This question paper contains 2 printed pages. PHY-802 ‘Time allowed : Three hours M.Sc. (2nd Semester) Examination, May 2018 PHYSICS (Atomic and Molecular Physics) ‘Maximum marks : 100 1. No Supplementary answer-book will be given to any candidate. Hence the candidate should write their ‘answers precisely in the main answer-book only. * 2. All the part of one question should be answered at one place in the answer-book One complete question should not be answered at different places in the answer-book. Part. Part 1. a) 4) © mo) (e) wo db) Ai) a @) ) (a) () PHY. $02 Altempt any five questions The paper consists of two parts. Question No. 1 contains 10 short answer questions. Each question 1s of two marks. Attempt four questions with internal choice. The limit of each answer is five pages. Each question is of 20 marks. Part-A Explain lamb shift using energy level diagram. What do you mean by scattering force? Describe the exchange symmetry of wave function. What do you mean by optical lattice? Explain first and second order Stark effect in the hydrogen atom. What do you mean by hyperfine structure of hydrogen atom? What do you mean by magnetic trapping? State the Frank-Condon Principle forthe intensity distribution. Explain Doppler cooling limit. What do you mean by chirp cooling of atoms? RRR RRNHKHKHKN Part-B Calculate the states of hydrogen atom in its first excited state using the first order perturbation theory.12 ‘What do you mean by spin-orbit interaction? Calculate the change in energy of s, p, d, f states due to it.8 oR Discuss in detail the quantum mechanical treatment of anomalous Zeeman effect. Draw a diagram to display the Zeeman Splitting of D, and D, lines of Na. 2 Calculate the wavelength separation between the unmodified line of wavelength 4000A and the modified lines when a magnetic field of 6000 Oersted is applied in normal Zeeman effect. 8 PTO. qa) Scanned by CamScanner Osanna wth onen scanner3 6©@) Cc) @ ® @ e &) @ ) © @ o) @ Ww b) © Describe the variational method. 2 State and explain Paschen Back effect using vector atom model. OR Discuss the energy levels and spectrum of helium, 10 Describe L-S and J-J Coupling for a two valence electron system. 10 What is Raman effect? Explain its theory on the basis of quantum physics. Also write down some important applications of Raman spectroscopy. 15 The force constant of CO bond in 187 N/m. Find frequency of vibration of CO molecule and spacing ‘between vibrational levels 5 OR Discuss vibrational-rotational spectra of diatomic molecules with neat diagram. 10 Explain why the ground state energy of vibrational energy bends can not be zero. 5 In which region of spectrum the electronic rotational and vibrational spectra lie? 5 Discuss in detail the working of Sisyphus cooling. 1s Outline the applications of atom LASER. 5 Prove that for an atom of mass M, the Sdfation force produces a maximum radiation equal to : a (4 st) wax =| Ou 5 ‘Show that the dipole force acting on the atoms in a LASER field, when 5>> I” and3>> is equal to the derivative of the light shift 5 Explain the mechanism of magneto- optical trap used for cooling the atoms. 10 (2) Scanned by CamScanner Osanna wth onen scannerScanned by CamScanner © scanned whore SanneScanned by CamScanner Osanna wth onen scannerScanned by CamScanner © scanned whore Sanne® question paper contains 2 printed pages. Roll No... ZN SS. '‘HY-802 si.No. 10085 \ M.Sc. (2"¢ Semester) EXAMINATION, May - 2021 PHYSICS (Atomic and Molecular Physics) me Allowed : Three Hours Maximum Marks : 100 No answers precisely in 1 upplementary siver-book will be given to any candidate. Henee the candidates should write their main answer-book only. All the part of one question should be answered at one place in the answer-book. One complete question should not be answered at different places the answer-book. your roll number on question paper before start writing answer of questions Attempt any five questions. The paper consists of two parts. ART =A: Question No, Econtains 10 short answer questions. Each question is of tivo marks. ART - Bz Attempt four questions with internal choice. The limit of each anste is of 20 marks. is five pages. Each question PART-A Attempt all the following questions (a) Write the statement for Wilson-Sommerfeld quanti (b) What do you mean by fine structure and hyper fine structure of atom ? 