¢ ALLEN Acid Strength & Basic ‘oon EERE ACID STRENGTH & BASIC STRENGTH EXERCISE # ~ 1. Write correct order of acidic strength of following compounds e ° @ (@ NO,-CH,-C-0-H () F-cH, -C-0-n t Ih (© Ph-ch, -C-0-4 (a) CHy-CH,-C-0-11 ABO001 i Gi (@) CH, -CH, -CH-C-0-H cH, -cH-cH, -C-0-4 I F i (©) CH -CHy~CH,-C-0-H F AB0002 Il Il Gi) @) ClCH, -C-0- 8 (b) CI-CH-C-0-H I a clo ABOO03 (iv)(a) CH,-CH,-O-H (b) CH, -CH-O-H - | CH, CH; (©) CHs-¢-O-H CH, ° ABO004 wa \ wf \, of ~\. d coon "Yoon coon ABO00S COOH COOH CH, -COOH (vi) (a) | (b) CH, (co) cooH \coou CH, -COOH ABOOO6 (vii) (a) HF (HCl Our aie ABO007 +MEN 122 Chemistry aa ALLEN (viii) (@) CH, (b) NH, oH ‘ABO008 (b) NO,-CH,-CH,-O-H ()(a) F-CH,-CH,-O-H (©) Br-CH,-CH,-O-H (@ Nik-CH,—CH-O-H on () (@) CH,COOH (b) CH,CH,OH (©) C,H,OH CHO 2. Explain which is a stronger acid. (@) CH,CH, or BrCH,NO, ABOOIL oO co (b) cr, -¢-cn, or cu,—-C-cr,cn ABOOL2 ou on «© or ABOO13 ota, by e on @ oO or oO ABO 3. Which of the following would you predict to be the stronger acid ? (a) Benzoic acid or para-nitrobenzoic acid ABOOIS (b) CH,-CH,-CH,-OH or CH,-CH = CH - OH ABOOIG (c) CH, - CH = CH ~ CH, - OH or CH, - CH = CH - OH ABOO17 4. Arrange the given phenol & its derivative in their decreasing order of acidity (1) CgH,-OH anF{O)-on auycr-{O)-on (ly) o,n-XO)-on Select the correct answer from the given code: (A)IV>Il>1> 1 (B)IV>H>II>1 (C)IV>Ml>M>1 (D)IV>1> I> 1 ABOOIS 5. Which one of the following is the most acidic? (A) VW wl oO) (D) CH,=CH-CH, ABOOISALLEN Strength. Acid Strength & Ba’ ‘Which ofthe following is weakest acid? coon coor cooH 00H OW ) ®) © © ‘OH OH AB0020 7. Arrange pH of the given compounds in decreasing order (J) Phenol (2)Ethyl alcohol (3) Formic acid (4) Benzoic acid (A)1>2>3>4 (B)2>1>4>3 (C)3>2>4>1 (D)4>3>1>2 AB0021 8 Arrange acidity of given compounds in decreasing order: (1) CH,-NH-CH,-CH,-OH (1) CH,-NH-CH,-CH,-CH,-OH e (it) (CH,),N-CH, ~CH, -O8 (A) I> I> (B)M>I>1 (C)I> Mem (D)M>1> TL AB0022 9, — Consider the following compound 0 on ° | Oye COOH CH,CCOOH ° on 1 0 Th Which of the above compounds reacts with NaHCO, giving CO, (A)1, Hand IIT (B) Land IIT (C) Mand 11 (D) land ABO0023 4 10. Say which pk, belong to which functional group in case of following amino acids : ; COOH (i) cysteine: ws 1,8, 8.3 & 10.8 AB0024 { Nh (ii) glutamic acid aaa 2.19, 4.25, 9.67 ABO025 1 NH) EMEE Chemistry ALLEK Ly 11. Record the following sets of compounds according to inereasing PK, (=— 108 Ka) oC): «cyclohexane carboxylic acid ABOL26 (b) 1-butyne, 1-butene, butane. AB0027 (c) Propanoic acid, 3-bromopropanoic acid, 2-nitropropanoic acid ABO028 (d) Phenol,o-nitrophenol, o-cresol AB0029 (e) Hexylamine, aniline, methylamine AB0030 12. Write correct order of acidic strength of following compounds: ‘ NO, NO» NO; O@ (b) © @® No, , Gi (a) oO ©) 2-H 6-H cl @)ta) ©OfO () cl 6 a 1 g C-O-H C-0-H CH, wi ofO ABO031 AB0032 AB0033 ABOO34, AB0035, ABOU36 j i iALLEN 13. ox 2 = (vii) (a) (o) o “So Acid Strength & Ba ‘oa Sel ; i “tect the strongest acd in each ofthe following sets OH ow oO ®) O cH, OH NO, ? ou Gia Ou ) CL Ol OH ou No, F OH “© cl OH OL, Hy 1H 10, 1H Me OH Gi) (ay C ry © ‘OMe 9° OH on No, no, me 0) © NO, ‘NO, No, The strongest acid is : (A)HF (B) CH,CO,H (C) HF + SbF, The weakest acid (does not show acidic character) is (A)HC = CH (B)CH,=CH, (©) Me,CH Which of the following is most acidic : [00H COOH COOH A) ©, (B) © Hy No, cH, Strength AB0037 on “) NH, ABO038 OH “© AB0039 OH #6) OMe * AB0040 on @ NO, No. “ABOOAL (D) HS ABODA2 (D) Ph,CH ABO043 00H (D) ABO +17. 18, 19. 20. ion 17 to 18 Paragraph for Ques : “The most important condition for resonance to occur is thatthe involved atoms in resonating structure ‘ust be coplanar or nearly coplanar for maximum deloealisation. If this condition does not fulfil, ~ involved orbitals cannot be parallel to each other and as a consequence delocalisation cannot occur, Bulky, groups present on adjacent atoms inhibit the plinarity of atoms involved in resonance. This phenomenon is known as sri inhibilion of resonancé.-Steric inhibition of resonance has profound effect on : (1) Physical properties (2) Acidity and basicity (3) Reactivity of organic compounds Arrange the following in the decreasing order of basicity NH CHeN-CH, NH, OC «O © oO) ‘NO, (A) I> I> I>IV— @B)IV> MID > 1 (i> 1>1V>I ()I>1V>m>T ‘ABO04S Which of the following is most acidic : :00H (00H COOH, 00H (a) &. ®) © © Hy &, oy, - AB0046 How many following compounds are more acidic than water ? @ (O)-son onc (OCH -C=CH (@ A/com OH ou © oO, (s) Ay =< 0, (i) NaOH ABOO47 Select correct order regarding acidic strength of given compounds (1) o-methylbenzoie acid (2) m-methylbenzoie acid (3) p-methylbenzoie acid (4) bensoie acid (Al >2>3>4 (B)4>3>2>1 ()l>4>253 (D)3>2>451 fs ee ABOO4SALLEN (a) CHT «i @F Gi) (@) NH, Gv) (@) NH, (v) (a) R-NH, Nu, (vii(a) : eo (it) (@) SO 0,.N7 ~~ fix) (a) @ NH, i Nn, (b) NH yer (b) MeNH, (b) MeNH, (b) Ph-NH,, NH Acid Strength & Basic Strength a BXERCISE OR LW rite decreasing order of basic strength of following : © oH (Br (©) Me,NH (©) Me,NH (©) R-C-NHz wor AB0049, @r ABO0S0 (d)Me,N (in H,O) ABOOSL (a) Me,N (Gas phase) ABO0S2 ABO0S3 ABO054 ABOOSS AB0056 ABO0S7a Chemistry. 2... Write deereasing order of basic strength of following :,» (a) Given, iy “(b) CH,-CH=NH (©) CH)-C: Gy (@ CH; -¢—-Ni, () CH,-CH,-NH, (6) CH;-C-Nu, I 0 Gi) (@) C\ fi u NH, Civ) (a) No, Nn, ) €@ NO, Nn, Me Me wi) @ oN, o7 "So NH NH S Z © wll Me Ni Ol Wn, NH, o © ( oN NH, NO, © © 10, s 0) 1), Me Me ovo NH, “O) NA, AB00S9 AB0060 ABO061 AB0062 AB0063- 3(viii) (a) o ABO06S, we we we sie me o ) ©, © © ® O “ 3. Select the strongest base in following compound : 0 @ OC ic) AB0066 ABO0067 NH, v ii) (a) © (b) Cou Gi) (@) L \ of S i HH AB0068 aisy(ay ABOO70 +ce Chemistry e rideSon : Arrange the following compound in decreasing order of their basicity. @ (a) H,C = CHNa- (6) CH,CH,Na ().CH,CH,ONa * __.