Sec: ISR.

IIT _*CO-SC(MODEL-B) Date: 18-05-25

Time: 3 Hrs Max. Marks: 180
18-05-25_ISR.IIT_STAR CO-SC(MODEL-B)_JEE ADV_WAT-47_SYLLABUS
MATHEMATICS: PRESENT WEEK (80%): DIFFERENTIAL EQUATIONS: Formation of
ordinary differential equations, solving differential equation (Variable &
separable, Homogeneous, linear differential equation of first order ),
Differential equations which are reducible to linear form of first order
PREVIOUS WEEK (20%): AREA: Application of Definite integrals to find the
area involving simple curves
PHYSICS: PRESENT WEEK (80%): MAGNETISM-II: Biot Savart’s Law, Ampere’s Law &
their applications, Moving coil galvanometer and its sensitivity
PREVIOUS WEEK (20%): MAGNETISM-I: Magnetic force on moving point
charges and current elements, Motion of a charged particle inmagnetic and
electric field, Magnetic dipoles moment, magnetic torque, magnetic dipoles,
Torque, P.E and interaction regarding magnetic dipole,Cyclotron
CHEMISTRY: PRESENT WEEK (80%): BIOMOLECULES : Carbohydrates: Classification;
preparation of glucose from sucrose and starch, Reactions of glucose with HI,
NH2OH, Br2, Acylation, HNO3 Oxidation; Reduction; D, L- configurstion,
Glycoside formation cyclic structure of glucose, fructose, maltose, sucrose,
lactose, Anomers, mutarotation, reducing and non- reducing sugars, poly
saccarides- starch and cellulose, tests of carbohydrates ,Amino acids; iso
electric point, Peptide linkage; Proteins Tests of amino acids
PREVIOUS WEEK (20%): AMINES: Preparation from nitro compounds, nitriles
and amides; Reactions: Hoffmann bromamide degradation, Gabriel
phthalimide synthesis, Physical properties, reaction with nitrous acid,
alkylation, acylation, carbylamine reaction, hinsberg test, Hoffman mustard oil
reaction ,Azo coupling reaction of diazonium salts of aromatic amines;
Sandmeyer and related reactions of diazonium salts;
Narayana IIT Academy 18-05-25_ISR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-47_QP
TIME: 3 hrs IMPORTANT INSTRUCTIONS Max Marks: 180

MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 4) Questions with Single Correct Options +3 -1 4 12
Questions with Multiple Correct Choice
Sec – II (Q.N : 5 – 7) +4 -2 3 12
(partial marking scheme) (+1,0)
Sec – III (Q.N : 8 – 13) Questions with Non-Negative Integer type +4 0 6 24
Sec – IV (Q.N : 14 – 17) Questions with MATRIX MATCH +3 -1 4 12
Total 17 60

PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 18 – 21) Questions with Single Correct Options +3 -1 4 12
Questions with Multiple Correct Choice
Sec – II (Q.N : 22 – 24) +4 -2 3 12
(partial marking scheme) (+1,0)
Sec – III (Q.N : 25 – 30) Questions with Non-Negative Integer type +4 0 6 24
Sec – IV (Q.N : 31 – 34) Questions with MATRIX MATCH +3 -1 4 12
Total 17 60

CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 35 – 38) Questions with Single Correct Options +3 -1 4 12
Questions with Multiple Correct Choice
Sec – II (Q.N : 39 – 41) +4 -2 3 12
(partial marking scheme) (+1,0)
Sec – III (Q.N : 42 – 47) Questions with Non-Negative Integer type +4 0 6 24
Sec – IV (Q.N : 48 –51) Questions with MATRIX MATCH +3 -1 4 12
Total 17 60

