Safety Data Sheet in accordance with

GB/T 16483 and GB/T 17519

GENAPOL PF 80 Page 1

First compiled on: 2017/08/21

Substance key: 000000067253 Revision Date: 2024/07/31
Version : 1 - 3 / CHI Date of printing : 2025/05/30

1. PRODUCT AND COMPANY IDENTIFICATION

Trade name
GENAPOL PF 80
Material number: 138808
CAS-No.: 9003-11-6
Use of the Substance/Mixture
Industry sector : Industrial Performance Chemicals
Type of use: Techno-chemical industry.
Identification of the company
Clariant Produkte (Deutschland) GmbH

65926 Frankfurt am Main

Telephone : +49 69 305 18000
Information about the substance/preparation
BU Care Chemicals
Product Stewardship
E-mail address: [email protected]
Emergency telephone number: +86 532-83889090
(For product with GHS classification (Qingdao NRCC))

+86 21 37911379
(For product without GHS classification (Jinshan Shanghai))

2. HAZARDS IDENTIFICATION

Emergency Overview
Appearance : Wax.
Colour : white
Odour : characteristic
Not a hazardous substance or mixture.
GHS Classification
Not a hazardous substance or mixture.
GHS label elements
Not a hazardous substance or mixture., Not a dangerous substance according to GHS.

Physical and chemical hazards

Not classified based on available information.
Health hazards
Not classified based on available information.

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Safety Data Sheet in accordance with
GB/T 16483 and GB/T 17519
GENAPOL PF 80 Page 2

First compiled on: 2017/08/21

Substance key: 000000067253 Revision Date: 2024/07/31
Version : 1 - 3 / CHI Date of printing : 2025/05/30

Environmental hazards
Not classified based on available information.
Other hazards which do not result in classification
No particular hazards known.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Substance

Substance name : A polymerisation product of propylene oxide and ethylene

oxide .

CAS-No. : 9003-11-6

Components
No hazardous ingredients

4. FIRST AID MEASURES

General advice : Remove/ Take off immediately all contaminated clothing.

If inhaled : If inhaled, remove to fresh air.

Get medical advice/ attention.

In case of skin contact : In case of contact, immediately flush skin with plenty of water.

In case of eye contact : In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.

If swallowed : Get medical attention immediately.

Most important symptoms : No symptoms known currently.

and effects, both acute and No hazards known at this time.
delayed

Notes to physician : Treat symptomatically.

5. FIREFIGHTING MEASURES

Suitable extinguishing media : Water spray jet

Foam

Unsuitable extinguishing : Carbon dioxide (CO2)

media Dry powder
High volume water jet

Specific hazards during : In case of fires, hazardous combustion gases are formed:

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Safety Data Sheet in accordance with
GB/T 16483 and GB/T 17519
GENAPOL PF 80 Page 3

First compiled on: 2017/08/21

Substance key: 000000067253 Revision Date: 2024/07/31
Version : 1 - 3 / CHI Date of printing : 2025/05/30

firefighting Carbon monoxide (CO)

Specific extinguishing : Wear full protective clothing and self-contained breathing

methods apparatus.

Special protective equipment : Self-contained breathing apparatus

for firefighters

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Wear suitable protective equipment.

protective equipment and Avoid dust formation.
emergency procedures

Environmental precautions : Do not allow to enter drains or waterways

Methods and materials for : Pick up mechanically. Rinse away rest with water.
containment and cleaning up

7. HANDLING AND STORAGE

Handling
Advice on protection against : Keep away sources of ignition.
fire and explosion Take precautionary measures against build-up of electrostatic
charges, e.g earthing during loading and off-loading
operations.
Dust can form an explosive mixture in air.

Advice on safe handling : Avoid dust formation.

Avoid dust accumulation in enclosed space.

Avoidance of contact : Strong acids and oxidizing agents

Storage

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Contains no substances with occupational exposure limit values.
Personal protective equipment
Respiratory protection : Use respiratory protection in case of insufficient exhaust
ventilation or prolonged exposure
Particle-filtering half-mask according to DIN EN 149
Filter class FFP2

Eye/face protection : Safety glasses

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Safety Data Sheet in accordance with
GB/T 16483 and GB/T 17519
GENAPOL PF 80 Page 4

First compiled on: 2017/08/21

Substance key: 000000067253 Revision Date: 2024/07/31
Version : 1 - 3 / CHI Date of printing : 2025/05/30

Hand protection
Remarks : Protective gloves complying with EN 374. Minimum thickness
(glove): not determined With solid dry substances permeation
is not to be expected, therefore the breakthrough-time for this
protective glove has not been measured.

