Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Sr.Super60, Elite,Target & LIIT BT's Paper -2(Adv-2024-P2-Model) Date: 13-04-2025
Time: 02.00Pm to 05.00Pm GTA-26 Max. Marks: 180*

KEY SHEET
MATHEMATICS
1 D 2 B 3 C 4 A 5 ABD 6 BD

7 CD 8 771 9 6 10 6 11 1 12 25

13 3 14 34 15 18 16 1 17 16

PHYSICS
18 B 19 C 20 A 21 B 22 AB 23 AC

24 AC 25 60 26 7 27 2 28 27 29 5

30 33 31 22 32 40 33 10 34 40

CHEMISTRY
35 A 36 D 37 D 38 B 39 BCD 40 AB

41 BC 42 23 43 115 44 344 45 50 46 3
630 –
47 9 48 10 49 1360 50 51 25
632
 Sri Chaitanya IIT Academy 13-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-26_Key& Sol’s

SOLUTIONS
MATHEMATICS
1. f  x    x  1  x   2  ........  x   6  with 2   i min
 2
f  2  min  8   i are either 1  i or 1  i .
f  x    x2  2x  2
3

f  1  1  a5  a4  .........  a0  53  125

a0  a1  a2  a3 ......  a5  124

2. Applying rotation formula at A and C,

z  2 PA i 2i  4 BC i(  )
 e ,  e
zi   AB
2
z4 PC
z  2 2i  4
Multiplying we get, ,  = –1  z = –2i
2i  2 z  4
C(-4)
-
P(z)



B(2i)
A(2)
a  8b
3. Let log10 x  a, log10 y  b a   2  1
a2  b2
8a  b
b  0   2
a2  b2
(1) + (2) gives 2ab  8  2b  ab  4  b   3
1  a   2  b gives a  1   b
b  a  1   a  1  4  0 has no real solution
2

b  1  a  a  3, 1  b  2, 2
 y1 y2  1,a  3  x  103 
 x1x2 100
1  x1 x2  100    100
a  1  x   y1 y2 1
10 
4. As M1M 2  m1 m2
m1m2  m1 R  Rm2  N1R  N 2 R
r1 r r r
M1M 2  M1P  PQ  QM 2  a  2  a 1 a 2
3 3 3 3
r r r r  r r 
From equation (1) and (2), we get a  1 2  2a   1 2  2 1 2   a
3  3   3 

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 Sri Chaitanya IIT Academy 13-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-26_Key& Sol’s

1  1  1  1  1
5. g   x    g   x    g    x   g    x   g     0
2  2  2  2  2
n
a  b  a  b  2  2n C2r  a 2n 2r b 2r
2n 2n
6.
r 0

     
n
2  2n Cr 
2r 2n 2n
put a  1,b  3 3  3 1  3 1
r 0

  4  2 3    4  2 3   2   2  3    2  3  
n n n n
n

 
   C   3   2   2  3    2  3  
n 2r n n
2n n 1
r
r 0  
 T  2  3  2  3
n n
n

 T   2  3    2  3   T   2  3  2  3  T  0  Tn  2  4Tn 1  Tn
a 2
  n 1 n

T1  2 C 0  3x 2 C 2  4
2T2  4 C0  3  4 C2  32  4 C4
 2T2  1  18  9  T2  14
T3  4  T2  T1  4  14  4  52
T4  4  T3  T2  4  52  14  194
  x 
 x  n  tan    
 4 2 
7. f  x 
2
 
g  x   tan   x 
4 
8. a  b  c  d  e  10
 a, b, e, d  1& e  0   9C3 & 9C3 .5
a  b  c  d  e  10
 a, b, c, d , e  1  9C4 .
a  b  c  d  e  10
 a, c  0, b, d , e  1  9C2
Similarly, 6  C2
9

a  b  c  d  e  10
 a, c, e  0, b, d  1  9C1  9C1  9C4  6. 9C2  5. 9C3  771
 33 
9. y  33  m  x  87  P  0,33  87 m  & Q  87  ,0 
 m 
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 Sri Chaitanya IIT Academy 13-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-26_Key& Sol’s
1 1 dA 33
  m  87   33  87   33
2 2
0m
2 2m dm 87
33 5742
Minimum when m   , A  5742  6
87 957
10. AT  A
A  AA T  I & A T  AA T  I  A  A T
A  A2  I  A2  A  I
A 4  A 2  2A  I  A  I  2A  I
A 4  A
A 6   A  A  I   A 2  A   A  I  A  A
 