ISR_IIT_*CO SC Page. No. 2

Narayana IIT Academy 18-05-25_ISR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-47_QP
MATHEMATICS MAX.MARKS: 60
SECTION–1 (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
1. The differential equation of the system of circles touching the x-axis at origin is
dy dy
A)  x 2  y 2   2 xy  0 B)  x 2  y 2   2 xy  0
dx dx
dy dy
C)  x 2  y 2   2 xy  0 D)  x 2  y 2   2 xy  0
dx dx
2. Solution of  xy 4  y  dx  xdy  0 is
3 3 2 3
x4  x  x4 1  x  x4 x x4 1  x 
A)     C B)     C C)  3   C D)     C
4  y 4 3 y  4  y 4 3 y 
d3y dy
3
 13
3. If the function y  e  2e is a solution of the differential equation dx
4x x dx  k then
y
the value of k is
A) 4 B) 6 C) 9 D) 12
2 2
4. The area bounded by the curves y  6 x  x and y  x  2 x is (in sq. units)
32 64 16 8
A) B) C) D)
4 3 3 3
SECTION - II (Maximum Marks : 12)
This section contains THREE (03) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.

ISR_IIT_*CO SC Page. No. 3

Narayana IIT Academy 18-05-25_ISR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-47_QP
5. Solution of the differential equation
 3tan x  4cot y  7  sin 2 ydx   4 tan x  7cot y  5 cos2 xdy  0 is
3 2 7
A) cot x  7 cot x  tan 2 y  5 tan y  4cot x.tan y  c
2 2
3 2 7
B) tan x  7 tan x  cot 2 y  5cot y  4 tan x.cot y  c
2 2
C) 3tan 2 y  14cot x.tan 2 y  7 cot 2 x  10 tan y cot 2 x  8cot x.tan y  2cot 2 x tan 2 y  0
D) 3cot 2 y  14 cot x.cot 2 y  7 cot 2 x  10 cot y tan 2 x  8 tan x.cot y  0
6. If y  x  satisfies the differential equation y '  y tan x  2 x sec x and y  0   0, then

 2  2  2  4 2 2
A) y    B) y '    C) y    D) y '    
4 8 2  4  18 3  9 3 3 3 3

7. Let f  x   x 2  3x  2 then which of the following is/are true

5
A) area bounded by y  f  x  , and x  axis, and y  axis is sq.units
6
B) area bounded by y  f  x  , and x  axis is 2sq.units
1
C) are bounded by y  f  x  , between 1  x  2 and x  axis is sq.units
3

D) area bounded by y  f  x  , and x  axis is 1sq.units

SECTION-III (Maximum Marks : 24)

This section contains SIX (06) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
8. A normal is drawn at a point P  x, y  of a curve. It meets the x-axis at Q. If PQ is of

constant length k and such a curve passing through (0,k) be x 2  py 2  k 2 , then the
value of ‘p’ is_______
dy
9. If y  y ( x ) is the solution of the equation esin y cos y  esin y cos x  cos x, y (0)  0,; then
dx

  3   1  
1 y   y   y   is equal to
6 2 3 2 4

ISR_IIT_*CO SC Page. No. 4

Narayana IIT Academy 18-05-25_ISR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-47_QP
y y
10. If solution of the differential equation, y cos  xdy  ydx   x sin  xdy  ydx   0 when
x x
 y 2
y 1  is xy sin    then k  ___ .
2 x k

11. The differential equation  xy 3 1  cos x   y dx  xdy  0 represents the curve

x2 x3
2
  x 2 sin x  cx cos x  d sin x  k. Then a  b  c  d is equal to
ay b

12. If area bounded by y  f  x  , y  axis and the line 2 y    x  1 where

1 
f  x   sin 1 x  cos 1 x  tan 1 x  tan1   is where k 
x k

13. The degree of the differential equation

 
satisfying 1  x 2  1  y 2  k x 1  y 2  y 1  x 2 is 
SECTION-IV (Maximum Marks : 12)
This section contains FOUR (04) Matching List Sets. Each set has ONE Multiple Choice Question
Each set has TWO lists: List-I and List-II. List-I has Four entries (P), (Q), (R) and (S) and
List-II has Five entries (1), (2), (3), (4) and (5).
FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these
four options satisfies the condition asked in the Multiple Choice Question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3ONLYif the option corresponding to the correct combination is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: – 1 in all other cases.

