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15-06-25 JR - Iit Star Co-Sc Cluster (A-Star) Jee Adv 2021 (P-I) Wat-09 QP

The document outlines the syllabus and examination structure for a Junior IIT Academy test scheduled for June 25, 2015, covering Mathematics, Physics, and Chemistry. It details the topics to be studied, including limits in Mathematics, capacitors in Physics, and alcohols in Chemistry, along with the marking scheme for different sections of the exam. The exam consists of multiple choice questions with varying point values and negative marking for incorrect answers.
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0% found this document useful (0 votes)
407 views17 pages

15-06-25 JR - Iit Star Co-Sc Cluster (A-Star) Jee Adv 2021 (P-I) Wat-09 QP

The document outlines the syllabus and examination structure for a Junior IIT Academy test scheduled for June 25, 2015, covering Mathematics, Physics, and Chemistry. It details the topics to be studied, including limits in Mathematics, capacitors in Physics, and alcohols in Chemistry, along with the marking scheme for different sections of the exam. The exam consists of multiple choice questions with varying point values and negative marking for incorrect answers.
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 17

Sec: JR.

IIT _*CO-SC(A-STAR) Date: 15-06-25


Time: 3 Hrs Max. Marks: 180
15-06-25_JR.STAR CO-SUPER CHAINA_JEE-ADV_WAT-09_SYLLABUS
MATHEMATICS: PRESENT WEEK (80%): LIMITS-III : Limits of (1)∞, 0o, ∞o forms
PREVIOUS WEEK (20%): LIMITS-II : L Hospital rule for evaluation of
limits, Limits of the form 0/0, ∞/∞, 0×∞, ∞-∞∞, limits using series
expansion, sandwich theorem
PHYSICS: PRESENT WEEK (80%): CAPACITORS –III : Force on liquid dielectrics
(optional) RC circuits
PREVIOUS WEEK (20%): CAPACITORS –II : Force on liquid dielectrics
(optional) RC circuits (Exclude: RC Circuits)
+Force on solid dielectrics
CHEMISTRY: PRESENT WEEK (80%): ALCOHOLS : Preparation of alcohols from
alkene, akyl halides, amines, aldehydes, ketones and carboxylic acid and
derivatives, Physical propertties, reactions: esterification, dehydration,
with metals, conversion into alkyl chlorides, oxidation into aldehyde,
ketones and carboxylic acids, Lucas test, victor meyer test (Exclude:
MPV reduction, exceptions of LAH & SBH, swern oxidation)
PREVIOUS WEEK (20%): ARYL HALIDES : preparation using EAS,
Sandmayer reaction, Mechanism of SNAr reactions (Exclude: Benzyne
mechanism & cine substitution) and EAS Reactions chlorobenzene,
Fittig, Wurtz-Fittig
& GRIGNARD REAGENT : Preparation and properties of Grignard
reagent, Preparation and properties of Grignard reagent & Organo
lithium
Narayana IIT Academy 15-06-25_ JR*CO-SC_JEE-ADV_(A-STAR)_WAT-09 _ QP
TIME:3hrs IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 4) Questions with Single Correct Options +3 -1 4 12
Questions with Comprehension Type With
Sec – II (Q.N : 5 – 10) Numerical value type +2 0 6 12
(3 Comprehensions – 2 + 2 + 2 = 6Q)
Questions with Multiple Correct Choice
Sec – III (Q.N : 11 – 16) +4 -2 6 24
(partial marking scheme) (+1,0)
Sec – IV (Q.N : 17 – 19) Questions with Non-Negative Integer type +4 0 3 12
Total 19 60

PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 20 – 23) Questions with Single Correct Options +3 -1 4 12
Questions with Comprehension Type With
Sec – II (Q.N : 24 – 29) Numerical value type +2 0 6 12
(3 Comprehensions – 2 + 2 + 2 = 6Q)
Questions with Multiple Correct Choice
Sec – III (Q.N : 30 – 35) +4 -2 6 24
(partial marking scheme) (+1,0)
Sec – IV (Q.N : 36 – 38) Questions with Non-Negative Integer type +4 0 3 12
Total 19 60

CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 39 – 42) Questions with Single Correct Options +3 -1 4 12
Questions with Comprehension Type With
Sec – II (Q.N : 43 – 48) Numerical value type +2 0 6 12
(3 Comprehensions – 2 + 2 + 2 = 6Q)
Questions with Multiple Correct Choice
Sec – III (Q.N : 49 – 54) +4 -2 6 24
(partial marking scheme) (+1,0)
Sec – IV (Q.N : 55 – 57) Questions with Non-Negative Integer type +4 0 3 12
Total 19 60

JR.IIT_*CO-SC(A-STAR) Page. No. 2


Narayana IIT Academy 15-06-25_ JR*CO-SC_JEE-ADV_(A-STAR)_WAT-09 _ QP
MATHEMATICS MAX.MARKS: 60
SECTION – 1 (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.

1  5x  4 x  2 1/ x
 1  5 x  4 x 2 
1/ x

1. The value of lim is :


x 0 x
A) e5 B) 8e5 C) 5e5 D) 25e5

  
  
3 1/3 1/ 2
e x  1  x3   1  x2  1 sin x
2. If   lim   then which are the following is correct
x 0 x sin x.tan x
1 4 2
A)   1 B)   C)   D)  
2 5 3
 1 
3. Let f  x  
tan x
x  x 0

, then log e  lim  f  x    x
2
  f  x   is

equal, (where   denotes
 
greatest integer function and  fractional part)
A) 1 B) 2 C) 3 D) 4
n
 1 
 a 1 b n 
4. If a  0, b  0 then lim   
n   a 
 
1 1
A) b a B) a b C) a b D) b a
SECTION - 2 (Maximum Marks : 12)
This section contains TWO (3) Paragraphs. Based on each paragraph, there are 2 questions.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.

Question Stem for Question Nos. 5 and 6:


1
 f  x  x
Let f1  x   1  x  , x  0 and f n  x    n1  n  N  1 .
1/ x

 e 

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Narayana IIT Academy 15-06-25_ JR*CO-SC_JEE-ADV_(A-STAR)_WAT-09 _ QP
1
Let lim  In , lim f n ( x )  mn and S  m j | j  N . Let n(S) denote number of
x 0 f n ( x) x 0

elements in set S

5. Value of I 2 is ________

6. Value of n(S) is ______

Question Stem for Question Nos.7 and 8


If f, g and h are functions having a common domain D and h  x   f  x   g  x  , x  D and

if lim h  x   lim g  x   l then lim f  x   l . This is known as Sandwich Theorem. Using this
x a x a x a

result, compute the following limits.

x
7. The value of lim
x 0
x4  4x2  7

 1 
8. lim x 4 sin   is
x 0
3 x 

Question Stem for Question Nos.9 and 10


In the evaluation of limits following the paragraph, one may use one or the other of the
following results:
1) If f  x  and g  x  are functions defined in some deleted neighborhood N of ‘a’ such
f  x
that g  x  never vanishes in N and lim exists, then lim g  x   0 implies Lt f  x   0
x a g  x x a x a

g x
2) If f  x   1 as x  a, g  x    as x  a and lim
xa
 f  x  exists, then this limit
equals Lt g  x   f  x   1
xa
e
sin ax  log e  e x cos x  1
9. If lim  then a  b =
x 0 x sin bx 2
10. Let f  x  be a function that is defined in a deleted neighborhood of ‘0’ such that

f  x x 1  a cos x   b sin x
lim  1 if lim  1 then a  b =
  
3
x 0 x x 0
f x

JR.IIT_*CO-SC(A-STAR) Page. No. 4


Narayana IIT Academy 15-06-25_ JR*CO-SC_JEE-ADV_(A-STAR)_WAT-09 _ QP
SECTION - 3 (Maximum Marks : 24)

This section contains SIX (06) questions.


Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
a tan x  b tan 1 x  c sin 1 x
11. Consider the limit lim  3, where a,b,cR then correct
x 0 x5
option/s is/are
A) a = 30 B) b = 10 C) c = -40 D) b = -5
x
 ax  1 
12. Let f ( x)    , where a  b  0, then lim
2 2
f ( x ), is
 bx  2  x 

A) exists for all values of a and b B) zero for 0 < a < b


1 1
   
C) non-existent for (a > b > 0) D) e a
or e b
for a  b
13. Which of the following limit (s) vanishes?


A) Lim x0 x x  x x

x

 B) Lim x0 x 2 ln

1
x

10 x  2 x  5x  1x
C) Lim x0 xln( x 1)
 D) Lim x0 
x  tan x

bx  acx 2  b | x |
14. Let L  xlim , where a, b, c are distinct positive real numbers, then choose
 x
correct options(s)-
A) if a, b, c are A.P., then L > 0 B) if a, b, c are in HP, then L < 0
C) if a, b, c are in G.P., then L = 0 D) L = 0  a, b, c
x 2 sin  x
15. lim
x 0 tan  x  sin x
 4 where  ,   R, then which of the following is/are correct-

A)     2 B)   2   5 C)   4 D)  2    3

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Narayana IIT Academy 15-06-25_ JR*CO-SC_JEE-ADV_(A-STAR)_WAT-09 _ QP
1
p cos x  xe x
16. If lim 1
 0, then which of the following is/are cannot be correct
x 0
1  sin x  q cos x.e x
about p,q?
A) p  0, q  R  0 B) p  4, q  2 C) p  2, q  R D) p  0, q  2
SECTION - 4 (Maximum Marks : 12)
This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
2/ x
 ax  bx  cx 
 3 
17. lim   is :- (Where a,b,c> 0)
2/3
x 0 (abc)
x A
18. lim(101)(1  x) tan is equal to A, then is equals :
x 1 2 101
n 1/ n

    
n
19. If lim  (5) 4  (4)5 is equal to ab (where a, b  N ) then minimum value of
n 

(b-a) is equal to (where  b  a)  0,9


PHYSICS MAX.MARKS: 60
SECTION – 1 (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
20. Initial charge on conducting sphere of radius r is Q0 . If S is closed at t  0 then charge on
sphereat any time t is

1 1
(A) Q0e  t / rR (B) Q0e 4 0 R (C) Q0e 4 0 Rr (D) none of these
JR.IIT_*CO-SC(A-STAR) Page. No. 6
Narayana IIT Academy 15-06-25_ JR*CO-SC_JEE-ADV_(A-STAR)_WAT-09 _ QP
21. A capacitor is made of two infinite coaxial metal cylinders with a dielectric material in
the space between the cylinders have radii a and b, respectively. The material has
dielectric constant which varies with radius r as k  r where  is a constant. Find the
capacitance per unit length of the system.
2 0  2 0 3
(A)
b
(B)
3
 b  a3 
n  
a

(C) 2 0 
 ab  (D)  0  b 2  a 2 
b  a 
22. A parallel plate capacitor with a capacity C with an air dielectric consists of two large
plates, located very close to each other. One of plates is uncharged, the other plate has a
charge Q. We connect the plates with a conductor having a high resistance R. Estimate
the amount of heat that will be dissipated in the conductor.
Q2 Q2 Q2 Q2
(A) (B) (C) (D)
2C 4C 6C 8C
23. A parallel plate capacitor is filled by a dielectric whose permittivity varies with the
applied voltage according to the law   V , (V=voltage) where   1V 1. The same (but
containing no dielectric) capacitor charge to a voltage U 0  156V is connected in parallel
to the first “nonlinear” uncharged capacitor. Determine the final voltage V across the
capacitors (nearly)
(A) 25 V (B) 12 V (C) 100 V (D) 50 V
SECTION - 2 (Maximum Marks : 12)
This section contains TWO (3) Paragraphs. Based on each paragraph, there are 2 questions.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
Question Stem for Question Nos. 24 and 25:
In a circuit shown, switch K is initially open. Both the cells are ideal and
C  30 F , E1  1V , R1  2, E2  3V , R2  4. At t  0 second, the switch K is closed. A and B

