FIITJEE – NJEETS (JEE-Advanced)-8

PHYSICS, CHEMISTRY & MATHEMATICS

CPT1-1 Q.P.CODE:00000.0 PAPER-1 11/05/2024

BATCHES - 2024 NJEETS (JEE-Advanced) - 8

Time Allotted: 3 Hours Maximum Marks: 183

▪ Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
▪ You are not allowed to leave the Examination Hall before the end of the test.

INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & C in the OMR. Part-B of OMR to be left
unused.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Two Parts.

(i) Part-A (01-07) – Contains seven (07) multiple choice questions which have One or More correct answer.
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO incorrect
option is darkened.
Zero Marks: 0 If none of the bubbles is darkened. Negative Marks: −1 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will
result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B) will result
in −1 marks, as a wrong option is also darkened.
(ii) Part-A (08-13) – Contains six (06) multiple choice questions which have ONLY ONE CORRECT answer
Each question carries +3 marks for correct answer and -1 marks for wrong answer.
(iii) Part-C (01-05) contains five (05) Numerical based questions with single digit integer as answer, ranging
from 0 to 9 (both inclusive) and each question carries +3 marks for correct answer. There is no negative
marking.

Name of the Candidate :_________________________________________________

Batch :________________________ Date of Examination :____________________

Enrolment Number :_____________________________________________________

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Useful Data Chemistry:

Gas Constant = 8.314 J K−1 mol−1
R
= 0.0821 Lit atm K−1 mol−1
= 1.987  2 Cal K−1 mol−1
Avogadro's Number Na = 6.023  1023
Planck’s Constant h = 6.626  10–34 Js
= 6.25 x 10-27 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
1 amu = 1.66 x 10-27 kg
1 eV = 1.6 x 10-19 J
Atomic No : H=1, D=1, Li=3, Na=11, K=19, Rb=37, Cs=55, F=9, Ca=20, He=2, O=8,
Au=79.
Atomic Masses: He=4, Mg=24, C=12, O=16, N=14, P=31, Br=80, Cu=63.5, Fe=56,
Mn=55, Si = 28 Pb=207, u=197, Ag=108, F=19, H=2, Cl=35.5
Useful Data Physics:
2
Acceleration due to gravity g = 10 m / s

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Section – I (Physics)
PART – A
One or More Than One Correct Type

1. A meter bridge is used to predict the value of

unknown resistance X, it is observed that current
is flowing from A to B initially (when jockey is fixed
at a point B). If the temperature of X is increased,
then select possible option/s :

(A) current reduces in magnitude (B) current remain constant

(C) current become zero (D) current flows in opposite direction

2. There is a circuit diagram in which capacitors, resistors &

battery are given. Then choose the correct option(s)
(Assume initially all the capacitors are uncharged)

(A) At steady state charge on capacitor A is zero

(B) At steady state charge on capacitor B is zero
(C) At steady state charge on capacitor B is 40µC
(D) Electric current in 2Ω resistor is 5A
space for rough work

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3. Aluminous point object is placed at O, whose image is

formed at I as shown in figure. Line AB is the optical axis.
Which of the following statement is/are correct?

(A) If a lens is used to obtain the image, then it must be a converging lens and its optical centre
will be the intersection point of line AB and OI.
(B) If a lens is used to obtain the image, then it must be a diverging lens and its optical centre will
be the intersection point of line AB and OI.
(C) If a mirror is used to obtain the image then the mirror must be concave and object and image
subtend equal angles at the pole of the mirror.
(D) I is a real Image.

4. Two point charges +q and – q are fixed on diametrically opposite

point on the uniform ring, such that – q is at bottom and is in
contact with a perfect insulator incline plane. Total mass is equal to
m. It remains in equilibrium on the rough inclined plane in the
presence of uniform vertical electric field

(A) the value of friction force is mg sin.

(B) the value of friction force is less than mg sin.
mg
(C) the value of electric field is .
2q
mg tan 
(D) the value of electric field is .
2q
space for rough work

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5. According to Maxwell's distribution of molecular

speeds, for the below graph drawn for two different
samples of gases A and B at temperature T1 and T2
respectively, which of the following statements is/are
INCORRECT:

(A) If T1 = T2, then molecular mass of gas B(MB) is greater than molecular mass of gas A(MA).
(B) If molecular mass of gas A(MA) is equal to molecular mass of gas B(MB), then T1 > T2.
(C) If T1 < T2 , then molecular mass of gas B(MB) is necessarily less than molecular mass of gas
A (MA).
(D) If gas A is O2 and gas B is N2, then considering them to be ideal gases, T1 is necessarily less
than T2.

