 1 ( x)  786 f ( x)  0, x  R
 e786 x f 1 ( x)  786e786 x . f ( x )  0
d
  f ( x).e786 x   0, x  R
dx
 g  x  is an increa sin g function
5. 
Clearly g ( x)  f 1 ( x)  log x  1  x 2 
1
 g 1 ( x)   0 x  R
1 x 2

 g ( x)  0 x  R
1

So no tangent is parallel to x axis

 g ( x) has no extremum.
At (0,0) g 1 (0)  1
So equation of tangent is y  x
6. clearly shortest distance of approach will occur along the common normal x  y  1 .
1 1
so when they are at their closest distance of approach, P must be at  ,  , Q must be
2 2
 2 2 7
at 1  ,  covering angle on the circle. since both P and Q happened to be
 6 6  4
7 1
at these points at same time t0 , we can have t0   also at this instant
4 2u
3 2
t0 , rmin   12rmin   6 2  4  4
3 2

7. Differentiating the given equation with respect to x we get

dy dy
2 y  6x2  4  0
dx dx
2
dy 3 x
 
dx y  2
 dy  3h2
  
 dx  h,k  k  2
3h 2
Now equation of the tangent at  h, k  is y  k   x  h
k 2
3h 2
This tangent passes through the point (1,2). This implies 2  k  1  h 
k 2
3h3  3h 2  2k  4  k 2  2k  0  (1)

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Also  h, k  lie on the curve. This implies k 2  2h3  4k  8  0  (2)
Adding Equations (1) & (2) we have
h3  3h 2  4  0
  h  1 h  2   0
2

 h  1,2
Now h  1 k is imaginary. So h  2 and k  2  2 3
Hence the slopes are 2 3
8. f  x   f  6  x   1
On differentiating (1) with respect to x , we get f 1  x    f 1  6  x    2
Putting x  0, 2,3,5 in (2) , we get f 1  0    f 1  6   0
Similarly, f 1  2    f 1  4   0
f 1  3  0
f 1  5    f 1 1  0
 f 1  0   0  f 1  2   f 1  3  f 1  5   f 1 1  f 1  4   f 1  6 
Therefore, f 1  x   0 has minimum seven roots in  0,6
Now, consider a function y  f 1  x 
As f 1  x  satisfies Rolle’s theorem in intervals 0,1, 1, 2 , 2,3 , 3,4 ,  4,5 and 5,6,
respectively, by Rolle’s theorem, the equation f 11 ( x)  0 has minimum six roots.
Now, g ( x)   f 11 ( x)   f 1 ( x ) f 111 ( x )  0  h1 ( x ), where h( x)  f 1 ( x) f 11 ( x) .
2

Clearly, h( x)  0 has minimum 13 roots in  0,6 .

Hence, again by Rolle’s theorem, g ( x)  h1 ( x) has minimum.
12 zeros in  0,6
 x  sin x 
9. f  x    
 5 
x  sin x 1 1  cos x
Consider g  x   ; g  x   0 for x   0, 20 
5 5
x  sin x
Thus, g  x  is an increasing function , also the range of g  x   is  0,4  .
5
At all integral values, f ( x ) will not be derivable. Hence there are  4   12 points, where
f ( x ) is not derivable.
g b  g  a 
Thus, there are 12 values of c , for which g 1  c   has same values.
ba
Thus, by Rolle’s Theorem for g1  x  , g11  x  will vanish (12-1)=11 points
(minimum).
Hence n  11
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n
Thus,    5
2
 2 x  log 1  k 2  6k  8 ,  2  x  1

10. f  x    2
 x  3 x  4 x  1,  1  x  3
3 2

If f  x  has smallest value at x  1, then we must have f  1   f  1

 2  log 1  k 2  6k  8   1  k   0,6  (1)
2

But in order to define log 1  k 2  6k  8  , we must have k 2  6k  8  0

2
  k  2  k  4   0  k  2 or k  4  (2)
 From (1) and (2) , we get k  0,2    4,6
Hence, possible integers in the range of k are 0,1,5,6.
11. Given function is f ( x)  5 x  7   x 2  2 x 
f ( x)  5 x  7   x  1   1
2
 
