Series : ZYWX1 SET ~ 1

Q.P. Code 56/1/1

Roll No.

Candidates must write the Q.P. Code

on the title page of the answer-book.

z/NOTE
)
Please check that this question paper contains 23 printed pages.

Please check that this question paper contains 33 questions.

question paper should be

Q.P. Code given on the right hand side of the candidate.
written on the title page of the answer-book by the

the answer
Please write down the serial number of the question in
book at the given place before attempting it.
()

question
15 minute time has been allotted to read this question paper. The a.m.,
to 10.30 the
paper will be distributed at 10.15 a.m. From 10.15 a.m.
candidates will read the question paper only and will not write any answer
on the answer-book during this period.

CHEMISTRY (Theory)
Aufta g44: 3 yu| 3f4 3j5 : 70
Time allowed : 3 hours Maximum Marks : 70

56/1/1 1 PT.0.
730-1
 General Instructions:
Read the following instructions carefully and follow them :
() This question paper contains 33 questions. All questions are
compulsory.
(ii) This question paper is divided into five sections - Section A, B, C, D
and E.
ii) Section A - 'questions number 1 to 16 are multiple choice type
questions. Each question carries 1 mark.
(0) Section B- questions number 17 to 21 are very short an8wer type
questions. Each question carries 2 marks.
(V) Section C- questions number 22 to 28 are short anaweT ype
questions. Each question carries &marks.
(vi) Section D - questions number 29 and 30 are case-based questions.
Each question carries 4 marks.
(vii) Section E- questions number 31 to 33 are long answer type question8.
Each question carries 5 marks.
(viii)There is no overall choice given in the question paper. However, an
internal choice has been provided in few questions in all the sections
except Section -A,
(ix) Kindly note that there is a separate question paper for Visually
Impaired candidates.
() Use of calculator is N0T allowed.
You may use the following values of physical constants wherever necessary:
c=3x 108 m/s
h= 6.63× 1034 Js
e=1.6x 10-19 C
Ho =47 x 10-7 Tm A-1
m2
Eo =8.854 x 10-12 C² N-1
1
=9x 109 N m2C2
Mass of electron (m)=9.1 x 10 31 kg.
Mass of neutron =1.675 x 1027 kg.
Mass of proton = 1.673 × 10-27 kg.
Avogadro's number = 6.023 × 100 per gram mole
Boltzmann's constant = 1.38 x 1028 JK-1

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 SECTION - A (16 x 1 = 16)
type questionscarrying 1mark
Questions No. 1to 16 are Multiple Choice
each.
1. case of association, abnormal molar mass of solute will
In (B) decrease decrease
(A) increase
(D) first increase and then
(C) remain same

potential for Sn+/Sn2+ couple is +0.15 V and that for

2. Standard electrode standard states are
The two couples in their
the Cr3/Cr couple is -0.74 V. potential will be
connected to make a cell. The cell (B) +0.89 V
(A) +1.19 V (D) +1.83 V
(C) +0.18 V
momentum and
magnetic moment is associated with its spin angular
3. The Cro+ ion
angular momentum. Spin only magnetic moment value of
orbital
(Atomic no. : Cr= 24) is
(A) 2.87 B.M. (B) 3.87 B.M.
(C) 3.47 B.M. (D) 3.57 B.M.

4 Acidified KMnO, oxidises sulphite to

(A) S,0 (B) S,0
(C) s0,g) (D) so

5.. The correct IUPAC name of

[Pt(NH),CL,j is
(A) Diamminedichloridoplatinum ()
(B) Diamminedichloridoplatinum ([)
(C) Diamminedichloridoplatinum (0)
(D) Diamminedichloridoplatinate (TV)
boiling points:
6. Arrange the following compounds in increasing order of their
CH
() CHH-CH,Br () CH,CH,CH,CH,Br (i) H,C-C- CH,
CH3 Br
The correct order is
(A) (i) < ()<(iü) (B) ()<(i) <(ü)
(C) (ii) <)<() (D) () <() <)
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7. Alkyl halides undergoing nucleophilic bimolecular substitution reaction
involve
(A) retention of configuration (B) formation of racemic mixture
() inversion of configuration D) formation of carbocation

8. Which is the correct order of acid strength from the following?

(A) CçHOH> H,0> ROH (B) CçH,OH> ROH>H,0
(C) ROH> CgH,OH> H,0 (D) H,0> CH,OH> ROH
9. The acid formed when propyl magnesium bromide is treated with CO,
followed by acid hydrolysis is :
(A) CsH,COOH (B) C,H,cOOH
(C) CH,COOH (D) C,H,OH
10. The best reagent for converting propanamide into propanamine 13