14. Match the following family of curves with their differential equations:
Column-I Column-II
A y  cx  c 2 p   dy 2  dy
y 1      2 x
  dx   dx
 
B y  ae2 x  be3x q d2y dy
x 2
 2  xy  x 2  2  0
dx dx
C y 2  4a  x  a  r d2y dy
2
5  6y  0
dx dx
D xy  ae x  be  x  x 2 s dy  dy 
2

y  x  
dx  dx 

ISR_IIT_*CO SC Page. No. 5

Narayana IIT Academy 18-05-25_ISR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-47_QP
A)  A  s  ,  B  r  ,  C  p  ,  D  q  B)  A  p  ,  B  r  ,  C  q  ,  D  s 

C)  A  p  ,  B  q  ,  C  r  ,  D  s  D)  A  s  ,  B  q  ,  C  p  ,  D  r 
15. Match the following
Column-I Column-II
A The solution of the differential equation p 2 ye2 x  ce2 x  1

1  x y  ydx   x
2 2 2
y 2  1 xdy  0 is

B The solution of the differential equation q 4e3 x  3.e4 y  C

2 x3 ydy  1  y 2  x 2 y 2  y 2  1 dx  0

C The solution of the differential equation r y

( x 2  y 2 )  2ln    c
X3 X5 x
X   ......
3! 5! dx  dy
2 4
 is
X X dx  dy
1   ....
2! 4!
D
The solution of In 
dy  s x 2 y 2   cx  1 1  y 2 
  3 x  4 y, is
 dx 

A)  A  p  ,  B  r  ,  C  q  ,  D  s  B)  A  s  ,  B  r  ,  C  p  ,  D  q 

C)  A  r  ,  B  s  ,  C  p  ,  D  q  D)  A  s  ,  B  q  ,  C  p  ,  D  r 
16. Match the following
Column-I Column-II
A xdx  ydy 2
a x y 2 2 p y
c 1/ x
e
 x3
xdy  ydx x2  y 2
B Solution of cos 2 x
dy
 y tan 2 x  cos4 x
q   y 
x 2  y 2  a sin c  tan 1   
dx   x 
 3 3
where x   / 4 and y   
6 8  
C The equation of all possible curves r x 2  y 2  cy  0
that will cut each member of the
family of circles
x 2  y 2  2cx  0 at right angle
D Solution of the equation s y
sin 2 x
x x 2 1  tan 2 x 
x  y  t  dt   x  1  t y  t  dt
0 0

ISR_IIT_*CO SC Page. No. 6

Narayana IIT Academy 18-05-25_ISR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-47_QP
A)  A  p  ,  B  r  ,  C  q  ,  D  s  B)  A  q  ,  B  s  ,  C  r  ,  D  p 

C)  A  r  ,  B  s  ,  C  p  ,  D  q  D)  A  s  ,  B  q  ,  C  p  ,  D  r 
17. Match the following: -
Column – I Column – II
(A) If order and degree of the differential equation formed
by differentiating and eliminating the constants from y
= a sin2x + b cos2x + c sin 2x + d cos 2x, where a, b, c, (p) O + 2D = 5
d are arbitrary constants are represented by O and D,
then
(B) The order and degree of the differential equation,
whose general solution is given by y = (c1 + c2) sin
(q) O=D
(x + c3) – c4 e x c5  c6 , where c1, c2, c3, c4, c5, c6 are
arbitrary constants, are O and D, then
(C) The order and degree of the differential equation
satisfying (1  x 2 )  (1  y 2 )  A(x (1  y 2 )  y (1  x 2 ) ) are (r) 2O+D=5

O and D, then
(D) If the order and degree of the differential equation of
(s) O=D3
all parabolas whose axis is x-axis are O and D then
A)  A  p  ,  B  p  ,  C  q  ,  D  r  B)  A  q  ,  B  s  ,  C  r  ,  D  s 

C)  A  r  ,  B  r  ,  C  p  ,  D  q  D)  A  r  ,  B  q  ,  C  p  ,  D  r 

ISR_IIT_*CO SC Page. No. 7

Narayana IIT Academy 18-05-25_ISR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-47_QP
PHYSICS MAX.MARKS: 60
SECTION–1I (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.