(d) HC = CNa ‘ABOO7I ; “i @(O)-nn, (KO)-cr,-NH, Sop @ (O)-¢-Nit NO; ° ‘ABOO72 Gi) (@ HO () NH, (HO (SO, ‘ABOO73 Correct decreasing order of basic strength - N yee cy Co HN Cy eas H @ a, ) Of following compound - (Ayilsus1 (B)N>1>m COPESTESTT (M150 ‘ABOO74 6. Consider the following bases: Mo-nitroanitine (11) m-nitroaniine (111) p-nitroaniline ‘The decreasing order of basicity (A) I> I> 1 (B) >> (Olen (D)1>I>1 ‘BOOTS 7. Consider the basicity of the following aromatic amines: () aniline (1) p-nitroanitine (AI) p-methoxyaniline (IV) p-methylaniline 3 The correct order of decreasing basicity is ! (A)MI>1V>151— (B)MIS1V>11>1 (I> >MI>1V_ (D)IV> >>I i ABOOT6 } 8. Which one of the following is least basic in character? ; oly ot} wl) | jee i | i ABOO7T | * m9. -~ In-each Bak " 1 Of the following pair of compounds; which. is more. basic in aqueous. solution? (0) CH,CONH, or H,N SSN (©) CH,CH,CH,NH, or CH,CN (@) C.H,N(CH,), or 2,6-dimethyl-N-N-dimethylaniline ABOO78 ‘ABOO78 ‘ABOO78, ABO078 10. "Choose the niember of each of the following pairs of compunds that is likely to be the weaker base, (a) H,0 or H,0* ABOO79 (cr, se” ‘AB0079 (FOF, NHG,CH, AB0079 (@ HF, H,0, NH, ABOO79 (©) OH SH, Se ABOO79 11, Explain which compound is the weaker base. nh «@ © or © ABO080 Ko; (b) CH, = CH - CH= CH~ CH, or CH, = CH- CH,” ‘AB0080 coo” cooH Ol o | ABO0080 coon COOH ou on (a) oOo or oO” ABO080 12. Arrange the basic strength of the following compounds. (@) OF CH,COO™ oc “ ci) «iy . ais) : ABOOSI “o ai) =e AB0082 3 fey CH, = CHCHjNH, CH,CH,CH,NH, * CH feeb fi) ai) (ii) ‘ABO083REE 122- Chemistry ALLER , MM, NH= Col Ni : @ . 1 a” (ii) (ii) ABO0084 13. Arrange the following compounds in order of increasing basicity. (a) CH,NH,, CH, NH? , CH,|NH™ ABO085, (b) CHO", CH,NH™, CH,CHy ABOO8S, 14. Which of the following is most basic 15. _Basicity order of N in following compound is: cH, oO ABO086 9 cat is HN-C-CH, CH, -NH-©- CH NH N cu cu, (A)b>d>a>c @B)a>b>d>c (C)a>b>c>d — (Dyade>b>d ABO087 T 16, The conjugate base of serotonin (used as tranquilisers) is given as follows i -CH-NH, } | i H i How-many:-basic groups present itr following’ compound ? i i ABOOSS | i + E17. -“The'structufé.of saccharin is given as follows : 0" : A a aid faa 4 &. i 4 ; Ow [Provided N is the donor aon fall cases] OS Teanasieen How many following compounds are’ more basié than saccharin? 9 I NH @ Cy ¢-NH, Gi) HN C-NE (il) CH= F—NMs Ly Ni NH ° 4 ci-NH, 1 o) or wid X ABO089 + EALLE! ne EXERCISE # |. In given reaction Gas liberated is/are _20-H sc SO,H (A) CO, & SO, (B)S0,& "CO, (©) "CO, only (D) SO, only AB0090 ‘Arrange marked atom in decreasing order of acidie strength (A) 1>2>3 (B)3>2>1 (©2>1>3 (D)2>3>1 ABO091 Column - 1 Column-I OH (A) (P) React with NaOH OH »© © Raat OH © (R) React with NaH ; No, i j _OH | NO, * ; z (Dy (S) React with Na ; i NO, | } i (1) “Reset with NaN, ABO092= ee Acid Strength & Busic Strength as ts Ca c round igh can. ve effevescences