6. Position time graph for a particle moving on straight

line is shown in figure. Assume same slope of x-t
graph at t = 0 and t = 20 s. Select correct
alternative/s :

(A) Average velocity of particle from t = 0 to t = 20 sec. is zero.

(B) Acceleration of particle from t = 10 sec. to t = 15 sec. is positive.
(C) Average acceleration of particle from t = 0 to t = 20 is zero.
(D) Average velocity & instantaneous velocity becomes same in magnitude and direction more
than once from t = 0 to t = 20 sec.
space for rough work

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7. A uniform rod of mass m and length l is released from rest in

the vertical position on a rough (surface is sufficientally rough to
prevent just sliding) square corner A, shown in figure, then
choose correct options :

(A) If the rod just begins to slip when θ = 37º with vertical, then the coefficient of static friction µ
between the rod and the corner is 0.3.
(B) If the end of the rod is notched so that it cannot slip, then the angle θ at which contact
between the rod and the corner ceases is 53º.
(C) If the rod just begins to slip when θ = 37º, then the coefficient of static friction µ between the
rod and the corner is 3/4.
(D) If the end of the rod is notched so that it cannot slip, then the angle θ at which contact
between the rod and the corner ceases is 37º.

Single Correct Choice Type

8. In an electric field shown in figure three equipotential

surface are shown. If function of electric field is E = 2x 2
V/m, and given that V1 − V2 = V2 − V3 then we have

(A) x1 = x2 (B) x1  x2

(C) x2  x1 (D) Data insufficient

space for rough work

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9. Wedge is fixed on horizontal surface. Triangular block

A of mass M is pulled upward by applying a constant
force F parallel to incline of the wedge as shown in the
figure and there is no friction between the wedge and
the block A, while coefficient of friction between A and
block B of mass m is  . If there is no relative motion
between A and B then frictional force developed
between A and B is
 F + ( m − M ) g sin  
(A)   m cos (B)  mg
 (m + M ) 
 F − ( m + M ) g sin  
(C)   m cos (D)  mg / 2
 (m + M ) 
3 4
10. A thin prism of glass is placed in air and water respectively. If ng = and nw = , then the ratio
2 3
of deviation produced by the prism for a small angle of incidence when placed in air and water
separately is :

(A) 9 : 8 (B) 4 : 3 (C) 3 : 4 (D) 4 : 1

11. A converging equiconvex thin lens forms real image of a particle as shown in case I. If now lens is
cut as shown in case II then select the correct alternative/alternatives:

(A) Image in case II will be at 240 cm from lens.

(B) Images is erect.
(C) Image in case II will be at the same location of case I.
(D) There will be two distinguished images.
space for rough work

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12. A triangular medium has varying refracting index

n = n0 + ax, where x is the distance (in cm) along x-axis
4
from origin and n0 = .A ray is incident normally on face OA
3
at the mid-point of OA. The range of a so that light does not
escape through face AB when it falls first time on the face AB
(OA = 4 cm, OB = 3 cm and AB = 5 cm) : (Surrounding
medium is air)

1 2 1
(A) a  (B) a  (C) a  (D) None of these
9 9 3

13. A uniform rod is kept at smooth horizontal surface, a constant

force is applied on the rod in horizontal direction at end ‘A’.
Find the ratio of energy stored per unit volume at end A to the
energy stored per unit volume in the middle of rod.

(A) 2 (B) 4 (C) 8 (D) 6

PART – C
Numerical Based Questions

1. A particle P is moving on a circle under the action of only one force,

which always acts towards a fixed point O lying on the circumference.
d 2  d 
2

Find ratio of to   at the moment when  = 45º. (C is

 dt 
2
dt
centre of circle)

2. The side of the cube is ' l ' and point charges are kept at each corner
as shown in diagram. Interaction electrostatic potential energy of all
4kq 2
the charges is , , then N is:
Nl

space for rough work

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3. Find the value of x so that image of object

formed at infinite from a quarter cylinder of
refractive index  = 4 .

