CT2000B Cyanoacrylate, Rubber Toughened

Safety Data Sheet

according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
Reference number: 01-005-2406
Issue date: 13/05/2024 Version: 1.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form : Mixture
Product name : CT2000B Cyanoacrylate, Rubber Toughened
UFI : 64MR-29MH-U7DG-T10W
Product code : CT2000B
Type of product : adhesives
Product group : Trade product

1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Use of the substance/mixture : Cyanoacrylate adhesive
Use of the substance/mixture : Adhesives, sealants
Function or use category : Adhesives, binding agents

1.2.2. Uses advised against

No additional information available

1.3. Details of the supplier of the safety data sheet

Manufacturer Only Representative

Chemence Ltd Chemence Graphics France SAS
13 Princewood Road, Parc d'activites Frederic Fays
Corby, 15, rue de la ligne de l'Est
Northamptonshire NN17 4XD 69100 Villeurbanne, Lyon,
United Kingdom France

Tel: +44 (0)1536 402600 Tel: +44 (0)1536 402600

Faxl: +44 (0)1536 400266 Faxl: +44 (0)1536 400266

email:[email protected] email:[email protected]

1.4. Emergency telephone number

Emergency number : +44 (0)1536 402600 (Monday - Friday 8:00 to 17:30)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]
Skin corrosion/irritation, Category 2 H315
Serious eye damage/eye irritation, Category 2 H319
Specific target organ toxicity – Single exposure, Category 3, H335
Respiratory tract irritation
Full text of H- and EUH-statements: see section 16

Adverse physicochemical, human health and environmental effects

No additional information available

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :

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CT2000B Cyanoacrylate, Rubber Toughened
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

GHS07
Signal word (CLP) : Warning
Contains : ethyl 2-cyanoacrylate
Hazard statements (CLP) : H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H335 - May cause respiratory irritation.
Precautionary statements (CLP) : P261 - Avoid breathing fume, vapours.
P271 - Use only outdoors or in a well-ventilated area.
P280 - Wear eye protection, protective gloves.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P337+P313 - If eye irritation persists: Get medical advice/attention.
EUH-statements : EUH202 - Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach
of children.
EUH208 - Contains Cis-1,2,3,6-tetrahydrophthalic anhydride. May produce an allergic
reaction.

2.3. Other hazards

Other hazards which do not result in classification : Contact with skin through cellulose based fabrics (i.e cotton, rayon, linen, viscose)
generates heat and may cause burns.

Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII

The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting
properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission
Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %

SECTION 3: Composition/information on ingredients

3.1. Substances
Not applicable

3.2. Mixtures

Name Product identifier % Classification according to

Regulation (EC) No. 1272/2008
[CLP]
ethyl 2-cyanoacrylate CAS-No.: 7085-85-0 ≥ 75 – < 90 Skin Irrit. 2, H315
substance with national workplace exposure limit(s) EC-No.: 230-391-5 Eye Irrit. 2, H319
(IE) EC Index-No.: 607-236-00-9 STOT SE 3, H335
REACH-no: 01-2119527766-
29

Cis-1,2,3,6-tetrahydrophthalic anhydride CAS-No.: 935-79-5 ≥ 0.3 – < 1 Eye Dam. 1, H318

EC-No.: 213-308-7 Resp. Sens. 1, H334
EC Index-No.: 607-099-00-5 Skin Sens. 1, H317
Aquatic Chronic 3, H412

1,4-dihydroxybenzene CAS-No.: 123-31-9 ≥ 0.01 – < 0.1 Carc. 2, H351

substance with national workplace exposure limit(s) EC-No.: 204-617-8 Muta. 2, H341
(IE) EC Index-No.: 604-005-00-4 Acute Tox. 4 (Oral), H302
Eye Dam. 1, H318
Skin Sens. 1, H317
Aquatic Acute 1, H400 (M=10)

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CT2000B Cyanoacrylate, Rubber Toughened
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

Specific concentration limits:

Name Product identifier Specific concentration limits (%)

ethyl 2-cyanoacrylate CAS-No.: 7085-85-0 (10 ≤ C ≤ 100) STOT SE 3, H335

EC-No.: 230-391-5
EC Index-No.: 607-236-00-9
REACH-no: 01-2119527766-
29
Full text of H- and EUH-statements: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures general : Do not pull bonded skin apart.
First-aid measures after inhalation : Move the affected person away from the contaminated area and into the fresh air. If
symptoms persist, consult a doctor.
First-aid measures after skin contact : Do not pull bonded skin apart. Remove all contaminated clothing and footwear. Unless
stuck to skin. Wash immediately with plenty of soap and water. Any bonded skin should be
gently peeled apart, preferably after soaking in warm, soapy water. In the case of large
spills on the skin, superficial burns may occur - treat accordingly. If irritation persists, consult
a doctor.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. If the eyelid is bonded closed, do not force
open. Cover with wet pad soaked in warm water. Get prompt medical attention in case solid
particles of cured cyanoacrylate get trapped behind the eye, there is a possibility of causing
abrasive damage. The affected eye should be covered with wet dressing until the
separation process is complete, usually 1-3 days. If eye irritation persists, consult a
specialist.
First-aid measures after ingestion : The product will polymerise immediately in the mouth, making it almost impossible to
swallow, but beware of possible choking hazard. Make sure the airways are not obstructed.
Saliva will separate the solidified product from the mouth within a few hours. If symptoms
persist, consult a doctor.

4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects : Not expected to present a significant hazard under anticipated conditions of normal use.
Symptoms/effects after inhalation : May cause shortness of breath, tightness of the chest, a sore throat and cough.
Symptoms/effects after skin contact : May cause an allergic skin reaction. Cyanoacrylates bond skin in seconds. In the case of
large spills on the skin, superficial burns may occur - treat accordingly.
Symptoms/effects after eye contact : Causes eye irritation. redness, itching, tears. Cyanoacrylates bond eyelids in seconds.
Symptoms/effects after ingestion : Causes irritation of the mouth and throat. The product will polymerise immediately in the
mouth, making it almost impossible to swallow, but beware of possible choking hazard.
Chronic symptoms : Repeated or prolonged skin contact can result in sensitisation in susceptible individuals.

4.3. Indication of any immediate medical attention and special treatment needed
An eyewash station should be available on the premises. Do not pull bonded skin apart.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO₂).
Unsuitable extinguishing media : high volume water jet or water based extinguishing media.

5.2. Special hazards arising from the substance or mixture

Fire hazard : Hazardous polymerization may occur if exposed to fire conditions.
Explosion hazard : Prolonged exposure to fire may cause containers to rupture/explode.
Reactivity in case of fire : On heating, there is a risk of bursting due to internal pressure build-up. Cool down the
containers exposed to heat with a water spray.

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CT2000B Cyanoacrylate, Rubber Toughened
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

Hazardous decomposition products in case of fire : Combustion products may include the following: carbon oxides (CO, CO₂) (carbon
monoxide, carbon dioxide) nitrogen oxides (NO, NO₂ etc.). Fire could produce a
combination of irritating and toxic gases.

5.3. Advice for firefighters

Precautionary measures fire : Exercise caution when fighting any chemical fire. Do not approach fire except upwind and
only with proper skin and respiratory protection (supplied air only). When
cooling/extinguishing: no water in the substance.
Firefighting instructions : Do not allow water to enter the vessels, a violent reaction may occur.
Protection during firefighting : Use self-contained breathing apparatus and chemically protective clothing. Avoid contact
with eyes, skin and clothing.
Other information : Do not allow run-off from fire-fighting to enter drains or water courses.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures : Avoid contact with skin and eyes. Cyanoacrylates bond skin and eyelids in seconds.
Provide emergency eye wash equipment with clean water at spill site.

6.1.1. For non-emergency personnel

Protective equipment : Gloves.
Emergency procedures : See section 8 of the SDS for more information on personal protective equipment. Avoid
contact with skin, eyes and clothing.

6.1.2. For emergency responders

Protective equipment : Protective gloves. ISO 374-2. Safety glasses. ISO 16321-1.
Emergency procedures : Do not touch or walk on the spilled product. Mark out the contaminated area with signs and
prevent access to unauthorized personnel. Stop the leak. Turn leaking containers leak-side
up to prevent the escape of liquid.

6.2. Environmental precautions

For a large spillage, contain the spillage by bunding. Do not allow contact with water. Do not allow to enter drains or water courses.

