SRI CHAITANYA IIT ACADEMY, INDIA 05-11.

2022_ Jee Sr ELITE (CIPL, IPL IC & ISB)_Jee-Main_RPTM-4_KEY & Sol’S

Sri Chaitanya IIT Academy., India.

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON Central Office – Madhapur – Hyderabad
Sec: Sr Jee ELITE (CIPL, IPL IC & ISB) Jee Main Date: 05-11-22
Time: 09.00Am to 12.00Noon RPTM-04 Max. Marks: 300

KEY SHEET
PHYSICS
1 1 2 2 3 4 4 2 5 4
6 1 7 3 8 1 9 2 10 4
11 3 12 3 13 3 14 4 15 3
16 2 17 1 18 1 19 1 20 3
21 5 22 101 23 2 24 9 25 20
26 2 27 20 28 6 29 4 30 5
CHEMISTRY
31 3 32 3 33 2 34 2 35 1
36 2 37 2 38 4 39 2 40 2
41 3 42 2 43 1 44 3 45 4
46 2 47 4 48 2 49 2 50 3
51 9 52 9 53 3 54 6 55 4
56 3 57 5 58 4 59 2 60 4
MATHEMATICS
61 1 62 1 63 1 64 1 65 2
66 3 67 2 68 1 69 1 70 4
71 1 72 2 73 2 74 1 75 3
76 2 77 1 78 2 79 3 80 2
81 2 82 4 83 3 84 2 85 1
86 4 87 3 88 1 89 3 90 3

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 SRI CHAITANYA IIT ACADEMY, INDIA 05-11.2022_ Jee Sr ELITE (CIPL, IPL IC & ISB)_Jee-Main_RPTM-4_KEY & Sol’S

SOLUTIONS
PHYSICS
1.
P  P  
V 2
2
 V12 
mg

 V2  50m / s
1 2
2 A
2. F1 F2 F 100 10  2
  F1  2 A1  2
 r  62.5N
A1 A2 A2   4r 
3. A 2
t h1  h2 
a g
4. av  const  r12 v1  r22 v2
5. Conceptual
6. 2 2
  2   2    1 v

v 2 82
 v  8m / s.h    3.2m
2g 2g
7. PV  PV
1 1  P2V2

4T  4 3  4T  4 3  4T  4 3 
 r     r1     r2 
r 3  r1  3  r2  3 
8.
U1 A1 2  4 R 
2
2R2 21/3
   
4 R `2 1/3 2
U 2 A2 2  R 12

4 3 4 `3 ` 1/3 
 3  R  2   R  R  2 R
3 
9. F  6 Rv
10. 4 3 4 
 R  2   r 3   R  21/3 r
3 3 

S .E  4 r 2T  4 2 2/3 r 2T  28/3  r 2T
11. 2T cos 
h
r g

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rHg THg cos  Hg  w  1  1 2

 . .  7.5    0.4 
rw Tw cos  w  Hg  2  13.6 5
12. w  2T  4  52  32  104

 0.4 mJ
13. 4T
P  P  P0   P1  0.01atm
R
 P2  0.02 atm

P1 4T / R1 R2 0.01 R1 2
    
P2 4T / R2 R1 0.02 R2 1
3
V R  8
 1  1  
V2  R2  1
14. 2
F  A u 2  20 106 103   2  9.8  20   7.84 N
15.

h1
h2

h1d1 g  h2 d 2 g

54.4  1  g  h2  13.6  g

54.4
h2  4
13.6
difference  54.4  4  50.4
16. 1 1 1 1
v1.d b . g  .v. 1 .g db   d oil = gm / cc   1000kg / m3  250kg / m3
4 4 4 4
17. Mg  v1d1 g  v2 d 2 g  A.x1 .d1 g  A. x2 d 2 g

M  225  10  0.8  225  5  1  2925 gm  2.925kg

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18. Since points A and C are in the same horizontal line but separated by distance l and
liquid tank is moving horizontally with acceleration a, hence PC  PA  l  a or
PC  PA  l  a

Points B and C are vertically separated by h

 PB  PC  h  g or  PB  PA  lpa  h  g

Or PB  PA  h  g  l  a
19. F  A u 2 ; ma1  a  u 2

a  u 2 a   2 gh
1
a  
m m
a  2 gh 2ag
 a1  
Ah  A
20. Density of mixture = mass of mixture