witiNalICO, °° GE — ‘ : nen ines (Benzene sulphonic acid) 6 Pere acid) OH H-COOH (cinnamic acid) (vi) OH oO) ww) w o* oO 5. Statement-1 : For the given two compounds-Iis more acidic than compounds-II. No, N : “ee seco : Ht OH and Statement-2 : Due to presence of ~CH; group at ortho positions to NO, ; the fe plane of -NO, ABO093 deviates, w.r1 plane of ring (A) Statement-1 is True, Statement-2 is True ; Statement-2 is a correct explanation for Statement-1 (B) Statement-1 is Tine, Statement-2 is True’ Statement-2 is NOT a correct explanation for Statement-1. (C) Statement-1 is True, Statement-2 is False, (D) Statement-1 is False, Statement-2 is True, ABO04‘RE Chemistry - - 6 Statement 1: SO i and ‘Statement 2 : Lone pair electrons on nitrogen in compound (1) does not participate in resonance. (A) Statement-1 is True, Statement-2 is True ; Statement-2 is a correct explanation for Statement-1 (B) Statement-1 is True, Statement-2 is True ; Statement-2 is NOT a correct explanation for Statement-1. (C) Statement-1 is True, Statement-2 is False. (D) Statement-1 is False, Statement-2 is True, AB0095 7. Match Column-1 with Column-IL Column - 1 (Facts) Column - I (Reasons) (A) Guanidine H,N-¢-NH, is example (P) Resonance stabilisation of conjugate acid ofstrong base NH of strong base. (B) Carbanion stability Gc, > CF, (Q) Due to s-character of central atoms (© Alkyne is more acidic than alkene (R) Due to d-orbital resonance (D) Acidity (S)_ Due to formation of aromatic anion number of identical resonating structure. AB0096 ‘Match Column-1 with Column-IL Column - I (Compounds) Column - 11 (pKa) (a) Ho-_\-F 7s () Ho Ya (Q)10.14 () Ho-€_Y-no, (R)9.98 (py Ho-L_Y-cH (8) 9.38 (T) pKa is more than phenol AB0097(Caiprehension) (Q.9 to 9.11) Fs | Observe the following feasible reactions: fs : ao ©. heid Strength & Basic Strength a " ‘COOH ‘ONa COONa- OW “ °O-O— Ln Re a . i NO, NO, On ONa UA NO: NO, (i) ) + NaHCO, —> +H,CO, NO, NO, - ‘ONa oH (ii) (CEQ) +4,co, oO + NaHCO, Answer the following question : 9. Which of the following is the correct order of acidi on oH coon OH on cooH NO, nes MO) > >H,CO, > “6 > > > H,CO, NO, NO, . on coon no, 9H LO) >Co> 16) (D) None i NO, i ABO0SS, | 10. Which of the following compound does not react with NaHCO, on Obs base te On _— : < ines i WO] » nO) © co) ) t : Ps ERA ono od cH: Noe, NO RS ‘AB0099 +MET 22. chemisry i. 12. 13. Identify the feasible reactions coon COONa ‘“ oO + NaHCO;—> © +H,0 +O, NH, NHNa “6 + a) +H,0+00, on ‘ONa TO) + saico,—+(G) + H,O+CO, COONa coon COOH coo -O -O-6- Mentify the non-feasible reaction (A) CH-C=CH+ NH, == CH-C=E4Nn, (B) CH,CH,—OH + NaH == CH,CH,ONa + H, (©) CH.