2 (© Show the variation by plot in Rydberg constant due to finite nuclear mass with atomic mass 2 numbers, (a) Classify the Zeeman Effect on the basis of strength of applied external magnetic field, 2 (©) Describe the exchange symmetry of wave function. 2 (State and explain Frank Condon Principle 2 (@) Write down the selection rules for electronic transition in atoms and also for rotational and 2 vibrational transition in molecules. (bh) Why do the molecules like Hy, 0, do not show vibrational spectra ? 2 (@ Show the electronic, vibrational and rotational energy levels of molecule in one picture. 2 (Why the magnetic quantum number is called 80? 2 PART-B. 2 (a) Explain the Paschen-Back effect (strong external magnetic field) in detail and find out the 10 ‘Zeeman transition line pattern for?P 2S (D, and Dg lines of Sodium atom) levels in external strong magnetic field. (b) Find out theenergy correction for hydrogen atom duc tospin-orbit interaction for ine structure. 10 or Show the sccond order stark effect (second order energy correction) for ground state of hydrogen atom is proportional to square of applied external electric field. PHY-802 1 PTO. © scaoedwthoxen scannerft. (a) Discuss advantages of variational method over the perturbation method. Use the variational 15 incthod to estimate the upper limit of the ground state of the hydrogen atom, (b) Construct the symmetric and anti-symmetric wave functions for hydrogen molecule. 5 OR ()' What in the WKB approximation and its validity ? Apply it for the determination of energy 15 <~Jevets ofa one dimensional bound system. @w, 7 {b) Show that a singlet state is stable and triplet state is unstable state in hydrogen molecul 5 s _ = 4 What do you mean by alkalie and alkaline atoms ? Draw energy level dingrams of sodium and 10 explain different spectral series of Na spectrum, Explain the fine structure and origin of Dy and D, lines of sodium spectrut ©) How the energy levels of Helium are affected by Coulomb interaction and the exchange forces” 49 ic Discuss the ortho-and para-helium and the spectrum of helium, i< or (0) Discuss vibrational-rotational spectra of diatomic molecules and explain origin of LQ.R series 10 “of the spectrum, a ee tb) What is Raman scattering ? Give a detailed explanation of Raman effect on the basis of 10 quantum theory. © i 5 What do you mean by Doppler cooling ? Deseribe mechanism of Magneto-optical trap method 12 in detail (b) What do you mean by Dipole force ? How is it different than the scattering force ? 8 on (a) Explain the principle of Sisyphus cooling in detail 6 (b) What do you mean by chirp cool 5 -000- . PHY-802 2 © scaoedwthoxen scannerDEPARTMENT OF PHYSICS, UNIVERSILY OF RAGASTHAN MID-TERM EXAMINATION-2019 M.Sc. (PHYSICS). H SEMESTER Atomic & Molecular Physics (PHY -802) ‘Time Duration: 1 Hour Maximum marky:40 Qu What is the basic difference in the perturbation, variational and WKI approsimat oa method's for stationary states 12) ‘ What do you mean by gross structure, s structure of ate fi%2*12) G ne structure and hyper i Show the variation in Rydberg constant duc to finite nuclear nnass sith: shouiie uty utIbe Q+12) o4 What is colour of the H,, Hp and Hl lines in visible spectrum of Barmer series for hydrogen atom? (es +12 Qs : The valence electron (¢ ) ina sodium atom in excited state Dy 0) (What are its possible j values? (i) What are maximum possible values of quantum numbers Ls, j. mand m+ O6 Pxplan tine structure of enetgy spectrum tor hydrogen stom and draw the transition speettum for H, line trom Harmer series (20) OR Jsplain the paschen - back effect, draw the transition spectrum tor “Py °S state in ste etic Held, (20) © scaoedwthoxen scannerM.Se. Physics (I Semester) Mid-term tion, M: Atomic and Molecular Phy sies Attempt all questions 1G Pyplain the importance of “spin ot electrons in specites. 5) (8) Wiie dowa four important applications ot Raman spectroscopy 151 (e) Explain the Reason of wiuth of atomie spectral lines 151 2. (a) Describe the general features of the spectra of alkali-like atoms, How ace thes explained? (4 (b) Lhe exciting line in an experiment is $450 A and the Stokes line is at $500.4 Find the wavelength of the anti-Stokes line. (6) on “Fe Wiese (itt s AXIO" ke-a?, Cale yular velocity in the lowes (© seamed wth sznerThis question paper contains 3 printed pages, 1a 2r7nt M.Se. (Sem. - II) 000045 Roll No. PHY - 802 Ato. & Mol. Phy. M.Se. (Semester - I) EXAMINATION - May,2019 PHYSICS Paper : PHY - 802 Atomic and Molecular Physics Time Allowed : Three Hours Maximum Marks : 100 le No Supplementary Answer - book will be given to any candidate, Hence the candidate should write their answers precise! All the part of one question should be answer at one place in the answer book. One complete question should not be answered at different places in the answer book. Auemptany five questions. The paper consists of two parts. PartA:- Question No. 1 contains 10 shorts answer questions. Each question is ofa two marks. PartB:- Attempt four question with internal choice. The limit of each answeris tive pages. Each question isof20 marks. PART - A Attemptall questions lL. Br Explain why the H,,N, and O, molecules do not show vibrational spectra. 