6.3. Methods and material for containment and cleaning up

For containment : For large spills, confine the spill in a dike and charge it with wet sand or earth for
subsequent safe disposal. (Do not use cloths; rags or materials made from cellulose).
Methods for cleaning up : Absorb spilled material with sand or earth. (Do not use cloths; rags or materials made from
cellulose). Or polymerise slowly with water (~10:1, adhesive : water) and then scrape up
residue. Place in an appropriate container and dispose of the contaminated material at a
licensed site.
Other information : For disposal of contaminated materials refer to section 13 : "Disposal considerations".

6.4. Reference to other sections

For further information refer to section 8: "Exposure controls/personal protection". For further information refer to section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Additional hazards when processed : Cyanoacrylates bond skin and eyelids in seconds.
Precautions for safe handling : Avoid contact with skin, eyes and clothing. Ensure that there is a suitable ventilation system.
Do not handle in a confined space. Ambient humidity should be >35% to minimise
discomfort.
Hygiene measures : Always wash hands after handling the product.

7.2. Conditions for safe storage, including any incompatibilities

Technical measures : Store in a well-ventilated place. Keep container tightly closed. Store away from direct
sunlight or other heat sources.

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CT2000B Cyanoacrylate, Rubber Toughened
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

Storage conditions : Keep only in original container. Protect from sunlight. For optimum shelf-life, it is
recommended to keep the product in a refrigerated storage area. . Storage temperature 2-
8°C.
Incompatible products : Oxidizing agent. Strong bases. Water. Amines. alcohols.
Incompatible materials : Heat sources. Water, humidity. Direct sunlight.
Storage temperature : 2 – 24 °C For optimum shelf-life, it is recommended to keep the product in a refrigerated
storage area.
Storage area : Store in a well-ventilated place. Store in a dry place.
Packaging materials : Always store product in a container of the same material as original container.

7.3. Specific end use(s)

adhesives.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

8.1.1 National occupational exposure and biological limit values

ethyl 2-cyanoacrylate (7085-85-0)

Ireland - Occupational Exposure Limits

Local name Cyanoacrylate, Ethyl [Ethyl cyanoacrylate]

OEL TWA 0.2 ppm

OEL STEL 1 ppm

Regulatory reference Chemical Agents Code of Practice 2021

1,4-dihydroxybenzene (123-31-9)
Ireland - Occupational Exposure Limits

Local name Hydroquinone [p-Dihydroxybenzene]

OEL TWA 0.5 mg/m³

Remark Sens. (In the workplace respiratory or dermal exposures to sensitising agents may occur.
Sensitizers may evoke respiratory or dermal reactions, e.g. asthma, rhinitis and allergic
contact dermatitis. The notation does not distinguish between respiratory or dermal
sensitisation. Chemical agents that are sensitizers present special problems in the
workplace. Should an employee become sensitised, subsequent exposure may cause
intense responses, even at low exposure concentrations well below the OELV. Exposure
should be eliminated or significantly reduced through control measures such as
engineering and process controls and use of personal protective equipment (PPE))

Regulatory reference Chemical Agents Code of Practice 2021

8.1.2. Recommended monitoring procedures

No additional information available

8.1.3. Air contaminants formed

No additional information available

8.1.4. DNEL and PNEC

CT2000B Cyanoacrylate, Rubber Toughened

DNEL/DMEL (Workers)

Acute - local effects, inhalation 9.25 mg/m³

8.1.5. Control banding

No additional information available

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CT2000B Cyanoacrylate, Rubber Toughened
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

8.2. Exposure controls

8.2.1. Appropriate engineering controls

Appropriate engineering controls:

Ensure that there is a suitable ventilation system. Wear recommended personal protective equipment. See section 7 of the SDS.

8.2.2. Personal protection equipment

Personal protective equipment:

Safety glasses. (ISO 16321-1). Gloves. (ISO 374-2).
Personal protective equipment symbol(s):

8.2.2.1. Eye and face protection

Eye protection:
Safety glasses. (ISO 16321-1)

Eye protection

Type Field of application Characteristics Standard

Safety glasses Droplet With side shields ISO 16321-

1:2021

8.2.2.2. Skin protection

Skin and body protection:

Normal overalls

Hand protection:
Wear protective gloves. (ISO 374-2)

Hand protection

Type Material Permeation Thickness (mm) Penetration Standard

Reusable gloves Nitrile rubber (NBR), 3 (> 60 minutes) >0.15 EN 374-2

Viton® II

8.2.2.3. Respiratory protection

Respiratory protection:
[In case of inadequate ventilation] wear respiratory protection. Recommended: Filter type A (brown). Keep self contained breathing apparatus
readily available for emergency use.