Volume of mixture

m1  m2  ....  mn

m1 m2 m
  .....  n
1  2 n
n

m
i 1
i
=
mi n

i
i
21. F  6 rv

Rate of heat produce  P  F .V

2 2   
V r g
9 
2
 2 r2    r  
2
 P  6 rv  6 r  g
 9  

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 P r 5
22. 2T cos  hr  g
h T 
rPg 2cos
23.  2  2
a1v1  a2 v2  d min vmax  d max vmin
4 4
2 2 2
V  d   4.8   3  9 9
 min   min        
Vmax  d max   6.4   4  16 8  2 
24. v1 R2
R  3r ;  9
v2  R / 32
25. v  2 gh  2 10  20  20m / s
26. 1 1 1 rr 63
  R 12   2cm
R r1 r2 r1  r2 6  3
27. Conceptual
28. dR
 0  h  6m
dh
29.  vD volumeflowrate
R ;v 
 areaofflow

V  2r 
R  2  104
  r 2  t

Order of 10 4
30. 10 4 m3 / s  10 4 v  v  1m / s

 2 gh  1  2 10  h  1

1
h m  5cm
20
CHEMISTRY
31. Conceptual

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32.

33. The reaction follows markonikoffs rule.

34.

35.

36.
37. During formation of most stable in preffered as intermediate which attaches to
Benzene.
38.

39.

40.

41. Wurtz reaction

42. 890
The heat combustion of per gm of CH 4   55.625kJ
16

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1411
The heat of combustion of per gm of C2 H 4   50.393kJ
28

1560
The heat of combustion of per gm of C2 H 6    52kJ
30
43. When 5 ml of strong acid reacting with 5ml of strong base, net heat evolved = H

Temperature increases  H
ms

When 10 ml of each are reacting, the heat evolved  2H ;but mass of the solution =2m

 Temperature increases  2H  H

2ms ms
0
44. Applying (I)+(2xII); H  6.2kJ
45. The work done by a gas is given by,

(82 lit atm)(2 cal deg 1 mol 1 )

  2000 cal
(0.082 lit atm deg 1 mol 1 )
46. 1.435
H ( perg )  kcal  0.0797kca lg 1
18
47. Internal energy and volume depend upon states.

48. NaCl ( s)  Na  ( g )  CL ( g ) H  780 kJ

Na  ( g )  aq  Na  (aq) H  406 kJ

Cl  ( g )  aq  Cl  ( ag ) H  364 kJ
49. For a reaction at equilibrium G  0 and not G0
50. G  ve for spontaneous charge

G  H  T S

G 4000
T S  H , T  T   T  400 K
S 10

51. [0.1][OH-] = 1X10-11 => [OH-] = 10-5

pOH = 5, pH = 9

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52. Enthalpy of combustion of 3.5 g of the gas = 2.5 x 0.45 = 1.125 kJ Enthalpy of
combustion per mole = 1.125/3.5/28 = 9
53. For mono atomic gas Cv = 3/2 R, Δ T = 1 ΔU = Cv ΔT
54. Cv = 4, Cp = Cv +R = 4 +2 = 6
55. Objective material Vol I D Additional Practice sheet advanced q.no. 60
56. Objective material Vol I D Additional Practice sheet advanced q.no. 54
57. Objective material Vol II B lecture sheet Ex II , Level II advanced q.no. 16
58. Objective material Vol II B practice sheet Ex I , Level II advanced q.no. 22
59. Objective material Vol II B additional practice sheet , Level I Main q.no. 4
60. Objective material Vol II B practice sheet Ex I , Level I advanced q.no. 13

MATHEMATICS
61. 1  33  1  33 
f `  c   0  cos c   c  cos 1  
8  8 
62. Let g  x   f  x   x 2 for x  1,3 , g 1  g  2   g  3  0. there exist
  1, 2  ,    2,3 such that g `    0 and g `     0  f `    2 and
 f `     2

