Bihar STET PGT Chemistry Official Paper II Held On 14 Sept 2023 Shift 1 2
Bihar STET PGT Chemistry Official Paper II Held On 14 Sept 2023 Shift 1 2
in
QUESTION PAPER
Uchcha Madhyamic Chemistry [SHIFT - 1]
6XEMHFW1DPH&KHPLVWU\ 6XEMHFW&RGH
Subject Question
Question 1 Question Id : 1
The Vander Waal's equation explains the behaviour of
Answer : Option Id
(A) Ideal gases
1001
(C) Vapour
1003
Question 2 Question Id : 55
Gases deviate from the ideal gas behaviour because their molecules
Answer : Option Id
(A) Possess negligible volume
55001
Question 3 Question Id : 54
according to Boyle’s law the volume of a fixed mass of a gas, at constant temperature, is
Answer : Option Id
(A) directly proportional to its pressure
54001
Question 4 Question Id : 53
The root-mean square deviation is also called…..
Answer : Option Id
(A) Mean deviation
53001
Question 5 Question Id : 52
Answer : Option Id
(A) The angle of incidence of X-rays
52001
Question 6 Question Id : 51
X-rays have larger wavelengths than which of the following?
Answer : Option Id
(A) Gamma rays
51001
(C) Microwave
51003
Question 7 Question Id : 50
Minimum interplanar spacing required for Bragg’s diffraction is:
Answer : Option Id
(A)
50001
(B)
50002
(C)
50003
(D)
50004
Question 8 Question Id : 49
The study of reaction kinetics is called __________
Answer : Option Id
(A) Rate of reaction
49001
Question 9 Question Id : 48
Plotting a graph between temperature and reaction rates can reveal the temperature dependence of reaction rates.
Answer : Option Id
(A) Concentration of reactants and temperature
48001
Question 10 Question Id : 47
A radioactive decay is always considered as
Answer : Option Id
(A) Zero order reaction
47001
Question 11 Question Id : 46
The ratio of the rate constant of a reaction at two temperatures differing by __________°C is called temperature coefficient of reaction.
Answer : Option Id
(A) 2
46001
(B) 10
46002
(C) 100
46003
(D) 50
46004
Question 12 Question Id : 45
In a dilute solution, any colligative property depends on
Answer : Option Id
(A) The total number of neutral species in the solution
45001
(C) The total number of species irrespective of whether they are ionic or non-ionic.
45003
(D) The types of forces operating between the non-ionic species, ionic species and the solvent molecules
45004
Question 13 Question Id : 44
Molarity of a solution is expressed as:
Answer : Option Id
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(A) the number of moles of a solute present in one litre of the solution.
44001
(C) the number of gram equivalent of solute present in one litre of solution.
44003
(D) the ratio of the number of moles of solute to the total number of moles of solution.
44004
Question 14 Question Id : 43
Which one of the following is not a colligative property?
Answer : Option Id
(A) Osmotic pressure.
43001
Question 15 Question Id : 42
The enthalpy of formation is nonzero for
Answer : Option Id
(A) O2
42001
(B) Cu
42002
(C) O3
42003
(D) H+
42004
Question 16 Question Id : 41
The enthalpy of an exothermic reaction
Answer : Option Id
(A) Is always Positive
41001
Question 17 Question Id : 56
Helmholtz free energy is called
Answer : Option Id
(A) Power function
56001
Question 18 Question Id : 57
At a certain temperature, 50% of HI dissociates into H2 and I2. The equilibrium constant is
Answer : Option Id
(A) 1.0
57001
(B) 3.0
57002
(C) 0.5
57003
(D) 0.25
57004
Question 19 Question Id : 58
According to Le Chatelier’s principle, adding heat to a system of solid and liquid at equilibrium will cause the
Answer : Option Id
(A) Amount of solid to decrease
58001
Question 20 Question Id : 67
In a reversible reaction, if the concentration of reactants are doubled, the equilibrium constant K will
Answer : Option Id
(A) Change to ¼ K
67001
(B) Change to ½ K
67002
(C) Change to 2K
67003
Question 21 Question Id : 73
How is the distribution among two or more phases at equilibrium determined by?