Respiratory protection

Device Filter type Condition Standard

Reusable half mask Type A - High-boiling (>65 °C) If conc. in air > exposure limit EN 140, EN 405,
organic compounds EN 14387

8.2.2.4. Thermal hazards

No additional information available

8.2.3. Environmental exposure controls

Environmental exposure controls:

Do not discharge into drains or the environment.
Other information:
Do not eat, drink or smoke when using this product. Emergency eye wash fountains should be available in the immediate vicinity of any potential
exposure.

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CT2000B Cyanoacrylate, Rubber Toughened
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Liquid
Colour : Black.
Appearance : medium viscous liquid.
Odour : Acrid.
Odour threshold : Not available
Melting point : -31 °C
Freezing point : Not available
Boiling point : 214 °C @ 100.3 Kpa
Flammability : Not flammable
Explosive properties : Product is not explosive.
Oxidising properties : Not oxidising. by EC criteria.
Lower explosion limit : Not available
Upper explosion limit : Not available
Flash point : > 85 °C
Auto-ignition temperature : 485 °C @ 1013 hPa
Decomposition temperature : Not available
pH : substance/mixture reacts with water
Viscosity, kinematic : ≈ 1455 mm²/s (calculated value)
Viscosity, dynamic : ≥ 1600 cP Anton Paar cone and plate, controlled stress rheometer
Solubility : Soluble in acetone. Reacts violently on contact with water.
Water: 24 μg/l @ 20 °C and pH 6.6
Partition coefficient n-octanol/water (Log Kow) : Not available
Partition coefficient n-octanol/water (Log Pow) : 0.776 @ 22 °C & pH 6.3
Vapour pressure : 21 Pa @20°C
Vapour pressure at 50°C : Not available
Density : Not available
Relative density : ≈ 1.1
Relative vapour density at 20°C : Not available
Particle characteristics : Not applicable

9.2. Other information

9.2.1. Information with regard to physical hazard classes
No additional information available

9.2.2. Other safety characteristics

VOC content : < 3 g/l
Additional information : Polymerises on exposure to water (moisture)

SECTION 10: Stability and reactivity

10.1. Reactivity
The product is non-reactive under normal conditions of use, storage and transport. Do not allow contact with water.

10.2. Chemical stability

Stable under normal conditions of use. Hazardous polymerization may occur if exposed to fire conditions. Polymerises on exposure to water
(moisture).
Hardening time : < 50 Seconds

10.3. Possibility of hazardous reactions

Stable under normal conditions of use. Polymerises on exposure to temperature rise: pressure build-up may cause closed container to burst.

10.4. Conditions to avoid

Heat. High temperature. Open flame. Water, humidity. Protect from sunlight.

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CT2000B Cyanoacrylate, Rubber Toughened
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

10.5. Incompatible materials

Incompatible with water, humid air. Oxidizing agent. Strong bases. Amines. alcohols.

10.6. Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced. When exposed to high temperatures may
produce hazardous decomposition products such as carbon monoxide and dioxide, smoke, nitrogen oxides (NOx). Fire could produce a
combination of irritating and toxic gases.

SECTION 11: Toxicological information

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

Acute toxicity (oral) : Not classified (Based on available data, the classification criteria are not met)
Acute toxicity (dermal) : Not classified (Based on available data, the classification criteria are not met)
Acute toxicity (inhalation) : Not classified (Based on available data, the classification criteria are not met)

ethyl 2-cyanoacrylate (7085-85-0)

LD50 oral rat > 5000 mg/kg bodyweight (OECD 423: Acute Oral Toxicity – Acute Toxic Class Method,
Rat, Male, Experimental value, Oral, 14 day(s))

LD50 dermal rabbit > 2000 mg/kg bodyweight LD50 dermal rabbit. (OECD 402 method)

1,4-dihydroxybenzene (123-31-9)
LD50 oral rat 367.3 mg/kg bodyweight Animal: rat, Animal sex: female, OECD Guideline 401

LD50 dermal rabbit > 2000 mg/kg bodyweight (OECD 402 method)
Skin corrosion/irritation : Causes skin irritation.
pH: substance/mixture reacts with water

1,4-dihydroxybenzene (123-31-9)
pH 3.7
Serious eye damage/irritation : Causes serious eye irritation.
pH: substance/mixture reacts with water

