SAFETY DATA SHEET

MasterTop P 650 PART B

Version Revision Date: SDS Number: Date of last issue: 18.05.2020

1.1 31.12.2020 000000314400 Date of first issue: 18.05.2020

1. PRODUCT AND COMPANY IDENTIFICATION

Product name : MasterTop P 650 PART B

Product code : 000000000055483568

Manufacturer or supplier's details

Company : Master Builders Solutions LLC

Address : Plot no. 959, Phase 2, Way No. 8342, Al Misfah, Bousher,
Sultanate of Oman

Emergency telephone : ChemTel: +1-813-248-0585

2. HAZARDS IDENTIFICATION

GHS Classification
Flammable liquids : Category 4

Acute toxicity (Oral) : Category 4

Acute toxicity (Inhalation) : Category 4

Acute toxicity (Dermal) : Category 4

Skin corrosion/irritation : Category 1B

Skin sensitization : Category 1A

Hazardous to the aquatic : Category 3

environment - acute hazard

Hazardous to the aquatic : Category 3

environment - chronic hazard

GHS label elements

Hazard pictograms :

Signal Word : Danger

Hazard Statements : H227 Combustible liquid.

H314 Causes severe skin burns and eye damage.
H312 Harmful in contact with skin.
H332 Harmful if inhaled.
H302 Harmful if swallowed.
H317 May cause an allergic skin reaction.
H402 Harmful to aquatic life.
H412 Harmful to aquatic life with long lasting effects.

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SAFETY DATA SHEET

MasterTop P 650 PART B

Version Revision Date: SDS Number: Date of last issue: 18.05.2020

1.1 31.12.2020 000000314400 Date of first issue: 18.05.2020

Precautionary Statements :
Prevention:
P280 Wear protective gloves/ protective clothing/ eye protec-
tion/ face protection.
P271 Use only outdoors or in a well-ventilated area.
P260 Do not breathe dust or mist.
P261 Avoid breathing mist.
P210 Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
P273 Avoid release to the environment.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P270 Do not eat, drink or smoke when using this product.
P264 Wash face, hands and any exposed skin thoroughly after
handling.
Response:
P310 Immediately call a POISON CENTER/ doctor/
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P304 + P340 IF INHALED: Remove person to fresh air and
keep comfortable for breathing.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediate-
ly all contaminated clothing. Rinse skin with water/ shower.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P361 + P364 Take off immediately all contaminated clothing
and wash it before reuse.
P370 + P378 In case of fire: Use water spray, alcohol-resistant
foam, dry chemical or carbon dioxide to extinguish.
Storage:
P405 Store locked up.
P403 + P235 Store in a well-ventilated place. Keep cool.
Disposal:
P501 Dispose of contents/container to appropriate hazardous
waste collection point.

Other hazards which do not result in classification

If applicable information is provided in this section on other hazards which do not result in classi-
fication but which may contribute to the overall hazards of the substance or mixture.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature : polyamine

modified
Components
Chemical name CAS-No. Concentration (%
w/w)
Benzyl alcohol 100-51-6 >= 25 - < 50
3-aminomethyl-3,5,5-trimethylcyclohexylamine 2855-13-2 >= 25 - < 50

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SAFETY DATA SHEET

MasterTop P 650 PART B

Version Revision Date: SDS Number: Date of last issue: 18.05.2020

1.1 31.12.2020 000000314400 Date of first issue: 18.05.2020

solvent naphtha 64742-94-5 >= 5 - < 7

triethylenetetramine 112-24-3 >= 1 - < 3
naphthalene 91-20-3 >= 0,3 - < 1
1,2,4-trimethylbenzene 95-63-6 >= 0,3 - < 1

4. FIRST AID MEASURES

General advice : Move out of dangerous area.

Consult a physician.
Show this material safety data sheet to the doctor in attend-
ance.
Do not leave the victim unattended.

If inhaled : Consult a physician after significant exposure.

If unconscious, place in recovery position and seek medical
advice.
In case of skin contact : Immediate medical treatment is necessary as untreated
wounds from corrosion of the skin heal slowly and with difficul-
ty.
Take victim immediately to hospital.
If on skin, rinse well with water.
If on clothes, remove clothes.
In case of eye contact : Small amounts splashed into eyes can cause irreversible tis-
sue damage and blindness.
In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed : Keep respiratory tract clear.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Take victim immediately to hospital.
Most important symptoms : Harmful if swallowed, in contact with skin or if inhaled.
and effects, both acute and May cause an allergic skin reaction.
delayed Causes serious eye damage.
Causes severe burns.
Notes to physician : Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Foam

Water spray
Dry powder
Carbon dioxide (CO2)
Unsuitable extinguishing : water jet
media
Hazardous combustion prod- : nitrogen oxides
ucts fumes/smoke
carbon black
corrosive gases/vapours

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SAFETY DATA SHEET

MasterTop P 650 PART B

Version Revision Date: SDS Number: Date of last issue: 18.05.2020

1.1 31.12.2020 000000314400 Date of first issue: 18.05.2020

Specific extinguishing meth- : Collect contaminated fire extinguishing water separately. This
ods must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
For safety reasons in case of fire, cans should be stored sepa-
rately in closed containments.
Use a water spray to cool fully closed containers.
Special protective equipment : Wear self-contained breathing apparatus for firefighting if nec-
for fire-fighters essary.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Use personal protective equipment.

tive equipment and emer- Ensure adequate ventilation.
gency procedures

Environmental precautions : Prevent product from entering drains.

Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for : Contain spillage, and then collect with non-combustible ab-
containment and cleaning up sorbent material, (e.g. sand, earth, diatomaceous earth, ver-
miculite) and place in container for disposal according to local
/ national regulations (see section 13).
Keep in suitable, closed containers for disposal.

7. HANDLING AND STORAGE

Advice on protection against : Do not spray on a naked flame or any incandescent material.
fire and explosion Keep away from open flames, hot surfaces and sources of
ignition.

Advice on safe handling : Avoid formation of aerosol.

Do not breathe vapors/dust.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Provide sufficient air exchange and/or exhaust in work rooms.
To avoid spills during handling keep bottle on a metal tray.
Dispose of rinse water in accordance with local and national
regulations.
Persons susceptible to skin sensitization problems or asthma,
allergies, chronic or recurrent respiratory disease should not
be employed in any process in which this mixture is being
used.
Conditions for safe storage : no smoking
Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.

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SAFETY DATA SHEET

MasterTop P 650 PART B

Version Revision Date: SDS Number: Date of last issue: 18.05.2020

1.1 31.12.2020 000000314400 Date of first issue: 18.05.2020

Observe label precautions.

Electrical installations / working materials must comply with
the technological safety standards.
Further information on stor- : Keep only in the original container in a cool, dry, well-
age conditions ventilated place away from ignition sources, heat or flame.
Protect from direct sunlight.
Store protected against freezing.

Materials to avoid : Observe TRGS 509/510 storage rules.

Further information on stor- : No decomposition if stored and applied as directed.

age stability

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

The substances without values are not listed in the occupational exposure regulations for the va-
lidity area of this safety data sheet.
Personal protective equipment
Respiratory protection : Wear respiratory protection if ventilation is inadequate.
Combination filter for gases/vapours of organic, inorganic,
acid inorganic and alkaline compounds (e.g. EN 14387 Type
ABEK).
Hand protection

Remarks : Suitable chemical resistant safety gloves (EN 374) also with
prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to
EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5
mm), butyl rubber (0.7 mm) etc. Manufacturer's directions for
use should be observed because of great diversity of types.
Eye protection : Tightly fitting safety goggles (splash goggles) (e.g. EN 166)
Skin and body protection : Impervious clothing
Choose body protection according to the amount and concen-
tration of the dangerous substance at the work place.
Protective measures : Do not inhale gases/vapours/aerosols.
Avoid contact with the skin, eyes and clothing.
Handle in accordance with good building materials hygiene
and safety practice.
Hygiene measures : When using, do not eat, drink or smoke.
Hands and/or face should be washed before breaks and at the
end of the shift.
At the end of the shift the skin should be cleaned and skin-
care agents applied.
Gloves must be inspected regularly and prior to each use.
Replace if necessary (e.g. pinhole leaks).

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Color : light yellow

Odor : characteristic

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SAFETY DATA SHEET

MasterTop P 650 PART B

Version Revision Date: SDS Number: Date of last issue: 18.05.2020

1.1 31.12.2020 000000314400 Date of first issue: 18.05.2020

pH : alkaline

Melting point : Not applicable

boiling temperature : > 150 °C

Flash point : > 70 °C

Density : 1,00 g/cm3 (25 °C)

Solubility(ies)
Water solubility : partly miscible (25 °C)

Autoignition temperature : not determined

Decomposition temperature : No decomposition if stored and handled as pre-

scribed/indicated.

Explosive properties : Not explosive

Not explosive

Oxidizing properties : not fire-propagating

Metal corrosion rate : No corrosive effect on metal.

10. STABILITY AND REACTIVITY

Reactivity : No decomposition if stored and applied as directed.

Chemical stability : No decomposition if stored and applied as directed.
Possibility of hazardous reac- : No decomposition if stored and applied as directed.
tions Vapors may form explosive mixture with air.

Conditions to avoid : Heat, flames and sparks.

Incompatible materials : Oxidizing agents
strong alkalies
Acids
Zinc
Aluminum
Hazardous decomposition : No hazardous decomposition products if stored and handled
products as prescribed/indicated.