Answer : Option Id
(A) Application of entropy
73001
Question 22 Question Id : 72
At equilibrium the total Gibb’s free energy for all phases is
Answer : Option Id
(A) Minimum
72001
(B) Maximum
72002
(C) Infinity
72003
(D) Zero
72004
Question 23 Question Id : 71
For a liquid-liquid case, what is phase equilibrium ratio?
Answer : Option Id
(A) Ratio of mole fractions of species in two phases at equilibrium
71001
Question 24 Question Id : 70
Which of the following is incorrect at equilibrium?
Answer : Option Id
(A) There is no net transfer of electrons, so E = 0.
70001
(C) Q > K.
70003
(D) Q < K.
70004
Question 25 Question Id : 69
Which of the following relation is correct?
Answer : Option Id
(A) F=Qn
69001
(B) n=Q
69002
(C) Q = nF
69003
(D) Q = n2F
69004
Question 26 Question Id : 68
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Question 27 Question Id : 66
What is the increasing order for the values of e/m for
Answer : Option Id
(A)
66001
(B)
66002
(C)
66003
(D)
66004
Question 28 Question Id : 59
Atomic number of an atom will be
Answer : Option Id
(A) Number of electrons.
59001
Question 29 Question Id : 65
Nickel has atomic number 28. The correct electronic configuration is
Answer : Option Id
(A) 1s2 2s2 2p4 3s2 3p8 3d10
65001
Question 30 Question Id : 64
According to Moseley, a straight-line graph is obtained on plotting
Answer : Option Id
(A) The frequencies of characteristic X-rays of elements against their atomic numbers.
64001
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(B) The square of the frequencies of characteristic X-rays of elements against their atomic numbers
64002
(C) The square root of the frequencies of characteristic X-rays of elements against their atomic numbers
64003
(D) The reciprocal of the frequencies of characteristic X-rays of elements against their atomic numbers
64004
Question 31 Question Id : 63
The tenth element in the periodic table resides in:
Answer : Option Id
(A) the second period
63001
Question 32 Question Id : 62
Which of the following order is not in accordance with the property stated against it?
Answer : Option Id
(A) F > Cl > Br > l Oxidising Power
62001
Question 33 Question Id : 61
The correct order of increasing electron gain enthalpy with a negative sign for the elements O, S, F, and Cl is :
Answer : Option Id
(A) Cl < F < S < O
61001
Question 34 Question Id : 60
The maximum number of 90° angles between bond pair-bond pair of electrons is observed in
Answer : Option Id
(A) dsp2 Hybridisation
60001
Question 35 Question Id : 40
The shape of the molecule depends on the _______
Answer : Option Id
(A) adjacent atom
40001
(C) surroundings
40003
(D) atmosphere
40004
Question 36 Question Id : 39
In NaCl crystal, the radius ratio is :
Answer : Option Id
(A) 0.4
39001
(B) 0.98
39002
(C) 1.0
39003
(D) 0.52
39004
Question 37 Question Id : 38
Which of the following is Not a structure insensitive property?
Answer : Option Id
(A) Elastic modulus
38001
Question 38 Question Id : 37
Which of the enlisted compounds is termed as slaked lime?
Answer : Option Id
(A) Calcium Oxide
37001
Question 39 Question Id : 17
Which of the following is true about interhalogen compounds?
Answer : Option Id
(A) They have unpaired electrons
17001
Question 40 Question Id : 16
Which of the following elements does not belong to group 16 of the periodic table?
Answer : Option Id
(A) Oxygen
16001
(B) Phosphorus
16002
(C) Sulphur
16003
(D) Selenium
16004
Question 41 Question Id : 15
Which groups of elements are called d-block elements in modern periodic table ?
Answer : Option Id
(A) 1 to 2
15001
(B) 3 to 10
15002
(C) 3 to 12
15003
(D) 13 to 18
15004
Question 42 Question Id : 14
Which block elements are more electropositive in modern periodic table?
Answer : Option Id
(A) s
14001
(B) P
14002
(C) c
14003
(D) f
14004
Question 43 Question Id : 13
Which block elements are less electropositive in modern periodic table ?
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Answer : Option Id
(A) s
13001
(B) p
13002
(C) d
13003
(D) f
13004
Question 44 Question Id : 12
The oxygen molecule is paramagnetic. It can be explained by
Answer : Option Id
(A) Resonance
12001
(B) Hybridisation
12002
Question 45 Question Id : 11
According to Werner’s theory of coordination compounds,
Answer : Option Id
(A) Primary valency is ionizable
11001
Question 46 Question Id : 10
Which of the following compound is paramagnetic?
