PEA Association Pvt. Ltd.

Thapathali, Kathmandu, Tel: 5345730, 5357187

2082-2-17 Hints & Solution
Section – I 17.(b) MHPO4 shows that valency of M = 2 (since HPO4
has valency 2). Hence chloride will be MCl2
1.(d) Bx = Dt
18.(b)
D
or, = LT–1 19.(d)
B
2
u sin2 20.(a)
2.(b) R= , R will be max if F¯ is the most electronegative element.
g 21.(d)
sin2 = 1 = sin90° 22.(c) The impurity in extraction of copper is FeO which is
removed by adding SiO2.
 = 45°
23.(d) It obeys Huckel’s rule i.e. it contains (4n+2)
1 1 1 delocalized π electrons e.g.10 π electrons.
3.(c) m (2ve)2 – mve2 = mv'2
2 2 2
or, 3 ve = v'

4.(c) r = r12 + r22 = 32 + 42 = 5 cm

5.(c) i.e. 0 to 4C  volume decreases, 4C to 15C 
volume increases 24.(a) It is known as enyne compound. Its IUPAC format is:
6.(c) a2 = 6 unit, a1 = 8 unit Alk-en-yne. Numbering is done by the lowest sum
2 2 2
rule.
Imax
Imin
= ( ) ( ) = (142) = 49 : 1
a1+a2
a1-a2
=
8+6
8-6 25.(d) Carbonium ion e.g. CH3+ (6 electrons)
Free radical e.g. .CH3 (7 electrons)
vp vp
7.(c) sin60° = Nitrene e.g. CH3N (6 electrons)
v
v Carbanion e.g. CH3- (8 electrons)
3v 60
vp = (CH3)3CNO2, CCl3CHO and (CH3)3CHO do not have
2 26.(d)
α hydrogen atoms so they do not show tautomerism.
27.(a) +R or +M groups viz. –OH, OR, –NH2, –X etc give
8.(c) ortho and para substituted product due to mesomeric
Q Q effect or resonating effect.
28.(c)
a/2 a/2
29.(a) BA, then AB = A
Qq Q.Q Q
= q= 1 2–i 2–i 2–i
a2 40a2 4 30.(a) z= × = =
40 2 + i 2 – i 2 2 – i2 5
4
2
2+i
R' 2l z̄ =
9.(b)
R
= () l
=4
31.(c)
5
AM × H.M = GM2
R' = 4R
G2
 810-4 or, H.M =
A
10.(c) E= = = 1.6mV
t 0.5
32.(c)  lies on 3rd quadrant.
11.(a) VL = 60V, VC = 30V, VR = 40V
 7
 =+ =
V = VR2 + (VL-VC)2= 50V 6 6
2eV 7
12.(d) v= = 21.81011100 = 6106 m/s Most general value = 2n +
6
m
0
13.(a) = hf0 f0 = = 81014 Hz
h
33.(b) Focus = (–52+ 3‚ 6 +2 6) = (–1, 6)
14.(b) P-type semiconductor holes are the majority charge 6 6 6 6
carriers. 34.(b) Let a = a1 i + a2 j + a3 k

15.(a) No. of protons = No. of mole × NA × No. of protons 66 66 66

Then, a . i = a1, a . j = a2, a .k = a3
in one molecule of CaCO3
666 666 666
16.(b) So, (a . i ) i + (a . j ) j + (a .k )k
6 6 6 6
= a1 i + a2 j + a3 k = a

1
 PEA Association Pvt. Ltd. Thapathali, Kathmandu, Tel: 5345730, 5357187
2082-2-17 Hints & Solution
35.(a) Section – II
36.(b) Let y = sec2x, z = tanx h g
61.(c) = (2n – 1)
dy 2 2
= 2secx.secx tanx
dx
1 1 2 g
dz or, × gn = (2n – 1)
2 2 2
& = sec2x
dx
or, n2 – 4n + 2 = 0
dy
 = 2 tanx or, n = 3.42 sec
dz
 1
sin–1(cosx) = – cos–1(cosx)  h = g (3.42)2
37.(b)
2 2

 1
= –x = × 10 (3.42)2
2 2

 x2 = 58 m
Now, I sin–1(cosx) dx = x– +c
2 2 Gm1 Gm2 1
62.(c) = x= m
x2 (1-x)2 11
38.(c) xy = 1 which is rectangular hyperbola. So, e = 2.
39.(a) 63.(b) Energy stored = K.E. of mass
40.(b) (0, 1, 0) 1 YAe2 1
= mv2
2 ml 2
41.(d) Greatest coefficient is the coeff. of mid term.
1 YAe2 5 × 108 × 10–6 × 0.022
42.(d) f(x) = will be minimum when v= = = 20 m/s
3sinx – 4cosx + 7 ml 5 × 10–3 × 0.1
3sinx – 4cosx + 7 is maximum.
64.(b) E = AT4t = 4.45 kJ
Maximum of denominator
( – 1)t (1.5 – 1) × 6 × 10–6
= 32 + 42 + 7 = 5 + 7 = 12 65.(a) ( – 1)t = n,  = =
n 5
43.(c) The given equation are intersecting lines. = 6 × 10–7 m = 6000 Å
44.(c) ax + by = 2ab
1 stress 1 Y × strain
x y 66.(b) f0 = = = 170 Hz
or, + =1 2L  2l 
2b 2a
Q1Q2 Q1Q2
1 1 67.(c) F = 9109.  r2 = 9  109 = 9cm
A= × b × h = . 2b.2a = 2ab r2 F
2 2
2 0 2
68.(b) Amount of heat energy required for the water to boil
45.(a) I –1
|x| dx = I –1
(–x) dx + I xdx
0
Q = 1 (100 - 20)  4200 + 42080 = 369600J

