Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60(Incoming)_STERLING BT WTA-30 Date: 27-04-2025
Time: 09:00AM to 12:00PM JEE-ADV_(2021-P1) Max. Marks: 180

KEY SHEET
PHYSICS
1 3 2 3 3 1 4 1 5 20 6 10

7 1.6 8 240 9 44.2 10 57.55 11 1,3 12 2,3,4

13 1,2,4 14 1,4 15 1,4 16 1,3,4 17 14 18 3

19 0

CHEMISTRY
20 4 21 3 22 3 23 3 24 1 25 12-12.05

26 9 27 16 28 1185 29 1 30 1,3,4 31 1,2,3

32 1,2,3 33 4 34 1,3,4 35 2,3,4 36 6 37 3

38 2

MATHEMATICS
1.06-
39 B 40 C 41 C 42 C 43 44 0.33
1.07
45 2 46 84 47 1 48 2011 49 ACD 50 BCD

51 AD 52 ABD 53 ABCD 54 AD 55 2 56 74

57 1
 Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60(Incoming)_STERLING! BT_Jee-Adv(2021-P1)_WTA-30_Key & Sol’s

SOLUTIONS
PHYSICS
  
01.  
F  q V  B  1.6  1013 N
P2  mV 
 Vq   Bqr   Vq 2m  r 
2
02. Kinetic Energy KE  Vq 
2m  Bq 
2
d  B2d 2q
B q    Vq 2m  m 
2 2

2 8V
 0 I1I 2  b   
03.  2 ln  1  a  j 
   
  I
 
Magnetic field B created by wire-I at a distance x from it, i.e.. B  0 1  k 
2 x
 
Force acting on a small element dx of wire -2, i.e
       I  II  I I
 2 x  2    
 
2 

dF  I 2 d  X B or dF  I 2 d  X  0 1  k    0 1 2 dx i   k  asd  d  i   0 1 2 d   j;

    I I a b 1 
F   dF   0 1 2  d 
 2 a  
j   0 I1 I 2 In 1  b   j
 2  
  a 

F point upward as indicated by j
04.  electric force on the slab
du 1  0bE 2
F   K  1
d 2 d
 bE 2
Mg  0  K  1
2d
05. Particle is projected in x-y plane which is  er to the magnetic field. Since field is along
z-axis.
Magnetic of velocity V  2V0
mV 2mV0
Radius of the circle r  
Bq Bq
06. Force on the charged particle
   
  
F  q  E  V  B   q  E0 k  B0V0 j 

Here the magnetic force is along y-axis it causes the change in direction of velocity.
Electric force is along z-axis it accelerate the charged particle. So velocity along -axis
increases continuously
 Path of the particles helix with non uniform pitch.
07. i  2  102 A
PR1  i 2 R1   2 10 2   4  103  1.6W
2

08. QC1  VR1  C1  80  310 6  240  C

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 Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60(Incoming)_STERLING! BT_Jee-Adv(2021-P1)_WTA-30_Key & Sol’s

C1 R1

220V
R2
C2

1
09.  d  2 Il
2
B
1 2
10. Il B  Kxl sin 530 find x
2
11. When ‘S’ is open across capacitors
18
i  2A
9
V  18.0V

A B

V1 6 F
6

a b
S
3 V2 3 F

C D

V1 C2 3 1
  
V2 C1 6 2
1
VA  Va  6  2   12;V1  18   6
3
2
Va  VC  3  2   6;V2  18   12
3
Va  6 VC  0  ;V1  VB  Va  6
V2  Vb  VD  12
Vab  Va  Vb  6  12  6
Vb  12 VD  0 
Q1  C1V1  6  6   36C ;
Q2  C2V2  3 12   36  C
When ‘S’ is closed
V11  12V  Q11  C1V11   6 12  72  C
V11  6V  Q21  C2V21  3  6   18C
 Charge flown through ‘S’
 Q11  Q12  72  18  54C
12. initially it acts as balanced wheat stone bridge
 current through G is zero

