TEST Biomolecules and Amines
TEST Biomolecules and Amines
A o B Øe' k%gks
xsa%
A and B will be respectively :
(1) 10 , ehu vkS
j N, N-MkbZ
, Ydkby csUt hu l Yi Q
ksukekbM
(1) 10 amine and N, N-dialkyl benzene sulphonamide
(2) 10 , ehu vkS
j N-, YgkbMcsUt hu l Yi Q
ksukekbM
(2) 10 amine and N-alkyl benzene sulphonamide
(3) 20 , ehu vkS
j N, N-MkbZ
, YdkbMcsUt hu l Yi Q
ksukekbM
(3) 20 amine and N, N-dialkyl benzene sulphonamide
ONO ONO
(1) (1)
NO2 NO2
(2) (2)
F F
NO2 NO2
(3) (3)
F NH2 F NH2
(4) (4)
NH2 NH2
(i) conc. HNO3
(i) conc. HNO3
acetylation conc. H2SO4
55. A
B C (ii) H2 O 55. acetylation
conc. H2SO4
A B C
(ii) H2 O
B, C, A respectively will be :
B, C, A Øe' k%gS%
NHCOCH3 NH2 NH2
NHCOCH3 NH2 NH2
NO2
NO2
(1) , ,
(1) , ,
NO2
NH2 NH2 NO2
NHCOCH3 NH2 NH2
NO2 NHCOCH3
NO2
, ,
(2) , ,
(2)
NO2
NO2
NH2 NH2 NHCOCH3
NH2 NH2 NHCOCH3
NO2
NO2
, ,
(3) , ,
(3)
NO2
NO2
NHCOCH3 NH2 NH2 NHCOCH3 NH2 NH2
(4) , , , ,
(4)
NO2 NO2
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All India Test and Discussion Series : Test-27 / [Paper] CRACK NEET 2021 / TD / 28 -May-2021
[H] C2 H5 ONa [H] C2 H5 ONa
R CN A R CN A
56. [H] C2 H5 ONa 56. [H] C2 H5 ONa
R NC B R NC B
Partial Hydrolysis
57. R–CN A , Product A will be : Partial Hydrolysis
57. R–CN A , mRikn A gS%
(1) RCOOH (1) RCOOH
(2) RCH2NH2 (2) RCH2NH2
(3) RCONH2 (3) RCONH2
(4) RCHO (4) RCHO
Fe/Steam Fe/Steam
NO2 A NO2 A
Zn / NH4Cl Zn / NH4Cl
58. B 58. B
Fe/HCl Fe/HCl
C C
Product C, B, A respectively will be :
mRikn C, B, A Øe' k%gks
xsa%
NO NHOH NH2
NO NHOH NH2
(1) , ,
(1) , ,
NO NH2 NHOH
NO NH2 NHOH
(2) , ,
(2) , ,
NH2 NHOH NO
NH2 NHOH NO
(3) , ,
(3) , ,
NHOH NH2 NO
NHOH NH2 NO
(4) , ,
(4) , ,
NO2
Na3AsO3 + NaOH NO2
A Na3AsO3 + NaOH
59. A
SnCl2 + NaOH 59.
B SnCl2 + NaOH
B
In product A and B the basic functional group will
be respectively : mRikn A vkS
j B es
ai k; st kusokysfØ; kRed l ew
g Øe'k%gS
%
O O
(1) –N=N–, –N=N– (2) –N=N–, –NH–NH– (1) –N=N–, –N=N– (2) –N=N–, –NH–NH–
O O O O
(3) –N=N–, –NH–NH– (4) –N=N–, –N=N– (3) –N=N–, –NH–NH– (4) –N=N–, –N=N–
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All India Test and Discussion Series : Test-27 / [Paper] CRACK NEET 2021 / TD / 28 -May-2021
NO2 NO2
(NH4 )2 S HNO2 H3PO2 (NH4 )2 S HNO2 H3PO2
60. A
0 50 C
B C 60. A
0 50 C
B C
NO2 NO2
NH2 N2Cl
NH2 N2Cl
NO2
NO2
(2)
, , (2)
NO2 NO2 , ,
NO2 NO2
NH2 N2Cl
NH2 N2Cl
NO2
NO2
(3)
, , (3)
NO2 NH2 , ,
NO2 NH2
NH2 NH2
NH2 NH2
(4)
, , (4)
NH2 N2Cl N2Cl , ,
NH2 N2Cl N2Cl
N2Cl
Aniline N2Cl
+ Dye-1 Aniline
H Dye-1
61. H
+
Phenol 61.
