Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Sr.Super60_STERLING BT JEE-ADV-2023_P1 Date: 15-06-2025
Time: 09.00Am to 12.00Pm WTA-34 Max. Marks: 180

KEY SHEET
MATHEMATICS
1 CD 2 BD 3 ABC 4 A 5 D 6 B

7 C 8 3 9 3 10 4 11 3600 12 4

13 35 14 C 15 C 16 C 17 A

PHYSICS

18 ACD 19 ABD 20 ABCD 21 B 22 B 23 A

24 A 25 3 26 5 27 4 28 5 29 3

30 4 31 A 32 C 33 B 34 C

CHEMISTRY
35 ABD 36 ABCD 37 ABD 38 C 39 A 40 C

41 B 42 3 43 9 44 6 45 4 46 1

47 3 48 A 49 B 50 B 51 A
 Sri Chaitanya IIT Academy 15-06-2025_Sr.Super60_STERLING! BT_Jee-Adv(2023-P1)_WTA-34 _Key & Sol’s

SOLUTIONS
MATHEMATICS
1. CD
If  is real root then   2, m  2, non real root  1  i ACD
2. BCD
2  2 2 
3.  ai  a j    ai  a j  ai a j  ai a j 
1 i  j  7 1 i  j  7
7 7
 2 R 2.7 C2   ai a j  42 R 2    ai ai
i j i 1 j 1
 7  7 
 35 R    ai   a i   7 R 2
2
  
 i 1  i 1 
7
 35 R 2   ai  35 R 2
i 1
4. Since OP  BC

 z  
 arg  
 z3  z2  2
 nk 1   nk 1 
5. z1, z2 , z3 ,.......zk  cos     i sin   
 n 1 n  n  1 n  2    n 1 n  n  1 n  2  
   
  1 1
 cos  i sin  i
4 4 2 2
6. B
zz 2
 z  1  x 2   x  1  y 2 or y 2  2 x  1
2
 t2 1   t2 1 
Let z1  1 , t  & z2  2 , t2 
 2 1  2 
   
 t t
 arg  z1  z2    2 1  3
3 t22  t12
2

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 Sri Chaitanya IIT Academy 15-06-2025_Sr.Super60_STERLING! BT_Jee-Adv(2023-P1)_WTA-34 _Key & Sol’s
2
 1m  z1  z2  
3
7. C
The image of z in the line x  y is i z.
 iz  i    zi  
 The image of the given curve is arg     arg  
 iz  i  4  z 1 4

8. Assume 1 
6
2  sin 1  sin  2  sin  3   3sin 1   2   3 
sin 1  sin  2  sin  3     2  3     
Also,  sin  1  1   0,  
3  3   2 
sin 1   2   3      2  3  3
  sin  1   sin 3t  sin t  4sin t  sin t  0
2  3 
1
 sin 2 t  , which contradicts assumption
4
9. 3
 z1  z  z22  z 2 2 , z3  z22 2
z
 2   or  
z1
z3
  2 or   2
z1
10. 4
Multiple the given equation z 3  1  0
Yield z 9  1  0
zn  cos n, 400  i sin n 400 n  0,1, 2.....,8 of these only z3 and z4 are in the second
quadrant. However, since the solution of z 9  1  0 are distinct and since z3 is a solution
of z 3  1 it cannot be solution of the original equation. It follows that desired root in z4
with of agree measure 1600
11. 03600.00
As z1  z2  z3  0  z1, z2 , z3 are vertices of an equilateral and z4 , z5 are end points of
diameter
2
So, zi  z j  3r 2
2 2
If i, j  1, 2,3 ; zi  z j  4r 2 if i  1,2,3 & z  4,5 & z4  z5  4r 2
   zi  z j  25r 2  3600
1i  j 5

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 Sri Chaitanya IIT Academy 15-06-2025_Sr.Super60_STERLING! BT_Jee-Adv(2023-P1)_WTA-34 _Key & Sol’s

12. Let z1  r1ei1 and z2  r2ei 2

z z 2  z1z2  z1z2  z1 z 2
 1  2cos 1   2   2cos 1   2 
z1z2

13. From the figure it is clear that for arg z  circle should either lie in second quadrant of
2
touch the positive imaginary axis  f    1
 2  7  13  1
 2  7  12  0
3  4
z  2 z2
14.  1 1
2  z1z2
2 2
  
 z1  2 z2  2  z1 z 2   z1  2 x2  z1  2 z2  2  z1 z2 2  z1 z 2  
  
  z1  2 z2  z1  2 z 2  2  z1 z 2 2  z1z2  

 z1 z1  2 z1 z 2  4 z2 z 2  4  2 z1z2  2 z1 z 2  z1 z1z2 z 2  z1  4 1  z2
2
 2
0
 z2  1
2
 z1  4 or z1  2  Point z1 lies on circle of radius 2
15. B
P-2, Q-1, R-3, S-5
3
z  2 z 2  4z  8  0
Let z  x  iy, y  0
3 2
Put x  iy  2  x  iy   4  x  iy   8  0  x  1, y 2  3
 P z2  x2  y2  1  3  4
2 2
Q  z  z  x  iy  x  iy  4 y 2  12
2
 R z 2  2
z  z  x 2 y 2  x  iy  x  iy  x 2  y 2  4 x 2  5 x 2  y 2  5  3  8
2
S  z 12  2
x  iy  1  1  i 3  1   4  3  7
5 2
 5  1 1  1 3 
 22  
 