These types of protective gloves are offered by various

manufacturers. Please note the manufacturers´ detailed
statements, especially about the minimum thickness and the
minimum breakthrough time. Consider also the particular
working conditions under which the gloves are being used.

Protective measures : Do not breathe dust.

Avoid contact with skin and eyes.

Hygiene measures : Wash hands before breaks and at the end of workday.
Use protective skin cream before handling the product.
Take off immediately all contaminated clothing and wash it
before reuse.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Wax.

Colour : white

Odour : characteristic

pH : 6 - 8 (20 °C)
Concentration: 10 g/l
Method: DIN 1262

Drop point : approx. 58 °C

Boiling point : > 360 °C

Method: Calculated by Syracuse.

Flash point : > 250 °C

Method: DIN/ISO 2592 (open cup)

Self-ignition : 350 °C

Burning number : 1
Does not catch fire

Upper explosion limit / upper : Not applicable

flammability limit

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Safety Data Sheet in accordance with
GB/T 16483 and GB/T 17519
GENAPOL PF 80 Page 5

First compiled on: 2017/08/21

Substance key: 000000067253 Revision Date: 2024/07/31
Version : 1 - 3 / CHI Date of printing : 2025/05/30

Lower explosion limit / Lower : Not applicable

flammability limit

Vapour pressure : < 0.001 Pa (25 °C)

Method: Calculated by Syracuse.

Relative vapour density : Not applicable

Density : approx. 1.06 g/cm3 (70 °C)

Method: DIN 51757

Solubility(ies)
Water solubility : soluble (20 °C)

Partition coefficient: n- : log Pow: < -1

octanol/water Method: Calculated by Syracuse.

Auto-ignition temperature : Not applicable

Decomposition temperature : > 350 °C

Heating rate: 3 K/min
Method: DSC

Viscosity
Viscosity, dynamic : 900 - 1,500 mPa.s ( 70 °C)
Method: DIN 53015

Viscosity, kinematic : Not applicable

Impact sensitivity : Not impact sensitive.

Molecular weight : approx. 9,600 g/mol

Metal corrosion rate : Not applicable

Particle size : no data available

10. STABILITY AND REACTIVITY

Reactivity : See section 10.3. "Possibility of hazardous reactions"

Chemical stability : Stable under normal conditions.

Possibility of hazardous : No dangerous reaction known under conditions of normal use.

reactions Stable

Conditions to avoid : Strong acids and oxidizing agents

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Safety Data Sheet in accordance with
GB/T 16483 and GB/T 17519
GENAPOL PF 80 Page 6

First compiled on: 2017/08/21

Substance key: 000000067253 Revision Date: 2024/07/31
Version : 1 - 3 / CHI Date of printing : 2025/05/30

Incompatible materials : Strong acids and oxidizing agents

Hazardous decomposition : When handled and stored appropriately, no dangerous

products decomposition products are known

11. TOXICOLOGICAL INFORMATION

Acute toxicity
Product:
Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg
Method: OECD Test Guideline 401

Acute inhalation toxicity : Remarks: not tested.

Acute dermal toxicity : Remarks: not tested.

Skin corrosion/irritation
Product:
Species : Rabbit
Method : OECD Test Guideline 404
Result : No skin irritation

Serious eye damage/eye irritation

Product:
Species : rabbit eye
Result : No eye irritation
Method : OECD Test Guideline 405

Respiratory or skin sensitisation

Product:
Remarks : not tested.

Germ cell mutagenicity

Product:
Germ cell mutagenicity - : No information available.
Assessment

Carcinogenicity
Product:
Carcinogenicity - : No information available.
Assessment

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Safety Data Sheet in accordance with
GB/T 16483 and GB/T 17519
GENAPOL PF 80 Page 7

First compiled on: 2017/08/21

Substance key: 000000067253 Revision Date: 2024/07/31
Version : 1 - 3 / CHI Date of printing : 2025/05/30

Reproductive toxicity
Product:
Reproductive toxicity - : No information available.
Assessment

No information available.