– Dye-2 Phenol
OH – Dye-2
OH
(4) 2, 2 (4) 2, 2
66. How many amino acids are basic in nature as given 66. uhpsfn, x, vehuksvEy es
afdrus{kkjh; gS%
below :
Isoleucine, Asparagine, Cystine, Arginine
Isoleucine, Asparagine, Cystine, Arginine
(1) 1
(1) 1
(2) 2
(2) 2
(3) 3 (3) 3
(4) 4 (4) 4
67. In acidic and basic medium amino acid moves 67. vEyh; o {kkjh; ekè; e es
avehuksvEy Øe' k%fuEu dhvks
j
towards respectively : xfr djrsgS%
(1) anode and cathode (1) , uksMvkS
j dS
FkksM
(2) no movement (2) dksbZxfr ugh
(3) both move towards cathode (3) nksuksdS
FkksMdhr ji Qt k; sxsa
(4) cathode and anode (4) dS
FkksMvkS
j , uksM
68. The point at which pH range of amino acid in 68. vehuksvEy dht y es apH js
a
t dkog fcUnqft l i j ; s
water, it exist in zwilter ion form and can't move TohVj vk; u ds: i es
afeyrsgSvkS
j xfrghu gks
r sgSfcUnqdks
point called : dgrsgS %
(1) Isoelectronic point (1) vkbl kb
sysDVªksfud fcUnq
(2) Isoelectric point (2) vkbl ksbysfDVªd fcUnq
(3) Isotectic point (3) vkbl ksVsfDVd fcUnq
(4) Isometric point (4) vkbl ksesfVªd fcUnq
69. Solution + conc. HNO3 yellow color solution 69. foy; u + l kUnzHNO3
ih
ykja
x] foy; u es
agS%
have :
(1) Xyw
d kst
(1) Glucose
(2) Fructose
(2) i zQ
DVkst
(3) Protein (3) i zksVhu
(4) Fat (4) ol k
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All India Test and Discussion Series : Test-27 / [Paper] CRACK NEET 2021 / TD / 28 -May-2021
70. When glucose oxidise with HIO4 the no. of moles 70. t c Xyw
d ks
t dksHIO4 }kjkvkDl hdr̀ fd; kt krkgSrkscuus
of formaldeh yde and fo rmic acid will be okysi Q
keZ
fYMgkbMo i Q
kfeZ
d vEy dseks yksdhl a[ ; kØe'k%
respectively : gks
xh%
(1) 1 & 5 (1) 1 & 5
(2) 1 & 3 (2) 1 & 3
(3) 5 & 1 (3) 5 & 1
(4) 3 & 1 (4) 3 & 1
71. Gluconic acid formed after oxidation of glucose 71. Xywd ks
t dsvkDl hdj.kl sXyw
fud vEy fuEu ds}kjkcus
xk%
with :
(1) VkW ysu vfHkdeZd
(1) Tollen reagent
(2) Br2 t y
(2) Br2 water
(3) i Qg
safya
x foy; u
(3) Fehling solution
(4) mi jksDr l Hkh
(4) All of these
O
O
NH
NH belong to the name : 72. lq
=k fuEu uke dksO;Dr djrkgS%
72. Structure N O
N O H
H
(1) fFk; kehu
(1) Thiamine
(2) ; wj kfl y
(2) Uracil
(3) l kbVks l hu
(3) Cytocine
(4) Fkkbfeu
(4) Thymine
73. Biuret test is not given by : 73. ckbZ
;wjs V Vs LV dkSu ughns
r kgS%
(1) proteins (1) i zksVhu
(2) carbohydrates (2) dkcz kg
skbMªsV
(3) polypeptides (3) i ksyhisIVkbM
(4) urea (4) ; fwj; k
74. Among the following compounds : 74. fuEu ; kS fxdksdk{kkjh; Øe gksxk%
NH2 NH2
18
All India Test and Discussion Series : Test-27 / [Paper] CRACK NEET 2021 / TD / 28 -May-2021
75. Aniline and methylamine can be differentiated by: 75. , uh yhu o es
fFku , ehu dksi gpku l drsgS%
(1) diazotisation followed by coupling with phenol
(1) MkbZ
, t ksuhdj.kdsckn i Q
huksy l s; q
Xed cukdj
(2) reaction with chloroform and aqueous solution of
KOH (2) DyksjksiQ
keZo t yh; KOH l svfHkfØ; kdjds
(3) reaction with HNO2 (3) HNO2 l sfØ; kdjds
(4) none of the above (4) dksbZugh
X
76. CH3 CH2 C N
CH3CH2 CHO , Here X is :
76.