2 _£b)"Write down some important applications of Raman spectroscopy. 2 _-fey Explain the reason of width of atomic spectral lines. 2 _S4F State and explain Franck - Condon principle. za (c) Whatdo youmean by ortho -and para- Helium? (1) Explain the terms scattering force and dipole force and their maximum values. 2 (2) Explain the Lamb shift (h) What do youmean by fine structure and hyper fine structure of atom? (i) Whatdo youmean by magnetic trapping? 2 GeWrite: ‘down the basic properties of trial function in variational approximation method. 2 2 PHY - 802 1 PTO. (Osanna neh onen scannerPART -B 2 (D Fyplain Paschen - Back effect (strong extemal magnetic field) in detail and find out the Zeeman (strong 0 {and fi in external strong 10 transition line pattern for 2P —» 28 (D, and D, lines of Sodium atom) level: atom due to relativistic correction for fine structure, 10, v \ ; sin = OR {a)_ Suppose we puta delta-function bump in the centre of the infinite square well. Find out the first order energy correction using perturbation method. ‘ veo! YS ‘en perturbed Hamiltonian H! = a(x -a/2) and unperturbed wave function is (b) A linear harmonic oscillator of charge e~ perturbed by an electric field E in the (+X) - direction. Find out the first and second order energy correction using perturbation approximation method. Unperturbed Hamiltonian is given, 12 lie desl Hy =-- +m x : : 2m dv 2 «$a Discuss variational principle to determine ground state energy of a system and apply it to find the ground stateenergy of Heliumatom, —~ . 14 t ee Explain the spectroscopic term 28 + 1,, for multi - electron system of atoms. Find spectroscopic terms foratom with two electronsin 4p 4d conti 6 oR Q QQ-Explain the WKB approximation method for bound state, Estimate the energy of an electron in one~ * dimensional infinite, potential well. 14 (Write the statement of Pauli Exclusion Principle. Write down the total antisymmetric and symmetric wave fictions of two electron system using Pauli EXclusion Principle. 6 ned on the basis of quantum theory? Write dowr What is Raman Effect lection ein their 10 { Ae The exe peoactng nel inan experimen theanti- Stokes line. w N31 Feo 10 Swoon s, OR Ve artca > WM eems nce between phosphorescence and fluorescence Trceave nds eicfacoral SY = (BS “lene ibs] y a ni They hu tat ve » Sin! Ll; Sword Sie Sw GeO et Fore TUM NE Gynesirtily fp avd, {OS Cy > Stoleet Lines Mp8 IES 129 cry O scanned wth onen camerAz Tag hh ONE aly. ote aa cn P-GP Force constant of a vibrating HCI molecule is 470 Nem’. Find out the wavelength of spectrum corresponding to vibration of HCI motecule a a 8 ( LUT Why do molecules show band Spectra rather than line spectra? 4 5. (a) Discuss in detail the working of Sisyphus cooling. 10 (b) Explain whatisan optical lattice? 6 (c) Whatdo youmean by thea.c. spark shift? 4 OR (2) Explain the working mechanism of magneto - optic trap. 10 @kxplainthe working of atomic clock. 3 “{¢)-What do you mean by Doppler cooling limit? PHY - 802 Osanna neh onen scannerThis question paper contains 2 printed pages. PHY-802 M.Se. (2"4 Semester) EXAMINATION, May - 2021 PHYSICS (Atomic and Molecular Physics) ‘Time Allowed : Three Hours Maximum Marks : 100 1. No Supplementary Answer-book will be given to any candidate. Hence the candidates should write their ‘answers precisely in the main answer-book only. 2% Alll the part of one question should be answered at one place in the answer-book. One complete question should not be answered at different places in the answer-book. Write your roll number on question paper before start writing answer of questions. Attempt any five questions. The paper consists of two parts. PART.- A: Question No. I contains 10 short answer questions. Each question is of two marks. —~PART-B: Ateempt four questions with internal choice, The limit of each anawer i five pages. Each question is of 20 marks. PART-A 1. Attempt all the following questions : _@~ Write the statement for Wilson-Sommerfeld quantization rule, 2 What do you mean by fine structure and hyper fine structure of atom ? 