18. Two identical wires A and B, each of length 'l', carry the same current I. Wire A is bent

into a circle of radius R and wire B is bent to form a square of side 'a'. If BA and BB are
the values of magnetic field at the centres of the circle and square respectively, then the
BA
ratio BB is :
2 2 2 2
A) 16 B) 8 2 C) 8 D) 16 2
19. A particle of mass m and charge q enters a region of magnetic field (as shown) with
speed v. There is a region in which the magnetic field is absent, as shown. The particle
after entering the region collides elastically with a rigid wall. Time after which the
velocity of particle becomes anti parallel to its initial velocity is

m m m m
  4    2    2   2  3
A) 2qB B) qB C) 4qB D) 4qB

ISR_IIT_*CO SC Page. No. 8

Narayana IIT Academy 18-05-25_ISR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-47_QP
20. A charged particle moves in a uniform magnetic field with its velocity vector making an
angle of 120° with the direction of the magnetic field. The path of the particle will be
(ignore any effects due to radiation)
A) a circle B) a helix with uniform pitch
C) a helix with non-uniform pitch D) a parabola

21. The figure shows two infinite semi-cylindrical shells: 1 and 2. Shell-1 carries current i1 ,

in inward direction normal to the plane of paper, while shell-2 carries same current i1 , in
opposite direction. A long straight conductor lying along the common axis of the shells

is carrying current i2 in direction same as that of current in shell-1. Force per unit length
on the wire is

0i1i2 20i1i2 20i1i2

2
A) zero B) 2 r C)  r D)  r

SECTION - II (Maximum Marks : 12)

This section contains THREE (03) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.

ISR_IIT_*CO SC Page. No. 9

Narayana IIT Academy 18-05-25_ISR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-47_QP
22. Two long thin, parallel conductors carrying equal currents in the same direction are fixed
parallel to the x-axis, one passing through y = a and the other through y = -a. The
resultant magnetic field due to the two conductors at any point is B. Which of the
following are correct ?

A) B = 0 for all points on the x-axis

B) At all points on the y-axis, excluding the origin, B has only a
z-component
C) At all points on the z-axis, excluding the origin, B has only a
y-component
D) B cannot have an x-component
23. A large plate with uniform surface charge density  is moving with constant speed v as
shown in the figure. The magnetic field at a small distance from plate is

0 v
A) 0 v in magnitude B) 2 in magnitude
C) Perpendicular to plate D) Parallel to plate

24. A long current carrying wire, carrying current I1 such that I1 is flowing out from the

plane of paper is placed at O. A steady state current I 2 is flowing in the loop ABED

ISR_IIT_*CO SC Page. No. 10

Narayana IIT Academy 18-05-25_ISR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-47_QP

A) the net force is zero B) the net torque is zero

C) as seen from O, the loop will rotate in clockwise along OO axis
D) as seen from O, the loop will rotate in anticlockwise direction along OO axis

SECTION-III (Maximum Marks : 24)

This section contains SIX (06) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.

25. A toroid having a square cross section, 5.00 cm on a side, and an inner radius of 15.0 cm
has 500 turns and carries a current of 0.80 A. What is the magnetic field inside the toroid

at the outer radius of the toroid in 10  T ?

4

26. An electron gun G emits electrons of energy 2keV travelling in the positive x-direction.
The electrons are required to hit the spot S where GS = 0.1m, and the line GS makes an

angle of 60° with the x-axis as shown in the figure. A uniform magnetic field B exists
parallel to GS in the region outside the electron gun. Find the minimum value of B (in
mT) needed to make the electrons hit S.