7
Critical point of f  x   , 6  1, 7  1, 8  1, 2
5
Therefore, maximum or minimum value of f  x  occur at critical points or
boundary points
5 3 19
So, f     4 
4 4 4
7
f  044
5
7
As both 5 x  7 and x 2  2 x are increasing in nature after x  .
5
7
f  2   3  8  11, f    4 and f  2 max  11
 5 min
Therefore, sum is 4+11=15.
12.

Let ABCD be the given trapezium

Let AM=BN= x cm. Then DM=CN=  36  x 
2

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1
Area of trapezium ABCD is S   6  x  6  x   36  x 2    6  x   36  x  2

2
Or S   6  x   36  x  . Let y   6  x   36  x 2 
2 2 2 2

dy
  6  x   2 x    36  x 2  .2  6  x   2  6  x   6  2 x   4  3  x  6  x 
2 2 2

dx
d2y
And  12 x  6  x 
dx 2
dy
For maximum or minimum of y ,  0 then
dx
d2y
x  3  x  6   2  324  0
dx x 3
 y is maximum at x  3 then S is also maximum at x  3
 S max   6  3  36  9   27 3cm 2
13. Put x  0, y  0 in the given relation, we get f (0)  0
f ( x  h)  f ( x )
f 1 ( x)  lim
h 0 h
f ( h)
f 1 ( x)  lim  3x 2  12  3 x 2
h0 h
f ( x)  12 x  x3  c
c  0 ( f (0)  0)
 f ( x)  12 x  x 3
f is increa sin g  12  3x 2  0
 3 x2  4  0
 x   2,2
 x 2  300 300
14. f ( x )  10  2    200 
 600  x x
da
15.  2  a  2t  c
dt

a  0, t  0  c  0  a  2t
The curve becomes y  x 2  4tx  4t 2  2t
 Now if x  0, then y  4t 2  2t
dy dy
 2 x  4t. Then  4t
dx dx at x 0
Equation of the tangent is y   4t 2  2t   4t  x  0   y  4tx  4t 2  2t
Vertex of y  x 2  4tx  4t 2  2t is  2t ,2t 
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Distance of vertex from the origin = 2 2t
 Rate of change of distance of vertex from origin with respect to
t 2 2 k 2 2
dc dc
If c(t )  4t 2  2t   8t  2   16 2  2
dt dt t 2 2
dm
Again m(t )  4t   4
dt
16. P) f 1 ( x)  6 x 2  18 x  12
For maxima or minima put f 1 ( x)  0  x  1 or x  2
f (1)  10, f (2)  9, f (3)  14
G  14, L  5
Q) f 1 ( x)  3x 2  12 x  9  3 x  1 x  3
Critical point is 1 in [0,2]
f (0)  1, f (1)  5 , f (2)  3
G=5, L=1
R) f 1 ( x)  5( x  3)( x  2) 2 ( x  1)
f 1 ( x)  0  x  3, 1,2
f (4)  216
f (3)  0, f (4)  392
G  392, L  216
1 5 3
S) f ( x)  cos x  sin x
2 2
1 25
G   3]  19
4 4
1 25
L   3]   19
4 4
17. (P) Given function is f ( x)  ( x  2)2/3  2 x  1
2
f 1 ( x)  ( x  2) 1/3  2 x  1  ( x  2) 2/3 (2)
3
2  2 x  1  3  x  2   10  x  1
f 1 ( x)   
3 x  2  3 x  2 
1/3 1/3

x 1
For critical points, f 1  x   0  0
 x  2
1/3

Critical points are x  1 and x  2

(Q) Given that , f ( x )  4cos 3 ( x )  3 3 cos 2  x   10; x   0,2 

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 f 1 ( x)  12cos 2 ( x)   sin  x    3 3  2cos  x     sin  x  
 f 1 ( x)  6sin( x )cos( x )  2cos( x)  3 