X
CH3 CH2 C N CH3CH2 CHO , ; gkW
X gS%
(1) SnCl2/HCl/H2O, boil (1) SnCl2/HCl/H2O, boil
(2) H2/Pd – BaSO4 (2) H2/Pd – BaSO4
(3) LiAlH4/ether (3) LiAlH4/ether
+
(4) NaBH4/ether/H3O (4) NaBH4/ether/H3O+
77. Hydrolysis of cyanogen gives : 77. l k; uks
tsu dkt y vi ?kVu djusi j ns
r kgS%
(1) oxalic acid + NH3 (1) vkW
Dt sfyd vEy + NH3
(2) oxalic acid
(2) vkW
Dt fsyd vEy
(3) NH3
(3) NH3
(4) Acetic ccid
(4) , fl fVd vEy
78. Identify the end product in the given sequence of
reactions : 78. nhxbZvfHkfØ; kvks
adkvfUre mRikn D; kgks
xk%
(i) CH CN
NBS
X M
g / ether
(i) CH CN
Y (ii)H33 Z NBS
X M
g / ether
Y (ii)H33
O
Z
O
COCH3 CN COCH3 CN
79. An organic compound 'A' having molecular 79. , d dkcZ fud ;kSfxd 'A' dkv.kq lq
=kC2H3N gSft l dkvi p;u
formula C 2H 3N on reduction gives another djusi j nq l jk; kS
fxd 'B' i zkIr gks
r kgSB dkukbVªl vEy ds
compound 'B'. Upon treatment with nitrous acid l kFkfØ;kdjkusi j , fFky , Ydks gky nsr kgSAft l dksDyks
jks
iQkeZ
'B' gives eth yl al coho l. On warming w ith
chloroform and alcoholic KOH, it forms an vkS j , Ydks
gkfyd KOH dsl kFkxeZdjusi j ; kS fxd 'C' dh
offensive semelling compound 'C'. The compound rh{k.kxa / nsr kgSA; kSfxd 'C' gS%
'C' is : (1) CH3NC
(1) CH3NC
(2) C6H5NC
(2) C6H5NC
(3) CH3C N
(3) CH3C N
(4) CH3CH2NC (4) CH3CH2NC
80. Compare boiling point of isomeric alkyl amines : 80. fuEu vkbl ks
es
fjd , fYdy , ehuksdsDoFkuka
d dkl ghØe gS
:
(1) 10 > 20 > 30 (1) 10 > 20 > 30
(2) 10 > 20 < 30 (2) 10 > 20 < 30
(3) 10 < 20 < 30 (3) 10 < 20 < 30
(4) 10 < 20 > 30
(4) 10 < 20 > 30
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All India Test and Discussion Series : Test-27 / [Paper] CRACK NEET 2021 / TD / 28 -May-2021
81. Acetamide is treated with the following reagents 81. , l h vkekbMdksfofHkUu vfHkdeZ d dsl kFkfØ; kdjkusi j]
separately. Which one of these would yield methyl
amine :
fuEu es al sfdl l ses
fFky , ehu i zkIr gks
xk%
(1) PCl5 (1) PCl5
(2) NaOH/Br2
(2) NaOH/Br2
(3) Sodalime (3) l kM
skykbe
(4) Hot conc. H2SO4 (4) xeZr Fkkl kUnzH2SO4
HNO2 PCl3 NH3
82. C2H5NH2 A B C . Recognize the 82. HNO2
C2H5NH2 PCl3
A NH3
B C . ; kS
fxd 'C' gks
xk%
compound C from the following :
(1) i zkissuukbZ
Vªkby
(1) propanenitrile
(2) esfFky, ehu
(2) methylamine
(3) , fFky , ehu
(3) ethylamine
(4) acetamide (4) , fl VkekbM
83. Identify the product (E) in the following sequence 83. fuEu vfHkfØ; kes
al smRikn (E) dhi gpku dfj; s%
of reactions :
CH3
CH3 Br2 Sn /HCl NaNO2 /HCl H2 O/H3PO2 KMnO4
A B
273278 K
C D
OH
E
Br2 Sn /HCl NaNO2 /HCl H2 O/H3PO2 KMnO4
A B
273278 K
C D
OH
E
NO2
NO2
COOH
COOH
(1)
(1)
COOH
COOH Br
Br (2)
(2)
CH3
CH3 (3)
(3) Br
Br
CH3
CH3 (4)
(4) O 2N Br
O 2N Br
– +
OH O Na
OH
–
O Na
+ 84. CHCl3 NaOH
84. CHCl3 NaOH CHO
CHO
mi jks
Dr vfHkfØ; kes
ai z;q
Dr bys
DVªks
iQkby gks
xk%
The electrophilie involved in the above reaction
is : (1) VªkbZ
esa
fFky , uk; u(CCl3 )
(1) trichloromethyl anion (CCl3 )
(2) iQ
kfeZ
y dsVk; u(CHO)
(2) formyl cation (CHO)
(3) MkbZ
DyksjksesfFky dsVk; u(CHCl2 )
(3) dichloromethyl cation (CHCl2 ) (4) MkbZ
Dyksjkd
s kchu
Z(:CCl2)
(4) dichlorocarbene (:CCl2)
20
All India Test and Discussion Series : Test-27 / [Paper] CRACK NEET 2021 / TD / 28 -May-2021
H2 O HCN H2 O / H H2 O HCN H2 O / H
85. CH CH
Hg2 H
CN excess
........ T he 85. CH CH
Hg2 H
CN excess
........ v fUr e
final product is : mRikn gks
xk%
O O
(1) CH3 C NH2 (1) CH3 C NH2
(2) CH3–CH2–COOH (2) CH3–CH2–COOH
(3) (4)
(3) (4)
21
All India Test and Discussion Series : Test-27 / [Paper] CRACK NEET 2021 / TD / 28 -May-2021
NO2 NO2
Zn /NH4 Cl Sn / HCl Zn /NH4 Cl Sn / HCl
90. Y X 90. Y X
22