4. Blocks A and B each have same mass m = 1 kg. The largest

horizontal force P which can be applied to B so that A will not
slip up on B is 5X N. Neglect any friction. Find the value of X.

5. Distance between two images formed by upper

and lower part of the point object placed at 30
cm from given lens is (60 + x) cm, then the value
of x is : (Roc20 = Radius of curvature of both the
surface is 20 cm)

space for rough work

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Section – II (Chemistry)
PART – A
One or More Than One Correct Choice Type

1. 34.3g Pb3O4 is dissolved in 500 ml of 4M HNO3 then (A.Wt: Pb = 207)

(A) there is no residue left
(B) the wt. of residue is 11.95g
(C) 300 ml of 6 M NaOH is required to neutralise excess of HNO 3
(D) It is a redox reaction

2. The solubility of CH3COOAg (Ksp = X) in a buffer solution of pH = Y (Y < 7)

(A) increases as the value of Y decreases
(B) decreases as the value of Y decreases
(C) will be greater if the Ka value of the CH3COOH is greater
(D) will be smaller if the Ka value of the CH3COOH is greater

3. Synergic bonding in metal carbonyl complexes [M = Metal]:

(A) decreases C – O bond strength
(B) increases M – C bond length
(C) increases bond order for M – C bond
(D) increases paramagnetic nature of complex

4. If a coordination complex M(CO)6 is colored due to d – d transition & its CFSE corresponds to
that wavelength which an electron emits on de – excitation from 4th orbit to 3rd orbit in Li+2 ion.
Find the value of CFSE for the given complex. (take R= 10 7m-1 ) h= 6.62 ×10-34

(A) 9.53 ×10-19 J (B) 1.36×10-18 J (C) 1.97 ×10-20 J (D) 2.59×10-17 J

5. For aq. solution of potash alum, which is/true are

(A) One gm eq of potash alum will give 1 gm eq of K+
(B) One gm eq of potash alum will give 1 gm eq of Al3+
(C) One gm eq of potash alum will give 2 gm eq of SO4-2
(D) 1/8 mole of potash alum will give 1 gm eq of SO4-2
space for rough work

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6. Potassium fluoride (KF) has NaCl type of unit cell with radius of K+ and F- ions 132 and 135 pm
respectively.Which of the following is/are correct?
(A) Shortest K - F distance is 267 pm (B) edge length of the unit cell is 524 pm
(C) Closest K – K distance is 377.6 pm (D) None is correct.

7. An element A has BCC structure and another guest atom B, of largest possible size is present at
each edge centre without disturbing the original unit cell dimension. Which of the following is/are
correct? If rA = radius of A ; rB = radius of B ; a = unit all length

rB
(A) = 0.155 (B) Packing fraction = 0.684
rA
(C) Packing fraction = 0.72 (D) 2 ( rA + rB ) = a

Single Correct Choice Type

8. The hybridization of C-1 and C-2 carbon atoms marked in the following structure of benzyne
intermediate?

1
2

(A) sp2 and sp2 (B) sp and sp (C) sp and sp2 (D) None of these

9. FeS + H2SO4 → Product ‘A’

Which is incorrect about gas ’A’ ?

(A) It produces white ppt. with FeCl3

(B) It produces black ppt. with (CH3COO)2Pb.
(C) It decolorizes the purple colour of KMnO4.
(D) It produces purple precipitate with sodium nitroprusside in alkaline medium.
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10. Number of monochloro structural isomers possible for the compound X is:

X
(A) 1 (B) 2 (C) 3 (D) 7

11. Which of the following is correct?

(A) An achiral molecule which is superimposable on its mirror image cannot exist as two
enantiomers.
(B) Changing the configuration of a molecule always means that bonds are broken.
(C) Both (A) and (B)
(D) None of these

12. A photon is emitted in β -line of Balmer series in He+ . This photon is absorbed by an electron
present in ground state of H – atom. If uncertainty in position now is equal to de-Broglie
wavelength then uncertainty in de-Broglie wavelength is:

(A) 0.529 Å (B) 2.116 Å (C) 4.232A Å (D) 0.265 Å

13 [M( NO2 )2 (NH3 )2 (py)2 ] ⟶[M( NO2 )(NH3 )3 (py)2]

Difference between the possible geometrical isomers of reactant and product is:

(A) 3 (B) 4 (C) 2 (D) 0

PART – C
Numerical Based Questions

1. Find the quantum number ‘n’ corresponding to the excited state of He + ion. If on transition to the
ground state that ion emits two photons in succession with wavelengths 108.5nm and 30.4 nm.