(A) excess H,
(B) Br, in aqueous NaOH
(C) iodine in the presence of red phosphorus
(D) LiAIH, in etber
about glucose ?
11. Which of the following statements is not true
(A) It is an aldohexose.
n-hexane.
(B) On heating with HI it forms
(C) It exists in furanose form.
(D) It does not give Schiff's test.
concentrated salt solution to prepare pickle,
12. An unripe mango placed in a
shrivels because
(A) it gains water due to osmosis
osmosis
(B) it loses water due to reverse
osmosis
(C) itgains water due to reverse
(D) it loses water due to o8mosis
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 questions number 13 to 16, two statements are given - one labellod as
For and the other labelled as Reason (R). Select the correct
Assertion A)
angwer to these questions from the codes (A), (B), (C) and (D) as given
below :
Both Assertion (A) and Reason (R) are true and Reason (R) is the
(A) Assertion (A).
correct explanation of the
true, but Reason R) is not the
D Both Assertion (A) and Reason (R) are
(A).
correct explanation of the Assertion
Reason (R) is false.
(C) Assertion (A) is true, but
Reason (R) is true.
D) Assertion (A) is false, but
are examples of
13. Assertion (A) : [Cr(H,0)]Ci, and [Fe(H,0)1Ci,
homoleptic complexes.
same.
Reason (R) : Althe ligands attached to the metal are the

(A): The boiling points of alkyl halides decrease in the order:

14. Assertion
RI > RBr > RCl> RE.
chlorides, bromides and
Reason (R) : The boiling points of alkyl
than that of the
jodides are considerably higher
hydrocarbon of comparable molecular mass.

The boiling point of ethanol is higher than that of

15. Assertion (A) :
methoxymethane.
: There is intramolecular hydrogen bonding in ethanol.
Reason (R)

occurring a-amino acids except glycine are

16. Assertion (A) : All naturally
optically active.
amino acids have
: Most naturally occurring
Reason (R)
L-configuration.
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56//1
17. (A) Give reasons:
SECTION- B
(a) Cooking is faster in (1+1=3)
(b) On
pressure cooker than in an open pan.
mixing liquid X and liguid Y,
solution decreases. What type of volume of the resulting
shown by the resulting solution ?deviation from Raoult's law is
would you observe after What change in temperature
mìxing liquids X and Y ?
OR
(B) Define Azeotrope. What type of Azeotrope is formed
deviation from Raoult's law ? Give an by negative
example. 2

18. Complete and balance the following chemical equations : 2

(a) 2Mn0,(a) + 101(aq) + 16H (ag)’

(b) Cr,0, (a) + 6Fe2t(aq) + 14H*(ag)

19. Would you expect benzaldehyde to be more reactive or less reactive in

nucleophilic addition reactions than propanal ? Justify your answer. 2

20. Identify Aand Bin each of the folowing reaction sequence: (1+1=2)

(a) CH,CH,CI NaCN A: H,Ni B

(b) CH,NH, NaNO,HCI
0-50 A CoH,NH,
H
B

21. Write the reactions involved when D-glucose is treated with the following
reagents : (1+1=2)
(a) HCN
(b) Br, water
56//1 11 ~ P.T.O.
 SECTION-C
22. A solution of glucose (molar
mass = 180 g mol-) in water has a boiling
point of 100.20 °C. Calculate the freezing point of
the same solution. Molal
Constants for water K, and K, are 1.86 K kg mol-l and 0.512 K kg mol
respectively.

28. (a) State the following: 3

Kohlrausch law of independent migration of ions and

(ii) Faraday's first law of electrolysis.
(b) Using E°values of X and Y given below, predict which is better for
coating the surface of iron to prevent corrosion and why ?
Given Eg =-2.36 V,
Ey2y =0.14 V,

EpFe =-0.44V
24. A certain reaction is 50% complete in 20 minutes at 300 K and the samne
reaction is 50% complete in 5 minutes at 350 K. Calculate the activation
3
energy if it is a first order reaction.
[R=8.314 J K-l mol-; log 4= 0.602]

ei (1+1+1= 3)
25. The elements of 3d transition series are given as :
Sc, Ti, V, Or, Mn, Fe, Co, Ni, Cu, Zn
Answer the following :

(a) Copper has exceptionally positive Ey value, why ?

Which element is a strong reducing agent in +2 oxidation state and
(b).
why ?
?
(c) Zn2+ salts are colourless. Why
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56/1/1
26. (A) Draw the structure of the major monohalo product for each of
the
following reaction : (1+1+1=3)

CH,- CH¡ Br, Heat

’?
(a) CI

+ HBr
(6) CH,

OH
HCL, Heat
’?

(c) HO - H,C
OR
(3 x1=3)
(B) How do you convert :
(a) Chlorobenzene to biphenyl
(b) Propene to 1-Iodopropane
(c) 2-bromobutane to but-2-ene.

in increasing order of their boiling

27. (a) Arrange the following compounds (1 +2=3)
point:
(CH), NH, CH,CH,NH, CH,CH,OH.
the following :
(b) Give plausible explanation for each of
cannot be prepared by Gabriel
) Aromatic primary amines
Phthalimide synthesis.
amines.
(iü) Amides are less basic than

between native protein and denatured protein ?