5 7
So, local maxima occurs at x  ,
6 6

R) f  x   3 x  2  4  x

x  2  0& 4  x  0

x   2, 4

Let x  2sin 2   4cos2 

 f  x   3 2 cos   2 sin 

 2  3 2 cos   2 sin   9  2  2
2  3 2 cos   2 sin   20
  2,   20

S) Centre of given circle =(2,8)

2
 y2 
 x  2   y  8    2    y  8
2 2 2
Distance of point (2,8) from parabola d 
 4 

y  8 y  8
2 2 2 2

  y  8  d 2  d1   y  8
2 2
d 
16 16
d  d1  2  y  8
2

 2 y  2  y  8
dy 16

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d  d1  y. y  8 
2
1
  2  y  8   0   y 3  64   0  y  4
dy 4 4

d 2  d1  1 3
2
  3 y 2    16  0
dy 4 4

 Distance is minimum at y  4

16  8 
2

  4  8   20
2
d 2

16

18.P) LHS of given equation is f 1 ( x) where f ( x)  ( x  1)( x  2)( x  3)( x  4)

 f ( x ) is continuous & derivable and f (1)  f (2)  0

 f 1 ( x)  0 has atleast one root in (2,3), (3,4)

 f 1 ( x) is a cubic function hence it has exactly one real root in (1,2), (2,3), (3,4)

 x2 
Q) g ( x)  2 f    f  6  x 2 
 2

  x2  
g 1 ( x)  2 x  f 1    f 1  6  x 2  
  2 

x2
 6  x 2  x  2 or x  2
2
x2
for  6  x2
2
1 x 
2
f    f 1  6  x2 
 2
  f  x   0  f  x  is increa sin g 
11 1

 g1 ( x)  0  x   2,    a  2

R) Applying LMVT in  0,1

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e 1 c
 e for come c   0,1
1 0

e c  1  e  ln  e c  1  1

mx  c, x  0
S) f ( x )   x
 e , x0

For application of LMVT function must be continuous & derivable in [-2,2]

f  0   f  0   c  1
f 1  0   f 1  0   m  1
 m  3c  4

PHYSICS:

19. Sol. Current through branch CD =5 amp

1  3  4  8  3  1  4  0  1  40V

2  7  2  5  2  5  4  8  3  0   2  68V

2 R  3  4  5  4  5  2  0 R9

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20.SOL.

Apply KCL at B , E and H

1 4 11
Req=1   1  K
 1 1 7 7
1   
 2 4
3.3
I  2.1mA
11
 10 3

7
VAB  VDE  VGH  2.1V
VBC  VEF  VHI  1.2V
I BC  1.2mA , I EF  0.6mA , I HI  0.3mA
At junction B 0.7  I 3  I1  1.2  I1  I 3  0.5mA.....(1)
At junction E 0.7  I 2  I1  0.6  I1  I 2  0.1mA....(2)
At junction H 0.7  I 2  I 3  0.3  I 2  I 3  0.4mA....(3)
Apply KVL in loop B E H J K B
 I 3 RA3  I1 RA1  I 2 RA2  0 
  I 3  I1  I 2  0.....(4)  RA1  RA2  RA3 
 I1  I 2  I 3
0.5  I 3  0.4  I 3  I 3  I 3  0.3mA
 I 2  0.1mA and I1  0.2mA
21. A)

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Narayana IIT Academy 27-04-25_ISR.*CO-SC(MODEL-A)_JEE-ADV_CAT-27_KEY&SOL

