0% found this document useful (0 votes)
15 views10 pages

TEST Biomolecules and Amines

The document is a chemistry test paper focused on amines and biomolecules, featuring multiple-choice questions related to various chemical reactions and processes. It includes questions on nitrene intermediates, Hoffmann bromamide process, Hinsberg reagent reactions, and oxidation reactions involving amines. The paper is designed for NEET 2021 preparation and covers a range of topics in organic chemistry.

Uploaded by

vivekcharan232
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
0% found this document useful (0 votes)
15 views10 pages

TEST Biomolecules and Amines

The document is a chemistry test paper focused on amines and biomolecules, featuring multiple-choice questions related to various chemical reactions and processes. It includes questions on nitrene intermediates, Hoffmann bromamide process, Hinsberg reagent reactions, and oxidation reactions involving amines. The paper is designed for NEET 2021 preparation and covers a range of topics in organic chemistry.

Uploaded by

vivekcharan232
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 10

All India Test and Discussion Series : Test-27 / [Paper] CRACK NEET 2021 / TD / 28 -May-2021

CHEMISTRY : Amies & Biomolecules


46. Nitrene as an intermediate formed in the following 46. bues
al sfdl vfHkfØ; kes
aukbVªhu , d b.VjehfM,V ds:i es
a
reaction: feyrkgS%
(1) Curtius reaction (1) dfV;Zl vfHkfØ; k
(2) Schmidt reaction (2) fLeMV vfHkfØ; k
(3) Hoffmann bromamide process (3) gkW
iQ
eS
u cz
ke
skekbMfof/
(4) All (4) mi jksDr l Hkh
47. In Hoffmann Bromamide process the sequence of 47. gki Q
eS
u czks
es
ekbMi zfØ; k l s10 , ehu cukuses
acuusokys
intermediate formed in formation of 10 amine : b.VjehfM,V dkl ghØe gS%

 (1) RCON : , R–NCO, RCONHBr
(1) RCON : , R–NCO, RCONHBr
(2) RCONHBr, R–NCO, RCON
(2) RCONHBr, R–NCO, RCON
(3) RCONHBr, RCON, RNCO
(3) RCONHBr, RCON, RNCO
(4) RCON< RCONHBr, RNCO
(4) RCON< RCONHBr, RNCO
aq. KOH
aq. KOH 48. A  Hinsberg Reagent 
B   C
(Amine) (water soluble)
48. A  Hinsberg Reagent 
B   C
(Amine) (water soluble)

A o B Øe' k%gks
xsa%
A and B will be respectively :
(1) 10 , ehu vkS
j N, N-MkbZ
, Ydkby csUt hu l Yi Q
ksukekbM
(1) 10 amine and N, N-dialkyl benzene sulphonamide
(2) 10 , ehu vkS
j N-, YgkbMcsUt hu l Yi Q
ksukekbM
(2) 10 amine and N-alkyl benzene sulphonamide
(3) 20 , ehu vkS
j N, N-MkbZ
, YdkbMcsUt hu l Yi Q
ksukekbM
(3) 20 amine and N, N-dialkyl benzene sulphonamide

(4) Both 1 and 3 (4) nksuks1 vkjS3


49. 30 amine can not react with : 49. 30 , eh
u bues
al sfdl dsl kFkvfHkfØ; kughns
r k%
(1) Hinsberg reagent (1) fga
l cxZvfHkdkjd
(2) Hoffmann reagent (2) gkW
iQ
eS
u vfHkfdkjd
(3) Schiff’s reagent (3) fl i QvfHkdkjd
(4) All of these (4) mi jksDr l Hkh
50. In Hoffmann's mustard oil reaction, product will 50. gkW
iQ
eS
u eLVMZvk; y vfHkfØ; kes
amRikn gks
xk%
be :

(1) Alkyl thiocyanate


(1) , Ydkby Fkk; kslkbusV

(2) Alkyl isothiocyanide


(2) , Ydkby vkbl kF
skk; kslkbukbM
(3) Alkyl isothiocyanate (3) , Ydkby vkbl ksFkk; kslkbusV
(4) Alkyl thiocyanide (4) , Ydkby Fkk; kslkbukbM
51. Anils are formed when benzaldehyde react with : 51. , fuYl cursgSt c cs
fUt yMhgkbMfuEu l sfØ; kdjrkgS
%
(1) 10 amine (1) 10 , ehu

