16-05-2025 - SR - Super60, Elite, Target & LIIT BT's - Jee-Adv (2018-P2) - GTA-36 - Key & Sol's
16-05-2025 - SR - Super60, Elite, Target & LIIT BT's - Jee-Adv (2018-P2) - GTA-36 - Key & Sol's
!KEY SHEET
PHYSICS
1 ABC 2 AB 3 AC 4 AC 5 AC 6 ABC
13 0.75 14 4 15 B 16 A 17 C 18 B
CHEMISTRY
19 ABC 20 BC 21 B 22 D 23 ABCD 24 ABC
3.9 - 13.71–
25 4 26 27 608 28 1 29 495 30
4.0 13.73
11.8 - 4.56 -
31 32 33 A 34 C 35 A 36 D
11.9 4.58
MATHEMATICS
37 ABD 38 AD 39 ABC 40 ABD 41 AB 42 AC
43 9 44 24 45 0.6 46 24 47 1 48 2
49 1 50 80 51 A 52 A 53 B 54 C
Sri Chaitanya IIT Academy 16-05-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2018 –P2)_GTA-36_Key& Sol’s
SOLUTIONS
PHYSICS
2 2 10
1. 1 4 m, 2 m
sin 30 sin 37 3
10 2
Displacement of point P : 1 2 4 m
3 3
2 100
Work done, W F 1 2 50 J
3 3
F cos30
Initial acceleration =
m
F cos37
Final acceleration =
m
cos30 3 5 5 3
Ratio =
2 4 8
cos37
2. As there is no slipping.
v A v and vB 2v
Two velocities are anti–parallel. The line joining tails of velocities intersects the line
joining their heads at instantaneous centre.
v 2v
From similar triangles,
x 2R x
2R x 2 x
3.
m m
v1 1 2 u 2m2 u
m1 m2 1 m1 m2 2
1 5
2 v 0
1 5 1 as v2 0
v1 3 ms1
m m
v2 2 1 u 2m1 u
m1 m2 2 m1 m2 1
2 1
3 1 ms1
6
= 0
PCM Pi 13 3 kg m / s
P5 51 5 kg m / s
2
PCM 9
KCM 0.75 J
2M CM 2 6
1
KTotal 13 4.5 J
2
2
4. Current in the loop has to be clockwise force on the loop is same as force on straight wire
PQ.
Length PQ 2 y tan30
FB Mg
IB 2 y tan 30 Mg
Mg
y
2 IB tan 30
If we displace the loop down by small distance y0
n . p cos i b
3
cos i b i 30
2
cot i 3
2
8.
3
F
9. a
M m
2t
Block slips when pseudo f max .m mg
M m
10.
T T1 T2 T1 T T
T T1 2 1 x
x L 2
x L
c c
T T
.dx T T
dx
2 1 x 2 1 x
k
kdx
0 T1
L
0 T1
L
dx x L
dx dx
0 0
Lc T Lc T
n n 2 x
T2 T1 T1 T2 T1 T1 n T x n T2 T T T2 L
T1 L T1
1
x L T1
KQ 2 KQ 2 KQ 2 KQ 2 KQ 2
11.
2a 2b b 2a 2b
12. Focal length for upper half is,
1 1.5 1
f1 f air 1.5 28 56cm
/ 1 1 1
1.2
Focal length for lower half is,
General t = t
di di q
So L1 1 L2 2 For maximum current in L2 :
dt dt C
E
L1 i1 ' L2 i2 ' 0 ………..(i)
r
2
1 E 1 '2 1 '
i L2i22
L1 L11 ………..(ii)
2 r 2 2
CHEMISTRY
19. Due to ligands there is geometrical and optical isomerism apart from metal centre
20. Reaction of A Pb3O4 with Conc. HNO3
Pb3O4 4 HNO3 PbO2 B 2 Pb NO3 2 2 H 2O
Reaction of Pb NO3 2 (Filtrate) with KI
Pb 2 2 I PbI 2 C yellow precipitate
Oxidation of Mn 2 by PbO2 in Conc. HNO3
2Mn2 5PbO2 4 HNO3 2MnO4 D 5Pb 2 2 H 2O
21.