2 0 2 2
Q = 90% of Pt, t = 467 sec
x x
= [ ] +[ ]–
2 –1 2 0 69.(d)
1
E = mv2
2
1 4 0
= –(0 – ) + ( – ) 2E 2 × 2 × 106 × 1.6 × 10–19
2 2 2 v= =
m 1.67 × 10–27
1 5
= +2= = 1.96 × 107 m/s
2 2
46.(b) F = Bev = 2.5 × 1.6 × 10–19 × 1.96 × 107
47.(a) Here, a = cos2 – 1 = –sin2 = 7.84 × 10–12 N
b = sin2 N
70.(c) L= = 2.510–3 H
and a+b=0 I

So, the lines are perpendiculars 1

The magnetic energy stored, U = LI2 = 5  10–3 J
2
48.(a) Obvious
49.c 50.c 51.a 52.a 53.c 54.c hc
71.(d) 0 = – K.E. = 3  10–19
56.b 57.a 58.b 59.b 60.b 
55.c
310-19
f0 = = 4.51014 Hz
h

2
 PEA Association Pvt. Ltd. Thapathali, Kathmandu, Tel: 5345730, 5357187
2082-2-17 Hints & Solution
1 1 1 81.(c) B shows + I effect and hyperconjugation
72.(d) For 1st member of Balmer series
B' ( )
=R –
4 9
C shows - I effect D shows -R and -I effect
36
 B = dy fx 2ax + 2hy
5R 82.(a) =– =–
dx fy 2hx + 2by
For second member of same series, ax + hy
=–
hx + by
1 1 1 16
B'
=R (–
4 16
B' = )
3R
……(i)
83.(a) f(x) = y = x2 – 6x + 9 – 3
B' 16 × 5R y + 3 = (x – 3)2  0
i.e. =
B 3R × 36
y+30
20
 B' = × 6563 = 4861Å y  –3
27

N' 84.(b) z is a locus of a point whose distance from a point (3,

73.(b) 4) is always 5 unit. So, locus of z is a circle.
N0

N N' 1 3 OR, put z = x + iy and solve.

So, =1– =1– =
N0 N0 4 4
We get; (x – 3)2 + (y – 4)2 = 25
t
N 1 T1/2 85.(a) Since, one of the lines bisects the angle b/w the axes
N0
= () 2 so the line is either y = x or

t y = –x
3 1 T1/2
or,
4
=() 2 Then the eqn is

3 ax2  2hx2 + bx2 = 0

ln( )
4 t
or, = or, a + b =  2h
1 T
ln( )
1/2
2  (a + b)2 = 4h2

or, t = 224 yrs 86.(d) The line passes through the centre of the circle. So, it
is a diameter.
74.(a) MnO4- + 8H+ + 5e- → Mn2+ + 4H2O]×3
 Angle between diameter and tangent of
Fe2+ → Fe3+ + 1e-]×5 circle is 90°
As 5 moles of Fe(C2O4) = 3 moles of KmnO4 87.(a) If a = 0, by + cz + d = 0 is a plane parallel to x-axis.
So, 1 mol of Fe(C2O4) = 3/5 moles of KmnO4 = 0.6 6 6 6
mol 6 6 i j k
88.(b) a ×b =1 1 1
75.(a) Nmix = (N1V1 + N2V2+ N3V3)/Vtotal –2 3 1

76.(b) 71 parts of chlorine combine with 32 parts sulphur 6 6 6

= –2 i – 3 j + 5k
35.5 parts of chlorine combine with 16 parts of
sulphur 1 6 6 38
Area = |a × b | =
2 2
Hence, eq.wt of S in SCl2 = 16
89.(b) a1/x = b1/y = c1/z = k
77.(d) 1mol of Au = 197g = 0.197kg = 6.02 × 1023 atoms so,
19.7 kg Au = 6.02 × 1025 atoms Then, a = kx, b = ky, c = kz
78.(a) No. of mol × NA Since, a, b, c are in G.P.
79.(c) Bond length order: Single bond > bond created by b2 = ac
resonance > double bond > triple bond
k2y = kx.ky = kx+y
80.(c)
or, 2y = x + y

3
 PEA Association Pvt. Ltd. Thapathali, Kathmandu, Tel: 5345730, 5357187
2082-2-17 Hints & Solution
 x, y, z are in A.P. dr 9
= cm/sec
dt 128
2
90.(a) nn! = (n –n 1)! 94.(a) Let y = sinx

n–1+1 Then dy = cosx dx

=
(n – 1)!

When x = 0; y = 0 and when x = , y = 1
1 1 2
= + 
(n – 2)! (n – 1)!
/2 1 1

= 2e
Then I 0
cosx
1 + sin2x
dx = I 1 dy+ y = [tan
0
2
–1
y] =
0 4

91.(c) f '(x) = 4x3 + 12x2 a

f"(x) = 12x + 24x 2

95.(c) Area = 2 I ydx
0

a
= 12x(x + 2)
= 2 4a I 21 dx
x
Point of inflection, x = 0, x = –2
a3/2 8 2
i.e. x  (–, –2)(0, ) = 4 a.
3/2 3
= a

92.(b) No of diagonals, nC2 – n = 144

96.(c) Apply, R2  R2 – R1
It is true when n = 11
and R3  R3 – R1
4
V = r3
93.(d)
3 1
= 0
1
x
1
0 = xy
dv 4 dr 0 0 y
=  3r2
dt 3 dt
i.e.  is divisible by both x & y
dv 97.(c) 98.(b) 99.(c) 100.(d)
18 = 4r2
dt

…The End…