ISR_IIT_*CO SC Page. No. 11

Narayana IIT Academy 18-05-25_ISR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-47_QP
27. Two parallel wires in the plane of the paper are distance X 0 apart . A point charge is
moving with speed u between the wires in the same plane at a distance X 1 from one of
the wires. When the wires carry current of magnitude I in the same direction, the radius
of curvature of the path of the point charge is R1 . In contrast, if the currents I in the two
wires have directions opposite to each other, the radius of curvature of the path is R2 . If
X0 R
 3 , the value of 1 is
X1 R2

28.. A cylindrical cavity of diameter a exists in side a cylinder of diameter 2a as shown in the
figure. Both the cylinder and the cavity are infinitely long. A uniform current density J
flows along the length. If the magnitude of the magnetic field at the point P is given by
N
0 aJ , then the value of N is
12
29. Two concentric coils, each of radius equal to 2 cm, are placed at right angles to each
other. Currents of 3A and 4A, respectively, are flowing through 2 coils. The magnetic
5
induction in Wb / m 2 at centre of coils will be ___________  10 .
30. Magnetic field at the centre of an equilateral triangular loop of side ‘2L’ and carrying

current ‘I’ is 90i then x  _________.

x L

ISR_IIT_*CO SC Page. No. 12

Narayana IIT Academy 18-05-25_ISR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-47_QP
SECTION-IV (Maximum Marks : 12)
This section contains FOUR (04) Matching List Sets. Each set has ONE Multiple Choice Question
Each set has TWO lists: List-I and List-II. List-I has Four entries (P), (Q), (R) and (S) and
List-II has Five entries (1), (2), (3), (4) and (5).
FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these
four options satisfies the condition asked in the Multiple Choice Question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3ONLYif the option corresponding to the correct combination is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: – 1 in all other cases.

31. Consider three infinite current-carrying wires through each of the vertices of an
equilateral triangle such that the wires are perpendicular to the plane of triangle.
All the wires carry identical currents in direction out of the page. M is the centroid
of triangle.

Column – I Column – II
Magnetic field at M for the given
i. p. Zero
situation is
Magnetic field at M if direction of
Perpendicular to
ii. current in A is reversed keeping its q.
BC
magnitude same is
Magnetic field at M if current in A is
iii. r. Along BC
halved keeping its direction same is
Magnetic field at M if current in A is
iv. s. Along CB
doubled keeping its direction same is

ISR_IIT_*CO SC Page. No. 13

Narayana IIT Academy 18-05-25_ISR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-47_QP
Codes :
A) i – p; ii – s; iii – s; iv – r B) i – p; ii – q; iii – r; iv – s
C) i – s; ii – p; iii – r; iv – q D) i – q; ii – s; iii – s; iv – p
32. A square wire frame ABCD made of uniform conducting wire is placed in x-y plane
(z = 0 plane) with its centre at origin and side BC is parallel to y-axis. Two straight
conducting wires EA and CF also lie in x-y plane and both are parallel to line y = x.
Current I is fed to square wire frame through wire EA and current I exits the square
wire frame through wire CF, P, Q and R are three points as shown on x-axis,
segment AC and segment BD respectively. In each situation of Column I, magnetic
field due to only current carrying square wire frame is to be considered (Neglect
the magnetic field due to current carrying segments EA and CF). Match the
statement in Column I with results in Column II.

Column – I Column – II
i. The magnetic field at origin p. Has zero magnitude
Has non-zero
ii. The magnetic field at point P q.
magnitude
Is along +ve
iii. The magnetic field at point Q r.
z-direction
Is along – ve
iv. The magnetic field at point R s.
z-direction
Codes :
A) i – p; ii – q,s; iii – r; iv – p,q B) i – p,q; ii – p,q; iii – q,s; iv – r,s
C) i – p; ii – q,r; iii – p; iv – q,s D) i – p; ii – q,r; iii – p,q; iv – q,s
ISR_IIT_*CO SC Page. No. 14
Narayana IIT Academy 18-05-25_ISR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-47_QP
33. Figure shows arrangement of three long parallel conducting wires, each carrying
equal current coming out of page. Four points A, B, C and D are also marked in the
figure, showing distances between points and wires. All points lie in the same plane

which dl is perpendicular to the wires.