R0 R R0
2  i1  i2 0  n  1  0 ….(1) and   i1   i1  i2  r  0 …(2)
n n n

From (1) and (2) Ammeter reading = i1  i2  1  
2
 n   r  R0  R0 
 
 n n2 
C)From above I min  0 for n  2
l
 for PS  reading will be zero
2
22.A) When zero of main scale coincides with zero of Vernier scale the uppers jaws are closed hence no
zero error for internal diameter measurement
B) For external diameter measurement when lower jaws are made to coincide the zero of Vernier
scale comes to the left of zero of main scale hence zero error is negative
C) For depth measurement when the steam coincides with right most end of main scale zero of
Vernier scale comes to the right of the zero of main scale hence zero error is positive
D) Magnitudes of zero errors for external diameter and depth measurements may be different
23. Time period of the pendulum is equal to time for one oscillation  40  2 S . Error
20
in the measurement of time for 20 oscillations=1 second. Therefore error T for
one oscillation is 1  0.05 second. Error in the measurement of length of the
20
pendulum-least count of the scale =1 mm.
l
g  4 2
T2
g l T 0.001 0.05
100  100  2 100  100  2  100  5.1%
g l T 1 2
24. Sol:

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Narayana IIT Academy 27-04-25_ISR.*CO-SC(MODEL-A)_JEE-ADV_CAT-27_KEY&SOL

Let  be the angle between the mirrors and  be the angle made by the M1 with the horizontal at any
instant. Let  be the angle made by incident ray with reference line and  be the angle made by the
incident ray with normal to M1 at any instant. Let r1 , r2 be the angles made by the ray after reflection
from M1 and after reflection from M2 with the reference lines respectively.
From  RTQ i  90    90   180  i    

r2       i           2      2          r2  2  

dr2  d   d 
 2    2  0  0  0  and  arecons tan ts 
dt  dt   dt 
i.e., ray reflected from M2 does not rotate.
     and r1            2  
dr1  d  d
 2   2  0  2 where  is angular velocity of rotation of the mirrors.
dt  dt  dt

25. Sol.

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Narayana IIT Academy 27-04-25_ISR.*CO-SC(MODEL-A)_JEE-ADV_CAT-27_KEY&SOL

8 2 2 6 32  10  20  120 78
I  I1  I 2  I 3  I 4        1.95 A
10 8 4 2 40 40
26. When battery with galvanometer was connected through the points A and B,
   
 15  R  15  R
 
5    80  1 and    5     l  120    2  equating (1) and (2)
 R l  R l
3  3 
l  200cm . When battery with galvanometer is connected through the point R
   
 15   15  R
   1   5   200  180    3 equating (1) and (3) R  10 3  substituting
5R   R  200
3  3 
R  10 3 in (1)    4V
27. Let R1 and R2 be the resistances of the wire in the left gap before and after stretching and
R 40 2
Q is resistance in the right gap. 1   R1  Q ,
Q 60 3
R2 60 3 3 3 9
  R2  Q   R1  R2  R1 when wire is stretched
Q 40 2 2 2 4
2
R l  3
R  l  2   2   l2  l1 when l1 and l2 are initial and final lengths of the wire.
2

R1  l1  2
Vd i il 4 1
28. Mobility      28  25  10 3 m 2 s 1V 1
E neA  V neAV 10 1.6  10 19  108  10
l
29.

In this scale 7th vernier division is nearest to one of the main scale divisions to the right of it and when
vernier is moving towards right, first 7th vernier division coincides with one of the main scale
divisions to the right of it after moving through a least distance of 0.1 mm. Hence least count of the
instrument is 0.1mm. Length of the rod l  9 mm  0.2 mm  9.2 mm ( After crossing 9mm mark on
main scale, 4th division of vernier coincided with one of the main scale divisions means 4th vernier
division which is at a distance of 0.2mm from the main scale division right to it has moved 0.2 mm
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Narayana IIT Academy 27-04-25_ISR.*CO-SC(MODEL-A)_JEE-ADV_CAT-27_KEY&SOL
to the right. That implies vernier has moved to right by 0.2mm after crossing 9mm mark on main
scale.
 Length of the rod l  9 mm  0.2 mm  9.2 mm