2x ; 0x
2

1 1   3
11. Let g(x)  sin sin x  cos (cos x)   ; x
 2 2
 3
 4  2x ;  x  2
2
G(x) is periodic with period 2 and is constant in the interval
  3 
 2n  2 ,2n  2  ,n  I Now f (x)  g(x)

 2n  2n 3  3  1
 f(x) is constant in   ,    2   
  2   2 2 2
12. sin mx  1& sin nx  1  sin  90  360K   1
m, n could be 1,5,9,13,17 or 3,7,11,15,19 or 2,10,18 or 6,14 or 4,20
 5C2  5C2  3C2  2C2  2C2  25
13. Let k be number of page that was counted twice then 0  K  n  1
0  1  2  3  ...n  1986  1  2  .. n  1
n  n  1  3972   n  1 n  2  On solving n  62
62  63
So, k  1986   1986  1953  33
2

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 Sri Chaitanya IIT Academy 13-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-26_Key& Sol’s

PHYSICS
18.
19. 3B  A
e  E A  3Eb
20. Let's take any small area element on the disc dA at depth y . Then
dF    0   gy  dA  0 A    gy  dA
It can be shown that   gy  dA   gyCM  A
i.e.  gh   R 2 .
D  a  b
21. Fringe width   
d 20
Where   deviation provided by Prism       1
22. For equilibrium w.r.t rotating frame.
1 gcos
mgcos  m  sin   2sin  0  
sin 
When  is made   x , then
mgcos  m    x   2sin 2  kx  ma
kcos 2
Using (1), we get a   x using k  m 2
m
2
h  h 
23. sin   cos  1   
2 R  2 R 
 I axis 0  Jsin  2 R 
But 0 
2 r 2 R
0 I
2 r
B inside 
0 Jcos
2
I  h 
 0 1  
h  2 R 
24. When a nuclide emits an  -particle, the daughter nucleus appears in an excited nucleus
in then de - excites to ground state and emit V - radiation. As the nuclear states like
atomic states are quantised, kinetic energy spectrum of  is line in nature. In  -
emission, Q - value is shared among  particle, neutrino and daughter nucleus.
Therefore, there are numerous possibility of kinetic energy of  - particles.
25. The thermal power dissipated by the radiator in the room is k1   r  , where k1 is a
certain constant. The thermal power dissipated from the room is k2  r   out  , where k2 is
another constant. In
Thermal equilibrium, the power dissipated by the radiator is equal to the power dissipated
from the room. There fore, we can write

  
k1    r1  k2  r1   out1 
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 Sri Chaitanya IIT Academy 13-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-26_Key& Sol’s
Similarly, in the second case, k1    r   k2  r   out 2 
2 2

Solve for  from the above two equations

4T
26. Before charging the bubble pressure inside the bubble P1  P0 
r
2
After charging electrostatic pressure will be
20
P1  2 4T
When radius becomes 2r then   Po 
8 2 0 2r
q
Where  
4 (2r) 2
27. Decrease in separation  Relative speed  Time

T
  V 1  cos  dt  a  s
0
a
Final x coordinate of  Final x  coordinate of C   s
2
T a
 0
Vcos dt  VT 
2
s

From (1) and (2)

a
s
4
28. Charge on each capacitor, when switch S is opened
C 10
Q  1   2   18  90 C
2 2
Charge on the capacitor when the current through the inductor is maximum after closing
the switch ' S '.
Q1  C1  10  36  360  C
Q 2  C 2  10 18  180 C

