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Chemical Kinetics & Equilibrium C.T# 11 Pending

The document is a chemistry class test containing multiple-choice questions related to reaction rates, catalysts, equilibrium, and solubility. It covers concepts such as order of reactions, the effect of temperature on reaction rates, and the solubility product. The test is designed for students at The Ascenders Academy, Autobhan Campus, and includes various scenarios and principles in chemistry.

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75 views2 pages

Chemical Kinetics & Equilibrium C.T# 11 Pending

The document is a chemistry class test containing multiple-choice questions related to reaction rates, catalysts, equilibrium, and solubility. It covers concepts such as order of reactions, the effect of temperature on reaction rates, and the solubility product. The test is designed for students at The Ascenders Academy, Autobhan Campus, and includes various scenarios and principles in chemistry.

Uploaded by

kamransoomro58
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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CHEMISTRY MCAT# 3 SIR: HAREESH KUMAR

DATE: 02-07-2024
1
CLASS TEST# 11

THE ASCENDERS ACADEMY


AUTOBHAN CAMPUS
STUDENT NAME: CLASS:
1. For the reaction between A and B, the order with respect to A is 2 and with respect to B is 3. If
concentrations of both A and B are doubled, the rate will increase by a factor of
(a) 10 (b) 12 (c) 16 (d) 32
2. Addition of catalyst during chemical reaction alters
(a) enthalpy change (b) internal energy (c) activation energy (d) all of these
3. If the rate of reaction is doubled with every 10 rise of temperature, we raise the temperature by 40o, the
o

rate of reaction will be


(a) 4 times (b) 8 times (c) 16 times (d) 32 times
4. In an elementary reaction 2A + B → C Product if concentration of A is doubled and that of B is halved, the
rate of reaction will
(a) be doubled (b) be halved (c) increase 4times (d) decrease 4times
5. A catalyst increases the rate of chemical reaction by
(a) increasing activation energy (b) decreasing activation energy
(c) increasing temperature (d) breaking the reactants into smaller pieces
6. Consider the reaction NO2 + CO → CO2 + NO, the mechanism is given as
i. NO2 + NO2 → NO3 + NO (slow) ii. NO3 + CO → NO2 + CO2 (fast)
The order of reaction is
(a) zero (b) one (c) two (d) three
7. Very large value of Kc shows that
(a) reactant is fairly stable (b) forward reaction is almost complete
(c) amount of product is very small (d) concentration of reactants is very large
8. For which of the following reaction Kc is expected to be very small?
(a) 2HF ↔ H2 + F2 (b) 2O3 ↔ 3O2
(c) CH4 + Cl ↔ CH3Cl + HCl (d) A.O.T
9. In which of the following gaseous equilibria, the change in pressure has no effect on equilibrium state?
(a) 2SO2 + O2 ↔ 2SO3 (b) 2NO2 ↔ N2O4
(c) PCl5 ↔ PCl3 + Cl2 (d) H2 + I2 ↔ 2HI
10. In synthesis of Nitric acid by Ostwald’s process, one of the important reactions is 2NO + O 2 ↔ 2NO2 ∆H = -
114KJ/mol. According to Le-chatelier’s principle the forward reaction is favored by
(a) increasing temperature (b) increasing concentration of NO2
(c) increasing pressure (d) Both A and C
11. The solubility product expression for a sparingly soluble compound Fe(OH) 3 is
(a) [Fe3+][OH3—] (b) [Fe+][OH—] (c) [Fe3+][OH—]3 (d) [Fe3+][3OH—]
12. Solution is said to be supersaturated when
(a) Qsp = Ksp (b) Qsp < Ksp (c) Qsp > Ksp (d) Qsp =1
13. The product of ionic concentration of a saturated solution at a given temperature is called
(a)solubility (b) solubility product (c) common ion effect (d) reaction quotient
14. Which of the following will decrease the solubility of BaSO4 in its solution?
(a) H2SO4 (b) HNO3 (c) HCl (d) H2O
Address: Opposite Asim Clinic Main, Qasimabad Road, Hyderabad. Add: Main Auto Bhan Road Opposite Giddu Chock Upstair
Contact no: 0331-2677132, 022-6118188 Pizza Max Hyd Contact No: 0300-9371971, 0331-2677132,
CHEMISTRY MCAT# 3 SIR: HAREESH KUMAR
DATE: 02-07-2024 CLASS TEST# 11
15. The unit of Kc for reaction N2 + O2 ⇌ 2NO
1

(a) Mol dm–3 (b) Mol–1ddm3 (c) Mol–2 dm6 (d) No units
16. The decrease in solubility of a sparingly soluble salt by the addition of an ion common to that salt is called
(a) Solubility product (b) solubility (c) Common ion effect (d) N.O.T
17. In an exothermic reversible reaction, increase in temperature shifts the equilibrium to
(a) Product side (b) Reactant side (c) remains unchanged (d) N.O.T
18. The precipitation occurs, if the ionic concentration is
(a) Less than Ksp (b) More than Ksp (c) Equal to Ksp (d) N.O.T
–3 –1
19. For which system does the equilibrium constant Kc have units (mole dm )
(a) H2 + I2 ⇌2HI (b) N2 + 3H2 ⇌2NH3
(c) 2NO2 ⇌N2O4 (d) CH3COOH + C2H5OH ⇌CH3COO C2H5 + H2O
20. Which of the following is true for the Kc
(a) It depends on initial concentration of reactant (b) It varies with the temperature.
(c) Its value is same for all reversible reactions (d) All of these
21. A catalyst is a substance which:
(a) Does not affect the rate of the reaction (b) Alters the equilibrium point
(c) Increase the activation energy of reactants (d) Alters the rate of reaction
22. The rate constant of a reaction depends on:
(a) Temperature (b) Time of reaction
(c) Initial concentration (d) Extent of reaction
23. The rate of the reaction is expressed in units of:
(a) Mol dm-3 s (b) Mol dm-3 s-1 (c) Mol dm3 s (d) Mol-1 dm3 s-1
24. Rate of reaction can be determined by:
(a) Physical method (b) Chemical method (c) Both methods (d) None of these
25. The number of atoms or molecules whose concentrations determine the rate of a reaction is called:
(a) Molecularity (b) Rate of reaction (c) Order (d) Rate constant
26. The rate of certain reaction (dx/dt) at different times are as follows:
Time Rate (mol/dm3 s-1)
0 2.80 x 10-2
10 2.78 x 10-2
20 2.87 x 10-2
30 2.79 x 10-2
The reaction is:
(a) First order (b) Zero order (c) Second order (d) Third order
27. The rate constant depends on:
(a)Solvent (b) Temperature (c) Pressure (d) All of the above
28. Molecularity of a reaction can never be:
(a) 1 (b) 0 (c) 2 (d) 3
29. In heterogeneous catalysts, the catalyst and reactants have:
(a) One phase (b) Different phase
(c) Only two phases (d) Same phase
2
30. Consider the following rate law: Rate= K [A] [B] .Doubling the concentration of A increases the rate of
reaction by a factor of:
(a) 2 (b) 3 (c) 4 (d) 9

Address: Opposite Asim Clinic Main, Qasimabad Road, Hyderabad. Add: Main Auto Bhan Road Opposite Giddu Chock Upstair
Contact no: 0331-2677132, 022-6118188 Pizza Max Hyd Contact No: 0300-9371971, 0331-2677132,

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