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 Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60(Incoming)_STERLING! BT_Jee-Adv(2021-P1)_WTA-30_Key & Sol’s
2
In steady state i   0.2 A
4 1 5
P.D. across C2  VG  V5  I  G  R   0.2 1  5   1.2V
13. From W-E theorems F.S= KE
1 1
E.q  2a   m 4v 2  mv 2
2 2
Y

E
Q P V


B
a

Q
X
2a

2v
2 2
3mv 3mv
E.q.2a  E
2 4qa
dw
Rate of work done by Electric field  P
dt
3mv 2 3mv 2
P  Fv  Eqv  qv 
4qa 4a
   
At (Q), P  F .v  Eq.v  Eqv  0, Hence © is wrong
   
At (Q), P  F .v  Eq.v  0 Work done by uniform magnetic field is zero
mv sin  2 m
14. R ; pitch  v cos  T  v cos  
Bq Bq
mv 2 mv  2 
15. Bqv   Bq   m  m  
r r  T 
2 m T
 v  r   T  a  1 1
Bq T2
 2 m 
 pitch  P   cos      P  cos 
 Bq 
P cos 30
 3   3
1/ 2
C 1 
P2 cos 60
mv 2 
As Bqr 
r
mv sin 
 Bq 
r
mv sin 
r
Bq
r sin 30 1
 r  sin   1  b  
r2 sin 60 3
 abc  1& a  bc

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 Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60(Incoming)_STERLING! BT_Jee-Adv(2021-P1)_WTA-30_Key & Sol’s

mv 2 m
16. R ;T  B
qB q
Rate of sweeping the area is
2
 mv 

dA  R 2
qB  1 mv 2
   
dt T 2 m 2 qB
qB

 B
v

q
R

 
17. Here V parallel to B
4 y z
  
2 3 6
 y  6 and z  12

B  16  36  144  196  14T
B 2q 2 R2 2mE 2mE
18. E  B2  2 2  B 
2m q R qR
2 m 1 Bq
19. T frequency f   ;
Bq T 2 m

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 Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60(Incoming)_STERLING! BT_Jee-Adv(2021-P1)_WTA-30_Key & Sol’s

CHEMISTRY
CH 3 
2
kf
20. K eq  
kb  C2 H 6 
104
 CH 3    105 M
10
1.57 103 10 
5 2


Kb 1
21. CONCEPTUAL
r1  k  0.01  0.01  6.93 10 6
a b
22. ..…..(i)
r2  k  0.02  0.01  1.386 10 5
a b
……(ii)
r3  k  0.02  0.02   1.386 105
a b
……(iii)
From data a  1; b  0;
overall order =1; k  6.93 10 4 sec 1
1 A
6.93  104  in 0 ;
50  60 At
When  A0  0.5  At  0.0625
rate of reaction  6.93 104  0.0625
 4.33 105 Ms 1
23. A  g   2B  g   C  g 
t 0 0.4 0.6
t t 0.3 0.4 0.1
r1  KPA .PB2
1

r1  K  0.4   0.6 
2

r1  K  0.3 0.4 
2

r1
3
r1
24. e  Ea / RT is fraction of molecules having energy greater than activation energy  Ea  , it is unit
less. So A has same unit of K. for 1st order reaction unit of K is s-1.
K 2 Ea 1 1 
25. In    
K1 R  T1 T2 
Ea  1 1 
In 2  
2cal  290 300 

2.303  0.3  2  290  300
Ea  cal  12 K Cal
10
nhC
26. E

n  6.6 10 34  3 108
7.2  103 J / s 
330 10 9
7.2  103  330 109
No.of photon  34
 120  1014
6.6  10  3  10 8

Mole of CO formed  0.4  20 109  8 10 9 mol / s

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 Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60(Incoming)_STERLING! BT_Jee-Adv(2021-P1)_WTA-30_Key & Sol’s
27. Rate of formation of C2 H 6  0.8  20 109  16  109 mol / s
n
N 1
28.    ; where n=no.of halves;
N0  x 
n
N 1 1
   n4
N 0 10  x 
Total time  n  t1/2 = 4740 = 4  4  t1/ 2 ;
t1/2  1185 years

r  k 1  O3  O   k 1  O3  K C
O3   k O 2 O 1
29.  3  2
O2 
30. CONCEPTUAL
31.  A K  Ae Ea / RT as T , K  rate of reaction 
(B) Rate of reaction  k  A =K = constant
0

