1733861 i OMR Answer Sheet No. tT 4026 B.Sc. (IV Semester) Examination, 2022-23 jon Booklet Number Booklet Series A Chemistry Quantum Mechanics and Analytical Techniques [ Time : 1 : 30 Hours (To be filled in by the Candidate / Pra feel fame warei #8) [aaa 1:30 Roll No. (in gars) —$<_—_—_$_$_— [ Maximum Marks : 75 aap (sei 4) [ aftroas oie + 75 Roll No. (in vords))§ —_—_$—_— spate (sat 4) so. (i OO Enrolment No. (in figures) —_—_———__——_ meof College. —OSS— ‘Signature of Invigilator Sia BA . ou Priee & eenet Instructions to the Examinee ? went &s fre Pret 1. Do not open the booklet unless you are 1 regan a a ah er AH STR ST al asked to do so. sea-gftaen # 75 97 EI adtarell ot ford 50 2. The booklet contains 75 questions. 2 Examinee is required to answer any 50 7 oar questions in the OMR Answer-Sheet srl at & mg oMR sot we AE provided and not in the question booklet, 21 gaan ort 50 & site set I Ect se In case Examinee attempts more than 50 a Rei 8, mer so Set a @ eta fsa Questions, first 50 attempted questions a 3 505 a will be evaluated. All Questions carry equal sum) wiht weet & ofes wars @ marks. 3. Examine the Booklet and the OMR = 3. wedi ab gare siftee aed Bod oes gfe aT Answer-Sheet very carefully before you OMR sav a) eraurigde ta Al araget proceed. Faulty question booklet due to -aficren, Berl go rt 7a missing or duplicate pages/questions or at 7 we oa te me ea ea es seftran ae WoT Te aT aT ose a sree having any other discrepancy should be immediately replaced. fot a, 3a ged wea ail (Remaining Instructions on last page) (as Préa aPaa FS OR)The equation mv?=2h(v-v,) Is known 1. Witt mv?=2h(v-v_) FT 4 oor as: aren & (A) Einstein's photoelectric equa- (A) omgerein akereaigan atten tion (B) Maxwell equation (8) fete toe (Cc) Lummer equation (O) BER whore (p) all (0) wh 2, The relation between frequency (v), 2. argh (v), 34 (¢) den wer Fa (Y) A velocity (¢) and wave number (¥) is weet 2 ) yF% () pry (e) vet (8) vet = (Cc) vee era (0) v=a (0) vem 3. S-orbitals are 3, s-anfders or aan & (A) Spherically shape pay tae De (B) Dumb bell shape g® are (C) Both (A) and (B) (©) (A) 3k (B) at (D) None (p) wi adi 4. Ce (atom no.=58) is anelement of: 4, aiftam (atom no.=58) E> ame: (A) s-block (A) s-block (B) p-block (B) p-block (C) d-block (Cc) d-block (D) block (D) F-block 4oz6\a\2023 131 PTO. a lll33. Which one of the following is micro- 34. 35. x wave inactive? (A) HCI (B) Cl, (Cc) NO (D) CO Zero point energy of harmonic oscillator is (A) 1/2 hw (B) 3/2 hw (Cc) nw (D) 5/2 hw Yrmax OF which compound Is maxi- mum? (A) (B) (C) (D) YOO 4026\A\2023 33, Prater a tartar arr nrg ffir e (A) HCI (8) Cl, (c) NO CG 2) co 34, graff offices at op firg sat é + (A) /2 aw 7 (8) 3/2 Aw (c) aw (D) 5/2 nw ay 35, Roa attest An4, HlRraHTH 2? @)13. When scattering angle is zero then the compton shift will be ~ B (A) Zero (B) 0.02424 (C) 0.0484 (D) 0.07264 14. The black body emits : (A) Line spectrum (8) Band spectrum (C) Mixed spectrum (D) Continuous spectrum 15. Compton equation is (8) An= 7eld +088) (D) None of these 16. Wave function in quantum mech. represents : (A) A state of the system (B) Shape of the system (C) Probability of the system (D) Energy of the system 4 go2eiaiz023 bn (c) aa= bea-sine) we LL ste ao am oe} MT THC 13, 9 fare, ef me nfl- (69) 0) 2 a (B) 0.02424 De (c) 0.04844 &) (D) 0.0726A a, ger ag sala ae 8 (A) aga Sag (B) as aT ae (©) Pres