5 NEET 2016 Phase II by ALLEN
5 NEET 2016 Phase II by ALLEN
2 230 V
(4) k = (k + k 2 + k 3 ) + 2k 4
3 1
V2 100 2
Ans. (1) Rbulb = 20
P 500
Sol. Circuit can be redrawn as
R 130
C1 C2 According to question
R bulb 100
A/3 A
k1 R 130
R = 26
20 100
k4
k2 94. A long wire carrying a steady current is bent into
a circular loop of one turn. The magnetic field at
A/3 k3 the centre of the loop is B. It is then bent into a
circular coil of n turns. The magnetic field at the
d/2 d/2 centre of this coil of n turns will be :-
1 1 1 (1) 2nB (2) 2n 2 B (3) nB (4) n 2 B
C C1 C 2 Ans. (4)
R
d 1 1 Sol. Since = 2 R = n(2 r) r
n
A 0 k A k1 k 2 k3 A 0 k 4
0
d /2 0 i
3 d/2 For one turn B an d
2R
2 3 1 n2 i
k k k k k For n turn B ' 0 ni B 0 n 2B
1 2 3 4 2r 2R
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CODE-YY
9 5. A bar magnet is hung by a thin cotton thread in a 98. A uniform magnetic field is restricted within a region
of radius r. The magnetic field changes with time
uniform horizontal magnetic field and is in
equilibrium state. The energy required to rotate it dB
at a rate . Loop 1 of radius R > r encloses the
dt
by 60° is W. Now the torque required to keep the region r and loop 2 of radius R is outside the region
magnet in this new position is :- of magnetic field as shown in the figure below. Then
the e.m.f. generated is :-
3W 2W
(1) (2)
2 3 ×× ×
× × × × r×
× × ×
× × ×× × R R
× × ××
W × ×
(3) (4) 1
3 3W 2
Ans. (4) dB 2
(1) R in loop 1 and zero in loop 2
Sol. = PE sin 60° .....(1) dt
W = PE (1 – cos60°) .....(2)
dB 2
From (1) and (2) (2) r in loop 1 and zero in loop 2
dt
3 /2 (3) Zero in loop 1 and zero in loop 2
= W 3
W 1/ 2
dB 2 dB 2
(4) r in loop 1 and r in loop 2
9 6. An electron is moving in a circular path under the dt dt
influence of a transverse magnetic field of Ans. (2)
3.57 × 10 –2 T. If th e value of e/m is Sol. For Loop 1
1.76 × 10 11 C/kg, the frequency of revolution of dB 2 dB
ind A cos 0 r
the electron is :- dt dt
(1) 62.8 MHz (2) 6.28 MHz For Loop 2, ind = 0 as no flux linkage
99. The potential differences across the resistance,
(3) 1 GHz (4) 100 MHz
capacitance and inductance are 80 V, 40 V and
Ans. (3) 100 V respectively in an L-C-R circuit. The power
factor of this circuit is :-
eB
Sol. f= (1) 0.8 (2) 1.0 (3) 0.4 (4) 0.5
2 m Ans. (1)
1.76 10 11 3.57 10
2
VL VC 10 0 40 3
f Sol. tan or = 37°
2 3.14 VR 80 4
f = 10 9 H z or 1 GHz
4
97. Which of the following combinations should be Power factor = cos = cos 37° = or 0.8
5
selected for better tuning of an L-C-R circuit used 100. A 100 resistance and a capacitor of 100
for communication ? reactance are connected in series across a 220 V
source. When the capacitor is 50% charged, the
(1) R = 15 , L = 3.5 H, C = 30 F peak value of the displacement current is :-
(2) R = 25 , L = 1.5 H, C = 45 F (1) 4.4 A (2) 11 2 A (3) 2.2 A (4) 11 A
(3) R = 20 , L = 1.5 H, C = 35 F Ans. (3)
(4) R = 25 , L = 2.5 H, C = 45 F 0 22 0 2
Sol. (id )max (ic max
) 0i
Ans. (1) Z 100 2 100 2