Answer : Option Id
(A) Hexa amine chromium (III) ion
10001
Question 47 Question Id : 9
As per Arrhenius Concept, Weak Acid among These is___?
Answer : Option Id
(A) HCL
9001
(B) HNO3
9002
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(C) HCN
9003
(D) H2SO4
9004
Question 48 Question Id : 8
As per the Bronsted and Lowry Concept, a Base is a Substance that___
Answer : Option Id
(A) Accepts proton
8001
Question 49 Question Id : 7
Which of the following species can act as Lewis Base?
Answer : Option Id
(A) Negatively charged species or Anions and Neutral Species with one lone pair of electrons
7001
(B) Positively charged species or Cations and Neutral Species with one lone pair of electrons
7002
Question 50 Question Id : 6
Which of the following gases is not a green house gas?
Answer : Option Id
(A) CO
6001
(B) O3
6002
(C) CH4
6003
Question 51 Question Id : 5
Photochemical smog occurs in warm, dry and sunny climate. One of the following is not amongst the components of photochemical smog, identify it.
Answer : Option Id
(A) NO2
5001
(B) O3
5002
(C) SO2
5003
Question 52 Question Id : 4
Which of the following statements is not true about classical smog?
Answer : Option Id
(A) Its main components are produced by the action of sunlight on emissions of automobiles and factories.
4001
Question 53 Question Id : 3
Biochemical Oxygen Demand, (BOD) is a measure of organic material present in water. BOD value less than 5 ppm indicates a water sample to be
__________.
Answer : Option Id
(A) rich in dissolved oxygen.
3001
Question 54 Question Id : 18
An sp3 hybrid orbital possesses
Answer : Option Id
(A) One-fourth's character
18001
Question 55 Question Id : 2
Which of the following molecules has the shortest carbon-carbon bond length?
Answer : Option Id
(A) Dimond
2001
(B) Ethane
2002
(C) Benzene
2003
(D) Acetylene
2004
Question 56 Question Id : 19
The nature of intermolecular forces among Benzene molecule is
Answer : Option Id
(A) Dipole attraction
19001
Question 57 Question Id : 21
The resonance stabilization is highest in
Answer : Option Id
(A) 1,3-butadiene
21001
(B) Cyclobutadiene
21002
(C) 1,3-cyclohexadiene
21003
(D) Benzene
21004
Question 58 Question Id : 36
Completely conjugated monocyclic hydrocarbons are called
Answer : Option Id
(A) Arenes
36001
(B) Allenes
36002
(C) Annulenes
36003
(D) cumulenes
36004
Question 59 Question Id : 35
Which of the following is the most reactive towards nucleophiles?
Answer : Option Id
(A) Acetaldehyde
35001
Question 60 Question Id : 34
The modern explanation of the Markovnikov rule regarding the addition product accepts the stability of the intermediate
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Answer : Option Id
(A) Carbon radical
34001
(B) Carbocation
34002
(C) Carbanion
34003
(D) Carbene
34004
Question 61 Question Id : 33
The compound which can show both geometrical isomerism and optical isomerism is
Answer : Option Id
(A) Maleic acid
33001
Question 62 Question Id : 32
Optically active isomers that are not mirror images of each other are called
Answer : Option Id
(A) Enantiomers
32001
(B) Mesoisomers
32002
(C) . Tautomer’s
32003
(D) diastereomers
32004
Question 63 Question Id : 31
Which of the following objects is chiral?
Answer : Option Id
(A) Hammer
31001
(B) Ear
31002
(C) Spoon
31003
(D) Fork
31004
Question 64 Question Id : 30
The smallest alkane having a 3° carbon is
Answer : Option Id
(A) Isopentane
30001
(B) 2,3-dimethylbutane
30002
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(C) 2,2-dimethylpropane
30003
(D) isobutane
30004
Question 65 Question Id : 29
Which of the following would yield a single monohalogen derivative?
