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Xi-Xii Centre Iit WPT 26.05.2025

The document contains a series of physics and chemistry problems designed for students in classes XI-XII, focusing on topics such as current electricity, resistance, and chemical reactions. Each question presents a scenario or concept, followed by multiple-choice answers. The problems require students to apply their understanding of physical laws and chemical principles to solve for unknowns or explain phenomena.

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0% found this document useful (0 votes)
18 views12 pages

Xi-Xii Centre Iit WPT 26.05.2025

The document contains a series of physics and chemistry problems designed for students in classes XI-XII, focusing on topics such as current electricity, resistance, and chemical reactions. Each question presents a scenario or concept, followed by multiple-choice answers. The problems require students to apply their understanding of physical laws and chemical principles to solve for unknowns or explain phenomena.

Uploaded by

Deena chemist
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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CLASS: XI-XII IIT WPT CENTRE DATE: 26.05.

2025

PHYSICS: CURRENT ELECTRICITY – I

1. A conductor with rectangular cross section has


dimensions (a × 2a × 4a) as shown in figure.
Resistance across AB is x, across CD is y and
across EF is z. Then
a) = = b) > >
c) > > d) > >

2. The current voltage graph for a given metallic conductor at two different
temperatures T1 and T2 are as shown in the figure. Then:-
a) >
b) −
c) nothing can be said about T1 and T2
d) <

3. The resistance across P and Q in the given figure is


a)
b)
c) 2R
d) 6R

4. Thirteen resistances each of resistance R are


connected in the circuit as shown in the figure. The effective
resistance between A and B is :-
a) Ω b) 2 Ω
c) Ω d) Ω

5. In the circuit shown in the figure, if the potential at


point A is taken to be zero, the potential at point B
is:-

a) + 1V b) – 1 V
c) + 3V d) – 3V

1
6. In the circuit shown the cells A and B have negligible
resistances. For VA = 10V, R1 = 300 and R = 200 the
galvanometer (G) shows no deflection. The value of VB
is:-
a) 12 V b) 6 V
c) 4 V d) 2 V

7. Five equal resistances each of resistance R are connected as


shown in the figure. A battery of voltage V is connected
between A and B. The current flowing in AFCEB will be
a) b)
c) d)

8. Eels are able to generate current with biological cells


called electroplaques. The electroplaques in an eel
are arranged in 100 rows, each row stretching
horizontally along the body of the fish containing
5000 electroplaques. The arrangement is suggestively
shown below. Each electroplaques has an emf of 0.15
V and internal resistance of 0.25. The water
surrounding the eel completes a circuit between its
head and its tail. If the water surrounding it has a resistance of 500, the current an eel can
produce in water is about :-
a) 1.5 A b) 3.0 A c) 15 A d) 30 A

9. The potential difference (VA – VB) between the points A and B in the given figure is:-

a) + 6V b) + 11V c) – 11V d) + 3V

10. In the circuit shown, if a conducting wire is connected between


points A and B, the current in this wire will:-
a) flow from A to B
b) flow in the direction which will be decided by the value of V
c) be zero
d) flow from B to A
11. For the network of resistance shown in the fig. the equivalent
resistance of the network between the points A and B is 18. The value of unknown
resistance R is:-

2
a) 8 b) 10  c) 16  d) 24 

12. In the circuit shown the equivalent


resistance between A and B is

a) R b) 2R/5
c) R/3 d) 2R

13. If a wire is stretched, so that its length is 20% more than its initial length, the percentage
increase in the resistance of the wire is:-
a) 40% b) 10% c) 44% d) 25%

14. Two metal wires of identical dimensions are connected in series. If 1, and 2 are the
resistivity of the metal wires respectively, the effective resistivity of the combination is :-
a) b) c) d) +

15. Two wires each of radius of cross section r but of different materials are connected together
end to end (in series). If the densities of charge carriers in the two wires are in the ratio 1:4,
the drift velocity of electrons in the two wires will be in the ratio :
a) 1 : 2 b) 2 : 1 c) 4 : 1 d) 1 : 4

16. A wire has a non-uniform cross-section as shown in figure. A


steady current flows through it. The drift speed of electrons at
points P and Q is vp and vQ, then :-
a) = b) < c) >
d) data is insufficient