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NEET-II (2016)
1 01. Two identical glass ( g = 3/2) equiconvex lenses of 1 03. The interference pattern is obtained with two
focal length f each are kept in contact. The space coherent light sources of intensity ratio n. In the
between the two lenses is filled with water Imax Imin
(w = 4 / 3). The focal length of the combination interference pattern, the ratio will be :-
Imax Imin
is :-
(1) 4f/3 (2) 3f/4 (3) f/3 (4) f n 2 n
(1) (2)
Ans. (2) (n 1) 2 (n 1) 2
n 2 n
4 (3) (4)
µ 2= n 1 n 1
3
Ans. (4)
I1 n
Sol. 3 µ3= 3
Sol. Let
µ 1= 2 1
2 2
2 2
Imax – Imin
I1 I2 – I1 – I2
4 I1 I2
2 2
Imax Imin
I1 I2
I1 – 2 2(I1 I2 ) I
f1 f3
Dividing numerator and denominator by I 2
f2
2 I1
R I2 2 n
f1 f3 = R = f (given) required ratio
3 I1 n 1
2 –1 I 1
2 2
1 04. A person can see clearly objects only when they lie
–R –3 3
f2 R– f between 50 cm and 400 cm from his eyes. In order
4 2 2
2 –1 to increase the maximum distance of distinct vision
3
to infinity, the type and power of the correcting lens,
1 1 1 1
1 – 2 1 the person has to use, will be :-
feq f1 f2 f3 f 3f f (1) concave, – 0.2 diopter
1 4 3f (2) convex, + 0.15 diopter
f 3f feq
eq 4 (3) convex, + 2.25 diopter
1 02. An air bubble in a glass slab with refractive index (4) concave, – 0.25 diopter
1.5 (near normal incidence) is 5 cm deep when Ans. (4)
viewed from one surface and 3 cm deep when Sol. As we want to correct myopia. So, far point must
viewed from the opposite face. The thickness (in cm) go to infinity.
v = –4 m, u = – , P = ?
of the slab is :-
1 1 1 1 1
(1) 12 (2) 16 (3) 8 (4) 10 P= – – = – 0.25 D
f v u –4
Ans. (1) (–) implies concave mirror
Sol. H R1 H R2 105. A linear aperture whose width is 0.02 cm is placed
immediately in front of a lens of focal length 60 cm.
O1 O O2 The aperture is illuminated normally by a parallel
beam of wavelength 5 × 10–5 cm. The distance of
the first dark band of the diffraction pattern from
H app H app
1 2 the centre of the screen is :-
(1) 0.20 cm (2) 0.15 cm
HR
H app = H R g H app (3) 0.10 cm (4) 0.25 cm
g
Ans. (2)
So, H R1 g H app 1 and H R2 g H app 2 Sol. f = D = 60 cm
For first minima,
So, thickness = H R1 H R2
D 5 10 –7 60 5 10 –3 60
3 3 y = 0.15 cm
= g H app 1 Happ 2 = 5 3 8 12 cm a 2 10 10
–2 –2
2
2 2
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1 06. Electrons of mass m with de-Broglie wavelength Ans. (1)
fall on the target in an X-ray tube. The cutoff Sol. Transition : 3 2 Wavelength
wavelength ( 0 ) of the emitted X-ray is :- Transition : 4 3 Wavelength '
2m 2 c 2 3 1 1 1
(1) 0 (2) 0 = R H Z2 2 2
h2 2 3 ' 20 ' 20
1 1 1 7 7
2mc 2 2h R H Z2 2 2
(3) 0 (4) 0 ' 3 4
h mc
Ans. (3) 1 09. The half-life of a radioactive substance is 30 minutes.
The time (in minutes) taken between 40% decay and
h h
Sol. p 85% decay of the same radioactive substance is :-
p
(1) 45 (2) 60 (3) 15 (4) 30
p2 h2 Ans. (2)
E
2m 2m 2 Sol. decay 40% 85%
hc Remaining 60% 15%
Also in X-ray E
0 t1 t1
2 2
60% 30% 15%
hc h2 2mc 2 t = 2t 1/2 = 60 min.