Column – I Column – II
Magnitude of the magnetic field is
i. At point A, p.
maximum
Magnitude of the magnetic field is neither
ii. At point B, q.
maximum nor minimum in magnitude
Magnitude of the magnetic field is
iii. At point C, r.
minimum
Direction of the magnetic field is along
iv. At point D, s.
negative y axis
Codes :
A) i – s,q; ii – p,r; iii – s; iv – r B) i – p,r; ii – s,q; iii – r; iv – p
C) i – s,q; ii – s,q; iii – r; iv – p D) i – p,r; ii – p,s; iii – s,q; iv – p

34. A uniform magnetic field B exists in the region between and (region 2
in the figure) pointing normally into the plane of the paper. A particle with charge +Q
and momentum p directed along x-axis enters region 2 from region 1 at point

. Find the corresponding values of ‘B’ for the condition in Column-I.

ISR_IIT_*CO SC Page. No. 15

Narayana IIT Academy 18-05-25_ISR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-47_QP

Column-I Column-II
(i) Minimum value ‘B’ such that charge can re-enter
region-1. (P)
(ii) Value of ‘B’ for which charge enter region-3
through ‘P2’. (Q)
(iii) Value of ‘B’ for which charge enters region-3 with

a deflection of . (R)

(iv) Value of ‘B’ for which charge enters region-3 with

(S)
deflection of
(a) i-Q, ii-P, iii-R, iv-S (b) i-Q, ii-S, iii-R, iv-P
(c) i-R, ii-P, iii-Q, iv-S (d) i-R, ii-S, iii-Q, iv-P

ISR_IIT_*CO SC Page. No. 16

Narayana IIT Academy 18-05-25_ISR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-47_QP
CHEMISTRY MAX.MARKS: 60
SECTION–1 (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
35. Cellulose is a straight-chain polysaccharide composed of only
A) D-glucose units joined by  -glycosidic linkage
B) D-glucose units joined by  -glycosidic linkage
C) D-galactose units joined by  -glycosidic linkage
D) D-galactose units joined by  -glycosidic linkage
36. Select option with compound and it’s correct laboratory test?
A) Carbohydrate – Ninhydrin test
B) Protein – Biurette test
C) Methyl Glucoside – Benedict’s test
D) Poly saccharide – Fehling’s test
37. Statement -I: Glucose gives reddish Brown precipitate with Fehling’s solution .
Statement -II: Reaction of Glucose with Fehling’s solution gives CuO and Gluconic
Acid.
A) Statement I true, Statement II False
B) Statement I & Statement II are correct and Statement II is correct explanation of
Statement I
C) Statement I & Statement II are correct but Statement II is not the correct
explanation of Statement I
D) Statement I False, Statement II correct

ISR_IIT_*CO SC Page. No. 17

Narayana IIT Academy 18-05-25_ISR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-47_QP
38. Identify the correct set of stereochemical relationships amongst the following
monosaccharides I to IV.

A) I and II are anomers; III and IV are epimers

B) I and III are epimers; II and IV are anomers
C) I and II are epimers; III and IV are anomers
D) I and II are epimers; I and III are anomers

SECTION - II (Maximum Marks : 12)

This section contains THREE (03) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
39. Which of the following hexoses will from the same osazone when treated with
excess of phenyl hydrazine
A)D-Glucose B) D-Galactose C) D-Fructose D) D-Mannose

40. Which among the following are essential amino acids?

A) Leucine B) Lysine C) Methionine D) Alanine
41. Which of the following aryl amines will form a diazonium salt on reaction with
sodium nitrite in hydrochloric acid?
A)m-Ethyl Aniline B) p-Amino Acetophenone

C)4-Chloro 2-Nitro Aniline D) N-Ethyl 2-Methyl Aniline

ISR_IIT_*CO SC Page. No. 18
Narayana IIT Academy 18-05-25_ISR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-47_QP
SECTION-III (Maximum Marks : 24)
This section contains SIX (06) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.