are two points on circuit as shown

JR.IIT_*CO-SC(A-STAR) Page. No. 7


Narayana IIT Academy 15-06-25_ JR*CO-SC_JEE-ADV_(A-STAR)_WAT-09 _ QP

24. Just after the switch K is closed, the magnitude of current in amperes through resistance
R1 is

25. Long after the switch K is closed, the magnitude of charge on the capacitor in steady
state is_____  C

Question Stem for Question Nos.26 and 27


In the circuit shown below, the switch S is connected to position P for a long time so that
the charge on the capacitor becomes q1 C. Then S is switched to position Q. After a
long time, the charge on the capacitor is q2 C.

26. The magnitude of q1 is ________.


27. The magnitude of q2 is ______.
Question Stem for Question Nos.28 and 29

Consider a simple RC circuit as in Figure 1.


Process 1: In the circuit the switch S is closed at t  0 and the capacitor is fully charged
to voltage V0 (i.e. charging continues for time T  RC ). In the process some dissipation
 ED  occurs across the resistance R. The amount of energy finally stored in the fully
charged capacitor is EC
V0
Process 2: In a different process the voltage is first set to and maintained for a
3
charging time T  RC .

JR.IIT_*CO-SC(A-STAR) Page. No. 8


Narayana IIT Academy 15-06-25_ JR*CO-SC_JEE-ADV_(A-STAR)_WAT-09 _ QP
2V0
Then the voltage is raised to without discharging the capacitor and again maintained
3
for T  RC .
The process is repeated one more time by raising the voltage to V0 and the capacitor is
charged to the same final voltage V0 as in process 1.
These two processes are depicted in the Figure 2.

28. In process 1, the energy stored in the capacitor EC and heat dissipated across resistance
ED
EC
Find the value of
ED
In process 2, total energy dissipated E D across the resistance is ED   CV02 
1 1
29.
2 
Find the value of 
SECTION - 3 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
30. A parallel plate capacitor is dipped in an insulated liquid, vertically so that half of
capacitor are joined to an ideal battery of emf  ,A, B, A' , B ' are four points on plate at
facing surface as shown. Which of the following is/are correct?

(A) V A  VB '  V A  V A'

JR.IIT_*CO-SC(A-STAR) Page. No. 9


Narayana IIT Academy 15-06-25_ JR*CO-SC_JEE-ADV_(A-STAR)_WAT-09 _ QP
(B) V A  VB '  VB  V A'
(C) Electric field around A in air(between the plates) = electric field around B ' in
liqiud(between the plates)
(D) Electric filed around B in liquid(between the plates)= Electric field around B ' in
liquid(between the plates)
31. A 4 F capacitor is given 20C charge and is connected with an uncharged capacitor of
capacitance 2 F as shown in figure. When switch S is closed.

40
(A) Charged flown through the battery is C
3
20
(B) Charge flown through the battery is C
3
200
(C) Work done by the battery is J
3
100
(D) Work done by the battery is J
3
32. A parallel plate capacitor has a dielectric slab of dielectric constant K between its plates
that cover 1/3 of the area of its plates, as shown in the figure. The total capacitance of
the capacitor is C while that of the portion with dielectric in between is C1 . When the
capacitor is charged, the plate area covered by the dielectric gets charge Q1 and the rest
of the area gets charge Q2 . Choose the correct option/options, ignoring edge effects.