0
0 2m 2 h 110. For CE transistor amplifier, the audio signal voltage
1 07. Photons with energy 5 eV are incident on a across the collector resistance of 2 k is 4 V. If the
current amplification factor of the transistor is
cathode C in a photoelectric cell. The maximum
100 and the base resistance is 1 k , then the input
energy of emitted photoelectrons is 2 eV. When
signal voltage is :-
photons of energy 6 eV are incident on C, no
(1) 30 mV (2) 15 mV
photoelectrons will reach the anode A, if the (3) 10 mV (4) 20 mV
stopping potential of A relative to C is :- Ans. (4)
(1) – 1 V (2) – 3 V Sol. = 100; V 0 = 4V; R i = 10 3 ;
(3) + 3 V (4) + 4 V R0 = 2 × 10 3 ; V i = ?
Ans. (2) V0 R 4 2 10 3
0 10 0
Vi Ri Vi 10 3
1
Sol. eVs mv 2max h 0 Vi = 20 mV
2 111. The given circuit has two ideal diodes connected as
2 = 5 – 3 eV shown in the figure below. The current flowing
through the resistance R 1 will be :-
In second case
eVs = 6 – 3 = 3 eV Vs = 3 V.
R1
D1 D2
V AC = –3 V
108. If an electron in a hydrogen atom jumps from the
3rd orbit to the 2nd orbit, it emits a photon of 10V R2 3 R3 2
wavelength . When it jumps from the 4th orbit to
the 3rd orbit, the corresponding wavelength of the
(1) 1.43 A (2) 3.13 A
photon will be :-
(3) 2.5 A (4) 10.0 A
20 20 Ans. (3)
(1) (2)
7 13 Sol. Current will not flow through D 1 as it is reverse
biased. Current will flow through cell, R 1 , D 2 and R 3 .
16 9
(3) (4) 10
25 16 i = 2.5 A
2 2
19
NEET-II (2016)
1 12. What is the output Y in the following circuit, when 1 15. In the given figure, a = 15 m/s 2 represents the total
all the three inputs A,B,C are first 0 and then 1 ? acceleration of a particle moving in the clockwise
direction in a circle of radius R = 2.5 m at a given
A instant of time. The speed of the particle is :-
B P Y
Q
C
°
(1) 1,0 (2) 1,1 (3) 0,1 (4) 0.0
30
R
O a
Ans. (1)
A AB
P (1) 5.7 m/s (2) 6.2 m/s
Sol. B Q y = (AB)C
C (3) 4.5 m/s (4) 5.0 m/s
for A = B = C = 0 ; y = 1 Ans. (1)
for A = B = C = 1 ; y = 0
v2
113. Planck's constant (h), speed of light in vacuum (c) Sol. acos30° = a c
R
and Newton's gravitational constant (G) are three
fundamental constants. Which of the following 3
v2 aR v2 = 32.47 v 5.7 m/s
combinations of these has the dimension of length? 2
116. A rigid ball of mass m strikes a rigid wall at 60° and
hc Gc hG hG gets reflected without loss of speed as shown in the
(1) (2) (3) (4)
G h3 /2 c3 / 2 c5 / 2 figure below. The value of impulse imparted by the
wall on the ball will be :-
Ans. (3)
m
Sol. h x G yc z
x y z V
M0 L1 T 0 = (ML2 T–1 ) (M–1 L3 T –2 ) (LT –1 )
= M x–y L2x+3y+z T –x–2y–z 60°
Equat ing :
60 °
1 1 3
xy0 x ; y ;z V
2 2 2
2 x 3y z 1
hG
x 2y z 0 3 /2
mV mV
c (1) (2) (3) mV (4) 2mV
2 3
1 14. Two cars P and Q start from a point at the same
Ans. (3)
time in a straight line and their positions are
represented by x p (t) = at + bt 2 and x Q (t) = ft – t 2 . Vcos6 0°
m
60 °
At what time do the cars have the same velocity ?