17. Assertion (A): A displacement can be added with a distance.


Reason (R): Adding a scalar to a vector of the same dimensions is a meaningful algebraic
operation.
a) Both (A) & (R) are true and the (R) is the correct explanation of the (A)
b) Both (A) & (R) are true but the (R) is not the correct explanation of the (A)
c) (A) is true but (R) is false d) Both (A) and (R) are false

18. Assertion (A): Mass, length and time may be taken as fundamental quantities.
Reason (R): Mass, length and time are independent of one another.
a) Both (A) & (R) are true and the (R) is the correct explanation of the (A)
b) Both (A) & (R) are true but the (R) is not the correct explanation of the (A)
c) (A) is true but (R) is false d) Both (A) and (R) are false
3
19. Match List – I with List – II.
List – I List – II
a) Resistivity e) Volt
b) Conductivity f) Siemen
c) emf g) ohm – metre
d) Conductance h) mho – metre–1
a) a – e, b – f, c – g, d – h b) a – f, b – e, c – g, d – h
c) a – g, b – h, c – e, d – f d) a – h, b – g, c – e, d – f

20. Six batteries of increasing emf and increasing internal resistance are as shown in figure.

Table – 1 Table – 2
a) Potential of point A p) Zero
b) Potential of point B q) 2V
c) Potential of point C r) 4V
d) Potential of point D s) 6V
t) None
a) a – p, b – p, c – p, d – p b) a – p, b – s, c – q
c) a – q, b – q, c – s d) a – r, b – r, c – p

21. The value of current I for the given circuit is ____ A.

22. The resistances of the four arms P, Q, R and S in a Wheatstone bridge are 1 ohms, 3 ohms,
3 ohms and 9 ohms, respectively. The e.m.f. and internal resistance of the cell are 7 volts
and 4 ohms respectively. If the galvanometer resistance is 50 ohms, the current drawn from
the cell will be _____ A.

23. In the following circuit diagram the value of resistance X for


the potential difference between B and D to be zero is _____
ohms.

4
24. In the part of a circuit shown in figure, the potential different
(VG – VH) between points G and H will be ______ V.

25. Electric current through the battery is ____ A.

CHEMISTRY

26. Assertion: During reaction of carboxylic acids with NaHCO 3, the CO2 evolved comes
from carboxylic acid and not from NaHCO3.
Reason: Carbonic acid is a stronger acid than carboxylic acid.
(a) Both A and R are correct and R is the correct explanation of A.
(b) Both A and R are correct but R is not correct explanation of A.
(c) A is correct but R is incorrect.
(d) Both A and R are false.

27. C6 H 6 HNO
3  P Sn
/ HCl
 Q NaNO
2  P H  S The end product S in the
3 PO 2

H 2 SO 4 HCl H 2O
given sequence of reaction of reactions is
(a) Benzoic acid (b) Benzene (c) Phenol (d) Chlorobenzene

28. Consider the following reaction :

 X II   Y AgOH
CONH2 I. CH 3I ( excess)
Br
2 ,
KOH  Z
. NaOH Heat
The final product Z is -

(a) CON(CH3)2 (b) N(CH3)2 (c) (d)

29. Methyl ethyl propyl amine forms non-super imposable mirror images but it does not
show optical activity because
(a) Of rapid flipping (b) Amines are basic in nature
(c) Nitrogen has a lone pair of electrons (d) Of absence of asymmetric nitrogen

5
30. Match the column I with column II and mark the appropriate choice.
Column I Column II
(A) RCOCH 3  Zn  Hg (i) Kolbe’s reaction
HCl

RCH 2 CH3
(B) 2C 6 H 5 CHO  
NaOH
(ii) Clemmensen
C6 H5COONa  C6 H5CH 2 OH Reduction
(C) C 6 H 6  CH 3 COCl AnH
.  (iii) Friedel-crafts
AlCl 3
reaction
(D) C6 H5OH  CO2  NaOH (iv) Cannizzaro
 HOC6 H 4 COONa Reaction

(a) (A)  (i), (B)  (iv), (C)  (iii), (D)  (i)


(b) (A)  (i), (B)  (iii), (C)  (ii), (D)  (iv)
(c) (A)  (iii), (B)  (ii), (C)  (i), (D)  (iv)
(d) (A)  (iv), (B)  (i), (C)  (ii), (D)  (iii)