2  2  i
5
1  i  1  3i  
  2 2  2 2 
16.  P  Z  
2i  3  i    3 i
2i 2   
 2 2
5 2   19
 Argument     
4 3 2 6 12
Therefore, the principle argument is 5 / 12

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 Sri Chaitanya IIT Academy 15-06-2025_Sr.Super60_STERLING! BT_Jee-Adv(2023-P1)_WTA-34 _Key & Sol’s
6  6 
 Q   sin  i 1  cos 
5  5 
6
1  cos
Lies in 2nd quadrant and 5  cot  3   cot       tan 
6    
sin  5   2 10  10
5

2nd quadrant   
10
11 11  11   11 11 
 R  z  1  cos  i sin   2cos  cos  i sin  1
9 9  18  18 18 
11 7
z  2cos  2cos
18 18
11 7
arg z   
18 18
 S  Z  sin x sin  x  600  sin  x  600 
1
Now, Z   sin 3x 3 x   0, 
4
Z is a negative real number hence principal arguments is 
17.
Z2
Z1

 P  z1  z2  z1  z2  2  1  3  P   1
 Q   2 z1  z2  minimum distance between z1 & z2  1 Q   2
 R   3 2 z1  3 z2 minimum is  6  2  4  R  3
 S  z1  2 z2  z1  2 z2
1 4  5
S   5

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 Sri Chaitanya IIT Academy 15-06-2025_Sr.Super60_STERLING! BT_Jee-Adv(2023-P1)_WTA-34 _Key & Sol’s

PHYSICS
18) Conceptual
19. Conceptual
1 I
20.  ;  
T H
21. E 0  c B0  3  108  1.6  106  4.8  102
   
E  r B  E.B  0
22. Susceptibility  for a paramagnetic substance varies with absolute temperature as
C

T
 T
 2  1
1 T2
300
 2   2.5  105  2.14  105
350
 Magnetisation at 350K is
I   H  2.14  105  2000 Am 1  4.28  10 2 Am 1
I
23. T  2
MBH
'M ' remains same
T I
T1 I
 1
T2 I2
I1  I
I2  I / 4
T I
  2  T2  T / 2
T2 I/4
mB
24. W  mB cos1  cos 2   
2
T  mBsin  2  mBsin 600
 mB 3
T  3W
2
   x 
25. E y  0.5 cos  w  t   
  c 
 w  2  108  2
C
  108 

3  10 8
 3m
108

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 Sri Chaitanya IIT Academy 15-06-2025_Sr.Super60_STERLING! BT_Jee-Adv(2023-P1)_WTA-34 _Key & Sol’s
2
 10 
26. A  4 r  4 
2
  400m
2

  
Intensity I   0 CE rms 2
P
and also I  
4 r 2
P
 0 CE rms 2 
4 r 2
60  8.85
E rms 
100  8.85  10 12  3  108  400
E rms  5 v / m  2.23 to 2.24 v / m
E 10
27. E  10 v / m  E rms  
2 2
  5  10 v 214

1 1 100 8.854
 E.D    0 E 2rms   8.854  1012    1010  2.21  1010 J / m3
2 2 2 4
10 10
 JED  U E  U B  2.21  10  2.21  10  4.42  1010 J / m 3  4
 2M
28. Ba  0 . 3 .......(1)
4 X
 M
Beq  0 . 3 .......(2)
4 X
Ba  2 Beq  2 Beq
200  2Beq
Beq  100 G
29. T1  73  273  200k
T2  173  273  100k
1 x1 T2
 
T x 2 T1
0.0075 1

x2 2
x 2  0.015  15  103
x
 102  15  103
2
x  30  103  102
 2x  102  15  103
x
 102  15  103
2
x  30  103  102
3

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 Sri Chaitanya IIT Academy 15-06-2025_Sr.Super60_STERLING! BT_Jee-Adv(2023-P1)_WTA-34 _Key & Sol’s
B
30. I  (1)
T
I1  8 A / m
B1  0.6T T1  4k
I2  ?
B2  1.2T
T2  16K
I 2 B2 T1
 
I1 B1 T2
1.2 4
I2  8   4
0.6 16
31. Conceptual
32. Conceptual
33. Conceptual
34. Conceptual

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 Sri Chaitanya IIT Academy 15-06-2025_Sr.Super60_STERLING! BT_Jee-Adv(2023-P1)_WTA-34 _Key & Sol’s

CHEMISTRY
35) ABD
36) ABCD
37) ABCD
38) 4
39) from sp 2 to sp
40) Conceptual
41) A will be faster both in S N 1 and S N 2 reaction
42) 6
Cl
Cl
C2 H 4Cl2
C2 H 5Cl Cl
43) Cl , Cl

Cl Cl
Cl Cl Cl
C2 H 2Cl4 Cl
C2 H 3Cl3 Cl
Cl Cl
Cl Cl Cl
, Cl Cl
Cl
Cl Cl Cl
Cl
C2 HCl5 C2Cl6
Cl Cl
Cl
Cl , Cl Cl
Total
44) 6 (ALL ARE CORRECT)
45) 5 (ALL ARE CORRECT)
46) 1
Cl C  C  Cl
CN

CN
Cl
CH 2 CH2CN
47) I
M .P  C19 H11N3Cl3 I  228  11  42  106.5  127  514.5
48) a-qr, b-ps, c-qr d-ps
49) a-s, b-r, c-p, d-q

50)
51) a-q, b-p, c-s, d-r

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