BRT (D) Fre Sage 15. wrest aT e LAK) b= Pe(-cos®) (B) a= etd +cos8) of (©) ad= Ped-sine (0) ag ae 16, aaien aise H aa thoes carter 8 : (A) somrett abt RRerfer (B) sone ar Tea (C) someht a eisrer,(0) 4026\A\2023 Frequency v and wavelength 2 are related to each other: (A) vcd (B) vavx () vat (D) vvaad de-Broglie equation Is : (a) A= ay (8) mvr= nh (c) E=me? (0) e= 2 The molecular orbitals formed as 3 result to LCAO method not obey. (A) Pauliss exclusion principle (B) Hund's rule of maximum multi- plicity (C) Aufbau's principle (D) Beer's law The relationship x. ap2=Z& shows : (A) de-Broglie equation (B) Heisenberg's uncertainity prin- ciple (C) Aufbau principle Hund's rule 5. rf w a are 7. ATE a reg (A) v2. ve } (B) vada os 1 va pe aK i 6) (D) Jvaar 6. Biaineht attra @ + h YY a= inv (B) mvr= gh 409) (Cc) E=mc? (0) E=2 7. LOAO fats & omer sibs were Te Fei wae (A) Tisch & saaaia Fram oT (8) gs agen Frm or (C) sitar & Fran ar (D) ae & Fran or 8. der ax. ap 2 fi saftfa wen & (A) d-aiteh ater © Lg» ear icon Frere (C) stars fret (D) gs or Fray [4]10. ii. 12. 4026\A\2023 The de-Broglie wavelength of an 9, electron moving with kinetic encray x 13.6 ev will be. (A) 3.326x10°°m (B) 3.326107! cm (C) 3.326x10°8m (D) None of the above The possible sub shells in n=3 ener- gy shell are (A) spd (B) s.p.dF (C) sp (D) sonly Wave mechanical model of the atom depends upon (A) de-Broglie's concept of duality (B) Uncertainty principle (C) Schrodinger wave equation (D) All of the above Value of Laplacian operator V? 10. n=3 sof mar # arinfar seme 2: 11. © (8) arte wht 12. TIMEMRAEA STOREX aT TAB 13.6 ev at nftrot sat dt pra geayTa BY fame minted ern, (A) 3.326107? m (B) 3.326%107% cm (C) 3.326%10°% m AO) wetten 18 as Ei ? aR (A) spd wel (8) s.pd,f ARSE (C) 5p ol. 3 (D) sonly TT) Tea or aT MPawTE ATT... Frk wea 2: (A) 2 anet & dat rae (8) ofSfaraat Prom \) (Cc) atfene aaa wer o 2+e YY +s © ete (co) d+ o +e Os Bree21. Which of the following molecular or- bitals has highest energy? (A) x*2 py (B) x*2 px (C) o2py (D) o*2 pz Who phenomenon of photoelectric effect? 22. the successfully explained (A) Einstein (8) Maxwell (C) Bohr (D) Planck 23. Hamiltonian operator is- (A) Difference of kinetic eneray and potential energy (B) Product of kinetic energy and potential energy (C) Sum of kinetic energy and po- tential eneray (D) Square root of kinetic energy and potential energy 24, The wave number range that is used for IR radiation : (A) 2000-200 cm (B) 4000-400 cm=? (C) 200-10 cm-t (D) None of the above 4026\A\2023 . 21, 22. ie fAriRaa Yd Row ania wer A Tere watt t? (a) (B) () ) rarer Fg woe Bt ere at CTE waren fever ft? (A) smgeerr (B) Aaaec (C) ae (D) wie eres site yy LY n*2 py n*2 px o2py o*2 pz : (A) Wit sof ote Raft sata sia ey afta sat atk Refi sort or sere (C) att sat atk Rats sf actor (D) afetat Saf ste Rerferst Saif er niger 24. rare Paftoeor & fore weep aT wa es v JAY 2000-200 em? (B) 4000-400 cm= (C) 200-10 cm=* (0) sR A Bas as25. Energy of the particle in a one di- 25, gas infer aerdt HY anor at Soa mensional box is : ay nh? w B= pts aa a (8) = 23 a Be ~ wo e-em © B= 2h = (0) &= (0) B= game C122 26. The value of wave number incm™! of 26, Aah 25 um & a ae AT aT wave length 25 pm: wir Fem: mee 280 , (A) 400 cm _SA)- 400 cm Pros (8) 200 cm (8) 200 cm" $ tos! (C) 100 cm 6P 100 cm \ eis (D) 50 cm (D) 50cm -_ 27. The degeneracy of rotational energy 