(2) 20 amine (2) 20 , ehu


(3) 30 amine (3) 30 , ehu
(4) all of these (4) mi jksDr l Hkh
13
All India Test and Discussion Series : Test-27 / [Paper] CRACK NEET 2021 / TD / 28 -May-2021
52. On oxidation with KMnO4 20 amine give : 52. KMnO4 dsl kFkvkDl h
dj.kl s20 , ehu ns
r sgS%
(1) Tetra alkyl hydrazine (1) VsVªk, YdyhgkbMªkt hu
(2) Aldimine (2) , YMhekbu
(3) Ketimine (3) dhVhehu
(4) Dialkyl hydrazine (4) M kbZ
, Ydhy gkbMªkt hu
53. The amine formed, with one less carbon in the 53. , d de dkcZ u dh, ehu fuEu esal sfdl vfHkfØ; kl scurh
reaction: gS%
(1) Schmidt reaction (1) fLeM j vfHkfØ; k
(2) Hoffmann Bromide reaction (2) gki QeSu czksekbZ
MvfHkfØ; k
(3) Curtius reaction (3) dfVZ ;ª l vfHkfØ; k
(4) All of these (4) mi jksDr l Hkh
NH2 NH2
CF3 COOH
54.   
[O]
X, Here X will be : 54. CF3 COOH
  X, ; gkaX gS%
[O]

ONO ONO
(1) (1)

NO2 NO2
(2) (2)
F F
NO2 NO2
(3) (3)

F NH2 F NH2
(4) (4)

NH2 NH2
(i) conc. HNO3
(i) conc. HNO3
acetylation conc. H2SO4
55.  A 
B  C (ii) H2 O 55. acetylation
 conc. H2SO4
A  B  C

(ii) H2 O

B, C, A respectively will be :
B, C, A Øe' k%gS%
NHCOCH3 NH2 NH2
NHCOCH3 NH2 NH2
NO2
NO2
(1) , ,
(1) , ,
NO2
NH2 NH2 NO2
NHCOCH3 NH2 NH2
NO2 NHCOCH3
NO2
, ,
(2) , ,
(2)
NO2
NO2
NH2 NH2 NHCOCH3
NH2 NH2 NHCOCH3
NO2
NO2
, ,
(3) , ,
(3)
NO2
NO2
NHCOCH3 NH2 NH2 NHCOCH3 NH2 NH2

(4) , , , ,
(4)
NO2 NO2
14
All India Test and Discussion Series : Test-27 / [Paper] CRACK NEET 2021 / TD / 28 -May-2021
[H] C2 H5 ONa [H] C2 H5 ONa
R  CN  A R  CN  A
56. [H] C2 H5 ONa 56. [H] C2 H5 ONa
R  NC  B R  NC  B

Product A and B will be respectively : mRikn A o B Øe' k%gks


xsa%
(1) R–NH–CH3 & RCH2NH2 (1) R–NH–CH3 & RCH2NH2
(2) RCH2NH2 & RNHCH3 (2) RCH2NH2 & RNHCH3
(3) RCH2NH2 & RN(CH3)2 (3) RCH2NH2 & RN(CH3)2
(4) RNH–CH3 & RCH2 NH (4) RNH–CH3 & RCH2 NH

Partial Hydrolysis
57. R–CN   A , Product A will be : Partial Hydrolysis
57. R–CN  A , mRikn A gS%
(1) RCOOH (1) RCOOH
(2) RCH2NH2 (2) RCH2NH2
(3) RCONH2 (3) RCONH2
(4) RCHO (4) RCHO

Fe/Steam Fe/Steam
NO2 A NO2 A
Zn / NH4Cl Zn / NH4Cl
58. B 58. B
Fe/HCl Fe/HCl
C C
Product C, B, A respectively will be :
mRikn C, B, A Øe' k%gks
xsa%
NO NHOH NH2
NO NHOH NH2
(1) , ,
(1) , ,
NO NH2 NHOH
NO NH2 NHOH
(2) , ,
(2) , ,
NH2 NHOH NO
NH2 NHOH NO
(3) , ,
(3) , ,
NHOH NH2 NO
NHOH NH2 NO
(4) , ,
(4) , ,
NO2
Na3AsO3 + NaOH NO2
A Na3AsO3 + NaOH
59. A
SnCl2 + NaOH 59.
B SnCl2 + NaOH
B
In product A and B the basic functional group will
be respectively : mRikn A vkS
j B es
ai k; st kusokysfØ; kRed l ew
g Øe'k%gS
%
O O
(1) –N=N–, –N=N– (2) –N=N–, –NH–NH– (1) –N=N–, –N=N– (2) –N=N–, –NH–NH–