Charge on each capacitor, when switch S is opened

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 Sri Chaitanya IIT Academy 13-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-26_Key& Sol’s
C 10
Q  1   2   18  90 C
2 2
Charge on the capacitor when the current through the inductor is maximum after closing
the switch ' S '.
Q1  C1  10  36  360  C
Q 2  C 2  10 18  180  C
Now
1 1 1 C 1 2
, ΔQ11  ΔQ 2 2  ( C 12  C 22 }    1   2   Li max
2

2 2 2 2 2

106  270  36   106  270 18 

1 1 1  1
 10 6  10  (36) 2  10  (18) 2   5  (18) 2    2  103 i 2max
2 2 2  2
14580  8100  810   1103  i 2max
103  i 2max  7290
i max  7.29  2.70 ampere
29.
k  10   100
2 1
S0  20 min    m
10 5
 100
f   50 Hz
2 2

v  10 m / s
k
B
v  v 2   B  100 1  100 Pa

P0  BkS0  100 10  20 103  20 Pa
 1 p2
 m 0  I avg
4 20 2 v
30. First steady state voltage at t  0 is with 0.5Ω in parallel with 1Ω
1 4
 Vi  4    volt
3 3

Final steady state voltage at t   is with only 1Ω in parallel

 Vf  4 volt
Time constant after t  0 is RC  1Ω  0.5 F   0.5 S

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 Sri Chaitanya IIT Academy 13-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-26_Key& Sol’s
8
V  4  e  t /
3
8 1
given t  2 ln2, V  4   
3 4
2 10
 4  volt
3 3
31. Displacement of rod at time t is x  acost
Motional EMF in the rodE  Blv   Blasint
Under steady state oscillations i  i0 cost  
Potential drop across resistor, inductor and capacitor are vR  iR  i0 Rcos t   
di    
vL  L  Li0 cos  t      i0 X L cos  t    
dt  2  2
q i  
VC   0 cos  t    
C C  2
Applying KVL,   VR  VL  VC
Solve the above equation for 
Current becomes maximum for the first time when  t   becomes integral multiple of 
for the first time
k 1
32. To maximize current in the circuit 
m LC
33, 34.

Acceleration of A and B along C and will be equal (as V  0 at this instant)

 a   2a
T T
Equation for B along horizontal is  Ma and vertical is Mg   Ma  2Ma
2 2
g 10
Solving a  
3 3
20 2 40
T  Ma 2  
3 3 2

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 Sri Chaitanya IIT Academy 13-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-26_Key& Sol’s

CHEMISTRY
35. Ans: A
h h h  h 
Sol:   ;d  ; d    2 dv;  
mv mv mv v mv  v v
36. Ans: D
Sol:

In 1,4  addition, the intermediate is not involved because if it is involved cis 

alkene to be formed but only trans alkene is formed.
37. Ans: D
Sol: A) No reaction

B) C)
O
HO
C CH3
HO OH
O HO B O
C CH3
C CH3
O
+ O
Now it is not electron def ficient,
C CH3
benzene ring activating,
O-,P- directing
O
Lewis base

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 Sri Chaitanya IIT Academy 13-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-26_Key& Sol’s
D)

38. Carbon has small size and forms a  bond with good overlap whereas silicon has larger
size hence has a poor  overlap
39. Ans: BCD
Sol: The mass of substance which combines or displaces 8 gm of oxygen in the reaction
 