—OH + NaOH == CH,ONa + H,0 (D) HC=CH + NaOH = HC=CNa + H,0 Select the number of compounds in which deprotonation gives aromatic anion 9 HO-CH, og o ° A 0 HN NH Hi ey ® ag ot) oO AA, wd nd ‘oH Barbiturie acid Ascorbic acid | (Vitamin-C). H ABO100 ABOI01 ABO102ALLEN Acid Strength & Bai i : Paragraph for’ Questions 14 and 18, Oa ©rcoo © Mixture of 3-compounds in hexane 14, Identify salt'A'? Na’ (a) B) 15, Identify compound OH Aqueous NaiCO, COO*Na’ cooH —>| Organic Layer ‘Aqueous Layer (Galt-B) ter Organic —| Layer L__5] Aqueous Layer (Salt A) (Compound -C) (D) Allof these ABO103 OH () COOH AB0103 +WEEE Chemistry ALLER | EXERCISE #.(JEE-MAIN) Picric acid is - [AIEEE-2002] coon... coon on 00H a o. : ao. eo ey oO. NO; on NH No, ABO104 2. Which of the following speices acts both as bronsted acid & base — [AIEEE-2002] ()NH, (2)0H7 (3) Hsog (4) Land 3 both ABO105 3. The correct order of inereasing basic nature for the bases NH,, CH,NH, and (CH,,NH is- [ATEEE-2003] (1) CH.NH, < NH, < (CH,),NH (2) (CH),NH < NH, < CHNH, (3) NH, < CH,NH, < (CH,),NH (4) CH,NH, < (CH),NH < NH ABO106 4. Consider the acidity of the carboxylic acids- (AIEEE-2004] () PhCOOH Gi) -NO,C,H,COOH (iil) p-NO,C,H,COOH (iv) m-NO,C,H,COOH Which of the following is the correct order of acidity- (Di>iiriii>iv Q)ii>iv>iti>i Q)ii> ive i>iit @ii>iiisivei ABO107 5. Which of the following is the strongest’base- [ATEEE-2004] ay (S—nn. ) @—nucr, 8) Qo. © Q-cuna, | CH, i vous | 6. Among the following acids which has the lowest pk, value- IATEEE-2005] 41) CH,CH,COOH (2) (CH),CHCOOR ; 3) HCOOH (4) CH,COOH i ABo109 | i a E10. i. 7 Sra ‘he following the ns basic cimpound i (AITEEE-20051 (1) p-nitro aniline : O° @) Abetanilide™ @) Aghia (4) Bemaylamine ABOI1O ‘What isthe conjugate base of OH”? [AIEEE-2005] (4,0 @)0, BO" oo . ABOLIL Among the following acids which has the lowest pK, value? [AIEEE-2005] (1) HCOOH (2 CH,COOH (3) CH,CH,COOH (4) (CH,),CH-COOH 7 ABOLIZ ‘The correct order of increasing acid strength of the compounds is [ATEEE-2006] (a) CH,CO,H (b) MeOCH,CO,H Me, (©) CF,CO,H @ Meo OOF (dB>a>D Q)D>C>A>B ()B>D3.A>€ @)A>B>D5C ABOLIT +15. Inthe following compounds (JEE(Main) 2012] Oe) og H the order of basicity is as Follows ()IV>M> i151 (2) I> >1>1V (G)1>1>n>1V (4) I>1>1>1V ABOLIS 16. The most basic compound among the following is [JEE(Main)-2012] () Acetanitide (2) Benzylamine (3) p-Nitvo aniline (Har ABOLI9 17. The order of basicity of amines in gaseous state is :- [JEE(Main)-2013] (1) 3° > 2° > NH, > 1° Q) 1° >2°>3°>NH, (3) NH, > 1° > 2% 3° (4) 3° > 2°> 1° > NH, AB0120 18. Arrange the following compounds in order of decreasing acidity UEE(Main)-2013) 3 3 é 3 cl CH, 2 NO, OCH, a as am ay ()M>1V>1>u1 Q)I>1>0I>1V (3)IM>1>1>1V (@)IV>M>1>01 ABOI21 19. The conjugate base of hydrazoic acid is - (1) HN (2)Ny (G)Ny (4) N° ABO122 20. | Which.one of the following eompourids will not be soluble in sodium bicarbonate ? : (JEE(Maiin)-2014] (1) Benzene stilphonic acid (2) Benzoic acid (3) ‘o-Nitrophenol (4) 2.4, 6 - Trinitrophenol ABOI23 ME Chemistry i ALLEN |ALLEN * Acid Strength & Basic Strength a 21... Consideris x sidering the basic strength of amines in aqueous solution, which‘one has the smallest pKy value ? [JEE(Main)-2014) () (CHy).N, (2) CgHsNH @) (CH),NH (@) CHNF; ABO124 22. Among the following oxoacids, the correct decreasing order of ‘acid strength is [JEE(Main)-2014) () HCIO, > HCIO, > HCIO, > HOCI 2) HCIO, > HCIO, > HCIO, > HOC! (3) HOC! > HCIO, > HCIO, > HCIO, (4) HCIO, > HOCI > HCIO, > HCIOs ABOI25: 23. Among the following compounds, the increasing order of their basic strength is:- NH, oO cc, 0h o or aon am Cy olla, () dD <() < (Ip < (IV) (2) 2) < (I) < dV) < GI) [JEE(Main)-On-Line 2017) (3) (I) < (1) < (IV) < GI) (4) @) < (ID < di) < Vv) ABO126 24, ‘The increasing order of basicity of the following compounds is : [JEE(Main)-2018] NH, OAM” OAL © Me © 7\wucn, (1) (b) < (a) < (¢) < (d) (2) (b) < (a) < (d) < (©) (3) (a) <(@)<(@) <(©) @)@<)<@<@ ABO127 } 4WET Cheinistry -XERCISE #, 1. In the following compounds OH OH OOH on a 4 a SNO, Q cH, 0, 1 om Vv The order of acidity is - (A)IllsIValsI1——(B) e1Vel> (©) pt II>1V___{D) 1VpII I> >I ABO137 2. Although phenoxide ion has more number of resonating structures than benzoate ion, benzoic acid is a stronger acid than phenol. Why? (T-JEE-1997] ABOI38 3. Amongst the following, the most basic compound is - [IIT-JEE-2000] (A) CNH, (B) p-NO,-CgH,NH, (C) m-NO,-C,H,NH, (D) CgH,CH,NH,, AB0139 ‘The correct order of basicities of the following compounds is : (1T-JEE-2001) 2NH 1 cHec CH,CH.NH, (CH),.NH CH,CNH, Nvu. 1 . 2" ay 4 (A)2>1>3>4 (B)1>3>2>4 (C3>1>2>4 D)1>2>3>4 ABO140 Statement-I : p-Hydroxybenzoic acid has a lower boiling point that o-hydroxybenzoic acid Because Statement-II : o-Hydroxybenzoie acid has intramolecular hydrogen bonding. [11T-JEE-2003] (A) Statement-I is True, Statement-II is True ; Statement-II is a correct explanation for Statement-1 (B) Stalement-Vis True, Siateméit-I1 is True; Statement] is NOT a coitect explanation for Statement-1 (C) Statement-1 is True, Statement-Il is False. (D) Statement-1 is False, Statement-I1 is True. ABOLIL iALLEN i : bea ‘Acid Strength & Basic Strength [Ea 6. "Match K, values with suitable acid: K, ee * Acid 5 (A) 3.3. a (A) 33x 105 gy (Op-coon (B) 4.2% 10° (@ me-(O)-coon (©63% 105 © e{C)-o0n (64x 108 © weo-{O)—coon (©) 30.6 x 10° © ox(C)-coort (a) Which of the following is more acidic and why ? Ru, Nu, F a ay HOOC, DQ om ties TAH 4, The product (A) will be [UT-JEE-2003), ABO142 [UIT-JEE-2004] ABO143 (IT-JEE-2007] 8 ON. . OO Xu oH HOC. ABOLAS +ME chemistry ALLEN | 9. The correct acidity order of the following is: UIT-JEE-2009) OH. OH COOH. CooH a cu, 0 ay ay avy (A) (ID > (IV) > (> (B) (IV) > (I) > () > AD) (©) I) > (1) > a) > avy (D) ay > AM) = V) > ABOI4S: + the {otal number of compounds soluble in aquesous NaOH is: (IT-JEE-2010) 10. Amongst the followi HG CH, NO COOH OCH,CH, OH NO, oO oye a OH CH,CH, COOH oO & 8 XN HC~ cu, ABO146 (UT-JEE-2011] 11. Among the following compounds, the most acidic is (A) p-nitrophenol (B) p-hydroxybenzoie acid (©) o-hydroxybenzoic acid (D) p-toluic acid ABO147 12. The carboxyl functional group (COOH) is present