2024 Theory Daily Recap – 37
Answers
1. fidhd .;af;a ldnka fkdj ksfhdakaj, iuia:dkslhs¡ ∴ m%ldYh wi;H fõ¡ (×)
2. Rb = 1s 2 2s 2 2p6 3s 2 3p6 3d10 4s 2 4p6 5s 1
fuys wjidk bf,lafg%dakh 5 jk Yla;s uÜgfï S ldlaIslhl we;¡ ∴ m%Odk lafjdkagï wxlh(n) = 5 fõ¡
WoaOs.xY lafjdkagï wxlh(l) = 0 fõ¡ S ldlaIshg wod< pqïnl lafjdkagï wxlh(m𝑙 ) = 0 fõ¡ fuys ms w.h
1 1
+ fyda − úh yel¡
2 2
1 1
∴ lafjdkagï wxl l=,lh (5, 0, 0, + ) fyda (5, 0, 0, − ) úh yel¡ m%ldYh i;H fõ¡ (✓)
2 2
3. wdrïNfha NaHCO3 mol = x o Na 2 CO3 mol = y f,i .ksuq¡
NaHCO3(aq) + HCl(aq) NaCl(aq) + H2 O(l) + CO2(g)
x x
Na 2 CO3(aq) + 2HCl(aq) 2NaCl(aq) + H2 O(l) + CO2(g)
y y
6.72dm3
msgjQ CO2 mol .Kk =
22.4dm3 mol−1
x + y = 0.3 mol ①
NaHCO3 ialkaOh + Na 2 CO3 ialkaOh = 27.4
84x + 106y = 2.74 ②
① × 106 – ②
106x + 106y – 84x – 106y = 31.8 – 27.4
22x = 4.4
x = 0.2 mol
① → y = 0.1 mol
Na 2 CO3 ialkaOh = 0.1 mol × 106gmol−1
= 10.6g
∴ m%ldYh i;H fõ¡ (✓)
4. MnO4− Mn2+ njg T’yrKh jk úg H2 S → S njg T’lrKh fõ¡ fuysoS ,efnk S ,dly fyda iqÿ mdg
wdú,;djhla fyda wjlafIamhla f,i we;sfõ¡ ∴ m%ldYh wi;H fõ¡ (×)
5. Cl ys Tlafid wï,j, T’ldrl yelshdj Cl j, T’lrK wxlh jeä jk úg wvqfõ¡ ta wkqj jeäu T’ldrl
yelshdj we;af;a +1 T’lrK wjia:dfõ mj;sj HCl wï,hghs¡ ∴ m%ldYh wi;H fõ¡ (×)
6. H H R
l
>
l R > C+
R > C+ R > C+
l
>
>
H R
R
> > >
ldnka mrudKqjg iïnkaO bf,lafg%dak úl¾Il we,alhs,a ldKav .Kk jeäfõ¡
ldnka mrudKqfõ Ok wdfrdamKh wvqfõ¡
ldfndlegdhkfha ia:dhs;dj jeäfõ¡
∴ m%ldYh wi;H fõ¡ (×)
wñ, oikdhl | wdidfjka bf.k.kak 1
7. [CoCl4 ]2− - ks,a
[MnCl4 ]2− - fld< meye ly
∴ m%ldYh iH fõ¡ (✓)
−
8. :O: −1
:
− −1 +1 +1 +
N:
:
:O
: :
N N N
+ (1) (2) (3)
+3 0 +1
N2 mrudKqfõ bf,lafg%dak hq., cHdñ;sh ;,Sh ;s%fldaKdldr fõ¡ wfkl=;a mrudkq jgd bf,lafg%dak hq.,
cHdñ;sh ksjeros fõ¡ kuq;a m%ldYh wi;H fõ¡ (×)
9. w¡ Y¡ fuys m%:u whkSlrK Yla;s úp,kh He > H > Be > B > Li fõ¡
He ∴ m%ldYh wi;H fõ¡ (×)
H
Be
Li B
mrudKql l%udxlh
10. CH2 CH3 COOH
l + l
H / KMNO4
fnkaiSkag ne÷Kq we,als,a ldKavfha fldmuK C mrudKq .Kka ;snqKo tajd ish,a, T’ lrKh ù wjidkfha
fnkafidhsla wï,h muKla ,efí¡ ∴ m%ldYh wi;H fõ¡ (×)
11. Cu(s) + 2H2 SO4(l) SO2(g) + CuSO4(aq) + 2H2 O(l)
∴ m%ldYh wi;H fõ¡ (×)
12. C – X nkaOkh iq¿ jYfhka O%eùh jqjo th c,fha oshùug ;rï m%udKj;a fkdfõ¡ ∴ we,alhs,a fya,hsv c,fha
oshùu wid¾:l fõ¡ ∴ m%ldYh wi;H fõ¡ (×)
13. CH3
l H + / KMNO4
CH3 – C – OH X (KMnO4 új¾K fkdfõ¡)
l
CH3
O O
ll H + / KMNO4 ll