22. From the given information D follows all.
23. Rate 3 NaSMe K 2 K MeI
K2 3 1 1 2
K K1 K 2 2
3 3 3 3 3
24. Since the equilibrium concentration of P increases with temperature, the reaction shifts
forward with increasing temperature. This implies the reaction is endothermic
H 0 . (A is correct) The reaction proceeds spontaneously under standard
conditions, meaning G 0 . (C is correct) For an endothermic reaction, the entropy of
the system increases S 0 , as heat is absorbed and disorder increases. (B is correct)
25. 1) N 2O4 : Two NO2 units linked by an N-N bond; each N has a bent structure.
2) N 2O5 : Two NO3 groups connected via an oxygen bridge, with planar NO3 geometry.
3) P4O6 : Cage-like structure with tetrahedrally bonded phosphorus atoms, similar to
P4O10 but missing four oxo groups.
4) P4O9 : Similar to P4O10 , but missing one terminal oxygen; retains cage-like structure.
5) H 4 P2O6 : Two phosphorus atoms connected by an oxygen bridge, each with = O and
– OH groups.
6) H 5 P3O10 : Three phosphorus atoms linked via oxygen bridges, with terminal = O and
– OH groups.
7) H 2 S2O3 : Contains S = O and S – S bonds; one sulfur replaces an oxygen in sulfuric
acid.
8) H 2 S3O6 : Three sulfur atoms joined
Sec : Sr.Super60, Elite,Target & LIIT BT's Page 8
Sri Chaitanya IIT Academy 16-05-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2018 –P2)_GTA-36_Key& Sol’s
26. Reactions Involved:
1. Partial oxidation: 2Cu2 S 3O2 2Cu2O 2 SO2
96g O2 forms 286 g Cu2O .
2. Self-reduction: Cu2O Cu2 S 4Cu SO2
286g Cu2O reacts to give 508g Cu.
Final Calculation:For 1000g (1 kg) O2 :
1000 508
5.29kg Cu
96
27. Step 1: Balanced Redox Reaction for FeSO4 Oxidation
6 FeSO4 K 2Cr2O7 7 H 2 SO4 3Fe2 SO4 3 Cr2 SO4 3 K 2 SO4 7 H 2O
Here, 1 mole of K 2Cr2O7 oxidizes 6 moles of FeSO4 .
Step 2: Iodometric Titration Reaction
The Fe2 SO4 3 formed oxidizes I from KI to I 2 , which is then tirated with Na2 S 2O3 :
I 2 2 S2O32 2 I S 4O62
1 mole of K 2Cr2O7 produces 3 moles of I 2 , which reacts with 6 moles of Na2 S 2O3 .
Step 3: Moles of Na2 S 2O3 used
Given 0.1 M Na2 S 2O3 and volume 40mL,
40
Moles of Na2 S2O3 0.1 0.004 moles
1000
Step 4: Moles of K 2Cr2O7 Involved
Since 1 mole K 2Cr2O7 reacts with 6 moles Na2 S 2O3 ,
0.004
Moles of K 2Cr2O7 0.0006667 moles
6
Step 5: Moles of FeSO4 Present
From Step 1, 1 mole K 2Cr2O7 oxidizes 6 moles FeSO4 , so
Moles of FeSO4 0.0006667 6 0.004 moles
Step 6: Mass of FeSO4
Molar mass of FeSO4 56 32 4 16 152 g / mol
Moles of FeSO4 0.004 152 0.608 g 608mg
28. The smallest possible case to satisfy the conditions would be:
1) One chiral center n 1
2) One fixed double bond m 1
Using the stereoisomer formula:
Total Stereoisomers 2 n m 211 2 2 4
1) Since meso compounds do not exist for a single chiral center, all 4 stereoisomers are
possible.