where oxide O 2  formed.
40. Ans: AB
Sol: With the alkali, D  Fructose converts to the mixture of D  glucose, D  Mannose
and D  Fructose. Now D  Glucose and D  Mannose will oxidise.
41. 2 Cr en2  NCS 2  SCN  Cr en2  NCS 2  Cr en NCS 4   en
In the reactant, the oxidation state of chromium is +3 also in product it is +3 in cation and
in coordination anion. So since the oxidation number of chromium or any other species is
not changed, it is not a redox or disproportionate reaction. The product can exhibit both
linkage and coordination isomerism and the coordination cation can exhibit cis - trans
isomerism. The cis isomer can exhibit optical isomerism.
42. Ans: 23 sec.
Sol: Since conc. of B is v.high when compared with A, So O.R.w.r.t is become zero
and it is pseudo first order reaction.
r  K  B  '  A '
r  K ' A ' where K '  K  B   pseudo first order rate constant
K '  6  103  5  0.03sec 1
0.693 0.693
t1/ 2    23.1sec
K' 0.03
43. Ans: 115
Sol: Irreversible
n  0.5 P1  500 K pa, P2  250 K pa
T1  300 KT2  ?
E  W
nCv T   Pext V2  V1 
3  nRT2 nRT1 
0.5   R T2  300    P2   
2  P2 P1 

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 Sri Chaitanya IIT Academy 13-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-26_Key& Sol’s
0.75 T2  300    n T2 P1  T1P2  / P1  T2  240 K
P T
S sys  2.3nR log 1  2.3 nCP log 2  2.3  0.5  2  0.3  2.5  log 0.8
P2 T1
 2.3 0.3  0.25  2.3  0.05

 0.115  115  103 cal / k

44. Ans: 344
Sol:

45. Ans: 50
Sol:

h

R. A  4  1  4 R. A  2  1  2
R. A  6  1  6
4 2
6 %  100
%   100  50 %   100  33.3% 12
12 12
 16.7%

46. Pig iron and blister copper contain metals

47. Silicon z = 14 Elec. Config. 1s 2 , 2s2 2p6 3s2 3p2 having 3 orbits
Atoms of B,C,N and F have only two orbits, so they are smaller than Si atom.
Atoms of P,S,Cl and Si have same number of orbits but present in same period and
comes after silicon. So they are smaller than silicon atom.
Ca,Cr and Ga contain 4 orbits. So they are larger than silicon but when Ca and Cr
converts into Ca 2 and Cr 3 the number orbits in these ions are 3 and also due to positive
charge they become smaller than silicon. Ga is larger than silicon
48. Ans: 10
Sol: Hg 22   2e    2 Hgl 
 0.06
EHg 2 / Hg  EHg 2
/ Hg
 log  Hg22  
2 2 2

Sec : Sr.Super60, Elite,Target & LIIT BT's Page 11

 Sri Chaitanya IIT Academy 13-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2024 –P2)_GTA-26_Key& Sol’s
2
Hg 2Cl2 S   Hg 22   2Cl  ; ksp   Hg 22   Cl    1052/3

 0.06 k sp of HgCl2
ECl  / HgCl / Hg  EHg 2  log 2
2 / Hg 2
2
Cl  
 
52/3
10
0.24  0.79  0.03log 2
Cl  
 
52/3
55 10 55/3 1052/3
  log 2
 10  2
3 Cl   Cl  
   
2
 Cl    10  Cl    10 M
49. Ans: 1360
 0.06

Sol: ECl 
/ Hg
 EHg 2 
log ksp of Hg 2Cl2
2 Cl2 / Hg 2 2 / Hg

 52 
 0.79  0.03     0.27V
 3 
  
Ecell  Ecathode  Eanode

Ecell  E pt / 2/  ECl


/ Hg 2Cl2 / Hg

1.09  E pt / X   0.27  E pt / X   1.36V

2/X 2/X

X 2  g   2e  
2X   g 
2
0.06 X 
E pt / X   E pt / X 2 / X  log  
2/X 2 Px2

 1.36  0.03log
 1.36V  1360mv
10 
1 2

102
50. Simultaneous excitation of 2 electrons from ground state to first excited states of two O 2
molecules requires
2  94.7  189.4kJ / mol
E 3.16 1019 J
γ   4.751014 s1
h 6.626 10 Js 34

c 31010
λ   6.311014 S1
υ 4.7510 14

 λ  631nm
51.

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