STOT - single exposure

Product:
Remarks : not tested.

STOT - repeated exposure

Product:
Remarks : not tested.

Repeated dose toxicity

Product:
Remarks : not tested.

Aspiration toxicity
Product:
no data available

12. ECOLOGICAL INFORMATION

Ecotoxicity
Product:
Toxicity to fish : LC0 (Poecilia reticulata (guppy)): > 500 mg/l
Exposure time: 24 h

Toxicity to daphnia and other :

aquatic invertebrates Remarks: not tested.

Toxicity to algae/aquatic :
plants Remarks: not tested.

Toxicity to microorganisms : EC50: > 1,000 mg/l

Method: OECD Test Guideline 209

Persistence and degradability

Product:
Biodegradability : Biodegradation: < 10 %
Method: OECD Test Guideline 302B

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Safety Data Sheet in accordance with
GB/T 16483 and GB/T 17519
GENAPOL PF 80 Page 8

First compiled on: 2017/08/21

Substance key: 000000067253 Revision Date: 2024/07/31
Version : 1 - 3 / CHI Date of printing : 2025/05/30

Chemical Oxygen Demand : 1,853 mg/g

(COD)

Dissolved organic carbon : 574 mg/g

(DOC)

Bioaccumulative potential
Product:
Bioaccumulation : Remarks: not tested.

Mobility in soil
Product:
Distribution among : Remarks: not tested.
environmental compartments

Other adverse effects

Product:
Environmental fate and : Remarks: no data available
pathways

Additional ecological : no data available

information

13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : In accordance with local authority regulations, take to special
waste incineration plant

Contaminated packaging : Packaging that cannot be cleaned should be disposed of as

product waste

14. TRANSPORT INFORMATION

IATA not restricted

IMDG not restricted
TDG_CN not restricted
RID not restricted

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Safety Data Sheet in accordance with
GB/T 16483 and GB/T 17519
GENAPOL PF 80 Page 9

First compiled on: 2017/08/21

Substance key: 000000067253 Revision Date: 2024/07/31
Version : 1 - 3 / CHI Date of printing : 2025/05/30

15. REGULATORY INFORMATION

National regulatory information

Apart from the data/regulations specified in this chapter, no further information is
available concerning safety, health and environmental protection.
GB 6944-2012: Classification and code of dangerous goods.
GB 12268-2012: List of dangerous goods.
GB 190-2009: Packing symbol of dangerous goods.
GB 30000.2~29 – 2013 , Rules for classification and labelling of chemicals.
Law of the People's Republic of China on Prevention and Control of Occupational
Diseases (Amended in 2011).
GB13690: General rule for classification and hazard communication of chemicals

16. OTHER INFORMATION

Revision Date : 2024/07/31

Further information
Other information : Observe national and local legal requirements

Date format : yyyy/mm/dd

Full text of other abbreviations

AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for
Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with
x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized
System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer;
IATA - International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory
concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing
Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50
- Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test
population (Median Lethal Dose); MARPOL - International Convention for the Prevention of
Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No
Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level;
NOELR - No Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National
Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for
Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution
Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines
Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity
Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the

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Safety Data Sheet in accordance with
GB/T 16483 and GB/T 17519
GENAPOL PF 80 Page 10

First compiled on: 2017/08/21

Substance key: 000000067253 Revision Date: 2024/07/31
Version : 1 - 3 / CHI Date of printing : 2025/05/30

Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals;

SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan
Chemical Substance Inventory; TDG - Transportation of Dangerous Goods; TECI - Thailand
Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United
Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods;
vPvB - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials
Information System

Disclaimer

This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Clariant makes no warranties, express
or implied, as to the information's accuracy, adequacy, sufficiency or freedom from defect and
assumes no liability in connection with any use of this information. Any user of this product is
responsible for determining the suitability of Clariant's products for its particular application.
Nothing included in this information waives any of Clariant's General Terms and Conditions of
Sale, which control unless it agrees otherwise in writing. Any existing intellectual/industrial
property rights must be observed. Due to possible changes in our products and applicable
national and international regulations and laws, the status of our products could change. Material
Safety Data Sheets providing safety precautions, that should be observed when handling or
storing Clariant products, are available upon request and are provided in compliance with
applicable law. You should obtain and review the applicable Material Safety Data Sheet
information before handling any of these products. For additional information, please contact
Clariant.

CN / EN

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