O O O O
(3) –N=N–, –NH–NH– (4) –N=N–, –N=N– (3) –N=N–, –NH–NH– (4) –N=N–, –N=N–

15
All India Test and Discussion Series : Test-27 / [Paper] CRACK NEET 2021 / TD / 28 -May-2021

NO2 NO2
(NH4 )2 S HNO2 H3PO2 (NH4 )2 S HNO2 H3PO2
60.   A 
0 50 C
 B  C 60.   A 
0 50 C
 B  C
NO2 NO2

Product A, B and C respectively will be : mRikn A, B vkS


j C Øe' k%gks
xsa%
NH2 N2Cl
NH2 N2Cl
(1)
, , (1)
NH2 NH2 NH2 , ,
NH2 NH2 NH2

NH2 N2Cl
NH2 N2Cl
NO2
NO2
(2)
, , (2)
NO2 NO2 , ,
NO2 NO2

NH2 N2Cl
NH2 N2Cl
NO2
NO2
(3)
, , (3)
NO2 NH2 , ,
NO2 NH2

NH2 NH2
NH2 NH2
(4)
, , (4)
NH2 N2Cl N2Cl , ,
NH2 N2Cl N2Cl

N2Cl
Aniline N2Cl
+ Dye-1 Aniline
H Dye-1
61. H
+
Phenol 61.
– Dye-2 Phenol
OH – Dye-2
OH

The color of Dye-1 and Dye-2 respectively : MkbZ


-1 o M
kbZ
-2 dsja
x Øe' k%gks
xsa%
(1) Yellow, Green (1) i hyk] gjk
(2) Yellow, Orange (2) i hyk] ukja
xh
(3) Orange, Yellow (3) ukja
xh] i hyk
(4) Green, Yellow (4) gjk] i hyk
62. Which of the following is correct for glucose : 62. Xyw
d ks
t dsfy, fuEu es
al sdkS
u l kl ghgS%
(1) Glucose give 2,4-DNP test (1) Xyw
d kst 2,4-DNP i jh{k.kns
r kgS
(2) does not form the hydrogen sulphite additon product (2) gkbMkªst u l Yi Q
kbM; q
Xed mRikn ughnsrkgS
(3) It give schiff's test (3) ; g f' ki Qi jh{k.knsrkgS
(4) All are correct (4) mi jkD
sr l Hkhl R; gS
63. In six memberd ring formation of glucose The 63. Xyw
d ks
t es
afl Dl es
EcMZfja
x es
] buj gS
eh,l hVy es
a–OH xzq
i
–OH group involved in inner hemiacetal is from : vkrkgS%
(1) C1 (2) C3 (1) C1 (2) C3

(3) C5 (4) C4 (3) C5 (4) C4


16
All India Test and Discussion Series : Test-27 / [Paper] CRACK NEET 2021 / TD / 28 -May-2021
64. In milk sugar linkage between : 64. nq
X/ ' kdZ
j kes
acU/ i k; st krsgS%
(1) C1 of glucose and C4 of galactose (1) Xyw
d kts dsC1 vkS
j XyS
DVkst dsC4 dseè;
(2) C1 of glucose and C2 of galactose (2) Xyw
d kts dsC1 vkS
j XyS
DVkst dsC2 dseè;
(3) C1 of galactose and C2 of glucose (3) XyS
DVkst dsC1 vkS
j Xyw
d kst dsC2 dseè;
(4) C1 of galactose and C4 of glucose (4) XyS
DVkst dsC1 vkS
j Xyw
d kst dsC4 dseè;
65. In the formation of osazone how many no. of 65. vks l kt ks
u dscuuses s
] iQs
fuy gkbMªkt hu dseks
yksdhl a
[;k
moles of phenyl hydrizine required per mole of i zfr Xyw d ks
t o i zQ
s
DVks
t ] Øe' k%gksxh%
glucose and fructose respectively :
(1) 3, 2
(1) 3, 2
(2) 2, 3
(2) 2, 3
(3) 3, 3 (3) 3, 3

(4) 2, 2 (4) 2, 2
66. How many amino acids are basic in nature as given 66. uhpsfn, x, vehuksvEy es
afdrus{kkjh; gS%
below :
Isoleucine, Asparagine, Cystine, Arginine
Isoleucine, Asparagine, Cystine, Arginine
(1) 1
(1) 1
(2) 2
(2) 2
(3) 3 (3) 3