By Rolle’s theorem h  x   f `  x   2 x on  ,   , there exists    ,   such that

h`    0  f "    2
63. 1 1 1 
Let F  x   f   , x   , 
 x b a 

1 1 
Use LMVT for F  x  . Then there exists d   , 
b a 

1 1
F F 
a
Such that    b   F` d   1 f ` 1 
   
1 1
 d2  d 
a b

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1 f b   f  a 
Put c  then  c 2 f `  c 
d 1 1

b a
64. 1
Let f  x   x1/3 in  27, 28  f 1  x   2/3
3x
1/3 1
By Lahrange’s theorem,  28  3  ..... 1
3c 2/3
1 1 1
27  c  28   2/3
 and by 1
28 3  c  27

1 1/3 1
  28   3  .
28 27
65. Use Lagrange’s theorem
66. 1
f  x   x ,  x  
x

(assuming 0  a  b )

f b   f  a  f `  c 

  b     b   ` b 

1
b a
  2 c  c  ab
1 1 1
 
b a 2 c
67. Applying R1  R1  R2 , R2  R2  R3 , we get

4  2 2 2 2 0
 4 2 4 2 0
32 2 22 2 1

 
1  4  2 2 4 2  2 2 4 2

16 2
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68. 1 1 1
m m 1 m2
C1 C1 C1
m m1 m 2
C2 C2 C2

1 1 1
m1 m 1
 mC1 C1 C0  m1C1
m1 m 1
m
C2 C2 C1  m1C2

1 1 1
m m 1 m 1
 C1 C1 C0 {Applying C3  C3  C2 }
m m1 m 1
C2 C2 C1

1 1 1
m 1
 mC1 m
C0  mC1 C0
m m m 1
C2 C1  mC2 C1

1 1 1
m1
 mC1 m
C0 C0 {Applying C2  C2  C1 }
m m m1
C2 C1 C1

 mC0 m1C1  m1

C0 mC1

 m 1 m
1
69. We have,  an21  an an 2

 2 log an 1  log an  log an  2

Similarly

2 log an  4  log an 3  log an 5

2 log an  7  log an  6  log an 8

Substituting these values in second column of determinant, we get

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log an log an  log an 2 log an 2

1
  log an3 log an 3  log an5 log an5
2
log an6 log an6  log an8 log an8

1
  0   0 {using C2  C2  C1  C3 }
2
70. n

1
k
n n
n n

 Dk  56   2k n2  n  1 n 2  n  56
k 1 k 1
n

  2k  1 n2 n2  n  1
k 1

n n n
Or n  n  1 n2  n  1 n2  n  56
n2 n2 n2  n  1

Applying C3  C3  C1 and C2  C2  C1 , we get

n 0 0
n  n  1 1 0  56 or n  n  1  56 or n  7
n2 0 n 1
71. A is involuntary. Hence

A2  I  A  A1
Also,

1 1 1
 kA   A
k
1
1  1
Or  A   2  A  or 2A
2 
72. 1 0   0 tan  / 2 
Since I    and given A    tan  / 2
0 1   0 

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 1  tan  / 2 
I  A    ............ 1
 tan  / 2 1 

cos   sin  
Now,  I  A  
 sin  cos  

 1 tan  / 2   cos   sin  

  tan  / 2 1   sin  cos  


IA
73. Since the product matrix is 3  3 matrix and the pre-multiplier of A is a 3  2 matrix,
therefore A is 2  3 matrix. Let

l m n 
A
x y z  . Then the given equation becomes
 

 2 1  1 8 10 
1 0  l m n 
  1 2 5 
   x y z   
 3 4   9 22 15 

 2l  x 2m  y 2n  z   1 8 10
Or  l m n    1 2 5 
   
 3l  4 x 3m  4 y 3n  4 z   9 22 15 

Or 2l  x  1, 2m  y  8, 2 n  z  10, l  1, m  2, n  5

 x  3, y  4, z  0, l  1, m  2, n  5

l m n  1 2 5
 A   3 4 0 
 x y z   
74. Given A is skew-symmetric. Hence,

AT   A
n n T
 An    AT     AT     An  (given n is odd)

Hence, An is skew-symmetric
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75. A2  A  I  0

Or I  A  A2

IA1  AA1  A2 A1

A1  I  A
76. Since the system has non-trivial solution, we have

a 1 1
1 b 1 0
1 1 c

Applying R1  R1  R2 , R2  R2  R3 , we get

a 1 1 b 0
 0 b 1 1  c  0
1 1 c

Or c 1  a 1  b   1  b 1  c   1  c  a  1  0

Dividing throughout by 1  a 1  b 1  c  , we get

c 1 1
  0
1 c 1 c 1 b
1 1 1
Or 1    0
1 c 1 b 1 a
1 1 1
  1
1 c 1 a 1 b
77. 1 1 1
The given system of linear equations has a unique solution if 1 2 3  0
2 5 

i.e if   8  0 or   8

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78.  1 1
For no solution or infinitely many solutions 1  1  0
1 1 