31. Match the compounds given in column I with column II and mark the appropriate
choice.
Column I Column II
(A) Benzenesulphonyl chloride (i) Zwitter ion
(B) Sulphanilic acid (ii) Hinsberg reagent
(C) Alkyldiazonium salts (iii) Dyes
(D) Aryldiazonium salts (iv) Conversion to alcohols
(a) (A)  (iv), (B)  (iii), (C)  (i), (D)  (ii)
(b) (A)  (ii), (B)  (iv), (C)  (iii), (D)  (i)
(c) (A)  (ii), (B)  (i), (C)  (iv), (D)  (iii)
(d) (A)  (ii), (B)  (iii), (C)  (iv), (D)  (i)

32. In the given transformation, which of the following is the most appropriate reagent?

(a) Zn-Hg/HCl (b) Na, liq. NH3 (c)NaBH4 (d) NH2 - NH2, OH-

33. Treatment of cyclobutylmethylamine with nitrous acid does not give:

(a) (b) (c) (d)

6
34. When benzene or its derivative is treated with carbon monoxide and hydrogen
chloride in the presence of anhydrous aluminium chloride, it gives
(a) Benzaldehyde (b) Benzophenone (c)Benzyl alcohol (d) Benzalchloride

35. The product obtained when phenol reacts with benzene diazonium chloride is
(a) Phenyl hydroxylamine (b) Para-aminoazobenzene
(c) Phenylhydrazine (d) Para-hydroxyazobenzene

36. Consider the following diazonium ions :

Me2N N2+ O2N N2+ CH3O N2+ CH3 N2+

(I) (II) (III (IV)


)
The order of reactivity towards diazo-coupling with phenol in the presence of
dil. NaOH is -
(a) I < IV < II < III (b) I < III < IV < II (c) III < I < II < IV (d) III < I < IV < II
37. Identify the compounds (X) (Y) and (Z) in the following reactions:
CH 3OH , H 
CH 3 Br  
 x  y  
Mg / ether ( i ) CO 2
( II) water 

(a) (x)  CH3 MgBr, (Y)  CH3COOH, (Z)  CH3COOCH3


(b) (X)  CH3CH 2 Br, (Y )  CH 3 CH 2 OH, (Z)  CH3CH 2 CH 2 CH3
(c) (x )  CH3 CH2 MgBr, (Y)  CH3 CH2 COCH3 (Z)  CH3CH 2 COCH3
(d) (x )  CH3COOH, (Y)  CH3 CH 2COCH3 , (Z)  CH 3COOCH3

38. Correct order of increasing basicity


(a) NH3 C6H5NH2 (C2H5)2NH  C2H5NH2 (C2H5)3N
(b) C6H5NH2 NH3 (C2H5)3N  (C2H5)2NH  NH3
(c) C6H5NH2 NH3 (C2H5)3N  (C2H5) NH  (C2H5)2NH2
(d) C6H5NH2 (C2H5)3N  NH3 C2H5NH2 (C2H5)2NH

39. Imine formation using an aldehyde/ketone and primary amine is acid-catalyzed, yet
the rate drops below pH 4.5. Why does the rate drop below this pH?
(a) The carbinolamine intermediate is stable at low pH
(b) The imine product is hydrolyzed at low pH
(c) Protonation of the amine decreases its nucleophilicity
(d) The amine is hydrolyzed at low pH.

40. A compound (X) with a molecular formula C5 H10 O gives a positive 2,4- DNP test but a
negative Tollen’s test. On oxidation it gives a carboxylic acid (Y) with a molecular
formula C 3 H 6 O 2 . Potassium salt of (Y) undergoes kolbe’s reaction and gives a
hydrocarbon (Z) (X), (Y) and (Z). respectively are

7
(a) Pentan-3-one, propanoic acid, butane
(b) Pentanal, pentanoic acid, octane
(c) 2-methylbutanone, butanoic acid, hexane
(d) 2,2-dimethylropanone, propanoic acid, hexane

41. Match the column I with column II and mark the appropriate choice.

Column I Column II
(A) (i) Coupling reaction

(B) (ii) Balz-sChiemann


reaction

(C) (iii) Gatterman


reaction

(D) (iv) Sandmeyer


reaction

(a) (A) (iv), (B) (iii), (C) (ii), (D) (i)


(b) (A) (iii), (B) (iv), (C) (i), (D) (ii)
(c) (A) (ii), (B) (iii), (C) (iv), (D) (i)
(d) (A) (i), (B) (ii), (C) (iii), (D) (iv)