(C) As surface area  No. of molecules will be more to react per unit time, more surface
site available for the reaction.
(D) Average rate defined for macro-scopic time and instantaneous rate defined for
micro-scopic time.
 cC  dD rate law is always r  K  A  B  but not
a b
32. For an elementary reaction aA  bB 
vice versa.
 cC  dD rate law may or may not be r  K  A  B 
a b
For a complex reaction aA  bB 
33. (A) In a rate law reactant, product or catalyst may be appeared.
(B) We can not
(C) In an elementary reaction only positive integer stoichiometric coefficient appears.
(D) A zero order reaction is always complex
34. (A) K  Ae E / RTa

As T , K  so if T   , then K  A or as Ea , K  so if Ea  0, then K  A
(B) Catalyst does not change H of reaction.
(C) A negative catalyst decrease rate of reaction by increasing activation energy.
35. A  B 
C

(A) If it is an elementary reaction then it will be bimolecular reaction.

(B) It may be exothermic eq. NH 3  g   HCl  g  
 NH 4Cl  s 

(C) It may be heterogeneous

(D) It may be photochemical reaction

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 Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60(Incoming)_STERLING! BT_Jee-Adv(2021-P1)_WTA-30_Key & Sol’s
36. 2 NH 3  g   N 2  g   3H 2  g 

Rate  K  NH 3 
0

Rate = 2
1 H2  H2 
Rate    6
3 t t

37. t1/2
 A   A0   200 min .  60 sec.  3
 0 
2 K A 2  5 K 2  5  400 20
38.
3B
k1

k2
A 8C
k3

3D K1 : K 2 : K 3  4 : 2 :1
Mole of A remain after 45 days
N0 N 1 1 1

 0  45/15  3 
2 n
T 2 2 8
t1 / 2
2
7
Moles of A convert into product  mol
8
K2 7 8
Moles of C     2
K1  K 2  K 3 8 1

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 Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60(Incoming)_STERLING! BT_Jee-Adv(2021-P1)_WTA-30_Key & Sol’s

MATHEMATICS
 
x4  2 
39. Let I   e x  dx
 1  x 2 5/2 
 
 
1 1  2 x2
  ex    dx
 1  x 2 1/2 1  x 2 5/2 
 
 
1 x x 1  2x2 
  ex     dx
 1  x 2 1/2
1  x 2 1  x 
3/2 2 3/ 2
1  x 2  
5/2


ex xe e 1  x  x
x x 2

  C  C
1  x  1  x 
2 1/2
1  x 
2 3/ 2 2 3/2

Hence, (d) is the correct answer.

x sin x  cos x   x cos x  x sin x  cos x 
4 3
40. Let I   e .  dx
 x 2 cos 2 x 
 x sin x  cos x 
  x.e x sin x  cos x 

.x cos x dx   e  x sin x  cos x  . 
  x cos x 2 
 dx
 
Applying integration by parts

 x.e
x sin x  cos x 
  e
x sin x  cos x 

dx
 1 
 e x sin x  cos x  .   e x sin x cos x  dx 
 x cos x 
x sin x  cos x   1 
 e x C
 x cos x 
Hence, © is the correct answer.
 1  x2 
41. Note that sec1 1  x 2  tan 1 x : cos 1  2 
 2 tan 1 x
 1  x 
For x  0

I 
e tan 1 x
1 x 2  
tan 1 x   2 tan 1 x dx,
2

1
Put tan x  t
  et  t 2  2t  dt  et .t 2  e tan 1x  tan 1 x   C
2

Hence, © is the correct answer.