2. How many isomers of C4H10O reacts with CH3MgBr to evolve CH4 gas? (Excluding stereoisomer)

3. 2.47 g of an element Ax when dissolved in 50 g of benzene, lowered the freezing point of

benzene to 0.4 K. Kf for benzene is 5.12 K kg mol-1 . The value of x, for atomic weight of A being
79, is ………..

4. What is the time (approximate) in hours for collecting 18 g of magnesium from molten MgCl 2
using a current of 10 amperes? (A.Wt: Mg = 24; Cl=35.5)

5. A thermally isolated vessel contains 100 g of water at 0℃ . When air above the water is pumped
out, some of the water freezes and some evaporates at 0℃ itself. If the mass of the ice
formed ( in gram ) such that no water is left in the vessel is x ,find x/10 (Latent heat of
vaporization of water at 0℃ = 2.10 ×106 J/Kg and latent heat of fusion of ice = 3.36 ×105 J / Kg)

space for rough work

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Section – III (Mathematics)

PART – A
One or More Than One Correct Type
1. Let ax 2 + bx + c is integer for all integral values of x , then which of the following must be true?

n
(A) c is integer (B) b = ,n I
2
n
(C) a = ,n I (D) a, b both are integers
2
y z y z
2. Two lines L1 : x = 5, = and L2 : x =  , = are coplanar. Then  can take
3 −  −2 −1 2 − 
value(s)
(A) 1 (B) 2 (C) 3 (D) 4

3. Consider the system of equations ax + by = 0 and cx + dy = 0 where a, b, c, d 1,2 . Then the

probability that the system of equations has

(A) unique solution is ½ (B) unique solution is 5/8
(C) non trivial solutions is 3/8 (D) non trivial solutions is ½

4. A square is inscribed in the circle x2 + y 2 − 10x − 6 y + 30 = 0. One side of the square is parallel to
y = x + 3, then one vertex of the square is

(A) (3, 3) (B) (7, 3) (

(C) 6,3 − 3 ) (
(D) 6,3 + 3 )
5. A function f ( x ) satisfies the relation f ( x + y ) = f ( x ) + f ( y ) + xy ( x + y ) ,  x, y  R. If

f ' ( 0) = −1, then

(A) f ( x ) is a polynomial function (B) f ( x ) is an exponential function

(C) f ( x ) is twice differentiable for all x  R (D) f ' ( 3) = 8

space for rough work

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1
6. Equation − 3x + sin x = 0 has
( x + 1)
3

(A) no real root (B) two real and distinct roots

(C) exactly one negative root (D) exactly one root between – 1 and 

 /2  /2  /2
7. Suppose I1 =  cos ( sin 2 x ) dx; I 2 =  cos ( 2 sin 2 x ) dx and I 3 =  cos ( sin x ) dx , then
0 0 0

(A) I1 = 0 (B) I 2 + I 3 = 0 (C) I1 + I 2 + I 3 = 0 (D) I 2 = I 3

Single Correct Choice Type

8. Three circles touch one-another externally. The tangents at their points of contact meet at a point
whose distance from a point of contact is 4. Find the ratio of the product of the radii to the sum of
the radii of circles.

(A) 16 : 1 (B) 1 : 16 (C) 8 : 1 (D) None of these

5 2
( ) + ( cot −1 x ) =
−1 2 2
9. Solve for x : tan x
8

(A) x = 2 (B) x = −1 (C) x = 1 (D) x = 0

10. The number of three digit numbers of the form xyz such that x  y and z  y is

(A) 221 (B) 240 (C) 256 (D) 276

If A is a skew symmetric matrix, then B = ( I − A)( I + A )

−1
11. is

(A) Idempotent matrix (B) Involuntary matrix (C) orthogonal matrix (D) Symmetric matrix

12. The lines joining the origin to the points of intersection of x2 + y 2 + 2gx + c = 0 and
x2 + y 2 + 2 fy − c = 0 are at right angle, if