in - UIT-JEE-2012] (A) pieric acid (B) barbituric acid (C) ascorbic acid (D) aspirin ABO1a8 15. Identify the binary mixtures (s) that can be separated into the individual compounds, by differential extraction, as shown in the given scheme - UIT-JEE-2012] NaOH(aq) Compound 1] + [Compound 2 Binary mixture containing |_ Compund | and compound 2 el I NaHCO,(aq) Le | Compound] +. [Compound 2 (A) C,H,OH and €,H,COOH (B) C,H,COOH and C,H,CH,OH (C) C,H,CH,OH and C,H,OH (D) C,H,CH,OH and C,H,CH,COOH : ABOLYD‘ALLER 14 16. ‘Acid Strengthi & Basic Strength Th ie compound that does NOT liberate CO,, on treatment with aqueous sodium bicarbonate solution, a [yEE-ADVANCED-2013) (A) Benzoie acid (B) Benzenesulphonie’ acid” (C) Salicylic acid (D) Carbolic acid (phenol) AB0150 Hydrogen bonding plays a central role in the following phenomena [JEE-ADVANCED-2014] (A) Ice floats in water (B) Higher Lewis basicity of primary amines than tertiary amines in aqueous SOIstOnS (C) Formic acid is more acidic than acetic acid (D) Dimerisation of acetic acid in benzene ABOIS1 ‘The order of basicity among the following compounds is [JEE-ADVANCED-2017] [X CN ia XN kN a NY NF om 0 m1 Ww (aye t> vem (wy v>t> mt (C)l>WeW>t (W)IV>l>u>M ABOIS2ALLEN ETE Chemistry —o ANSWER-KEY CO ANSWER-KEYO EXERCISE # O-1 OO CEXERCISE # OD 1. @ a>b>e>d, (i) a>b>e, (iil). e>b>a, (iv) a>b>o, () e>b>a, (vi) a>boe (il) d>e>b>a, — (vilJd>c>b>a, (x) d>b>a>c, @) d>ared 2 (a) 25 (b)25 (15 (aL 3. (a)25(b)2:()2 4. (C) 5. (B) 6B) 7. (B) 8. (A) 9. (A) coon 10. (i)eystein on 18 Gi glutamic acid :! yon 108 Ni M. (@) 3<2<15 (b)1<2<35(€)3<2<1;(d)2<1<3; (2<3<1 12, @ d>e>a>b, Gi) a>b>e, c>a>b>d, — (ivyd>b>e>a, @) a>b>e (vi) b>a (Wi)e>a>b 13. (ib, Gia, Gi), Gvyb 4. © 1s. (C) 16. (B) 7 © 18. (B) vw & 20 (©) EXERCISE # 0-2 1. @ a>b>ed, ii) a>b>e>d, (iii) e>b>d>a, (iv) d>e>b>a @) a>boe, (Wwi)e>b>a ‘i)c>a>b, (viii) b>e>a, (ix)e>d>b>a 2 @ a>beg (ii) d>c>b>a, ii) b>e>a, (iv) d>e>b>a, ) b>arc, (vi) b> a, (vil) e>b>a, d>a>b>e (ixyd>e>b>a 3. @ 4, (ii) b, (iii)a, (ivja 4. (i) b>a>d>e, (ii) b>a>e>d, ii)a>b>e>d 5. (A) 6.(A) 8.(A) i 9 (adi, (b) ii, (c)i, (A) ii 10. (a) 2 5 (b) 15 (c) 15 (d) 15 (e)3 11. (a) 25 (b) 13(c) 25 (d) 2 12. (a) 1>2>3 5 (b) 1 <2<3;()3<1<2;(d)2<1<3 13. (a)2<1<3;(b)1<2<3 14.(C) 15. (B) 16. 3, 3 basic groups are NHy:-NH-;O- 17. (6)1 3 4. 1 9. 1B. ALLEN Acid Strength & Basic Strength 2) BWC (O-RS.T5B)-PRS, 15 (C)-P, RS, Gi) Gd) (iv), (v) (x) 5,(D) 6 (A) =P,T ; (B)-R;(C)-Q;(D)-S,T 8. a) 10. (A) u. (A,B, CD) 14. (B) 15. 3(D)- P,Q, R,S,T (A) (A) = ; (B)-S;(©)-P 5 (D)-@T (A, D) 12. (D) (©) EXERCISE # JEE-MAIN i. 16. 2. @ ® 2 4) 3 @) 4 @) @) 7 (4) 8. (3) 9% a 10. (2) @) 12. (2) 13.) 14. Q) 15. @) @) 17. (4) 18. (3) 19. (2) 20. @) 8) 22. (I) 23. (3) 24. (2) EXERCISE # J-ADVANCED @) 2. Benzoate has equivalent resonating structures 3. (D) ®) 5D) 6. Axfs) 5 Be(q) 5 Cp) 5 D-() 5 EO (IL is most acidic) 8. (C) 9. (A) 10. (4) 11. (C) (D) 13. (B,D) 14. (D) 15. (A, B,D) (D)