1,4-dihydroxybenzene (123-31-9)
pH 3.7
Respiratory or skin sensitisation : Not classified (Based on available data, the classification criteria are not met)

CT2000B Cyanoacrylate, Rubber Toughened

Additional information Contains :. Cis-1,2,3,6-tetrahydrophthalic anhydride. May cause sensitisation of
susceptible persons by skin contact
Germ cell mutagenicity : Not classified (Based on available data, the classification criteria are not met)
Carcinogenicity : Not classified (Based on available data, the classification criteria are not met)

1,4-dihydroxybenzene (123-31-9)
IARC group 3 - Not classifiable
Reproductive toxicity : Not classified (Based on available data, the classification criteria are not met)

1,4-dihydroxybenzene (123-31-9)
NOAEL (animal/male, F0/P) 15 mg/kg bodyweight

NOAEL (animal/female, F0/P) 15 mg/kg bodyweight

NOAEL (animal/male, F1) 150 mg/kg bodyweight

NOAEL (animal/female, F1) 150 mg/kg bodyweight

STOT-single exposure : May cause respiratory irritation.

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CT2000B Cyanoacrylate, Rubber Toughened
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

ethyl 2-cyanoacrylate (7085-85-0)

STOT-single exposure May cause respiratory irritation.
STOT-repeated exposure : Not classified (Based on available data, the classification criteria are not met)
Aspiration hazard : Not classified (Based on available data, the classification criteria are not met)

CT2000B Cyanoacrylate, Rubber Toughened

Viscosity, kinematic ≈ 1455 mm²/s (calculated value)

11.2. Information on other hazards

11.2.1. Endocrine disrupting properties
No additional information available

11.2.2. Other information

Potential adverse human health effects and : Causes skin irritation,Causes serious eye irritation,Inhalation of vapours may cause
symptoms respiratory irritation,Cyanoacrylates bond skin and eyelids in seconds.

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment.
Ecology - water : Polymerises on exposure to water (moisture).
Hazardous to the aquatic environment, short–term : Not classified (Based on available data, the classification criteria are not met)
(acute)
Hazardous to the aquatic environment, long–term : Not classified (Based on available data, the classification criteria are not met)
(chronic)
Additional information : Based on available data, the classification criteria are not met.

CT2000B Cyanoacrylate, Rubber Toughened

Additional information This product is not considered to be hazardous to the aquatic environment due to the
rapid polymerisation on contact with water.

1,4-dihydroxybenzene (123-31-9)
LC50 - Fish [1] 0.638 mg/l Test organisms (species): Oncorhynchus mykiss (previous name: Salmo
gairdneri)

EC50 - Crustacea [1] 0.134 mg/l Species: Daphnia magna

EC50 - Crustacea [2] 0.061 mg/l Species: Daphnia magna

12.2. Persistence and degradability

CT2000B Cyanoacrylate, Rubber Toughened

Persistence and degradability Biodegradability in water: no data available.

ethyl 2-cyanoacrylate (7085-85-0)

Persistence and degradability Readily biodegradable in water.

Cis-1,2,3,6-tetrahydrophthalic anhydride (935-79-5)

Persistence and degradability Rapidly degradable

1,4-dihydroxybenzene (123-31-9)
Persistence and degradability Rapidly degradable

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CT2000B Cyanoacrylate, Rubber Toughened
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

12.3. Bioaccumulative potential

CT2000B Cyanoacrylate, Rubber Toughened

Partition coefficient n-octanol/water (Log Pow) 0.776 @ 22 °C & pH 6.3

Bioaccumulative potential No bioaccumulation potential.

ethyl 2-cyanoacrylate (7085-85-0)

Partition coefficient n-octanol/water (Log Pow) 0.776 @22°C & pH 6.3

Bioaccumulative potential Low bioaccumulation potential. (Log Kow < 4).

1,4-dihydroxybenzene (123-31-9)
Partition coefficient n-octanol/water (Log Pow) 0.5 – 0.59

12.4. Mobility in soil

CT2000B Cyanoacrylate, Rubber Toughened

Ecology - soil Potential for mobility in soil is slight.

Additional information Mobility is considered to be very low due to rapid polymerisation with water.

ethyl 2-cyanoacrylate (7085-85-0)

Organic Carbon Normalized Adsorption Coefficient 0.834
(Log Koc)

Ecology - soil Mobility is considered to be very low due to rapid polymerisation with water.