(A) g 2 + f 2 = c (B) g 2 − f 2 = c (C) g 2 − f 2 = 2c (D) g 2 + f 2 = c2

space for rough work

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NJEETS JEEA P1 –CPT1-(FT-8)-PCM-IITJEE/24 15

The number of points of discontinuity of f ( x ) =  2 x  − 2 x (where  denotes the greatest

2 2
13.
integer function and 
 denotes the fractional part of x in the interval ( −2,2 ) are

(A) 6 (B) 8 (C) 4 (D) 3

PART – C
Numerical Based Questions

1. Let  be a complex number such that  = 1 . If the equation  z 2 + z + 1 = 0 has a purely

a+ b
imaginary root, then tan 2 ( arg  ) = , where a, b, c are coprime natural numbers, then
c
a + b + c is

2. The area bounded by the curves y = lnx, y = ln|x|, y=|lnx| and y = |ln|x|| is __________.

3. If p is the length of the perpendicular from a focus upon the tangent at any point P of the ellipse
x2 y 2 2a b 2
2
+ 2 = 1 and r is the distance of P from the focus, then the value of − 2 is ______.
a b r p

Let the 3rd, 4th, 5th and 6th terms in the expansion of (1 + x ) be a, b, c, d respectively. Then
n
4.
b 2 − ac ma
= where m and n are coprime natural numbers, then m + n is equal to
c 2 − bd nc
_____________.

5. ( ) ( )
Let r = a  b sin x + b  c cos y + ( c  a ) , where a, b and c are non-zero non-coplanar

vectors. If r is orthogonal to 3a + 5b + 2c , then the value of sec2 y + cos ec2 x + sec y cos ecx is
___________.

space for rough work

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NJEETS JEEA P1 –CPT1-(FT-8)-PCM-IITJEE/24 16

FIITJEE NJEETS
JEEA
JEE (ADV) - 2024
NJEETS - 8 Paper Code
Conduction Date: 11/05/2024
PAPER - 1
SET-A
ANSWER KEY
Physics
PART– A

1. A, C, D 2. A, C 3. A, C, D 4. A, C
5. A, B, C, D 6. A, B, C 7. A, B 8. B
9. C 10. D 11. A 12. B
13. B
PART - C
1. 2 2. 3 3. 1 4. 3
5. 6
Chemistry

PART – A
1. B, C 2. A, D 3. A, C 4. A
5. D 6. A, C 7. A, B, D 8. A
9. D 10. C 11. C 12. A
13. C

PART – C
1. 5 2. 4 3. 8 4. 4
5. 9

Mathematics

PART – A
1. A, B, C 2. A, D 3. B, C 4. A, B
5. A, C, D 6. B, C, D 7. A, B, C 8. A
9. B 10. D 11. C 12. C
13. A

PART - C
1. 8 2. 4 3. 1 4. 8
5. 3

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NJEETS JEEA P1 –CPT1-(FT-8)-PCM-IITJEE/24 17

HINTS & SOLUTIONS

Physics
PART– A
1. A, C, D
Sol. If x (1 − l )  Rl then v A  vB if x is increased the current may decrease, become zero or may
increase.
2. A, C
Sol.

3. A, C, D
Sol.

4. A, C
Sol. f = mg sin  and PE sin  = mg sin  R
q 2 RE sin  = mg sin  R
mg
E=
2q
5. A, B, C, D

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NJEETS JEEA P1 –CPT1-(FT-8)-PCM-IITJEE/24 18

Sol. (V )  (V )
mp T
1
mp T
2

T1 T T M
  2  2 B
MA MB T1 M A
MB
But, can be less than or greater than 1
MA
M A T1

M B T2
If gas A is O2 and gas B is N2, then MA > MB.
(V )  (V )
mp T
1
mp T
2

T1 T
  2
MA MB
T M
 2 B
T1 M A
6. A, B, C
Sol. Average velocity of particle from t = 0 to t = 20 sec, is zero. Acceleration of particle from t = 10
sec to t = 15 sec is positive.
7. A, B