42. The final product (C) obtained in the reaction sequence is.
  (C)
NH 2NH 2
CH 3 CH 2 COOH ( A) C
PCl 3
( B)
6 H6 base,heat
AlCl 3

(a) (b)

(c) (d)

8
43. Match the column I with column II and mark the appropriate choice.
Column I Column II
(A) Reaction of (i) Sandmeyer
benzene diazonium chloride reaction
with cuprous salts dissolved
in the halogen acid
(B) Reaction of benzene (ii) Gatterman
Diazonium chloride with Reaction
halogen acid in the
presence of copper powder
(C) Reaction of amines with (iii) Hinsberg’s
chloroform reaction
(D) Reaction of (iv) Carbylamine
amines with benzene reaction
sulphonyl chloride

(a) (A) (i), (B) (ii), (C) (iii), (D) (iv)


(b) (A) (iv), (B) (iii), (C) (ii), (D) (i)
(c) (A) (iii), (B) (iv), (C) (i), (D) (ii)
(d) (A) (i), (B) (ii), (C) (iv), (D) (iii)

44. Assertion: Carbon−oxygen bond length in formic acid are 1.23 Å and 1.36 Å.
Reason: Formic acid gives rise to nucleophilic.
(a) Both A and R are correct and R is the correct explanation of A.
(b) Both A and R are correct but R is not correct explanation of A.
(c) A is correct but R is incorrect.
(d) Both A and R are false.

45. The appropriate reagent for the transformation

(a) Zn(Hg),HCl (b) NH2NH2,OH- (c)H2/Ni (d) NaBH4

46. On electrolysis of aqueous solution of sodium butanoate gives a hydrocarbon. The


number of carbon atoms present in hydrocarbon are_____________.

47. Among the following compounds how many will give silver mirror with ammoniacal
silver nitrate
A. Formic acid B. Formaldehyde C. Benzaldehyde D. Acetone

48. How many of the following reactions are used in the preparation of aliphatic primary
amines
A. Gabriel-phthalimide reaction B. Hoffmann Bromamide reaction
C. Carbylamine reaction D. Sandmayer reaction

9
49. An aromatic compound 𝐴(C7 H9 N) on reacting with NaNO2 /HCl at 0∘ C forms benzyl
alcohol and nitrogen gas. The number of isomers possible for the compound 𝐴 is ___.

50. Maximum number of molecules of CH3 I that can react with a molecule of CH3 NH2
are _____.

MATHS
1
   
51.  1  2 tan x(tan x  sec x) 2 dx   where x   0, 2  
  
1) log |sec x (sec x - tan x) | + c 2) log |sec x (sec x + tan x)| +c

sec x
3) log c 4) log |cos x(Sec x+Tan x )| + c
sec x  tan x

x 2  1 log  x 2  1  2log x 
52.  dx is equal to
x4

3/ 2 3/ 2
x 2
 1 2  x2  1  x 2
 1   x2  1  2 
1)   log  2    c 2) log  2     c
x3 3  x  3x3   x  3
3/2 3/ 2
2  x2 1  1 1  x 2  1  x 2
 1   x2  1  2 
3)   log  2   c 4) log  2     c
3x3  3 2  x  3x3   x  3

mx m  2 n 1  nx n 1
53.  2 m  2 n dx is equal to
x  2 x mn  1

xm xn x m n  1 xn
1) c 2) c 3) m  n c 4)  c
x m n  1 x m n  1 x 1 x m n  1

Cos x
54.  Cos 3x dx 
1 1  3 tan x
1 1  tan x 2) log c
1) log c 2 3 1  3 tan x
2 3 1  tan x

1 1  3 tan x 2 1  tan x
3) log c 4) log c
3 1  3 tan x 3 1  tan x

x x
55.   x   2 x log e x  x  dx is equal to

1) x x   C
x
x
2)  x x   C 3) x x .log e x  C
x
 
4) x  C

dx
56.  sin 1/ 2

x cos 7 / 2 x
2
2 2 2 2
tan x(5  tan 2 x )  c 4) tan x (5  tan 2 x)  c
1) (5  tan x)  c 2) tan x  c 3) 5
5 5 5