1  7 cos 2 x  sec 2 x 7 
42.  7 2
dx    7  7  dx
sin x cos x  sin x sin x
sec2 x 7
 7
dx   7 dx  I1  I 2
sin sin x
sec 2 x tan x tan x.cos x
Now, I1   7 dx  7
 7 dx
sin x sin x sin 8 x
tan x
  I2
sin 7 x
tan x
 I1  I 2   C  f  x   tan x
sin 2 x

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 Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60(Incoming)_STERLING! BT_Jee-Adv(2021-P1)_WTA-30_Key & Sol’s
43. Let P  sin x cos x 3 3

dP
 3sin 2 x cos 4 x  3sin 4 x cos 2 x
dx
 3sin 2 x 1  sin 2 x  cos 2 x  3sin 4 x cos 2 x
 3sin 2 x cos 2 x  6 sin 4 x cos 2 x
P  3I 2,2  6 I 4,2
1
I 4,2 
6
  P  3I 2,2 
44. Let P  sin 5 x cos3 x
dP
 5sin 4 x cos 4 x cos 4 x  3sin 6 x cos 2 x
dx
 5sin 4 x 1  sin 2 x  cos 2 x  3sin 6 x cos 2 x
 5sin 4 x cos 2 x  8sin 6 x cos 2 x
 P  5 I 4,2  8 I 6,2
1
 I 4,2 
5
 P  8I 6,2 
45.  f  x   0   x 2  4 x  8  (
x 2  4 x  17  0
 D 0
D 0
 Equation has two distinct and two imaginary roots.
46. f  x    x 2  4 x  17  x 2  4 x  8 

  x  2 2
 21 x  2  42

  f  x  min   21 4   84

Which occurs at x  2
 f  x  h  f  x f  x x  h  f  x 
47. Here, 2 f /  x   lim   
h 0
 h h 
 f  x  h  f  x  h 
 lim   ….(i)
h 0
 h 
 f  h   f  0  f  h   f  0  
 2 f /  0   lim   
h 0
 h h 
f  h   f  h 
 lim ....  ii 
h 0 h
Now by given relation, we have
f  x  h  f  x  h
f  h   f  h   and f  0   1
h
f /  x
From Eqs. (i) and (ii), we have  2010
f  x
 f  x   e2010e , f  0   1
 f  x  Is non-periodic
48. Here,  f  g  x   cos xdx   f  log  sin x   .cos xdx
 
 e 2010log sin x
.cos xdx
   sin x  .cos xdx
2010

Sec: Sr.Super60(Incoming)_STERLING BT Page 10

 Sri Chaitanya IIT Academy 27-04-2025_Sr.Super60(Incoming)_STERLING! BT_Jee-Adv(2021-P1)_WTA-30_Key & Sol’s

 sin x 
2011

 C
2011
 sin x 
2011

 h  x 
2011

  1
 h  
 2  2011
49. Conceptual
50.   sin 3  sin   cos  e
sin 
d   4sin 3   12 cos 2   20 sin   32   F

 
1 1/ 2
x 1/3  4
1
dx = 6 tan 1  x 1/3  4 
1/2
51.  x  C = 6cot C
5/6
 5 x 7/6  . 1  4 x1/3

5 cos ec3 x cot x 3cos ecx cot x 3

52.  cos ec xdx   4

8
 log | cos ecx  cot x |  K
8
cos x (1  4cos 2 x ) 1 2 2
53.  sin x  4sin x cos 2 x dx  log sin x  2 log sin x  5cos x  c,
 2
54.  sin 1 x cos 1 xdx    sin 1 x   sin 1 x  dx
2 


2
 x sin 1
 
x  1  x 2  x  sin 1 x   2 sin 1 x 1  x 2  2 x  C
2

[Integrating by parts]
   
 sin 1 x  x  x sin 1 x  2 1  x 2   1  x2  2x  C
2  2
 f 1  x   sin 1 x, f  x   sin x
55. Conceptual
dx 1 1 x
56.   tan 1 x  C
x  1 2 x2  1
2
2 2

57. e  3x  2 x  2 x  dx
x3  x 2 1 4 3

 
x e 3x  2 x dx   e
2

x3  x 2 1 2 x3  x 2 1
2 xdx
I
II
2 x3  x 2 1
  2 xe x dx   e x
3
 x 2 1 3
 x 2 1
x e 2 xdx
3
 x 2 1
 x 2e x C
1
 f 1  e and f  1 
e

Sec: Sr.Super60(Incoming)_STERLING BT Page 11