1  ml 2  2
Sol. mgl / 2 = mg ( l / 2 ) cos  +  
2 3 
…(1)
mg cos − N = m 2 ( l / 2)
…(2)
ml 2
( mg sin  ) l / 2 = 
3
…(3)
mg sin  − f a = m ( l / 2)
…(4)
fs   N
…(5)
8. B
Sol. Rate of change of potential is increasing
 v1 − v2 / x1  v2 − v3 / v2
 x1  x2
9. C

 F − ( m + M ) g sin  
Sol. a= 
 (m + M ) 
So, f = ma cos 
 F − ( m + M ) g sin  
=  m cos
 (m + M ) 
10. D

3  A
Sol.  a =  − 1  A =
2  2
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NJEETS JEEA P1 –CPT1-(FT-8)-PCM-IITJEE/24 19

3/ 2  A
w =  − 1 A =
4/3  8
 air 4
=
 water 1
11. A
1 1 1
Sol. − = ….(1)
40 −60 f
1 1 1
− = … (2)
v −60 2 f
1 1 1 100
 + = 
v 60 2 40  60
1 1 1
 = −
v 48 60
 v = 240 cm
12. B
3
Sol. Clearly, PM = cm
2
1
37°  sin −1
n0 + a ( 3 / 2 )
3 1

5 n + 3a
0
2
9a
3n0 + 5
2
9a 2
 1; a 
2 9
13. B
1 ( stress )
2

Sol. U=
2 Y
UA TA2 F2
= = =4
U middle (Tmiddle )2 ( F / 2 )2
PART– C
1. 2

F
Sol. at = sin 
m
Rd 2 ( 2 ) F d 2 F sin 
= sin   = …(1)
dt 2 m dt 2 2mR
F
ac = cos
m
2
d  F
R  ( 2 )  = cos  …(2)
 dt  m

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NJEETS JEEA P1 –CPT1-(FT-8)-PCM-IITJEE/24 20

 d 2 
 2 
 dt  = 2 tan  = 2
 d 
2

 
 dt 
2. 3

Sol. Only effective pairs will be body diagonals for this interaction electrostatic potential energy is
4kq 2
= .
3l
3. 1
xR
Sol. image of object is = −  d distance at current surface
12
 xR 
u = −  4 + R
 12 
v =  ROC = −R
 r − i  r  i
= −
R v u
1− 4 −4
=  x =1
−R  xR 4 
− + R
 12 
4. 3
Sol. N cos37 = 1g …(1)
N sin37 = 1a … (2)
a
= tan 37
g
3
a = 10  = 7.5 m / s 2  P = 2a  P = 15 N
4
5. 6
1  3  1 1 
Sol. =  − 1 + 
f L  2  20 20 
 FL = 20 cm
1 1 2 1
= − =−
f −10 20 5
1 1 1 1 1 1
+ =  = −
v −30 −5 v 30 5
1 1 1
for lens − =
v −30 20
Chemistry
PART – A
1. B, C

Sol. Pb 3O4 + 4 HNO3 → 2Pb (NO3)2 + PbO2 +2H2O

0.05 2 0 0 0 initial moles
0 1.8 0.1 0.05 final moles

HNO3 + NaOH→ NaNO3 + H2O

1.8mol
∴ moles of NaOH required= 1.8
Residue is PbO2 . Its moles formed= 0.05
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NJEETS JEEA P1 –CPT1-(FT-8)-PCM-IITJEE/24 21

mass of PbO2 =0.05× 239 =11.95 g

2. A, D

Sol. CH3COOAg ⇋ CH3COO− + Ag+ ........Ksp

CH3COO− + H+ ⇆ CH3COOH ………1/Ka

If we decrease pH of the solution and increase the concentration of H + ions, solubility increases.
If Ka is small, solubility increases.
3. A, C

Sol. M⟵ :C ≡ O
M= C= O
4. A
2 1 1
Sol. ∆E = 2.18 × 10−18 Z ( − ) ; Z=3 ; n1=3 ;n2 =4⇒∆E=9.53 ×10-19 J
n21 n22
⬚
5. D
Sol. K2SO4.Al2(SO4)3.24H2O → 2K+ + 2Al+3 + 4SO4-2
n factor = 8; 1 mole 2 mol 2 mol 4 mole
8 gm eq 2 gm eq 6 gm eq 8 gm eq
1 gm eq 1 gm eq cations 1 gm eq
6. A, C
a
Sol. r+ + r− = 132 + 135 = 267 pm; a = 267 × 2 = 534; d K − K = = 377.6 pm
2
7. A, B, D