12.5. Results of PBT and vPvB assessment

No additional information available

12.6. Endocrine disrupting properties

No additional information available

12.7. Other adverse effects

No additional information available

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Regional waste regulation : Disposal must be done according to official regulations.
Waste treatment methods : The product can be polymerised slowly with water (10:1, adhesive : water). Cured product
can then be disposed of in land-fill sites by licensed contractors. Use suitable disposal
containers.
Product/Packaging disposal recommendations : Do not dispose of the packaging without first carrying out the necessary cleaning.
Additional information : Empty containers should be taken for recycling, recovery or waste in accordance with local
regulation.
Ecological information : Do not empty into drains.
European List of Waste (LoW, EC 2000/532) : 08 04 09* - waste adhesives and sealants containing organic solvents or other dangerous
substances
HP Code : HP5 - “Specific Target Organ Toxicity (STOT)/Aspiration Toxicity:” waste which can cause
specific target organ toxicity either from a single or repeated exposure, or which cause
acute toxic effects following aspiration.
HP4 - “Irritant – skin irritation and eye damage:” waste which on application can cause skin
irritation or damage to the eye.
HP13 - “Sensitising:” waste which contains one or more substances known to cause
sensitising effects to the skin or the respiratory organs.

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CT2000B Cyanoacrylate, Rubber Toughened
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

SECTION 14: Transport information

In accordance with ADR / IMDG / IATA / ADN / RID

14.1. UN number or ID number

UN-No. (ADR) : UN 3334
UN-No. (IMDG) : UN 3334
UN-No. (IATA) : UN 3334
UN-No. (ADN) : UN 3334
UN-No. (RID) : UN 3334

14.2. UN proper shipping name

Proper Shipping Name (ADR) : Aviation regulated liquid, n.o.s. (MIXTURE CONTAINS ethyl 2-cyanoacrylate)
Proper Shipping Name (IMDG) : AVIATION REGULATED LIQUID, N.O.S. (MIXTURE CONTAINS ethyl 2-cyanoacrylate)
Proper Shipping Name (IATA) : Aviation regulated liquid, n.o.s. (MIXTURE CONTAINS ethyl 2-cyanoacrylate)
Proper Shipping Name (ADN) : aviation regulated liquid, n.o.s. (MIXTURE CONTAINS ethyl 2-cyanoacrylate)
Proper Shipping Name (RID) : Aviation regulated liquid, n.o.s. (MIXTURE CONTAINS ethyl 2-cyanoacrylate)
Transport document description (IMDG) : UN 3334 AVIATION REGULATED LIQUID, N.O.S. (MIXTURE CONTAINS ethyl 2-
cyanoacrylate), 9
Transport document description (IATA) : UN 3334 Aviation regulated liquid, n.o.s. (MIXTURE CONTAINS ethyl 2-cyanoacrylate), 9,
III
Transport document description (ADN) : UN 3334 aviation regulated liquid, n.o.s. (MIXTURE CONTAINS ethyl 2-cyanoacrylate), 9
Transport document description (RID) : UN 3334 Aviation regulated liquid, n.o.s. (MIXTURE CONTAINS ethyl 2-cyanoacrylate), 9

14.3. Transport hazard class(es)

ADR
Transport hazard class(es) (ADR) : 9

IMDG
Transport hazard class(es) (IMDG) : 9
Danger labels (IMDG) : 9
:

IATA
Transport hazard class(es) (IATA) : 9
Danger labels (IATA) : 9
:

ADN
Transport hazard class(es) (ADN) : 9

RID
Transport hazard class(es) (RID) : 9

14.4. Packing group

Packing group (ADR) : Not applicable
Packing group (IMDG) : Not applicable
Packing group (IATA) : III
Packing group (ADN) : Not applicable
Packing group (RID) : Not applicable

14.5. Environmental hazards

Dangerous for the environment : No

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CT2000B Cyanoacrylate, Rubber Toughened
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

Marine pollutant : No
Other information : No supplementary information available

14.6. Special precautions for user

Overland transport
Classification code (ADR) : M11

Transport by sea
Special provisions (IMDG) : 960
Stowage category (IMDG) : None
Properties and observations (IMDG) : Not subject to the provisions of this Code but may be subject to provisions governing the
transport of dangerous goods by other modes.