Vsin60° V
af fa
(1) (2) Sol. 60°
2(1 b) 2(1 b)
Vcos6 0° 60°
a f af
(3) (4) 60°
1b 2(b 1)
m V Vsin60°
An s. (2)
V Vf Vi
Sol. xP (t) = at + bt 2 xQ (t) = ft – t 2
vP = a + 2bt vQ = f – 2t V cos 60 iˆ V sin 60 j ˆ
as vP = v Q V cos 60 iˆ V sin 60 jˆ
a + 2bt = f – 2t
V 2V cos 60 iˆ
Impulse
fa
t I P m V m(2V cos 60 ) = mV
2(1 b)
20
CODE-YY
1 17. A bullet of mass 10g moving horizontally with a Ans. (4)
velocity of 400 ms –1 strikes a wooden block of mass Sol. Since both bodies are identical and collision is elastic.
2 kg which is suspended by a light inextensible string Therefore velocities will be interchanged after
collision.
of length 5 m. As a result, the centre of gravity of
vA = –0.3 m/s and v B = 0.5 m/s
the block is found to rise a vertical distance of
10 cm. The speed of the bullet after it emerges out 119. A particle moves from a point (2iˆ 5j)
ˆ to
horizontally from the block will be :-
ˆ when a force of
(4 ˆj 3k) ˆ N is applied.
(4iˆ 3j)
(1) 120 ms –1 (2) 160 ms –1
How much work has been done by the force ?
(3) 100 ms –1 (4) 80 ms –1 (1) 5 J (2) 2 J (3) 8 J (4) 11 J
Ans. (1)
Applying momentum conservation
L2A L2
10 10 Sol. KA = K B B
40 0 0 2 v 1 v 2 2I A 2I B
10 00 1000
Applying work energy theorem for block 1 21. A solid sphere of mass m and radius R is rotating
W = KE about its diameter. A solid cylinder of the same mass
and same radius is also rotating about its geometrical
1
2 × 10 × 0.1 = ×2 ×v 1
2 axis with an angular speed twice that of the sphere.
2
The ratio of their kinetic energies of rotation
v1 = (Esp here / Ecylinder) will be :-
2 = 1.4 m/s
Putting the value of v is equation (2) (1) 1 : 4 (2) 3 : 1
1
GMe
m1m 2 2 m1 m 2 2 g R
2
(3) m m (4) m 1m 2
1 2
Ans. (3)
r1 r2 O R r
Sol. m1 (CM) m2
1 24. A satellite of mass m is orbiting the earth
(of radius R) at a height h from its surface. The total
m2 m1 energy of the satellite in terms of g 0 , th e value of
r1 , r2
m1 m 2 m1 m 2 acceleration due to gravity at the earth's surface,
is :-
m1 m 2 2
Icm m 1r12 m 2 r22
m1 m 2
2mg 0 R 2 2mg 0 R 2
(1) (2)
1 23. Starting from the centre of the earth having radius Rh R h
R, the variation of g (acceleration due to gravity) is
shown by :- mg 0 R 2 mg 0 R2
(3) (4)
2(R h) 2(R h)
g
Ans. (4)
(1)
GMe m
O R r Sol. Total energy =
2(R h)
g GMe g0 R 2
g0 Me
R2 G
(2)
mg 0 R2
O R r Energy =
2(R h)
22
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1 26. Th ree liquids of densities 1 , 2 and 3 heat lost = heat gained
(with 1 > 2 > 3 ), having the same value of surface sh (100 °C – ) = s c
tension T, rise to the same height in three identical sh 100 C
capillaries. The angles of contact 1 , 2 and 3 obey:- = 100 C
(sh sc ) sc
1 s
h
(1) 1 2 3 sc / s <1 1 + s c / s <2
2 h h
100 C
> or > 50°C
2
(2) 1 2 3
2 1 28. A body cools from a temperature 3T to 2T in
10 minutes. The room temperature is T. Assume
that Newton's law of cooling is applicable. The
(3) 1 2 3 0 temperature of the body at the end of next
2
10 minutes will be :-
4 7 3
(4) 0 1 2 3 (1) T (2) T (3) T (4) T
2 3 4 2
Ans. (4)
Ans. (4) Sol. Newton's laws of cooling
2 T cos T1 T2 T T2
Sol. h= k 1 T
gr t 2
as r, h, T are same 3 T 2T 5T 2T T 3T
k 10 k 2 ...(i)
cos 10 2
constant
2T T' 2T T '
k T
10 2
cos 1 cos 2 cos 3
1 2 3 2T T' T'
k ...(ii)
as 1 > 2 > 3 10 2
cos 1 > cos 2 > cos 3 By solving (i) and (ii)
1 < 2 < 3 3
T' T
As water rises must be acute 2
So, 0 1 < 2 < 3 < /2 1 29. One mole of an ideal monatomic gas undergoes a
process described by the equation PV 3 = constant.