27, gif sat adi at ferpis fea art a ore levels is given by : a: (a) JG#1) (A) 3Q+1) (B) 30+2) (8) 30+2) (c) 30+3) De 300+3) la (D) (23+1) kBY (23+1) | 28, The maximum number of electrons (26. ayer Star H gaagra oft sift He | in a principal shell are : x (a) n (A) n (ay nt AB) (©) 20 (C) 2n? (D) 3n? he (D) 3n? A026\A12023, 19]AD. Vas, maximum among the following com- pounds? a b () [>~e (f 41, How many PMR signals given by the given compound (A) is (A) (A) 3 (B) 2 (5 (D) 4 42. Pick out the incorrect match- Nucleus. (A) (B) (Cc) (D) 4026\A12023 Oo . (C=O) of which compound is Spin 3/2 3 40, Praia cia # @ fn ett ov 41. 42. 113] (C=0) afters & Te (8) [>-e oO ©) fra 1d cific (A) 3 Fea PR (a) 3 (B) 2 () 5 (D) 4 Tee fora oa aR Nucleus Spin (A) ov 3/2 (B) Be 3 oO s® ° (Dp) oN 1 PTO.51. The number & IR active vibrational Modes for CO, molecules are: (A 4 (8) 3 (2 (oy a 52, Which one will show the non* transition? A (A) Alkenes: () bao Jj. (B) Alkynes . x () oiler (C) Carbonyis —— (D) All of the above: (0) sats wit 53. Raman effect is: 53. Ame: (A) Inelastic scattering of light (a) sere an ameerer wala (B) Elastic scattering of light (B) Serer amr weaTe WaT (C) Absorption of light (C) seer oT agin (D) All of the above (D) arte anit 54. In Raman spectrum the middié line 54, ean etagar a ne tar anecav Is called : x (a) wate (A) Raman line (8) ata (B) Rayleigh line 7 —_—_ 6 Arar wag tar (C) Functional group line ye E (D)_None of the above (D) ante 4 a ate aah 40261A\2023 (16) 55. The electron sf example of (A) Stark effec (8) Russel-Sa (©) Paschan-e (D) Vibration 56. How many h spectrum are 2 (8) 3 () 5 (0) 6 57. For oo" tr (A) IR regi (8) Visible (C) UV res (0) None « 58. Which mol energy? (A) 2 (8) (> (D) o* 4026\A1202343. How many NMR signats are found in 43, anger afte ergaeinhirr yclopropane and cyclopropene? tar Ferran et 7 (A) 23 23 () 34 (cy (0) 8,10 (0) 8,10 44. Which one of the following nucleus 44, Prafifisa a at an aam C5 CH Ht Gimmnioace ye eet & ", ic ‘0, cy (D) None of these (0) FAS og Number of signals gives by (A*) In 45, (at) & dt om ome Saag a Ramer St its PMR-spectrum is = x vent 4s. cH,—CH,-OH CH;—CH,-OH (ar) Oo) (A) one A) (8) Two ore (C) Three (© a (0) Four (0) ak 46. Which bond has maximum V,,, val- 46, fing are ar V,., TH waa afte 8? ue? 0 (A) -N-H ar on GD (©) -0-H AO Ors (0) ~S-H (0) -S-H 426.2023 114)47. Which of the following electromag: netic radiations has maximum wavet~ length? (a) (B) (c) (0) The vibrational frequency depend Uv-rays X-rays Radiowaves IR-rays 48. upon: (A) Reduced mass (B) Dipole moment (C) Force constant (D) All of these 49, The proton magnetic resonance is studied in- (A) (B) (c) (0) For the vibrational Raman spectrum Microwave region Radio-frequency region Infrared region Visible region 50 of a homonuclear diatomic molecule the selection rule under hormone approximation Is = (A) (B) (c) (D) All of these 40261A\2023 Av=0 only Av=+1 only 4v=+2 only a fra forge Gentiva ffir \F arftraemt arta 7 48. 49. 50. [15] (A) Uv-feract | (8) x-fi} = “sorte ats (D) 1R-freei aor argft Pk oi & (A) A ca (8) feqa ange (C) aa Praca (0) awh ster dada sare or eet feb fioar sre & (A) arg@raa ea (B) ei ongfe da (C) grace aa (0) aa da erect Reems 31 th eos Ta tage a fre sian wiftene 2 ona aor Fara 2 : (A) av=0 dart By Av=+1 tat oa (2) ) Ave+t2 dat (D) sare wh55. The electron spin resonance is an example of (A Stark effect (B) Russel-Saunders state (C) Paschan-Backett effect (D) Vibration effect 58. yaagr wan aqa ow ETT A (A ti6 ma or (B) Ta-ded geen at (C) orar-afee mae eT (0) Sa aT Q 56. How many hyperfine lines in ESR 56, Mn?