Sol. 2 ( rA + rB ) = a
Also 3 a = 4rA
rB
 = 0.155
rA
1
In the unit cell, there are 2 ‘A’ and12  = 3 ' B '
4
 
4 3 3 
 (2rA + 3rB ) 4 2r 3 + 3r 3 
 A B 
3 3
P.F = = =  (2 + 3(0.155)3 )
a 3
3   4   16
3

  rA  
 3  
3
=  (2.0111) = 0.6836
16
8. A
Sol. Factual
9. D
Sol. FeS +H2SO4 →FeSO4+ H2S

FeCl3 +H2S→ FeCl2 + HCl +S

(CH3COO)2Pb + H2S → PbS

MnO4- + H2S+ H+ → Mn+2 + S+ H2O

H2S + Na2[Fe(CN)5NO] →purple colour (in alk. Medium)

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NJEETS JEEA P1 –CPT1-(FT-8)-PCM-IITJEE/24 22

10. C

Sol. There are 3 different positions possible marked with *

*
*
11. C
Sol. Factual
*
12. A

Sol. ∆E = 13.6Z2 (
1
− 2)
1 X
n21 n2
⬚
⬚ ⬚
1 1 1 1
∆E = 13.6(2)2 ( 2 − 2 ) = 10.2eV ; ∆E = 13.6(1)2 ( 2 − 2 ) = 10.2eV
2 4 1 n
⇒n=2
n2
As, 2πr = nλ ; r = 0.529
Z
⟹ λ = 4π × 0.529
⟹ (∆x)(∆λ)=λ2/4π ⟹ ∆λ=0.529 Å
13. C

Sol. [M a2 b2 c2 ] has G.I.= 5 [Ma3 b2 c] has G. l. =3

PART – C
1. 5
Sol. Given, λ2=30.4×10-7 cm ; λ1 =108.5 ×10-7 cm
Let excited state of He+ be n2. It comes from n2 to n1 and then n1 to 1 to emit two successive
photon.
Using
1 1 1 2 1 1
+ = = RH Z ( − 2)
λ1 λ2 λ n21 ⬚ n2
Thus, excited state for He+ is 5th orbit.
2. 4
Sol. CH3-CH2-CH2-CH2OH ; CH3-CH2-CH(OH)-CH3 ; (CH3)2CH-CH2-OH; (CH3)3CH-OH
3. 8
Kf 1000wB
Sol. △ Tf = ; MB = 79x
MB wA
x=8
4. 4

Sol. Mg+2 + 2e - → Mg
2F 24 g
24 g Mg need charge = 2F= 2×96500 C
18 g Mg needs charge = (2× 96500×18) /24=Q
it =Q ⇒ t=4.02hr.
5. 9

Sol. Total mass of the water = M = 100 g; Latent heat of vaporization of water at 0℃= L1 = 21.0×105
J/ Kg
Latent heat of fusion of ice = L 2 = 3.36 ×10 5 J/ Kg
Suppose, the mass of the ice formed = m(Kg)
Then, the mass of water evaporated = 0.1 –m Kg
Heat lost by the water in freezing = Heat taken by the water in evaporation
Thus, mL2 = (100-m)L1 or the mass of the ice formed in gm = 86.2 g

Mathematics
PART – A
1. A, B, C
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Sol. f ( 0) = c  I

f (1) = a + b + c  I and f ( −1) = a − b + c  I

 f (1) − f ( −1) = 2b  2b  I
f (1) + f ( −1) = 2 ( a + c )  2a  I
2. A, D
Sol. Lines will be coplanar if shortest distance is zero.
5 − 0 0
0 3 − −2 = 0
0 −1 2 −
3. B, C
Sol. ad − bc  0 for unique solution.
values of ad and bc can be 1, 2 or 4.
4. A, B

Sol. Let slope of OA is m, where O is centre of the circle and A is a vertex of square.
m −1
= tan 45  m = 0
1+ m
Equations of diagonals of square can be y = 3 or x = 5.
5. A, C, D

f ( h)
Sol. f ( 0 ) = 0  lim = −1
h →0 h
f ( x + h) − f ( x) f ( x ) + f ( h ) + xh ( x + h ) − f ( x )
 lim = lim = −1 + x 2
h →0 h h →0 h
x3
 f ( x) = − x + c
3
6. B, C, D
Sol. D f is ( −, −1)  ( −1,  )