127. Two identical bodies are made of a material for The heat capacity of the gas during this process is
which the heat capacity increases with temperature.
3 5
One of these is at 100 °C, while the other one is (1) 2 R (2) R (3) R (4) R
2 2
at 0°C. If the two bodies are brought into contact,
Ans. (2)
then, assuming no heat loss, the final common x
Sol. PV = constant (Polytropic process)
temperature is :- Heat capacity in polytropic process is given by
(1) less than 50 °C but greater than 0 °C R
(2) 0 °C C C V 1 x
(3) 50 °C 3
Given that PV = constant x = 3 ...(1)
(4) more than 50 °C also gas is monoatomic f = 3 ...(2)
Ans. (4) by formula
Sol. Let be the final common temperature. Further, fR R
C
let s c and s h be the average heat capacities of the 2 1 x
cold and hot (initially) bodies respectively (where s c
3 R
< sh given) C R R
2 2
From, principle of calorimetry,
23
NEET-II (2016)
1 30. The temperature inside a refrigerator is t 2 °C and Ans. (2)
the room temperature is t 1 °C. The amount of heat
m
delivered to the room for each joule of electrical Sol. T 2
k
energy consumed ideally will be :-
m
3 2 ...(1)
t 2 273 t1 t 2 k
(1) t t (2) t 273
1 2 1
m 1
5 2 ...(2)
k
t1 t1 273
(3) t t (4) t t (1)2 9 m 9
1 2 1 2 2
m
(2) 25 m 1 16
Ans. (4) 1 33. The second overtone of an open organ pipe has the
same frequency as the first overtone of a closed pipe
Sol. Heat delivered = Q 1
L metre long. The length of the open pipe will be
t 2 273 Q 2 Q 1 W Q 1
COP( ) = 1 L
t 1 t2 W W W (1) (2) 4 L (3) L (4) 2 L
2
24
NEET-II (2016)
NEET–II (2016) TEST PAPER WITH ANSWER & SOLUTIONS
(HELD ON SUNDAY 24th JULY, 2016)
1 36. Hot concentrated sulphuric acid is a moderately 1 40. The correct increasing order of trans-effect of the
strong oxidizing agent. Which of the following following species is :
reactions does not show oxidizing behaviour ? (1) Br– > CN – > NH 3 > C 6 H 5 –
(1) C + 2H 2 SO 4 CO 2 + 2SO 2 + 2H 2 O (2) CN – > Br – > C 6 H 5– >NH 3
(2) CaF 2 + H 2 SO 4 CaSO 4 + 2HF (3) NH 3 > CN – > Br– > C 6 H 5–
(3) Cu + 2H 2 SO 4 CuSO 4 + SO 2 + 2H 2 O (4) CN – > C 6 H 5– > Br – > NH 3
(4) 3S + 2H 2 SO 4 3SO 2 + 2H 2 O Ans. (4)
Ans. (2) Sol. Trans effect order – CN C 6 H 5 Br NH 3
Sol. CaF 2 + H 2 SO 4 CaSO 4 + 2HF
1 41. Which one of the followng statements related to
In this reaction, oxidation number of none of the
lanthanons is incorrect ?
atom is not changed. Hence H 2 SO 4 is not acting as
(1) All the lanthanons are much more reactive than
oxidising agent. aluminium
137. Which of the following pairs of d-orbitals will have (2) Ce(+4) solutions are widely used as oxidizing
electron density along the axes ? agent in volumetric analysis
(3) Europium shows +2 oxidation state.
(1) d z2 ,d x 2 y 2 (2) d xy ,d x 2 y2
(4) The basicity decreases as the ionic radius
(3) d z2 ,d xz (4) d xz ,d yz decreases from Pr to Lu.