2) However, only half of them will be optically active (because enantiomers exist in
pairs).
Since K
pH 2
4
, and given 1% H 2O,
pH 2O 4
pH 2O
1
1 0.01bar K
pH 2
4
100 0.01 4
Taking logarithm:
ln K 4ln pH 2 4ln 0.01
Since ln (0.01) = – 4.6,
ln K 4ln pH 2 4 4.6
ln K 4ln pH 2 18.4
Equating to ln K = –36.46:
4ln pH 2 18.4 36.46
4ln pH 2 54.86
pK a log 4 106 5.4
Since strong acid (HCl) is used for titration, the solution will be acidic.
Approximate pH 2.4.
d : 20mL0.125MC5 H 5 NHCl 5mL5 103 MHCl
Kb C5 H 5 N 5 1010
This is a buffer solution involving C5 H 5 NH and C5 H 5 N .
Using the Henderson-Hasseslbalch equation :
pH pK a log
Base
Acid
Approximate pH = acidic region, making pH 7, indicating H OH .
MATHEMATICS
37. f x 0 always for x 0
38. Given, x sin by e ay
Now, 1 sin by 1 e ay e ay sin by e ay e ay x e ay
a
j 1 j a
be b
Now, S j sin by.e ay dy e b 1
j / b a2 b2
a
j
a
be b e b 1
a
j a
Sj e b
a 2 b2 e b Cons tan t
a a
j 1
S j 1 a
j 1
be b e b 1 e b
a 2 b2
2
2
39.
2 2
12 z 2 z 2 z 1 31 2
12 z z 2 z 2 z 2 z 1 z 1 31
2
2 2
12 z z 2 z z 2 z z 4 z 2 z z 2 z 1 31
2 2
z 2 2 z z z 4 z z 4 z 2 z 12 z z 36 0
z z 2 zz 6 2 0 z z 2 0 & z z 6 z z 2 z
6
z
2
40. P x is an even function.
P x ax 4 bx 2 1 and P ' x 4ax 3 2bx 2 x 2ax 2 b
b
So, at x , P x has minima.
2a
b
2 2 b 2a Maximum at (0, 1).
2a
1 ax
a
8 2 4 1
Also, 2 bx 2 1 dx b 1a
15 2
0
P x g x g x 1
Now, lim is finite. C , B 1
x 0 x2 2
1
Also, y 1 is tangent to Ax 2 x f x
2
1 1
Ax 2 x 1 has equal roots A
2 2
41.
V a. b c a b c cos
similarly, V b c a cos
and V c a b cos
while S 2 a b b c c a
V V V
2
c cos a cos b cos
Now, V a. b c a b c cos a b c
Also, sin a, b sin b, c sin c, a
So, it not necessary that they are equally inclined.
42.
We have sin cot 1 cos tan 1 x sin cot 1 cos , where tan 1 x
1 1 1 1 1 x2
sin cot sin cot
1 tan 2 1 x2 2 x2
1 x2
Now for all x R,0
2 x2
1 x2
1 1
1 , then sin cot cos tan x
2 x2
0
The equation is sin 0 n , n I
43. We observe that
f 9 f 4 5 f 4.5 f 16 4 f 16.4 f 64 f 8.8
f 8 8 f 16 f 4.4 4 4 f 8 9
2h r2 1
or 2r 2
3 h 3
1 5
Putting in (3), we get cot 2 1 2.