Air transport
Transport regulations (IATA) : Primary packs containing less than 500ml are unregulated by this mode of transport and
may be shipped unrestricted.
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y964
PCA limited quantity max net quantity (IATA) : 30kgG
PCA packing instructions (IATA) : 964
PCA max net quantity (IATA) : 450L
CAO packing instructions (IATA) : 964
CAO max net quantity (IATA) : 450L
Special provisions (IATA) : A27
ERG code (IATA) : 9A

Inland waterway transport

Classification code (ADN) : M11

Rail transport
Classification code (RID) : M11

14.7. Maritime transport in bulk according to IMO instruments

Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations

REACH Annex XVII (Restriction List)

Contains no substance(s) listed on REACH Annex XVII (Restriction Conditions)

REACH Annex XIV (Authorisation List)

Contains no substance(s) listed on REACH Annex XIV (Authorisation List)

REACH Candidate List (SVHC)

Contains no substance(s) listed on the REACH Candidate List

PIC Regulation (Prior Informed Consent)

Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)

POP Regulation (Persistent Organic Pollutants)

Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)

Ozone Regulation (1005/2009)

Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 1005/2009 on substances that deplete the ozone layer)

Dual-Use Regulation (428/2009)

Contains no substance subject to the COUNCIL REGULATION (EC) No 428/2009 of 5 May 2009 setting up a Community regime for the control of
exports, transfer, brokering and transit of dual-use items.

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CT2000B Cyanoacrylate, Rubber Toughened
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

VOC Directive (2004/42)

VOC content : < 3 g/l

Explosives Precursors Regulation (2019/1148)

Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)

Drug Precursors Regulation (273/2004)

Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain
substances used in the illicit manufacture of narcotic drugs and psychotropic substances)

15.1.2. National regulations

No additional information available

15.2. Chemical safety assessment

No chemical safety assessment has been carried out for the substance or the mixture by the supplier

SECTION 16: Other information

Indication of changes:
Initial preparation date.

Abbreviations and acronyms:

CAS-No. Chemical Abstract Service number

ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways

ADR European Agreement concerning the International Carriage of Dangerous Goods by Road

ATE Acute Toxicity Estimate

DMEL Derived Minimal Effect level

DNEL Derived-No Effect Level

EC-No. European Community number

EC50 Median effective concentration

EN European Standard

IARC International Agency for Research on Cancer

IATA International Air Transport Association

IMDG International Maritime Dangerous Goods

IOELV Indicative Occupational Exposure Limit Value

LC50 Median lethal concentration

LD50 Median lethal dose

LOAEL Lowest Observed Adverse Effect Level

NOAEC No-Observed Adverse Effect Concentration

NOAEL No-Observed Adverse Effect Level

NOEC No-Observed Effect Concentration

OECD Organisation for Economic Co-operation and Development

OEL Occupational Exposure Limit

REACH Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006

WGK Water Hazard Class

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CT2000B Cyanoacrylate, Rubber Toughened
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

Data sources : Supplier's safety documents. ECHA (European Chemicals Agency). UNECE,
http://www.unece.org/.

Full text of H- and EUH-statements:

Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4

Aquatic Acute 1 Hazardous to the aquatic environment – Acute Hazard, Category 1

Aquatic Chronic 3 Hazardous to the aquatic environment – Chronic Hazard, Category 3

Carc. 2 Carcinogenicity, Category 2

EUH202 Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children.

EUH208 Contains Cis-1,2,3,6-tetrahydrophthalic anhydride. May produce an allergic reaction.

Eye Dam. 1 Serious eye damage/eye irritation, Category 1

Eye Irrit. 2 Serious eye damage/eye irritation, Category 2

H302 Harmful if swallowed.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H335 May cause respiratory irritation.

H341 Suspected of causing genetic defects.

H351 Suspected of causing cancer.

H400 Very toxic to aquatic life.

H412 Harmful to aquatic life with long lasting effects.

Muta. 2 Germ cell mutagenicity, Category 2

Resp. Sens. 1 Respiratory sensitisation, Category 1

Skin Irrit. 2 Skin corrosion/irritation, Category 2

Skin Sens. 1 Skin sensitisation, Category 1

STOT SE 3 Specific target organ toxicity – Single exposure, Category 3, Respiratory tract irritation

Safety Data Sheet applicable for regions : IE

Safety Data Sheet (SDS), EU

The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. Chemence Ltd. and/or its
agents cannot accept any liability for the use of information contained in this data sheet or for the use, application or processing of the product
described in this data sheet. Users should note the possibility of hazards occurring due to improper uses of the product.

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