10
1
 x 6  log x dx 
57.
 2
 7log x  2 
2 log x  1 2 log x  1 2 log x  1 3log x  1
 C 2) log C 3) log  C 4) log C
1) log 3log x  2 2 log x  2
3log x  2 3log x  2

x1/ 2
58.  x1/ 2  x1/ 3 dx is equal to
5 2 1 1
5 2 1 1  1 
   x x6
x 3
x2
x3  16 
 x x x x x3 16
6 3 2  16  6
6      x  log x 1  C
1) 6  6  5  4  3  2  x  log  x 1  C 2)  6 5 4 3 2 
 
  
  
5 2 1 1
 1 
 5 2
1
1
 1
 x x 6
x 3
x 2
x 3
6
 16 
 x x x x x 6 3
6
 61 
2 3
4) 6  6  5  4  3  2  x  log  x 1  C
3) 6  6  5  4  3  2  x  log  x 1  C   

 
 

dx
 n  n  1 1  z n1 z n 1 
     C where
59.
 1  x2  x  2  n 1 n 1 

1) z  x  1  x 2 2) z  1  x 2  x 3) z  x  1  x 2 4) z  x  1  x 2

60. x2
Let f  x    dx and f  0   0....Then f 1 is
1  x  1  2
1  x2 

 
3 ) lo g 1  
2  4) log( 2  1)
1) log 1  2  
2) log 1  2   4
4

dx
61.  ( x  p) 
( x  p )( x  q)
1 xq
c
2 x p
c
2 xq
c 3) ( x  p )( x  q)  c 4)
x p
1) 2)
pq xq pq x p

1
62. If  f  x  dx  g  x   c, then  f  x  dx is equal to

1 1
1) x f 1  x   c
1
2) f  g  x    c 3) x f  x   g  f  x    c 4) g 1  x   c

x 2  x sec 2 x  tan x   x2
63.  2
dx   f  x  c then f  x  
 x tan x  1 x tan x  1

1) log x sin x  cos x  c 2) log x cos x  sin x  c 3) 2 log x sin x  cos x  c 4) 2 log x cos x  sin x  c

x
  2
1  Sin x
64. If x   0,  then  e dx =
 2 1  Cos x
x x
x x x x
x / 2 x 3) e 2 Sec  c 4)  e 2 Sec  c
1) e Sec  c 2
2)  e Sec  c 2 2
2 2

11
2
65.  x e 5 x Sin 4 x 2 dx = Ke 5 x A Sin 4 x 2  B Cos 4 x 2   c then ( K , A, B) (Where K  0) =
2

1 1 1 1 1 1
1) , 5, 4 2) , 5, 4 3) , 5,  4 4) , ,
82 82 82 82 5 4
x3  1
66.  d x equal to
x3  x
1
1) x  log x  log( x 2  1)  tan  1 x  c 2) x  log x  log( x 2  1)  tan 1 x  c
2
1 2 1
3) x  log x  log( x  1)  tan x  c 1 2 1
2 4) x  log x  log( x  1)  tan x  c
2
xm
I =   log x n dx then
67. If m ,n
 m1 Im,n nI. m,n1 
xm xm x m1 x m1
1) 2)  3)  4)
log x n log x n log x n log x n
dx x 
68. If  1  sin x  tan  2  k   b, then k 
5 
  3) 4)
1)  2) 4 4
4 2

69. If f  x  
x 2
 sin 2 x 
sec2 x dx and
f  0   0 then f 1 
2
1 x
   
1) 1  2) 1 3) tan1  4)  tan1
4 4 4 4
4e x  6e  x
70. If  x x
dx  ax  b log (9e 2 x  c)  d , then descending order of a,b, c, is
9e  4e
1) a, b, c 2) b,c,a 3) b, a, c 4) c, a, b

2 
71. If . denotes greatest integer function and x   ,1 and
5  3x dx  k log x  2  c
3   x2
then K=

5 tan x
72. If  tan x  2 dx  x  a log sin x  2cos x  k then a is equal to

 l  x  2 
1/ 8
dx
73.  x  2  c then l+m=
m  x3
7 /8 9/8
 x  3
e2 x
74.  e
2x
 3 Cos x  Sin x dx   2 3 1 Cos x  3  2 Sin x  c then l =
   
l
dx 1 x6  1 1  12 
75. The value of  x  x 13 6 is  log  x 6
 x   c then l =
1 l  x6 2 

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