E1 E1 1 Q1 3 C 2K
(A) 1 (B)  (C)  (D) 
E2 E2 K Q2 K C1 K

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Narayana IIT Academy 15-06-25_ JR*CO-SC_JEE-ADV_(A-STAR)_WAT-09 _ QP
33. A capacitor of capacitance C is charged with a battery of emf V, with battery remaining
connected, a dielectric of constant K is inserted in it to fully fill the capacitor. On
inserting the dielectric:
(A) The capacitance increases K times.
(B) The charge increases K times.
(C) The electric field remains the same.
(D) The potential difference remains the same.
34. A capacitor is charged by using a battery and then a dielectric slab is released from the
position shown in the figure (battery remains connected). Then, (Dielectric has the same
dimensions as the space between plates and there is no friction)

(A) Force on dielectric slab does not depend on the dimension x.


(B) Force on dielectric slab depends on the dimension x.
(C) Time period of oscallation does not depend on the dimension x.
(D) Time period of oscillation depends on the dimension x.
35. A capacitor of capacity C0 is connected to a battery of voltage V0 .When steady state is
attained a dielectric slab of dielectric constant K is slowly inserted in the capacitor to fill
the space between the plates completely. In final steady state which of the following
statements is/are correct.
(A) Magnitude of induced charge on the each surface of slab is C0V0  k  1
(B) Electric force due to net induced charges on any plate is zero.
k  C0V0 
2

(C) Force of attraction between plates of capacitor is


2 0 A

(D) Field due to induced harges in dielectric slab is


 k  1 C0V0
0 A

JR.IIT_*CO-SC(A-STAR) Page. No. 11


Narayana IIT Academy 15-06-25_ JR*CO-SC_JEE-ADV_(A-STAR)_WAT-09 _ QP
SECTION - 4 (Maximum Marks : 12)
This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
36. In the given R-C circuit switch S is closed at t=0 and the variation of potential difference
across the resistor the resistor VR and across the capacitor Vc are shown in the graph
V1  V2 at t  CR ln p . Find value of p

37. A parallel plate capacitor C with plates of unit area and separation d is filled with a
liquid of dielectric constant K=2. The level of liquid is d/3 initially. Suppose the liquid
level decreases at a constant speed v, the time constant as a function of time t is
 CdR
find  ?
 5d  3vt 

38. Capacitance of parallel plate capacitor with plates are A and separation d which filled
0 A
two wedges of dielectric medium of dielectric constants K1 and K 2 is C  N . log 2 . If
d
K 2  8 and K1  4 , then find the value of N

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Narayana IIT Academy 15-06-25_ JR*CO-SC_JEE-ADV_(A-STAR)_WAT-09 _ QP
CHEMISTRY MAX.MARKS: 60
SECTION – 1 (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
39. Which of the following is incorrect
A)In chloro benzene Due to resonance, the electron density increases more at ortho- and
para-positions than at meta-positions.
B) A mixture of an alkyl halide and aryl halide gives an alkylarene when treated with
sodium in dry ether
C)

D) electrophilic substitution reactions in haloarenes occur fastly and require less drastic
conditions as compared to those in benzene.
40. Which of the following is incorrect
A) Methanol is a colourless liquid.
B) Oxidation of phenol with chromic acid produces a conjugated diketone known as
benzoquinone.
C) Fermentation takes place in anaerobic conditions (in absence of air), Carbon
monoxide is released during fermentation.
D) In wine making, grapes are the source of sugars and yeast.
41. Which of the following alcohol has highest boiling point.
A) butan-2-ol B) ethanol
C) propan-1-ol D) butan-1-ol