30. Energy of a system as a function of time t is given as E (t )  A2 e t

Taking natural log on both sides
ln E  ln A2  ln e t
ln E  2 ln A   t
Differentiating
E A
2   t
E A
Percentage error in measurement of E is given as
E A
100  2 100   t 100
E A
E 2
100  2  1.25   1.5  5  2.5  1.5  4%
E 10


31. Velocity of object v0  5cos 53i  5sin 53j  3i  4j

Velocity of mirror vm  2i
1 1 1 1 1 1
      v  60 cm
v u f v 30 20
Differentiating
1  dv  1  du    v  
2

      0  vim     vom  along principal axis

v 2  dt  u 2  dt  u
  60  
2
 
 vim     
 vom  4  5i  vix  vm  20i
 30 
 
 
 vix  20i  vm  20i  2i  22i  component of velocty of image along principal axis


If m is transverse magnification
dhi dh   v     60  
hi  mh0   m  0  viy     voy  viy    
 4 j  8 j
dt dt  
u  30 
  
viy  vim  8j  viy  0  8j

 viy  8j  component of velocity of image perprndicular to principal axis
  
vi  vix  viy  22i  8j  velocity of image w.r.t ground
32.

Length of each division   1mm =length of a Vernier division.

 5
Length of each main scale division   mm
cos 37 4
i.e., 5 Vernier divisions match with 4 main scale divisions

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Narayana IIT Academy 27-04-25_ISR.*CO-SC(MODEL-A)_JEE-ADV_CAT-27_KEY&SOL
  1  5  1
Least count     1  1    1  mm
cos 37 4 5  4  4

   5 1 5 25
Length AB   4     VC  LC   4    5    5   mm
 cos 37   4 4 4 4

33. SOL: A) Plane mirror forms virtual image for a real object and real image for avirtual object
B) Concave mirror can form only real images for a virtual object
1 1 1 1 1 1 1 1 
         
v u f v u f u f 
v is –ve for any position of virtual object hence can form only real images
C) Convex mirrorcan form both real and virtual images for a virtual object
1 1 1 1 1 1 u f fu
      v
v u f v f u fu u f
i ) If u  f , v is  ve  virtual image
ii ) If u  f , v is  ve  real image

35
G G 100 100
a) S     
n 1 i
 1 100  1 99
ig
b)V  ig  G  R   100  103 100  R   R  99.9k  in series
c)V  ig  G  R   100  101 100  R   R  900 in series
G G 100 2
d)S   where ig   10 A
n 1 i 10  10 3
1
ig
10000 10000
S   10.01 in parallel
10 999
2
1
10
36. Loop FEDCF : e  6  RI1  4I 2 ...(i)
Loop AFCBA : 6  4  4 I 2  2  I1  I 2   2  2I1  6I 2 ...(ii)

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Narayana IIT Academy 27-04-25_ISR.*CO-SC(MODEL-A)_JEE-ADV_CAT-27_KEY&SOL

3e  14 R6e
Solving them, we get I1 , I2 
4  3R 4  3R
A) I 2  0 if e  R  6  e  6V  R  0 
B) For current from F to C direction I 2  0  R  6  e  e  R  6
Possible for any finite value of e , because R is finite
C) For current C to F direction
I 2  0 or e  R  6
D) For current in 2 from B to A direction
R  8  2e
I1  I 2  0
4  3R
R
R  8  2e  0 or e  4 
2
Depending on the value of R, e can take any value from zero to infinity

CHEMISTRY:

A)  r H   436   495    242   925.5 kJ

1
37.
 2 

B)  r H    436   495    42   423.5 kJ

1 1
2 2 

1
C)  f H H ( g )   436  218 kJ / mol
2

D)  f H OH ( g )  42 kJ / mol

38.