Answer : Option Id
(A) Propane
29001
(B) Cyclopropane
29002
(C) Propene
29003
(D) Propyne
29004
Question 66 Question Id : 28
The carbon-carbon bond in cyclopropane is called
Answer : Option Id
(A) sigma bond
28001
(B) Pi bond
28002
Question 67 Question Id : 27
The IUPAC name of t-butyl group is
Answer : Option Id
(A) 1,1dimethylethyl
27001
(B) 2-methylpropyl
27002
(C) 1-methylpropyl
27003
(D) 1-methylethyl
27004
Question 68 Question Id : 26
Which of the following reagents would convert1-butyne into 2-butyne?
Answer : Option Id
(A) Ethanolic KOH, heat
26001
(B) NaNH2/NH3(l)
26002
Question 69 Question Id : 25
The presence of unsaturation in an organic compound can be detected by
Answer : Option Id
(A) Schiff’s reagent
25001
Question 70 Question Id : 24
The index of hydrogen deficiency (IHD) of benzene is
Answer : Option Id
(A) 2
24001
(B) 3
24002
(C) 4
24003
(D) 6
24004
Question 71 Question Id : 23
The nitration of benzene is an example of
Answer : Option Id
(A) Nucleophilic substitution
23001
Question 72 Question Id : 22
Which of the following represents an electrophilic aromatic substitution reaction?
Answer : Option Id
(A) Wurtz reaction
22001
(D) Dehydrohalogenation
22004
Question 73 Question Id : 74
Aromatic compounds burn with a sooty flame because
Answer : Option Id
(A) They have a ring structure
74001
Question 74 Question Id : 20
The rate of nitration of phenol is
Answer : Option Id
(A) Slower than that of benzene
20001
Question 75 Question Id : 75
which of the following does not produce a white precipitate of AgCl on warming with alcoholic silver nitrate?
Answer : Option Id
(A) Allyl Chloride
75001
Question 76 Question Id : 78
Which of the following will react with water?
Answer : Option Id
(A) CHCl3
78001
(B) Cl3CCHO
78002
(C) CCl4
78003
(D) ClCH2CH2Cl
78004
Question 77 Question Id : 92
Reaction of ethyl benzoate with an excess of Phenyl magnesium bromide in dry ether and subsequent hydrolysis produces
Answer : Option Id
(A) Benzophenone
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92001
(B) propiophenone
92002
(C) Diphenylmethanol
92003
(D) triphenylmethanol
92004
Question 78 Question Id : 93
which one of the following compounds is most readily hydrolyzed by SN1mechanism?
Answer : Option Id
(A) CH3CH=CH-Cl
93001
(B) CH2=CHCH2Cl
93002
(C) (C6H5)3C-Cl
93003
(D) C6H5CH2Cl
93004
Question 79 Question Id : 94
Benzaldehyde reacts with PCl5 to give
Answer : Option Id
(A) Benzyl Chloride
94001
(D) chlorobenzene
94004
Question 80 Question Id : 97
Methanol can be distinguished from ethanol by
Answer : Option Id
(A) Sodium
97001
Question 81 Question Id : 96
Piperidine is a
Answer : Option Id
(A) homocyclic compound
96001
Question 82 Question Id : 91
Ethyl amine can be prepared by the action of Br2 and NaOH solution on
Answer : Option Id
(A) acetamide
91001
(B) propionamide
91002
(C) formamide
91003
Question 83 Question Id : 98
The aromaticity of the following heterocycles follows the order
Answer : Option Id
(A) Thiophene> pyrrole> furan> pyridine
98001
(B) Furan>pyrrole>thiophene>pyridine
98002
(C) Pyridine>thiophene>Pyrrole>furan
98003
(D) Pyridine>furan>Pyrrole>thiophene
98004
Question 84 Question Id : 99
Which one amongst the following compounds is the least basic?
Answer : Option Id
(A) Piperidine
99001
(B) Pyridine
99002
(C) Pyrrole
99003
(D) Quinoline
99004
(B) 3- pentanone
100002
(C) Pentanal
100003
Question 86 Question Id : 95
Which is not present in Grignard reagent?
Answer : Option Id
(A) Methyl group
95001
(B) Magnesium
95002
(C) Halogen
95003
Question 87 Question Id : 90
Which of the following compounds does not give a tertiary alcohol upon reaction with methyl magnesium bromide?