3 3
46. Form two pool
P4 is the best in one of the pool
n S P4 has any 2 players in pool 7 C3
4
n E P4 has 3 out of P5 , P6 , P7 , P8 4 C3
C3 4
P E
7 35
C3
1 1 1 1 1 1 1 1
47. S ......
an 1 an an 1 an an 1 a1 a2 a100 a101
1 1 1
2
a1 a101 a101
Since, a101 1 S 1
a c sin 200
48. d ……(1)
cos 200 cos 200
b d sin 200
c ……(2)
cos 200 cos 200
a d cos 200 c sin 200 ……(3)
b c cos 200 d sin 200 ……(4)
a 2 b2 c2 d 2
a 2 b2 c 2 d 2 2 c2 d 2
ac dc cos 200 c 2 sin 200
bd cd cos 200 d 2 sin 200
Also
ac bd c 2 d 2 sin 200
So
a 2 b2 c 2 d 2
2 c2 d 2
2cos ec 200 p2
ac bd
c 2 d 2 sin 200
n . Cr 1 3 1 3
n
1 r r 1 r n
1
49. lim
n r 1 5n
Cr C
k .3k
lim
n
n r r
r 1 5
r 1
lim n
n
Cr .
4r 3r 1
lim
5 1 4n 1 2n 1
n
n r 1 5n n 5n
5 4n 2n 1
n
lim 1
n 5n
Sec : Sr.Super60, Elite,Target & LIIT BT's Page 16
Sri Chaitanya IIT Academy 16-05-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2018 –P2)_GTA-36_Key& Sol’s
50.
a1 a, b .a 2 a 2, b 5 , a3 a 2, b 5
Area of , whose vertices are a1, a 2 , a 3 is
1 a b 1 a b
1 1
1 a 2 b 5 2 1 a 2 b 5
2 4
1 a2 b 5 1 a2 b 5
a1 a 2 3, a1 a3 3, a1 a 3 4
5 2 2 1 2 5
1 a1.a1 1 a1.a 2 1 a1.a 3
2 1
2 5 1 a 2 .a 2 1 a 2 .a 2 1 a 2 .a3
4
1 a 3.a1 1 a3.a 2 1 a3.a3
Required answer 4 5 4 80
D C
15 15
H
G
A
51. M B
1 1
P.FH 1 2 tan15 3 1 EG 1 2 tan15 3 1
2 2
1
Area of quadrilateral EFGH FH EG
2
1
2
2
3 1 2 3 ab 235
1 3
Q.EM EG GM 3 1 tan15
2 2
In AKM ,
3
EM
tan EAM 2 3 EAM 60
AM 1
2
1
52. A) We have f x
ln cos1 x
For domain of f(x), ln cos 1 x 0 cos 1 x 1 and cos 1 x
0 0
1
6 6 x x tan 6x x2 6 dx. Put ( x + 2) = z, we get
2
Now K
2
1
6 6 z 2 z 2 tan 6 z 2 z 2 6 dz.
2 2
K
2
1
22 10 z z tan 22 10z z 2 dz
2
0
Hence (J + K) = 0
53. A) Let D, E, F be the mid points then
EF 2
BC 2
4
BC 2 4 b2 c 2
Similarly AB 2 4 a 2 b2 and AC 2 4 a 2 c 2
AB 2 BC 2 CA2
8
a 2 b2 c 2
B) The image x1, y1, z1 is given by
x1 1 y1 2 z 3 2
1 2 3 5
1 1 1 3
Sec : Sr.Super60, Elite,Target & LIIT BT's Page 18
Sri Chaitanya IIT Academy 16-05-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2018 –P2)_GTA-36_Key& Sol’s
x1, y1, z1 3, 4,5
desired distance 50 5 2
C) D. R. of edge OA are 1, 0, 0 and D. R. of diagonal OP are 1, 1, 1.
1
cos tan 2
3
3 1
p
2 2
3
D) We have 1 1 0 and p + 1 + q = 0.
2
1
1 q
2
4 pq 4 p 5q 5 0 and p 1 q 0
3
Eliminating p, we get q 3, .
4
T T
54. A D DA
DDT DT D I
DDT AT D DAT DA1 DAT A1 AT
BC 2 BT B BT
(A) B B 1 B2 I
B 2018C C 1
AAT
2 2018
(D) BBT B 1 11 2