42. The pK a1 and pK a 2 values of alanine are 2.3 and 9.7 respectively.

The isoelectric point of alanine is

43. How many amino acid units are present in insulin?
44. A decapeptide (mol. wt. 796) on complete hydrolysis gives glycine (mol. wt. 75),
alanine and phenylalanine. Glycine contributes 47% of the total weight of the
hydrolysed products. The number of glycine units present in the decapeptide is
45. An amine on treatment with HNO2 evolved N 2 .The amine on exhaustive

methylation with CH 3 I formed a quarternary Salt containing 59.07% Iodine.

Molecular weight of that amine will be?
46. Specific rotation for  -anomer of a given mono Saccharide is 100 0 and for
 - anomer is 200 .specific rotation of equilibrium mixture is 680 . what is the % of
 -anomer?
47.
CH=NH
2X
D-Glucose X D-Glucose Phenyl Hydrazone heat C=0 D- Glucosazone
-H2O -Y heat

(CHOH)3

CH2OH

Molar mass of Y is

ISR_IIT_*CO SC Page. No. 19

Narayana IIT Academy 18-05-25_ISR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-47_QP
SECTION-IV (Maximum Marks : 12)
This section contains FOUR (04) Matching List Sets. Each set has ONE Multiple Choice Question
Each set has TWO lists: List-I and List-II. List-I has Four entries (P), (Q), (R) and (S) and
List-II has Five entries (1), (2), (3), (4) and (5).
FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these
four options satisfies the condition asked in the Multiple Choice Question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3ONLYif the option corresponding to the correct combination is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: – 1 in all other cases.
48. List I (Carbohydrate) List II (Glycosidic Linkage)
A. Starch 1. C1  C6
B. Sucrose 2. C1  C4
C. Cellulose 3. C1   C4 
D. Maltose 4. C1  C2 
5. C1  C4 

A) A-1, B-4, C-3, D-2 B) A- 4, B-1, C-2, D-3

C) A-5, B- 4, C-2, D-1 D) A-1, B-2, C-3, D-4
49. Match the amino acids with their structures:
Structure of amino acids Name of amino acids
A) 1. Tryptophan

B) 2. Histidine

C) 3.Aspargine

ISR_IIT_*CO SC Page. No. 20

Narayana IIT Academy 18-05-25_ISR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-47_QP
NH 2

D)
HOOC COOH 4. serine
5. Glutamic acid

A) A-1, B-5, C-3 D-2 B)A-3, B-4, C-2 D-5

C)A-1, B-2, C-4 D-3 D)A-3, B-1, C-2 D-5
50. List I (Compounds) List II (Chemical characteristics)
A. Insulin 1. Component of cell membrane
B. Phospholipids 2. Regulates glucose metabolism
C.  - Amino acids 3. Transports oxygen from lungs to tissue
D. Haemoglobin 4. Forms zwitterion
5. Regulates Blood pressure
A) A-3, B-5, C- 4, D-2 B) A-2, B-3, C-5, D-4
C) A-1, B-2, C-3, D-4 D) A-2, B-1, C-4, D-3

51.
NH 2
A) Py
 CH 3COCl 
1) Diazo coupling

NH 2 SO2Cl
B)  NaOH
 
2) Hinsberg test

NH 2
C)  i HNO , 0C
2

ii  HCl , Cu

CH 3
3) Liberman's test

N2Cl N  CH3 2

D) 
4) Schotten -Baumann reaction
5) Gattermann reaction

A) A-1 B-2 C-3 D-4 B)A-2 B-4 C-5 D-1

C)A-4 B-2 C-5 D-1 D)A-4 B-5 C-3 D-2

ISR_IIT_*CO SC Page. No. 21