Answer : Option Id
(A) 3-methylpentanal
90001
(C) 4,4-dimethylcyclohexanone
90003
(D) 4-heptanone
90004
Question 88 Question Id : 77
The protein which transports oxygen in the bloodstream is
Answer : Option Id
(A) Haemoglobin
77001
(B) insulin
77002
(C) Albumin
77003
(D) collagen
77004
Question 89 Question Id : 88
The secondary structures of proteins of silk and wool are
Answer : Option Id
(A)
88001
(B)
88002
(C)
88003
(D)
88004
Question 90 Question Id : 87
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(B) polymerization
87002
(C) Esterification
87003
(D) condensation
87004
Question 91 Question Id : 89
Turpentine is an essential oil obtained from
Answer : Option Id
(A) camphor tree
89001
Question 92 Question Id : 86
Among the following which one has the least iodine number?
Answer : Option Id
(A) Sunflower oil
86001
(C) Ghee
86003
Question 93 Question Id : 85
Which of the following gives maximum energy in a metabolic process?
Answer : Option Id
(A) Carbohydrates
85001
(B) Proteins
85002
(C) Fats
85003
(D) Vitamins
85004
Question 94 Question Id : 84
The polymers that cannot form intermolecular hydrogen bond are
Answer : Option Id
(A) Nylon 6
84001
(B) Polythene
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84002
(C) Proteins
84003
Question 95 Question Id : 76
Among the following which one is homopolymers
Answer : Option Id
(A) Bakelite
76001
(B) Terylene
76002
(C) 6,6
76003
(D) Neoprene
76004
Question 96 Question Id : 83
The catalyst used in the manufacture of polyethylene by Ziegler-Natta process is
Answer : Option Id
(A) Triphenylaluminium and titanium tetrachloride
83001
Question 97 Question Id : 82
Which of the following is used as defoliant?
Answer : Option Id
(A) Gammaxene
82001
(B) DDT
82002
Question 98 Question Id : 81
Which of the following is not a semisynthetic polymer?
Answer : Option Id
(A) cis-polyisoprene
81001
Question 99 Question Id : 80
The commercial name of polyacrylonitrile is ______________.
Answer : Option Id
(A) Dacron
80001
(C) PVC
80003
(D) Bakelite
80004
(C) Phenolphthalein
79003
Art Of Teaching
(B) analysis
120002
(C) evaluation
120003
(D) synthesis
120004
(B) synthesis
124002
(C) organisation
124003
(D) comprehension
124004
(C) demonstrates
119003
Answer : Option Id
(A) method of teaching
117001
(B) Vygotsky
128002
(C) Merrill
128003
(D) Gagne
128004
(C) enrichment
108003
(D) acceleration
108004
(C) Purposeful
115003
(B) Informal
116002
(B) Measurement
106002
(C) Evaluation
106003
(D) Examination
106004
(A) Child
103001
(B) Activity
103002
(B) Content
109002
(C) Teacher
109003
(D) Evaluation
109004
(B) Home
110002
(C) Classroom
110003
(D) Syllabus
110004
(B) Justice
111002
(C) Fidelity
111003
(B) Writing
113002
(C) Doing
113003
(D) Reading
113004
(B) Model
114002
(C) Chart
114003
Other Skills
(B) 1857
149002
(C) 1836
149003
(D) 1885
149004
(B) 1961-66
147002
(C) 1969-1974
147003
(D) 1979-1984
147004
(B) Haathi
146002
(C) Development
146003
(D) Malba
146004
(B) Afghanistan
145002
(C) Germany
145003
(D) Russia
145004
(B) Odisha
143002
(C) Karnataka
143003
(D) Kerala
143004
(B) B and C
142002
(C) A and C
142003
(D) A and B
142004
(B) 146 g
141002
(C) 142 g
141003
(D) 143 g
141004
(B) 36
139002
(C) 28
139003
(D) 32
139004
(B) Eight
138002
(C) Four
138003
(D) Five
138004
(B) 200
137002
(C) 0
137003
(D) 50
137004
(B) 15
136002
(C) 0
136003
(D) -5
136004
(B) Desert
134002
(C) Water
134003
(D) Tree
134004
(B) Snake
133002
(C) Swan
133003
(D) Crocodile
133004
(B) 26 23
132002
(C) 26 24
132003
(D) 25 23
132004
(B) OPKVPAV
140002
(C) OPOVKBQ
140003
(D) KBQVOPA
140004
(B) Nephew
150002
(C) Niece
150003
(D) Aunt
150004