11. TOXICOLOGICAL INFORMATION

Acute toxicity
Harmful if swallowed, in contact with skin or if inhaled.
Product:
Acute oral toxicity : LD50(Rat): 1.030 mg/kg

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SAFETY DATA SHEET

MasterTop P 650 PART B

Version Revision Date: SDS Number: Date of last issue: 18.05.2020

1.1 31.12.2020 000000314400 Date of first issue: 18.05.2020

Skin corrosion/irritation
Causes severe burns.
Serious eye damage/eye irritation
Causes serious eye damage.
Respiratory or skin sensitization

Skin sensitization
May cause an allergic skin reaction.
Respiratory sensitization
Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Reproductive toxicity
Not classified based on available information.
STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Not classified based on available information.
Aspiration toxicity
Not classified based on available information.
Components:

naphthalene:
Not applicable

Further information

Product:
Remarks : Health injuries are not known or expected under normal use.
The product has not been tested. The statements on toxicolo-
gy have been derived from the properties of the individual
components.

12. ECOLOGICAL INFORMATION

Ecotoxicity

Product:
Toxicity to daphnia and other : EC50 (Daphnia magna): 23 mg/l
aquatic invertebrates Exposure time: 48 h

Ecotoxicology Assessment
Acute aquatic toxicity : Harmful to aquatic life.

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SAFETY DATA SHEET

MasterTop P 650 PART B

Version Revision Date: SDS Number: Date of last issue: 18.05.2020

1.1 31.12.2020 000000314400 Date of first issue: 18.05.2020

Chronic aquatic toxicity : Harmful to aquatic life with long lasting effects.

Components:

naphthalene:
M-Factor (Acute aquatic tox- : 1
icity)

M-Factor (Chronic aquatic : 1

toxicity)

Persistence and degradability

No data available
Bioaccumulative potential

Components:

3-aminomethyl-3,5,5-trimethylcyclohexylamine:
Partition coefficient: n- : log Pow: 0,99 (23 °C)
octanol/water pH: 6,3
Method: Partition coefficient
GLP: no

solvent naphtha:
Partition coefficient: n- : log Pow: 2,9 - 6,1
octanol/water Method: Partition coefficient (n-octanol/water), HPLC method.

triethylenetetramine:
Partition coefficient: n- : log Pow: -2,65 (25 °C)
octanol/water Method: other (calculated)
GLP: no
Remarks: The data refers to the undissociated form of the
substance.

naphthalene:
Partition coefficient: n- : log Pow: 3,4 (25 °C)
octanol/water Method: Partition coefficient (n-octanol/water), Shake-flask
method

1,2,4-trimethylbenzene:
Partition coefficient: n- : log Pow: 3,63 (25 °C)
octanol/water Method: other (calculated)

Mobility in soil
No data available
Other adverse effects

Product:
Additional ecological infor- : An environmental hazard cannot be excluded in the event of

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SAFETY DATA SHEET

MasterTop P 650 PART B

Version Revision Date: SDS Number: Date of last issue: 18.05.2020

1.1 31.12.2020 000000314400 Date of first issue: 18.05.2020

mation unprofessional handling or disposal.

Harmful to aquatic life.
Harmful to aquatic life with long lasting effects.

13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with chemi-
cal or used container.
Send to a licensed waste management company.
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.

14. TRANSPORT INFORMATION

International Regulations

UNRTDG
UN number : UN 2735
Proper shipping name : AMINES, LIQUID, CORROSIVE, N.O.S.
(POLYAMINE MODIFIED)
Class : 8
Packing group : III
Labels : 8
IATA-DGR
UN/ID No. : UN 2735
Proper shipping name : AMINES, LIQUID, CORROSIVE, N.O.S.
(POLYAMINE MODIFIED)
Class : 8
Packing group : III
Labels : Corrosive
Packing instruction (cargo : 856
aircraft)
Packing instruction (passen- : 852
ger aircraft)
IMDG-Code
UN number : UN 2735
Proper shipping name : AMINES, LIQUID, CORROSIVE, N.O.S.
(POLYAMINE MODIFIED)
Class : 8
Packing group : III
Labels : 8
EmS Code : F-A, S-B
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

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SAFETY DATA SHEET

MasterTop P 650 PART B

Version Revision Date: SDS Number: Date of last issue: 18.05.2020

1.1 31.12.2020 000000314400 Date of first issue: 18.05.2020

Special precautions for user

The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and var-
iations in regional or country regulations.

15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mix-
ture

16. OTHER INFORMATION

Full text of other abbreviations

AICS - Australian Inventory of Chemical Substances; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for
Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with
x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-
tem; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA
- International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory con-
centration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemi-
cal Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International
Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Or-
ganisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Con-
centration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median
Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships;
n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop-
ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu-
lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc-
es; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No
1907/2006 of the European Parliament and of the Council concerning the Registration, Evalua-
tion, Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition Tem-
perature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Trans-
portation of Dangerous Goods; TSCA - Toxic Substances Control Act (United States); UN - Unit-
ed Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods;
vPvB - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials In-
formation System

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific

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SAFETY DATA SHEET

MasterTop P 650 PART B

Version Revision Date: SDS Number: Date of last issue: 18.05.2020

1.1 31.12.2020 000000314400 Date of first issue: 18.05.2020

material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

UN / EN

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