INSTITUTO POLITÉCNICO NACIONAL
Escuela Superior de Ingeniería Química e Industrias Extractivas
Termodinámica Del Equilibrio de Fases
VERIFICAR PARA DELTA T PEQUEÑA, DELTA
H = CTE PARA EL CO2
Materia:
Termodinámica Del Equilibrio de Fases
Profesor:
Galicia Luna Luis Alejandro
Alumno:
Ramírez Muñoz Fatima Natalia
Grupo:
2IV31
Verificar para delta T pequeña, delta H = cte para el CO2
1. Datos con que se usaron para llenar la tabla de Excel.
CO2
Presión 1 atm 5 atm 10 atm
Pc 72.808 atm
Tc 30.9782 C
2. Analizamos los datos de CO2 con la ecuación de Clausius-Clapeyron
𝑃2 𝑇2
𝑑𝑇 Si ∆𝑇 pequeño 𝑑 𝐿𝑛 𝑃 ∆𝐻̅
̅∫
∫ 𝑑 𝐼𝑛𝑃 ≈ ∆𝐻 =
𝑃1 𝑇1 𝑅𝑇 2 ∆𝐻 = 𝑐𝑡𝑒 𝑑𝑇 𝑅𝑇 2
𝑃2 ̅̅̅̅ 1
∆𝐻 1
ln ≈− ( − )
𝑃1 𝑅 𝑇2 𝑇1
3. Y con esto podemos concluir que se cumple con la fórmula de Clausius-
Clapeyron.
❖ Referencias
Equation of state
Span, R.; Wagner, W., A New Equation of State for Carbon Dioxide Covering the
Fluid Region from the Triple-Point Temperature to 1100 K at Pressures up to 800
MPa, J. Phys. Chem. Ref. Data, 1996, 25, 6, 1509-
1596, https://doi.org/10.1063/1.555991 . [all data]
Span, R. and Wagner, W., "A New Equation of State for Carbon Dioxide Covering
the Fluid Region from the Triple-Point Temperature to 1100 K at Pressures up to 800
MPa," J. Phys. Chem. Ref. Data, 25(6):1509-1596, 1996.
The estimated uncertainties at pressures up to 30 MPa and temperatures up to 523
K range from 0.03% to 0.05% in density, 0.03% (in the vapor) to 1% in the speed of
sound (0.5% in the liquid) and 0.15% (in the vapor) to 1.5% (in the liquid) in heat
capacity. Special interest has been focused on the description of the critical region
and the extrapolation behavior of the formulation (to the limits of chemical stability).
Auxillary model, Cp0
Span, R. and Wagner, W., 1996.
Auxillary model, PX0
Span, R. and Wagner, W., 1996.
Viscosity
Laesecke, A.; Muzny, C.D., Reference Correlation for the Viscosity of Carbon
Dioxide, J. Phys. Chem. Ref. Data, 2017, 46, 1,
013107, https://doi.org/10.1063/1.4977429 . [all data]
Thermal conductivity
Huber, M.L.; Sykioti, E.A.; Assael, M.J.; Perkins, R.A., Reference Correlation of the
Thermal Conductivity of Carbon Dioxide from the Triple Point to 1100 K and up to
200 MPa, J. Phys. Chem. Ref. Data, 2016, 45, 1,
013102, https://doi.org/10.1063/1.4940892 . [all data]
Huber, M.L., Sykioti, E.A., Assael, M.J., and Perkins, R.A., "Reference Correlation of
the Thermal Conductivity of Carbon Dioxide from the Triple Point to 1100 K and up
to 200 MPa," J. Phys. Chem. Ref. Data, 45, 013102, 2016.
The overall uncertainty (at the 95% confidence level) of the proposed correlation
varies depending on the state point from a low of 1% at very low pressures below
0.1 MPa between 300 K and 700 K, to 5% at the higher pressures of the range of
validity.
Auxillary model, the thermal conductivity critical enhancement
Huber, M.L., Sykioti, E.A., Assael, M.J., and Perkins, R.A., "Reference Correlation of
the Thermal Conductivity of Carbon Dioxide from the Triple Point to 1100 K and up
to 200 MPa," J. Phys. Chem. Ref. Data, 45, 013102, 2016.
Surface tension
Mulero, A.; Cachadiña, I.; Parra, M.I., Recommended Correlations for the Surface
Tension of Common Fluids, J. Phys. Chem. Ref. Data, 2012, 41, 4,
043105, https://doi.org/10.1063/1.4768782 . [all data]
Dielectric constant
Harvey, A.H.; Lemmon, E.W., Method for Estimating the Dielectric Constant of
Natural Gas Mixtures, Int. J. Thermophys., 2005, 26, 1, 31-
46, https://doi.org/10.1007/s10765-005-2351-5 . [all data]
Metling line
Span, R.; Wagner, W., A New Equation of State for Carbon Dioxide Covering the
Fluid Region from the Triple-Point Temperature to 1100 K at Pressures up to 800
MPa, J. Phys. Chem. Ref. Data, 1996, 25, 6, 1509-
1596, https://doi.org/10.1063/1.555991 . [all data]
Span, R. and Wagner, W., "A New Equation of State for Carbon Dioxide Covering
the Fluid Region from the Triple-Point Temperature to 1100 K at Pressures up to 800
MPa," J. Phys. Chem. Ref. Data, 25(6):1509-1596, 1996.
Sublimation line
Span, R.; Wagner, W., A New Equation of State for Carbon Dioxide Covering the
Fluid Region from the Triple-Point Temperature to 1100 K at Pressures up to 800
MPa, J. Phys. Chem. Ref. Data, 1996, 25, 6, 1509-
1596, https://doi.org/10.1063/1.555991 . [all data]
Span, R. and Wagner, W., "A New Equation of State for Carbon Dioxide Covering
the Fluid Region from the Triple-Point Temperature to 1100 K at Pressures up to 800
MPa," J. Phys. Chem. Ref. Data, 25(6):1509-1596, 1996
Vapor pressure
Functional Form: P=Pc*EXP[SUM(Ni*Theta^ti)*Tc/T] where Theta=1-T/Tc, Tc and Pc
are the reducing parameters below, which are followed by rows containing Ni and ti.
Saturated liquid density
Functional Form: D=Dc*EXP[SUM(Ni*Theta^(ti/3))] where Theta=1-T/Tc, Tc and Dc
are the reducing parameters below, which are followed by rows containing Ni and ti.
Saturated liquid volume
Functional Form: D=Dc*EXP[SUM(Ni*Theta^(ti/3))] where Theta=1-T/Tc, Tc and Dc
are the reducing parameters below, which are followed by rows containing Ni and ti.