*& ESR spectrum 4 Se Seas spectrum are shown by Mn?*? a anit (2 25 4 2 * 1 a @3 LL Lo (c) 5 «5 (0) 6 (0) 6 57. For oc* transition,» lies in 57. coot ARS Reasentuae: (A) IRregion ~ (a) IReTe (B) Visible region (B) qa aaa (Cc) ware (C) UV region (0 None of the above 58. Which molecular orbital is lowest in energy? (D) sais FS SS a 58. ota aitan mam Sots pas é? (A) i (A) % @ = (B) (C) © (Cc) o (D) o* “)(D) o* 4026\A\2023 017)59. The region between 1500-400 cm! Is called (A). Visible region (8) Ultraviolet region (C) Finger print region (D) None of these 60. A wave number of 4000 cm" corre- sponds to wavelength (4)- (A) 0.0025 (B) 0.000025 (C) 0.025 (D) 0.00025 61. Which of the following has higher Aman? (A) Cis-stilbene (B) Trans-stilbene (C) Both have same 2... ya (D) Cannot say 40z6vat2023 59, 1500-400 cm ® ata & ata ot wet 60. 61. 18] aaa & (a) qa aT (B) aerdtrtt era Te Bs) fom fic err (D) ete arg sei 4000 et! at ain ten fina ante -3M ae at 82 6-6xl0 (A) 0.0025 10 ooo ao (B) 0.000025 (C) 0.025 LUBY 0.00025 29 Profeiac a & fireét 1, sftres # (A) Rre-Reedr - (8) yha-Readt (©) tia, ware (0) Bera wa65. Which of the following electronic 6s frcstiftan a1 fon gAcrplfeem raz transitions — requires minimum feet expert sank fh TTT rt? energy? yn on? (A) nox . (B) non \ (B) noon . TN (C) 0-0" (C) ava 2 vi) (0) no* (0) none —— 66. Theintensity of Raman peakdepends , , 66. Ha da ai Ain a7 at .......... Pre on the of the molecule. oN arch t1 (A) Dipole moment (A) feqa amt (B) Absorption maximum @ gran after (C) Polarizability (Cc) gam (D) None of these (0) a a ae = 67. Mass spectrometer separates ions, g7. ary erachiter frafafaa 2 a fab on the basis of which of the follow- % Str eae ee ne? LA) a (A) Mass ° (B) Mass-to-charge ratio we Jo morgan gr | (C) Molecular weight (C) sere sax G, (D) Charge . (D) sia 68. Which of the following is used 68. Sit wari H tac wx ana axa ob to bombard the sample in mass * fora Prafafaaa #8 firme seen Peer spectrometry? aren &? (A) Alpha partides al HEB BM (B) Neutrons (8) =r (C) Electrons (C) sdagiar aor shogfoons ia) (0) setawrrgy 2 73. The number of signals in the PMR 73, CH,OCH,CH, a fara PIAA 777) spectrum of CH,OCH,CH, will be- ‘eibsedt ath cheat vA eve oe Me (A) 1 (A) 4 \ ‘ (8) 2 (8) 2 j (© 3 rs f\ UY a ¢ 4 (0) 4 (02) 4 At , % 74, Which technique is known as colour 74, fig gant at in as wea Se writing? arene (A) Mass spectroscopy (A) are Baga (8) Chromatography 28) miter (C) NMR (C) ea (D) All of these (D) sate ait 75. In the chromatography the station- 75, pica 4 Ree ae. ary phase can be supported anfla er wad & on solid: woe OW (A) Solid only (B) Solid-tiquid ) ore exer (C) Liquid onty (C) wa (D) Liquid or gas Pt 40261A12023 [22]62. Which of the following is an auxo- chrome? 