JR.IIT_*CO-SC(A-STAR) Page. No. 13


Narayana IIT Academy 15-06-25_ JR*CO-SC_JEE-ADV_(A-STAR)_WAT-09 _ QP
42. Which of the following is correct.
A)the relative ease of dehydration of alcohols : Me3COH > Me2CHOH < MeCH2OH
B)Acidic character of MeOH is less than isopropyl alcohol
C) Methyl alcohol and ethyl alcohol are miscible with water in all proportions.
conc H2SO4 C2H5OC2H5
C2H5OH 443K
D)
SECTION - 2 (Maximum Marks : 12)
This section contains TWO (3) Paragraphs. Based on each paragraph, there are 2 questions.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
Question Stem for Question Nos. 43 and 44:
For the following reaction scheme

(Use: Molar mass (in g/mol) of H, C, N, O, Cl as 1, 12, 14, 16, and 35.5 respectively)
43. The percentage of Carbon in the product ‘P’ is ----------
44. The percentage of Hydrogen in the product ‘Q’ is ---------
Question Stem for Question Nos.45and 46
For the following reaction scheme

(Use: Molar mass (in g/mol) of H, C, N, and O as 1, 12, 14, and 16 respectively)
45. The percentage of oxygen in the product ‘Q’ is ----------
46. Total number of Pure ‘P’ orbitals present in the one molecule of product ‘W’ are ---------
Question Stem for Question Nos.47and 48

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Narayana IIT Academy 15-06-25_ JR*CO-SC_JEE-ADV_(A-STAR)_WAT-09 _ QP
47. Total number of tertiary hydroxyl groups present in one molecule of product ‘P’ are
______
48. Total number of hybridized SP2 atoms present in one molecule of product ‘Q’ are
______
SECTION - 3 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
49. In the following reaction scheme ’X’ and ‘Y’ can be

A)

B)

C)

D)
50. Choose the correct statement(s) regarding given reaction scheme

H3O PCl5
C3H6 W X
alkene major

PCC 1)MeMgCl
Y Z
2)NH4Cl

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Narayana IIT Academy 15-06-25_ JR*CO-SC_JEE-ADV_(A-STAR)_WAT-09 _ QP
A)’Z’ gives red colour in victor meyer test
B)’W’ reacts with HI faster than ‘Z’
C)No of Sp2 hybridized atoms in ‘Y’ are two
D)Alkaline hydrolysis of ‘X’ produces ‘W’

51. Which of the following molecule can liberate methane gas from MeMgCl
A) Ethyl alcohol B) Ethoxy ethane

C) D)
52. In the following reaction ‘X’ can be

A)Acetaldehyde B)Acetone C)Ethyl acetate D)2-Pentanone


53. In the following reaction ‘X’ can be

A)PCC B)KMnO4/H2SO4
C)H2CrO4 D)CrO3 in anhydrous medium
54. Which of the following are correct
O OH O OH

1)LiAlH4 1)NaBH4
O OH O OH
2)H2O 2)H2O
O O
A) HO B) HO

C) D)
SECTION - 4 (Maximum Marks : 12)
This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.

JR.IIT_*CO-SC(A-STAR) Page. No. 16


Narayana IIT Academy 15-06-25_ JR*CO-SC_JEE-ADV_(A-STAR)_WAT-09 _ QP
55. Number of carbons present in root word (as per IUPAC) of major product ‘P’ in the
following reaction

56. In the following reaction the molar mass of the product ‘P’ is 797 g/mol

Total hydroxy groups present in compound ‘X’ are----------


(Use: Molar mass (in g/mol) of H, C, N, O, Cl as 1, 12, 14, 16, and 35.5 respectively)
57. A polyester (Mol. Wt. 418) on complete hydrolysis gives acetic acid (Mol. Wt. 60) and
propanoic acid . acetic acid contributes 35.44% to the total weight of the hydrolysed
products. The number of ‘’CH3CH2CO’’ groups units Present in the one molecule of
polyester is.
(Note: Polyester contains five ester linkages and all are acetyl and propanoyl groups)

JR.IIT_*CO-SC(A-STAR) Page. No. 17

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