28. (a) What is the difference (1+1+1=3)
is adisaccharide ?
(b) Which one of the following
Glucose, Lactose, Amylose, Fructose
Which vitamin is responsible for the coagulation of blood ?
(c)
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56/1/1
 The following
questions SECTION-D
are case based
carefully and answer the questions that guestions, Read the passage
The rate of a chemical
follow.
reaction is expressed either in
the concentration of terms of decrease n
per unit
reactants Or
increase in the concentration of a
product time. Rate of the
reactants, reaction depends upon the nature of
concentration of reactants,
face area of the reactants and temperature, presence of catalyst,
presence of light. Rate of reaction 18
rectly related to the concentration of reactant, Rate
law states that the
wote of reaction depends upon the
concentration terms on which the rate
of reaction actually, depends, as observed experimentally. The sum of
nowers of the concentration of the reactants in the Rate law expression
is called order of reaction while the number of reacting species taking
part in an elementary reaction which must collide simultaneously in
order to bring about a chemical reaction is called molecularity of the
reaction,
Answer the folowing questions :
(1+1=2)
(a): () What is a rate determining step ?
(i) Define complex reaction.
1
temperature on the rate constant of a reaction ?
(b) What is the effect of
OR

molecularity applicable only for elementary reactions

(b) Why is elementary as well as complex
for
whereas order is applicable 1
reactions ?
Y folows second order kinetics. If
molecule X to
(C) The conversion of how will it affect the rate of
3 times,
concentration ofX is increased 1
formation of Y ?
P.T.0.
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5611
 Phenols
30.
undergo electrophilic
activating of OH substitution reactions
strong
the OH
effect group attached to the
readily due to the
group benzene ring. Since,
therefore OH increases the electron density more to o- and p- positions
group is ortho,
one of the
examples of para-directing. Reimer.Tiemann reaction is
aldehyde group being introduced on the aromatic
ring of phenol, ortho tothe
for the hydroxvl group. This is a general methoa
ortho-formylation of phenols.
Angwer the following questions :
u

(a) What happens when

2 phenol reacts with 2

() BrCS,
(üi) Conc. HNO,
(b) Why phenol does not undergo protonation readily ? 1
1
(C) Which is a stronger acid - phenol or cresol ? Give reason. 1
1
OR

(c) Write the IUPAC name of the product formed in the Reimer
1 Tiemann reaction. 1

SECTION- E

following
31. (A) () Write the cell reaction and calculate the e.m.f. of the
cell at 298 K: (3 +2=5)

Sn(s) | Sn2+ (0.004 M)||H* (0.02 M) |H,(g) (1 Bar) |Pt (9)

(Given : E20.14 V, E°H+Ee, PtP =0.00V)

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 6) Account for the following:
) On the basis of
E° values, O, LANA shuld be lterated st
anode but it is Cl, gas which in libersted in
of aqueous NaCl.
the eleetrslysis
(1) Conductivity of CH,C0OH decreases on dilution.
OR
31. (B) (a) Write the anode and cathode reactions and the overall cell
reaction occurring in alead storage battery during its use. (Z+3=0)
(b) Calculate the potential for half-cell containing 0.01 M
KzOr,0,(aq),0.01 MCrot (ag) and 1.0 x104MH*(a).
The half cell reaction is

Cr,0 (a)+14H*(ag) +6er 2Cr*(aq) +7H,00)

and the standard electrode potential is given as E° = 1.33 V.

[Given : log 10 = 1]

5
32. (A) Answer the following :
not known.
(a) Low spin tetrahedral complexes are
presence of a strong ligand
(b) Co2+ is easily oxidised to Co+ in the
[At. No. of Co = 27]
complex [CoNH)l
(c) What type of isomerism is shown by the
[Cr(CN)J?
Why a solution of Ni(H,0)* is green while a solution of
(d)
Ni(CN),J iscolourless. (At. No. of Ni = 28)
: [Co(NHJ,(COJJCI
(e) Write the IUPACname of the following complex
OR

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56/1/1
5) S2. (B) (a) What is meant by 'Chelate effect' ?
Give an example. (2+2+1 6)
(b) Write the hybridization and
magnetic behaviour of [Fe(CN)J.
(Atomic number: Fe= 26)
(©) Ptol, 2NH, does not react with AgNO what will be its
formula?

98, (A) (a) Carry out the following

converions : (2 +3= 6)
(i) Ethanal to But-2-enal
(i) Propanoic acid to ethane
(b) An alkene Awith mÍlecular formula CH,o on ozonolysis gives
a mixture of two compounds B and C. Compound B gives
positive Fehling test and also reacts with iodine and NaOH
solution. Compound C does not give Fehling solution test but
forms iodoform. Identify the compounds A, B and C.
OR

33. (B) An organic compound (A) (molecular formula CH,0,)

Was

hydrolysed with dilute sulphuric acid to get a carboxylic acid (B) and
(C)
an alcohol (C). Oxidation of (C) with chromic acid produced (B).
and write
on dehydration gives But-l-ene. Identify (A), (B) and (C)
chemical equations for the reactions involved.

56/1/1