 
Or   2  1  1  1  11     0

 
Or   2  1  2  2  0

Or    1  1  2(  1)  0

 
Or   1  2    2  0

Or   1  2   1  0

2
Or   1   2   0

Or   1,1, 2
79. 1 1 1
The given system is consistent. Therefore,   2 1 c  0
b 3b c

Or c  bc  6b  b  2c  3bc  0

Or 3c  4bc  5b  0

5b
Or c 
4b  3
Now, c  1

5b
 1
4b  3
5b
Or 1  0
4b  3

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b 3
Or 0
4b  3

 3 
 b    ,3 
 4 
80. For non-trivial solution

a 1 1 1
1   b  1 1 0
1 1   c  1

a 1 1 0
Or 1   b  1 b  0
1 1 c

Or  a  1 bc  c  b   1 c  b   0

Or abc  ac  ab  bc  b  c  c  b  0

Or ab  bc  ac  abc
81. a1 a2 a3
We have D  5 4 a6 ,
a7 a8 a9

20 1
Since an  ;d 
n 20

20 20 1 1
20 1
3 3 2 3
3
20 20 20  20  4 2
Hence, D   1
4 5 6 47 5 3
20 20 20 7 7
1
7 8 9 8 9

R1  R1  R2 and R2  R2  R3

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50

21
D2
82. x  2 2 x  3 3x  4
  2 x  3 3x  4 4 x  5  0
3x  5 5 x  8 10 x  17

Applying R3  R3  R2 and R2  R2  R1

x2 2x  3 3x  4
  x 1 x 1 x 1 0
x  2 2  x  2 6 x  2

x  2 2 x  3 3x  4
   x  1 x  2  1 1 1 0
1 2 6

   x  1 x  2   x  2  .4   2 x  3 .5   3x  4  .1  0

   x  1 x  2  3x  3  0
2
Or  x  1  x  2  0
 x  1, 1, 2
83. Equation x 3  ax 2  bx  c  0 has roots  ,  ,  . Therefore,

      a

      b

Since the given system of equations has non-trivial solutions, we have

  
   0
  

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Or  3   3   3  3  0
2
Or       [       3      ]  0

 a  a 2  3b   0 or a 2 / b  3
84. System of equations

 x  y  z   1
x   y  z   1
x  y   z   1

Since system has no solution.

Therefore, 1   0 and  2    1  0

 1 1
1  1  0,   1
1 1 

R1  R1  R3 , R2  R2  R3

 1 0 1  
0  1 1    0
1 1 

  1,1, 2 or   1, 2

85.  1 tan x 
A
  tan x 1 

Hence, det . A  sec 2 x

 det AT  sec 2 x


Now f  x   det. AT A1 

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  det. AT  det. A1 

1
  det . AT   det . A 

det .  AT 
 1
det .  A 

Hence, f  x   1.
86. Given that AAT  4 I
2
 A  4  A  2

adjA
AT  4 A1  4
A

 a11 a21 a31   c11 c21 c31 

4
  a12 a22 a32   c12 c22 c32 
  A 
 a13 a23 a33   c13 c23 c33 

4
Now aij  cij
A

4
 2cij  cij  asaij  2cij  0 
A

 A  2

Now A  4 I  A  AAT

 A I  AT

 2 I  AT

 2 I  A

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 A  4I  2 A  I  0 ,

2
So on comparing, we get 5  2   
5
Hence, 10  4 `
87. 4ax 4 3bx3 2cx 2
Let f  x      dx
4 3 2

 f  0   0  f  3  c   0,3  f `  c   0
88. f a  h  f a 1
f ` a  h      2  1
h 2
89. 4
f `    0  8b  3c  16
3

f 1  f  2   3b  c  7

b  5, c  8  b  c  3
90. f b   f  a 
By LMVT  f `  c  
ba

f  6  f  2 
f 1 c  
62
1 20
  c3
2 c2 62

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