Ans. (1) Ans. (1)
Sol. dz2 and dx 2 –y2 has electron density concentrated on Sol. (1) Lanthanon's are less reactive than aluminium due
the axis. to high IP (Lanthenoid contraction)
(2) Ce +4 is good oxidising agent and easily converted
138. The correct geometry and hybridization for XeF 4 into Ce +3
are : (3) Eu(63) = 4f 7 5d 0 6s 2 , Eu+2 = 4f 7
(1) Planar triangle, sp 3 d3 (4) In lanthenoids series 'Ce' to Lu ionic radius regular
(2) square planar, sp d
3 2 decreases and covalent character increase, basic
character of hydroxide decrease
(3) octahedral, sp d 3 2
142. Jahn-Teller effect not observed in high spin
(4) trigonal bipyramidal, sp 3 d complexes of :-
Ans. (3) (1) d4 (2) d9 (3) d7 (4) d8
Sol. XeF 4 , AB 4 L2 sp 3d 2 Ans. (4)
Sol. John Teller effect explain axial distortion in perfect
geometry octahedral octahedral geometry. It is present in d 4 high spin,
shape square planar d7 low spin and d 9 co nfiguations which have odd
139. Among the following which one is a wrong number of electrons in eg set.
statement? A weak John Teller effect in also present in d 7 high
spin complex which has odd number of electrons
(1) SeF 4 and CH 4 have same shape
in the set.
(2) I3+ has bent geometry 143. Which of the following can be used as the halide
(3) PH 5 and BiCl 5 do not exist component for Friedel-Crafts reaction ?
(4) p-d bonds are present in SO 2 (1) Chloroethene (2) Isopropyl chloride
(3) Chlorobenzene (4) Bromobenzene
Ans. (1)
Ans. (2)
Sol. (1) SeF 4 –sp 3 d, lp = 1, shape = see-saw
CH 4 –sp 3 , lp = 0, shape =tetrahedral CH 3
C
(2) I3 –sp 3 , lp =2, shape = bent/angular H CH3
Sol. + CH CH Cl
Anhy AlCl3
(3) PH 5 = d-orbital contraction absent CH 3 cumene
BiCl 5 = due to inert pair effect
(Bi +5 act as OA, Cl – act as RA) But in chlorobenzene, Bromobenzene, chloroethene
(4) SO 2 : O=S=O lone pair of halogen are delocalised with bonds,
so attain double bond character.
P -d, P –P both type bonds are present
8
CODE-YY
1 44. In which of the following molecules, all atoms are 1 46. In pyrrole
coplanar ? 4 3
CH 3 CN
(1) C=C (2) –— 5
CH 3 CN .. 2
N1
H
Th e electron density is maximum on :-
(1) 2 and 4 (2) 2 and 5
(3) (4) (3) 2 and 3 (4) 3 and 4
Ans. (2)
Ans. (3) 4 3
5 .. 2 + + + +
H H H H N 1 N N N N
H H H H H
H H (I) (II) (III) (IV) (V)
Sol.
H H H H Maximum electron density at (2) and (5)
as resonating structures III & IV are more stable than
All carbons are sp 2 hybridised (II) & (V) so are major contributor.
145. Which one of the following structures represents
147. Which of the following compounds shall not
nylon 6,6 polymer ?
produced propene by reaction with HBr followed
H2 H2 by elimination of direct only elimination reaction ?
H2 H2 C H C H
C H C C C (1) H 2 C=C=O
(1) C C 6
6
CH 3 CO OH
NH 2 Cl H2
(2) H C–C–CH
3 2Br
O
H2 H (CH2 )6 –NH
(2) C ( C) N H 2 C—CH 2
C 2 C
H2 n (3) C
O H2
H2 H2
C H C H
(3) C C H2
66 (4) H 3 C–C–CH 2OH
NH 2 CH 3
Ans. (1)
H2 H2
C H C H Sol.