(4) 4 (4) 4
67. In acidic and basic medium amino acid moves 67. vEyh; o {kkjh; ekè; e es
avehuksvEy Øe' k%fuEu dhvks
j
towards respectively : xfr djrsgS%
(1) anode and cathode (1) , uksMvkS
j dS
FkksM
(2) no movement (2) dksbZxfr ugh
(3) both move towards cathode (3) nksuksdS
FkksMdhr ji Qt k; sxsa
(4) cathode and anode (4) dS
FkksMvkS
j , uksM
68. The point at which pH range of amino acid in 68. vehuksvEy dht y es apH js
a
t dkog fcUnqft l i j ; s
water, it exist in zwilter ion form and can't move TohVj vk; u ds: i es
afeyrsgSvkS
j xfrghu gks
r sgSfcUnqdks
point called : dgrsgS %
(1) Isoelectronic point (1) vkbl kb
sysDVªksfud fcUnq
(2) Isoelectric point (2) vkbl ksbysfDVªd fcUnq
(3) Isotectic point (3) vkbl ksVsfDVd fcUnq
(4) Isometric point (4) vkbl ksesfVªd fcUnq

69. Solution + conc. HNO3   yellow color solution 69. foy; u + l kUnzHNO3 
 ih
ykja
x] foy; u es
agS%
have :
(1) Xyw
d kst
(1) Glucose
(2) Fructose
(2) i zQ
DVkst
(3) Protein (3) i zksVhu
(4) Fat (4) ol k
17
All India Test and Discussion Series : Test-27 / [Paper] CRACK NEET 2021 / TD / 28 -May-2021
70. When glucose oxidise with HIO4 the no. of moles 70. t c Xyw
d ks
t dksHIO4 }kjkvkDl hdr̀ fd; kt krkgSrkscuus
of formaldeh yde and fo rmic acid will be okysi Q
keZ
fYMgkbMo i Q
kfeZ
d vEy dseks yksdhl a[ ; kØe'k%
respectively : gks
xh%
(1) 1 & 5 (1) 1 & 5
(2) 1 & 3 (2) 1 & 3
(3) 5 & 1 (3) 5 & 1
(4) 3 & 1 (4) 3 & 1
71. Gluconic acid formed after oxidation of glucose 71. Xywd ks
t dsvkDl hdj.kl sXyw
fud vEy fuEu ds}kjkcus
xk%
with :
(1) VkW ysu vfHkdeZd
(1) Tollen reagent
(2) Br2 t y
(2) Br2 water
(3) i Qg
safya
x foy; u
(3) Fehling solution
(4) mi jksDr l Hkh
(4) All of these
O
O
NH
NH belong to the name : 72. lq
=k fuEu uke dksO;Dr djrkgS%
72. Structure N O
N O H
H
(1) fFk; kehu
(1) Thiamine
(2) ; wj kfl y
(2) Uracil
(3) l kbVks l hu
(3) Cytocine
(4) Fkkbfeu
(4) Thymine
73. Biuret test is not given by : 73. ckbZ
;wjs V Vs LV dkSu ughns
r kgS%
(1) proteins (1) i zksVhu
(2) carbohydrates (2) dkcz kg
skbMªsV
(3) polypeptides (3) i ksyhisIVkbM
(4) urea (4) ; fwj; k
74. Among the following compounds : 74. fuEu ; kS fxdksdk{kkjh; Øe gksxk%
NH2 NH2

i. ii. Et3N i. ii. Et3N

NO2 NO2 NO2 NO2

iii. iv. iii. iv.


NH2 NH2
NH2 NH2

the order of basicity is :


(1) iv > iii > ii > i
(1) iv > iii > ii > i
(2) ii > i > iii > iv
(2) ii > i > iii > iv
(3) iii > iv > ii > i
(3) iii > iv > ii > i
(4) i > iii > iv > ii (4) i > iii > iv > ii