CH3 – C – H CH3 – C – OH (KMnO4 új¾K fõ¡)
fjkalr y÷kd.; yelsh¡ ∴ m%ldYh i;H fõ¡ (✓)
14. CuCl2 , H2 S iuÕ CuS l¿ meye wjlafIamh ,nd foa¡ CuCl2 , SO2 iuÕ wjlafIamhla ,nd fkdfoa¡ ∴ fjka lr
y÷kd.; yelsh¡ (✓)
wñ, oikdhl | wdidfjka bf.k.kak 2
15. Z > 1 jk úg jdhq wKq w;r úl¾IK n, m%n, neúka iïmSvkh wiSre fõ¡ tfiau úl¾IK n, mej;Su
fya;=fjka jdhqj mßmQ¾K;ajfhka wm.ukh fõ¡∴ m%ldYh i;H fõ¡ (✓)
16. S f.dkqfõ ish¨ uQ,øjH yqud,h iuÕ m%;sls%hd lrhs¡ ∴ m%ldYh wi;H fõ¡ (×)
17. m%ldYh i;H fõ¡ (isoaOdka;hls¡) (✓)
18. W;afm%arlhla fhÿ úg m%;sls%hdj ils%hk Yla;sh wvq kj ud¾.hla Tiafia .uka lrjhs¡ wod< m%;sls%hdfõ ils%hk
Yla;shg n,mEula fkdfõ¡ ∴ m%ldYh wi;H fõ¡ (×)
19. :Cl : Al mrudKqjla tla odhl nkaOkhla muKla idok w;r odhl nkaOkfha
:
:Cl :
:
:Cl :
:
e odhl lrkqfha Cl úisks¡
Al Al
: :
Cl:
: :
Cl:
: :
:Cl
∴ m%ldYh wi;H fõ¡ (×)
20. we,afldlaihsâ whkh kshqla,sfhda*hs,hls¡ ∴ m%ldYh wi;H fõ¡ (×)
21.
Yla;sh
Ear = wdmiq m%;sls%hdfõ i¡ Y¡
Eaf Ear
Eaf = bosß m%;sls%hdfõ i¡ Y¡
∆H = tka;e,ams úm¾hdih
∴ Ear = Eaf + ∆H
m%;sls%hl
∆H
M,
m%;sls%hd LKavdxlh
m%ldYh i;H fõ¡ (✓)
22. A2 B4(g) 2AB2(g)
1 mol
−0.2 mol
0.8 mol 0.4 mol
0
27 C
PV = nRT
1 × 105 Pa × V = 1 mol × R × 300K ①
0
327 C
PV = nRT
P × V = 1.2 mol × R × 600K ②
② P 1.2 ×600
=
① 1 × 105 1 ×300
P = 2.4 × 105 Pa
m%ldYh wi;H fõ¡ (×)
wñ, oikdhl | wdidfjka bf.k.kak 3
23. 3d uQ,øjHj, N+ñ wjia:dfõ jeäu úhq.au bf,lafg%dak ixLHdjla we;af;a Cr gh¡
Cr – [Ar]3d5 4s 1
∴ m%ldYh wi;H fõ¡ (×)
H
l
24. HBr C – CH3
CH = CH2 l
l
Br
lhs/,a ldnka
∴ m%ldYh i;H fõ¡ (✓)
25. m%ldYh i;H fõ¡ (✓)
q lrKhla mej;Sug uOH mrudKqj jgd úl¾IK tall 3 mej;Su m%udKj;a fõ¡ iEuúgu 𝜋 nkaOk
26. sp2 uqyï
mej;Su wjYH yel¡ Wod: - BCl3
∴ m%ldYh wi;H fõ¡ (×)
27. CH3 – O – CH3 wKq w;r H nkaOk fkdue;s w;r C2 H5 OH ys H nkaOk mj;S¡
O–H
lllllllll
lllllllll
C2 H5
C2 H5
H–O
∴ m%ldYh wi;H fõ¡ (×)
28. fojk mshjf¾ YS>%;d ksh;h úYd, f,i wvq ùfuka woyia jkafka idfmalaI fojk mshjf¾ YS>%;djh wvq njhs¡
ta wkqj fojk mshjr fifukau isÿjk mshjrhs¡ ∴ m%ldYh i;H fõ¡ (✓)
29. wkql ialkaOh jeä jk ms<sfj<g wmlsrK n, m%n,;djh jeä jk neúka tu ms<sfj<sg ;dmdxlh jeäfõ¡ ∴
m%ldYh i;H fõ¡ (✓)
1
30. PV = mNC −2
3
mN = m(jdhqfõ uq¿ ialkaOh)
1
PV = mC −2
3
m = M × n wdfoaYfhka,
1
PV = MnC −2
3
3PV
M=
nC −2
3 × 8.2 × 105 Pa ×20 × 10−3 m3
=
2 mol × (820ms −1 )2
= 36.6 × 10−3 Kg mol−1
= 36.6g mol−1
m%ldYh wi;H fõ¡ (×)
wñ, oikdhl | wdidfjka bf.k.kak 4