62. Rad aata woe steeiaie 87 (A) -NR, (B) >C-0 (C) >C-N- (D) >C-C< 63. Which of the following solvent is not 63. used in NMR? (A) CHCl, (B) D,0 (c) CCl, (D) cocl, 64. Hypsochromic shift is towards 64. (A) Lower intensity (B) Higher intensity AO Shorter wavelength (D) Longer wavelength 4026112023 119] (C) >C=N- Vy (D) >C=C< NMR & Prafefad 4 @ fa Gera oF saat Ae fea srren B? (A)CHCI, (8) 0,0 (c) CCl, (D) CDCI, fecataiftre Faroe fara atk ett 2? (A) oa daar (8) sation fey or wrth (D) rat aented69. The most intense peak In mass spec- GQ, mat Bag Ht arral Ata en A tra is - (a) a titan (A) Base peak a (B) Aenea ara tas (C) Fragment ion peak (Cc) dente grat das (D) None of these (0) wath and afi 2G 70. The spacing between lines within a 70. NMR Wag 4 uw nee a sere erga (B) Metastable ion peak multiplet in NMR spectrum is known dad gO at on at es (a) zara Rae (A) Chemical shift . (B) Coupling constant BY wr ere \ (©) Spin spin coupling (C) Reever gs (D) None of the above (D) ane 8 a ag AEF 71. Chemical shift value (5) with = 71. weTaPre Rime ara (5) faqa sere the increase in electronegativity H qfe bare ...... (A) Increases AAT wee Zz lon’ (B) Decreases (B) ueme (C) Cannot say (© sentient (D) No effect (D) arg wa at RX 7] 72. Which of the following is used asa 72, Praffaa 8 ata eI NMR Rea reference compound in NMR spec- hum dan atfires & wa F sei fier oe troscopy? a (A) Ethyl alcohol ‘ (a). eferer (B) Tetramethy! silane S _sey tia (C) Carbon tetrachloride (c) oa (D) None of the above (D) HTB 4026\A\2023 (2t]17. 18. 19, 20. For, H-like atom, the ground state energy in proportional to ; (A) y/z? (B) 2/n (C) pa? (D) pz? The angular part of an atomic orbital wave function depends upon- (A) monly (B) land m (C) nlandm (D) nand! The value of a in Schrodinger wave equation By ow BY, Bm = Bet Sy tage t PR E-vy =a will be- (A) 1 (B) 0 (C) -1 (D) » One postulate of wave mechanics is- (A) Ay =a (B)_ y(@)=y(0+2hr) (C) AW = Ey (D) None of these 4026\A\2023 x 17. wrogTar a fee wea at ois HATA oat & argu @ (A) (B) (c) ) (A) (B) So n,l and m wfz? 2M uzz | 2 ‘Ss yz Iu . RAT wela aT weer on writ aT Feet wr Pak axa é : monly land m o (D) nandt ; 19. aiféne aon warn Fa’ ae er (C) -1 — (D) © 20. wn aia wr ee ue A “OA) Ay = ay (B) y(6)=y(0+2hx) a ey Ay = By (0) $i arg ae ero36. The C-H vibration frequency of 36, veta aft C-H ama rats wich # : Alkene is : (A) 2850 cm"! (A) 2850 cm"! (8) 3050 cm (B) 3050 cm"! (C) 2750 cm! (C) 2750 cm sy (D) 3200 cm"! (D) 3200 em"! 37. IR spectroscopy provides informa- 37. aig sire waren sistant wars wera @ = tion about: A) (A) arate gt Internuclear distance (B) agar & emt an Frater (B) Determination of moment of in- ers (CO) fiserene aye aT eT ETAT (C) Detection of functional group (D) All of the above (>) awk 38. The separation between each rota~ 38, Weert Wea Way A wedi@ tee ST tional line in case of rotational Ra- Shad ade: man spectrum is : AS 3B (A) 28 ‘ay an (B) 4B a © 8 oe 6B) (D) 68 (D) 68 39. The base value of homoannular 39, amok seg a SMU Ae: dienes is : te 253 nm (A) 253 nm (B) 214nm (8) 2141nm (C) 180 nm (C) 180 nm (©) 215 nm (D) 215 nm 40261A\2023 112)29. 30. 31. 32. Out of the following which electronic transition — required = maximum energy? (A) nor (B) ron* (C) noo* (D) ao0* Rotational constant B is ®) eric (B) hv (Cc) me? (0) 4 The selection rule for pure-rotational Raman spectrum is (A) AJ=0, £1 (B) aj=+2 (C) AJ=0, +2 (D) al=1 Which of the following molecules will not show IR spectrum? (a) H, (B) HCl (©) CH, (D) H,0 40261A\2023 ill 29. Bren 1 er wera HHT fae ra oh reer ret 8? (A) nose (8) non (Cc) no>o* AB) 000" 30. wi Rein Be AS atic (B) hv (Cc) mc? o) ¢ 31, Qe tere was wr aes Pram é : XX (A) AJ=0, +1 (B) aj=#2 (C) aJ=0, £2 Soy =+1 32. Prafeiftad 4 ate a any 1k WaT aE Rare? Eh (A) H, (8) HCI (C) cH, — 22) 1,0 110} —_