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1.2  1000
39. A) nC ( s )   100
12
 Maximum obtainable heat= 100  94 =9400 cal
B) Heat released =100  68  100  68 =13600 cal
13600  1200 
C) heat released=   =5440 cal
100  30 

40.

1
41. A) Z C 3  4, Z A  4, Z B2   8  4 Crystal is electrically neutral and hence, it is
2
possible.
1
B) Z B2  6, Z A  6, ZC3   12  6 Crystal is electrically neutral and hence, it is
2
possible.
1 1 1 1
C) Z A  4   , Z B2     , ZC 3  1 Crystal is negatively changed and hence, it is
8 2 8 2
not possible.
D) Z B 2   4, Z C 3  8, Z A  4 Crystal is negatively changed and hence, it is not possible.

42. A) gives  2-methyl-1-chlero cyclo-hexane via S N 1 mechanism.

PCl3 ; SOCl2 / pyridine, PCl5 gives the product via S N 2 mechanism.
SOCl2 gives the product with the same configuration.
43.
r r

3a
In a b.c.c lattice 4r  3a  r 
4
Edge length = a
Edge length not covered by atoms= a  2r

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Narayana IIT Academy 27-04-25_ISR.*CO-SC(MODEL-A)_JEE-ADV_CAT-27_KEY&SOL
2 3a 3a 2a  1.732a a  2  1.732  a  0.268 
a a     a  0.134 
4 2 2 2 2
Edge length not covered by atoms=0.134= x
x%  13.4%
44. Volume of unit cell=  5  10 8   1.25  1022 cc
3

Density of FeO = 4 g/cc

Mass of unit cell = d  v  4  1.25  1022  5  1022 g / cc
M 72
Mass of FeO molecule=   11.95  1022 g / cc
N A 6.023  10 23

Number of FeO molecules per unit cell =

mass of unit cell 5  1022
  4.184
mass of FeO molecule 11.95  1023

5
45. C2 H 2  g   O2  g   2CO2  g   H 2O  l  ; H1  312 kcal mol 1
2

H1  2H f  CO2 , g   H f  H 2O, l   H f  C2 H 2 , g 

312  2  94.38    68.38  H f  C2 H 2 , g 
H f  C2 H 2 , g   312  188.76  68.38  54.86 kcal
2C  s   H 2  g   C2 H 2  g  ; H 2  54.86 kcal
H 2  2H C  S C  g   H H  H  2H C  H  H C C
54.86  2 150   2  51.5   2  93.64   H C C
H C C  300  103  187.28  59.86  160.86 kcal

46. Fe2O3  2 Al  2 Fe  Al2O3

Heat of reaction=399-199=200 kcal [Al & Fe are in their standard states]

Total weight of reactants=160+54=214 g

 Fuel value/gram =200/214=0.9346 kcal/g

Volume of Al=54/2.7=20 cc

Volume of Fe2O3 =160/5.2=30.77 cc

Total volume=20+30.77=50.77 cc

 Fuel value per cc=200/50.77=3.94 kcal/cc

47. The chemical reaction for combustion of diborane is

B2 H 6  g   3O2  g   B2O3  s   3H 2O  g  , H  ?

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Narayana IIT Academy 27-04-25_ISR.*CO-SC(MODEL-A)_JEE-ADV_CAT-27_KEY&SOL
For this the enthalpy change can be calculated in the following way.

H   H B2O3  s   3H H 2O g    H B2O2  g  ;

H 0
f of O2  0 
H H 2O  g  can be obtained by adding 3H H 2O l  and
H H 2O  g  i.e.  286  44  242 kJ mol 1
H   1273  3  242  36 kJ mol 1  1273  726  36  2035 kJmol 1

48.

49. Compound P is phenol.

Compound C is picric acid and No.of O-atoms in C is 7

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50. Increase in mol. wt.=390-180=210

210
Number of –OH groups= 5
42

51.

JR.*CO SC Pg.No: 21