 1 
 f ' ( x ) = −3  + 1 + cos x  f ' ( x )  0
 ( x + 1)
4

 f is decreasing.
Also, lim f ( x ) → , lim f ( x ) → −
x →−1+ x →−1−

and lim f ( x ) → −, lim f ( x ) → 

x → x →−

 f ( x ) = 0 has exactly two roots

7. A, B, C
 /2
I1 =  cos ( cos x ) dx
2
Sol.
0

 /2  /2
cos ( sin 2 x ) + cos ( cos 2 x )  dx =
  
 2 I1 = 
0
   2cos 2 cos  2 cos 2 x  dx = 0
0

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 /2  /2
Now, I 2 =  cos  (1 − cos 2 x )  dx = −  cos ( cos 2 x ) dx
0 0
Put 2x = t
  /2
1
I 2 = −  cos ( cos t ) dt = −  cos ( cos t ) dt = − I 3
20 0

I 2 + I3 = 0
8. A
Sol. O is the incentre of C1C2 C3 with,
R
OP = OQ = OR = 4
C2 C1
Area of C1C2C3
 4= O
1
C1C2 + C2C3 + C1C3  P Q
2

C3

9. B
5 2
( tan x + cot −1 x ) − 2 tan −1 x cot −1 x =
−1 2
Sol.
8
−3 2   3 2
 tan −1 x cot −1 x =  tan −1 x  − tan −1 x  = −
16 2  16
 3 2
3 −
 ( tan −1 x ) − tan −1 x −
2
= 0  tan −1 x = or
2 16 4 4
3
tan −1 x = is not possible
4
 x = −1
10. D
Sol. x  z  y or x  z = y or x = z  y or z  x  y
Number of ways = 9 C3 + 9C2 + 9C2 + 10C3 = 276
11. C
Sol. BBT = ( I − A)( I + A)
−1
( ( I + A) )
T −1
( I − A)
T

= ( I − A)( I + A) ( I − A) ( I + A)
−1 −1

( I + A)( I − A) = ( I − A)( I + A)  ( I − A) ( I + A) = ( I + A) ( I − A)
−1 −1 −1 −1

 BBT = I
12. C
Sol. On subtracting and adding the given equations we get,
2 gx − 2 fy + 2c = 0 … (1)
and x2 + y 2 + gx + fy = 0 ….(2)
Homogenising equation (2) with the help of equation (1), then
 fy − gx 
x2 + y 2 + ( gx + fy )  =0
 c 
The lines will be at right angle, when
 g2   f2
 1 − +
  1 + =0
 c   c 
13. A
Sol. f ( x ) = ( 2 x  + 2 x) ( 2 x  − 2 x) = 2 x ( 2 x − 22 x)

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NJEETS JEEA P1 –CPT1-(FT-8)-PCM-IITJEE/24 25

= 4 x2 − 4 x2 x
Now, 2x is discontinuous at integers.
PART - C
1. 8

Sol.  = ei , z = ik , k ,  R
Let
 − ( cos + i sin  ) k 2 + ik + 1 = 0 1 − k 2 cos = 0 and k (1 − k sin  ) = 0  k sin  = 1
1
 = sin 2  = cos  cos 2  + cos − 1 = 0
k2
−1 + 5 5 −1
 cos =  tan 2  =
2 4
2. 4

1
Sol. Required area = 4 ln xdx 
0
3. 1
1 − e cos
Sol. p=b and r = a (1 − e cos )
1 + e cos
4. 8
b T4 ( n − 2 ) x c ( n − 3) x d ( n − 4)
Sol. = = , = and = x
a T3 3 b 4 c 5
 b 2 − ac  b c
  ab  − 
b − ac  ab 
2
=
a b a 5 a
= 2 =
c − bd  c − bd 
2
c d  c 3c
 −
 bc  b c 
 bc   
5. 3

Sol. ( ) ( )
r  3a + 5b + 2c = 0  a  b  c ( 2sin x + 3cos y + 5) = 0
 sin x = −1, cos y = −1

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