(4) C C
66
NH 2 NH 2 H Br Elimination
H 2 C CH 2 CH 3 CH 2 CH 2 H 3 C CH CH 2
Ans. (2) C
Sol. H2 Br
Br O
Polymerisation H Br
CH 2 =C= O H2 C C OH H3 C C Br
O O
C (CH 2 )4 C NH (CH 2 )6 NH CH 3 –CH 2 –CH 2 –Br
n
E lim ination
CH 3 –CH=CH 2
9
NEET-II (2016)
1 48. Which one of the following nitro-compounds does
not react with nitrous acid ? CHO CHO
H OH HO H
H3C
H OH H OH
(1) H 3 C–C–NO 2 Sol. CH 2 OH CH 2 OH
H3C
D-Erythrose D-Threose
CH 3
H 3C C
(2) H
NO 2 CHO CHO
O
HO H H OH
H2 HO H HO H
H 3C C
(3) C NO 2 CH 2 OH CH 2 OH
H2
L-Erythrose L-Threose
H2
H 3C C 1 51. In the given reaction
(4) CH NO 2
H 3C
Ans. (1) + HF
P
0 C
Sol. 3°-Nitro compound does not react with HNO 2
because of absence of –H
the product P is :-
149. The central dogma of molecular genetics states that
the genetic information flows from :-
(1) DNA RNA Proteins
(2) DNA RNA Carbohydrates
(3) Amino acids Proteins DNA (1) (2)
(4) DNA Carbohydrates Proteins
Ans. (1)
H OH HO H (3) (4)
H OH H OH
CH 2 OH CH 2 OH
CH O CH O Ans. (1)
HO H H OH +
H
HO H HO H Sol. Carbocation
(HF)
CH 2 OH CH 2 OH
respec tively, is :-
(1) L-erythrose, L-threose, D-erythrose, D-threose
(2) D-erythrose, D-threose, L-erythrose, L-threose
H
(3) L-erythrose, L-threose, L-erythrose, D-threose ESR
+
(4) D-threose, D-erythrose, L-threose, L-erythrose (alkylation)
Ans. (2)
[Friedel Craft reaction]
10
CODE-YY
1 52. A given nitrogen-containing aromatic compound A 1 54. The correct structure of the product A formed in
reacts with Sn/HCl, followed by HNO 2 to give an
the reaction
unstable compound B. B, on treatment with phenol,
forms a beatiful coloured compound C with the
molecular formula C 12 H 10 N2 O. The structure of O
compound A is :-
H 2 (gas, 1 atmosphere)
CN CONH 2 Pd/ carbon, ethanol
A is :-
(1) (2)
OH OH
NH 2 NO 2
(3) (4) (1) (2)
Ans. (4)
OH O
NO 2 NH 2 N 2· Cl
(3) (4)
HNO 2
Sn+ HCl
Reduction
(A) Aniline (B) Ans. (4)
Benzene Diazonium
chloride
Sol.
Ph—OH O O
N N OH
H 2 gas, (1 atmosphere)
p -Hydroxy azo benzene (red colour dye)
Sol.
Pd /Carbon,Ethanol
1 53. Consider the reaction 1 55. Which among the given molecules can exhibit
tautomerism ?
CH 3 CH 2 CH 2 Br + NaCN CH 3 CH 2 CH 2 CN + NaBr
11
NEET-II (2016)
1 56. The correct order of strengths of the carboxylic 159. The molar conductivity of a 0.5 mol/dm 3
acids solution of AgNO 3 with electrolytic conductivity of
5.76 × 10 –3 S cm –1 at 298 K is
(1) III > II > I (2) II > I > III Sol. C = 0.5 mol / dm 3
= 5.76 × 10 –3 S cm –1
(3) I > II > III (4) II > III > I
T = 298 K
Ans. (4) 3
1000 5.76 10
m 11 .52 Scm 2 /mol
Sol. Acidic Strength M 0.5
1 60. The decomposition of phosphine (PH 3 )on tungsten
COOH COOH CO OH at low pressure is a first-order reaction. It is because
O the
> >
O
(+I) (1) rate is independent of the surface coverage
more(—I) less (—I)
(2) rate of decomposition is very slow
1 57. The compound that will react most readily with (3) rate is proportional to the surface coverage
gaseous bromine has the formula
(4) rate is inversely proportional to the surface
(1) C4 H 10 (2) C2 H 4 coverage
(3) C3 H 6 (4) C2 H 2 Ans. (3)
163. How many electrons can fit in the orbital for which
(1) 0.77% (2) 1.6%
n = 3 and l = 1 ?