18
All India Test and Discussion Series : Test-27 / [Paper] CRACK NEET 2021 / TD / 28 -May-2021
75. Aniline and methylamine can be differentiated by: 75. , uh yhu o es
fFku , ehu dksi gpku l drsgS%
(1) diazotisation followed by coupling with phenol
(1) MkbZ
, t ksuhdj.kdsckn i Q
huksy l s; q
Xed cukdj
(2) reaction with chloroform and aqueous solution of
KOH (2) DyksjksiQ
keZo t yh; KOH l svfHkfØ; kdjds
(3) reaction with HNO2 (3) HNO2 l sfØ; kdjds
(4) none of the above (4) dksbZugh
X
76. CH3  CH2 C  N 
 CH3CH2 CHO , Here X is :
76.
X
CH3  CH2 C  N  CH3CH2 CHO , ; gkW
X gS%
(1) SnCl2/HCl/H2O, boil (1) SnCl2/HCl/H2O, boil
(2) H2/Pd – BaSO4 (2) H2/Pd – BaSO4
(3) LiAlH4/ether (3) LiAlH4/ether
+
(4) NaBH4/ether/H3O (4) NaBH4/ether/H3O+
77. Hydrolysis of cyanogen gives : 77. l k; uks
tsu dkt y vi ?kVu djusi j ns
r kgS%
(1) oxalic acid + NH3 (1) vkW
Dt sfyd vEy + NH3
(2) oxalic acid
(2) vkW
Dt fsyd vEy
(3) NH3
(3) NH3
(4) Acetic ccid
(4) , fl fVd vEy
78. Identify the end product in the given sequence of
reactions : 78. nhxbZvfHkfØ; kvks
adkvfUre mRikn D; kgks
xk%

(i) CH CN
NBS
 X M
g / ether

(i) CH CN
 Y (ii)H33 Z NBS
 X M
g / ether
  Y (ii)H33
O
Z
O

COCH3 CN COCH3 CN

(1) (2) (1) (2)

COOH COOH COCH3


COCH3
(3) (4) (3) (4)

79. An organic compound 'A' having molecular 79. , d dkcZ fud ;kSfxd 'A' dkv.kq lq
=kC2H3N gSft l dkvi p;u
formula C 2H 3N on reduction gives another djusi j nq l jk; kS
fxd 'B' i zkIr gks
r kgSB dkukbVªl vEy ds
compound 'B'. Upon treatment with nitrous acid l kFkfØ;kdjkusi j , fFky , Ydks gky nsr kgSAft l dksDyks
jks
iQkeZ
'B' gives eth yl al coho l. On warming w ith
chloroform and alcoholic KOH, it forms an vkS j , Ydks
gkfyd KOH dsl kFkxeZdjusi j ; kS fxd 'C' dh
offensive semelling compound 'C'. The compound rh{k.kxa / nsr kgSA; kSfxd 'C' gS%
'C' is : (1) CH3NC
(1) CH3NC
(2) C6H5NC
(2) C6H5NC
(3) CH3C  N
(3) CH3C  N
(4) CH3CH2NC (4) CH3CH2NC
80. Compare boiling point of isomeric alkyl amines : 80. fuEu vkbl ks
es
fjd , fYdy , ehuksdsDoFkuka
d dkl ghØe gS
:
(1) 10 > 20 > 30 (1) 10 > 20 > 30
(2) 10 > 20 < 30 (2) 10 > 20 < 30
(3) 10 < 20 < 30 (3) 10 < 20 < 30
(4) 10 < 20 > 30
(4) 10 < 20 > 30
19
All India Test and Discussion Series : Test-27 / [Paper] CRACK NEET 2021 / TD / 28 -May-2021
81. Acetamide is treated with the following reagents 81. , l h vkekbMdksfofHkUu vfHkdeZ d dsl kFkfØ; kdjkusi j]
separately. Which one of these would yield methyl
amine :
fuEu es al sfdl l ses
fFky , ehu i zkIr gks
xk%
(1) PCl5 (1) PCl5
(2) NaOH/Br2
(2) NaOH/Br2
(3) Sodalime (3) l kM
skykbe
(4) Hot conc. H2SO4 (4) xeZr Fkkl kUnzH2SO4
HNO2 PCl3 NH3
82. C2H5NH2   A   B   C . Recognize the 82. HNO2
C2H5NH2  PCl3
 A  NH3
 B   C . ; kS
fxd 'C' gks
xk%
compound C from the following :
(1) i zkissuukbZ
Vªkby
(1) propanenitrile
(2) esfFky, ehu
(2) methylamine
(3) , fFky , ehu
(3) ethylamine
(4) acetamide (4) , fl VkekbM
83. Identify the product (E) in the following sequence 83. fuEu vfHkfØ; kes
al smRikn (E) dhi gpku dfj; s%
of reactions :
CH3
CH3 Br2 Sn /HCl NaNO2 /HCl H2 O/H3PO2 KMnO4
  A   B 
273278 K
 C  D 
OH
E
Br2 Sn /HCl NaNO2 /HCl H2 O/H3PO2 KMnO4
  A   B 
273278 K
 C  D 
OH
E
NO2
NO2
COOH
COOH
(1)
(1)