2 Show the variation by plot in Rydberg constant due to finite nuclear mass with atomic mass 2 bers. an ‘Zeeman Effect on the basis of strength of applied external magnetic field. 2 Describe the exchange symmetry of wave function. 2 n State and explain Frank Condon Principle. Ye 2 re Write down the selection rules for electronic transition in atoms and also for rotational ¢nd 2 Y, vibrational transition in molecules. JR y PF, Why do the molecules like Hy, 0, do not chow vibrational spectra ? a 2 Show the electronic, vibrational and rotational energy levels of molecule in one picture. 2 Ye Why the magnetic quantum number is called so? 2 nt PART-B ce wt & \S so ixplain the Paschen-Back effect (etrong external magnetic field) in detail and find out the 10 $1 Zeeman transition line pattern for *P -» 9S (D, and Dg lines of Sodium atom) levels in external strong magnetic field. 57" Find out the energy correction for hydrogen atom due tospin-orbitinteruction forfine structure, 19 or Show the second order stark effect (second order energy correction) for ground state of hydrogen 99 9 “tom is proportional to square of applied external electric field. PHY-802 1 PTO. O scanned neh onen scanner+ the perturbation method. Use the v: (a) Discuss advantages of variational method over 2 method to estimate the upper limit of the ground state of the hydrogen atom. ©) Construct the eymmetric and anti-symmetric wave functions for hydrogen molecule. OR (#) What i the WKB approximation and its validity ? Apply it for the determination of eneryy levels of a one dimensional bound system. ©) Show that a singlet state is stable and triplet state is unstable state in hydrogen molecule. (@) What doyou mean by alkalie and alkaline atoms ? Draw energy level diagrams of sodium and explain different pectral series of Na spectrum. Explain the fine structure and origin of D, and Dg lines of sodium spectrum. (©) How the energy levels of Helium are affected by Coulomb interaction and the exchange forces? iscuss the ortho-and para-helium and the spectrum of helium, OR @) Discuss vibrational-rotational spectra of diatomic molecules and explain origin of P.Q.R series of the spectrum, © What is Raman scattering ? Give a detailed explanation of Raman effect on the basis of quantum theory. @ What do you mean by Doppler cooling? Describe mechanism of Magneto-optical trap method in detail. ©) What do you mean by Dipole force? How is it different than the scattering force ? : OR ‘407 Explain the principle of Sisyphus cooling in detail (&) What do you mean by chirp cooling ? -000- PHY-802 2 Osanna wth onen scanner 10 10 10 10DEPARTMENT OF PHYSIGS-UNIVERSITY OF RAJASTHAN MID-TERM EXAMINATION-2021 M.Sc. (PHYSICS) - I SEMESTER Atomic & Molecular Physies (PHY-802) ‘Time Duration: 1 Hour Maximum marks:40 ~ in region show the Lyman. Balmer and Paschen series? 1+ 1/2) ae ie oe What is colour of the Ha, Hy and Hy at Gee lines in visible spectrum of Barmer series for hydrogen +12) ‘What do you mean by gross structure, ae w structure and hyper fine structure of atom? (3) Show the variation in Rydberg constant due to nite nuclear mass with atomic mass number. gp —-[\_ \& oy Sa) ca yee we © Determine the wavelength of the 9 % for ground sate of hydrogen atom is proportional to square of applied external electric field. first Lyman line, the transition from n =2 ton = 1. how the Second order stark effect (second order energy correc as) we rot structure. a a0) 2. @ _ Féin the anamotous Zeeman effect What do you mean by space quantization? Calculate and draw the allowed directions of angular momentum 1. of an electron with respect to its Z-component (Lz) in1=1 state. (6) ew hy all the molecules do not show rotational spectra? ‘) ope 22 Ao What do you mean by fine structure of spectral lines? Discuss the hydrogen spectrum in lig of fine structure. as Or as) orbital and spin value. (a0) Or as . homveive an expression for rotational energy levels of diatomic molecules. Draw rotational r _ energy level of molecules. Show that molecules may be in the exited rotational state at normal temperatures while they cannot be in the excited vibrational state at room temperatures. as) SPF Explain the cause of width of atomic spectral lines. (10) wt Bs efter droncliins Gor pe we a Osanna wth onen scanner