(3) 0.0060% (4) 0.013%
(1) 10 (2) 14 (3) 2 (4) 6
Ans. (4)
Ans. (3)
Sol. Pyridine (C 5 H 5 H 5 N) is a weak base
Sol. n=3, l =1 3p
Kb = C2
Total 2 electron can fit in the orbital of 3p
164. For a sample of perfect gas when its pressure is 1.7 10 9
changed isothermally from p i to p f, the entropy 0.1
change is given by
4
1.3 0 10
pf pi
(1) S = nRT ln (2) S = RT ln % 1.30 10 4
100
pi pf
% 0.013%
(4) G° > 0; K eq >1 Ksp = 1.6 × 10 –10 = [Ag + ] [Cl–] = S (0.1+S)
Ksp is small, S is neglected with respect to 0.1 M
Ans. (3)
1.6 × 10 –10 = S × 0.1
Sol. E0cell ve S = 1.6 × 10 –9 M
171. Suppose the elements X and Y combine to form
G 0 nF E cell
0
two compounds XY 2 and X 3 Y2 . When 0.1 mole of
G 0 ve G 0 XY2 weigh s 10 g and 0.05 mole of X 3 Y2 weighs
9 g, the atomic weights of X and Y are
G 0 2.303RT log K eq
(1) 20, 30 (2) 30, 20
K eq 1
(3) 40, 30 (4) 60, 40
1 69. Which one of the following is incorrect for ideal
solution ? Ans. (3)
(2) G mix = 0 10
n xy2 0.1
A x 2A y
(3) H mix = 0
Ans. (2)
9
n x3 y2 0.05
Sol. For an ideal solution H mix 0 3 A x 2A y
3A x + 2A y = 180 ...(2)
U mix 0
on solving eq. (1) and (2)
S mix 0 Ax = 40, A y = 30
According to G mix H mix T S mix 172. The number of electrons delivered at the cathode
G mix 0 during electrolysis by a current of 1 ampere in
Incorrect answer, is G mix =0 60 seconds is (charge on electron = 1. 60 × 10 –19 C)
170. The solubility of AgCl(s) with solubility product (1) 3.75 × 10 20 (2) 7.48 × 10 23
(4) 1.6 × 10 –9 M 1 60 20
n 3.75 10 electrons
1. 6 10 1 9
Ans. (4)
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CODE-YY
1 73. Boric acid is an acid because its molecule 177. The hybridizations of atomic orbitals of nitrogen in
–
(1) accepts OH from water releasing proton NO 2 , NO 3 and NH 4 respectively are
(2) combines with proton from water molecule (1) sp, sp2 and sp 3
+
(3) contains replaceable H ion (2) sp 2 , sp and sp 3
(3) K3 [AlF3 H 3 ] (4) K3 [AlF6 ] 178. Which of the following fluoro-compounds is most
likely to behave as a Lewis base ?
Ans. (4)
(1) CF4 (2) SiF4
Sol. AlF3 + 3KF K3 [AlF6 ]
(3) BF 3 (4) PF 3
1 75. Zinc can be coated on iron to produce galvanized
Ans. (4)
iron but the reverse is not possible. It is because
Sol. PF 3 act as Lewis base due to present of lone pair
(1) zinc has lower negative electrode potential than on P atom.
iron 179. Which of the following pairs of ions is isoelectronic
and isostructural ?
(2) zinc has higher negative electrode potential than
iron (1) SO 23 , NO 3 (2) ClO 3, SO 23
(3) zinc is lighter than iron
(3) CO 23 , NO 3 (4) ClO 3, CO 2
3
(4) zinc has lower melting point than iron
Ans. (2 & 3)
Ans. (2)
Sol. Zinc has higher negative electrode potential than Sol. (2) In SO 23 ,ClO 3 , No. of electrons = 42,
176. The suspension of slaked lime in water is known as (3) In CO 3 2 ,NO 3 , No. of electrons = 32
Shape : trigonal planar
(1) milk of lime
180. In context with beryllium, which one of the following
(2) aqueous solution of slaked lime statements is incorrect ?