COOH
COOH Br
Br (2)
(2)

CH3
CH3 (3)
(3) Br
Br
CH3
CH3 (4)
(4) O 2N Br
O 2N Br
– +
OH O Na
OH

O Na
+ 84. CHCl3  NaOH 
84. CHCl3  NaOH  CHO
CHO
mi jks
Dr vfHkfØ; kes
ai z;q
Dr bys
DVªks
iQkby gks
xk%
The electrophilie involved in the above reaction
is : (1) VªkbZ
esa

fFky , uk; u(CCl3 )

(1) trichloromethyl anion (CCl3 ) 
(2) iQ
kfeZ
y dsVk; u(CHO)

(2) formyl cation (CHO) 
(3) MkbZ
DyksjksesfFky dsVk; u(CHCl2 )

(3) dichloromethyl cation (CHCl2 ) (4) MkbZ
Dyksjkd
s kchu
Z(:CCl2)
(4) dichlorocarbene (:CCl2)

20
All India Test and Discussion Series : Test-27 / [Paper] CRACK NEET 2021 / TD / 28 -May-2021
 
H2 O HCN H2 O / H H2 O HCN H2 O / H
85. CH  CH 
Hg2 H

CN excess
   ........ T he 85. CH  CH 
Hg2 H

CN excess
   ........ v fUr e
final product is : mRikn gks
xk%
O O
(1) CH3  C  NH2 (1) CH3  C  NH2
(2) CH3–CH2–COOH (2) CH3–CH2–COOH

(3) CH3  CH  CH3 (3) CH3  CH  CH3


CN CN
H H
(4) CH3  C  COOH (4) CH3  C  COOH
OH OH
86. Which one of the following statements about
CH3CN is not true :
86. fuEu es
al sdkS
u l kdFku CH3CN dsckjses
al ghughgS%
(1) Its IUPAC name is ethanenitrile (1) bl dkIUPAC uke , FksuukbVkby gS
(2) The bond between C and N is a triple bond (2) C vkjSN dschp f=kcU/ gksrkgS
(3) The C–C–N bond angle is 1800. (3) C–C–N dschp 1800 gS
(4) The carbon-carbon bond is shorter than the carbon-
nitrogen bond. (4) dkcZ
u&dkcZ
u cU/ dkcZ
u ukbZ
Vªkst u cU/ l sNksVkgkrskgS
i.NH3 NaNO2 NaOI
87. A i.NH3 NaNO2
 B  NaOI
 C  CH3COONa  CHI3 87. A   B 
ii.H2 /Ni HCl
 C  CH3COONa  CHI3
ii.H2 /Ni HCl

Recognize the compound A from the following : ; kS


fxd 'A' gks
xk%
(1) CH3CHO ((1) CH3CHO
(2) CH3CH2OH (2) CH3CH2OH
(3) CH3COCH3 (3) CH3COCH3
(4) CH3COOH (4) CH3COOH
88. Arrange the following in decreasing order of their
Pkb values : 88. fuEu dksmudsPkb eku ds?kVrsØe es
afy[ kks
a%
A. C6H5NH2 B. C2H5NH2 A. C6H5NH2 B. C2H5NH2
C. (C2H5)2NH D. NH3 C. (C2H5)2NH D. NH3
(1) A > D > C > B (1) A > D > C > B
(2) A > D > B > C (2) A > D > B > C
(3) B < C < D < A (3) B < C < D < A
(4) C > B > D > A (4) C > B > D > A
89. Among the following compounds, the most basic 89. fuEu ; kS
fxdks
aes
a
] l cl svf/ d {kkjh; dkS
u l kgS%
compound is :
(1) (2)
(1) (2)

(3) (4)
(3) (4)

21
All India Test and Discussion Series : Test-27 / [Paper] CRACK NEET 2021 / TD / 28 -May-2021
NO2 NO2
Zn /NH4 Cl Sn / HCl Zn /NH4 Cl Sn / HCl
90. Y    X 90. Y    X

X and Y are : X o Y gS%


(1) aniline, phenyl hydroxylamine (1) , uhyhu] i Q fsuy gkbMkªD Wl hy,ehu
(2) phenyl hydroxylamine, aniline (2) iQfsuy gkbMkªD Wl hy, ehu, , uhyhu
(3) aniline and hydrobenzene (3) , uhyhu vkjSgkbM kªcsU
st hu
(4) hydrobenzene and aniline (4) gkbM kªcsU
st hu vkjS, uhyhu

22

You might also like