Sec: XII_STU_IC Date: 02-06-2025

Time: 3 Hrs. RTA – 01 Max. Marks: 180

JEE – ADVANCE – 2020 – P2 – Model
IMPORTANT INSTRUCTIONS
MATHS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs Marks
Sec – I(Q.N : 1 – 6) Questions with Single Digit Integer Type +3 -1 6 18

One of More Correct Options Type (partial marking

Sec – II(Q.N : 7 – 12) +4 -2 6 24
scheme) (+1)
Questions with Numerical Answer Type
Sec – II(Q.N : 13 – 18) (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30 Decimal +4 0 6 18
Numbers)
Total 18 60

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs Marks
Sec – I(Q.N : 19 – 24) Questions with Single Digit Integer Type +3 -1 6 18

One of More Correct Options Type (partial marking

Sec – II(Q.N : 25 – 30) +4 -2 6 24
scheme) (+1)

Questions with Numerical Answer Type

Sec – II(Q.N : 31 – 36) (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30 Decimal +4 0 6 18
Numbers)

Total 18 60

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs Marks

Sec – I(Q.N : 37 – 42) Questions with Single Digit Integer Type +3 -1 6 18

One of More Correct Options Type (partial marking

Sec – II(Q.N : 43– 48) +4 -2 6 24
scheme) (+1)
Questions with Numerical Answer Type
Sec – II(Q.N : 49– 54) (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30 Decimal +4 0 6 18
Numbers)

Total 18 60

Exam Syllabus
Class XII: Electrostatics, Capacitance
PHYSICS
Class XI : Work, Energy, Power & Circular Motion
Class XII : Liquid Solution, Chemical Kinetics
CHEMISTRY
Class XI : Chemical Bonding
Class XII : Functions, Inverse Trigonometry Function
MATHEMATICS
Class XI : Straight Line
 XII-STU-IC-02-06-2025

MATHEMATICS Max Marks: 60

SECTION – I
(SINGLE DIGIT INTEGER TYPE)
 This section contains SIX (06) questions.
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE
 For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen
virtual numeric keypad in the place designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct integer is entered;
Zero Marks : 0 If the question is unanswered;
Negative Marks : –1 In all other cases.
1. Let f : X  Y be a function such that f ( x)  x  2  4  x , then the set of X and Y for which f ( x ) is both
injective as well as surjective, is [3, m] and [ 2, n] , then the value of m  n is
1
  x 25   50
f :R R f ( x)   2 1    2  x   .
25
2. Let be a function defined by If the function
  2  
g ( x)  f ( f ( f ( x)))  f ( f ( x)) , then the greatest integer less than or equal to g (1) is

3. Number of solution(s) of the equation cos 1 (1  x)  2cos 1 x  is
2

4  1 
4. The value of

 tan
r 2
 2
 r
1

 5r  7
 , is

5. The line parallel to the x-axis and passing through the intersection of the lines ax  2by  3b  0 and
bx  2ay  3a  0 , where ( a, b)  (0,0) is  units below the x-axis, then the value of 2 is
6. The set of real values of k for which the lines x  3 y  1  0, kx  2 y  2  0 and 2 x  y  3  0 form a triangle is
  
R –  , ,  , then the value of |  |     is
 5 3
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
 This section contains SIX (06) questions.
 Each question has FOUR options ONE OR MORE THAN ONE of these four option(s) is(are) correct
answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which
are correct;
 Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.

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 XII-STU-IC-02-06-2025
7. If P is an interior point in ABC which is at a distance of 1 unit from each side and length of the tangents to the
incircle from the vertices B and C are 2 and 3 respectively, then
(A) circumradius of the triangle is 5 units (B) area of the triangle is 6 square units
A
(C) sec  2 (D) PA : PB : PC  2 : 5 : 10
2
8. If the point ( , 0) lies inside the quadrilateral formed by lines 2 x  5 y  15, 5 x  4 y  21 , 3 x  5 y  17  0 and
y  x  3 then  can be
(A) –3 (B) 0 (C) 4 (D) 5
1 1
9. Let  ,  (   ) are roots of the equation sin 1 x  1  cos 1 x  then
sin x cos 1 x
1 1
(A)   (B)   
2 2
   2 
(C) sin 1   (D) sin 1    1  
3 4  16 
10. Let f ( x)  sin 1
x  cos 1 x  , g ( x)   tan 1
x  cot 1 x  and h( x )   sec 1
x  cos ec 1 x  then correct
statement(s) is(are)?
(A) Domain of f ( x)  g ( x) is {1}
(B) Domain of g ( x )  h( x ) is [ 2, )
 1 
(C) Domain of h( x)  f ( x) is  ,1
 2 
(D) Domain of f ( x)  g ( x)  h( x) is 
11. Let f : I  I , defined as f ( x)  2sin(2 x)  10 tan(5 x)  7 cos(4 x)  3 , then which of the following
statement(s) is/are TRUE?
(A) f ( x ) is periodic function. (B) f ( x ) is an even function.
(C) f ( x ) is an odd function and its inverse exists. (D) f  f  f  x     f  f  x   for all x  I .
[Note: I denote the set of all integers.]
12. If graph of a function f ( x ) which is defined in [–1, 4] is shown in the adjacent figure then identify the correct
statement(s).
f(x )
2
1
–1 O
0 1 2 4
–1

(A) domain of f (| x | 1) is [ 5,5] (B) range of f (| x | 1) is [0, 2]

(C) range of f (  | x |) is [–1, 0] (D) domain of f (| x |) is [–3, 3]

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SECTION-III
(Numerical Value Answer Type)
 This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter the answer. If the numerical value has more than two
decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct numerical value is entered;
Zero Marks : 0 In all other cases.
13. If f :[2, )  [8, ) is a surjective function defined by f ( x)  x2  ( p  2) x  3 p  2, p  R then sum of values of
n
p is m  n , where m, n  N . Find the value of .
m
x
14. Find the sum of all the solutions of the equation cot  log 2 {x} in x  (0, 100) .
2
[Note: {k}denotes the fractional part function of k.]
15. If the point P (0,  ) lies inside or on the triangle formed by the lines y  x  1, y  3 x  4 and y  7 x  17 then
the range of  is [m, M]. Find the value of (m2  M 2 ) .
16. Consider a square ABCD of side 12 and let M, N be the midpoints of AB, CD respectively. If a point P is taken on
MN such that AP  r , PC  s and the area of triangle whose sides are r, s and 12 is , then find the value of .

17.    1 
If f ( x)  sin 1 2 x 1  x 2  cos 1  2 x 2  1 simplified to a sin 1 x  b , where x  ,0 then find the value
 2 
of (| a |  | b |) .
a ac
 tan  n  n  1 
100
1
18. If 2
 tan 1 c , then find the value of where a, b, c  N and a & b are relatively
n 1 b b
prime.

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 XII-STU-IC-02-06-2025

PHYSICS Max Marks: 60

SECTION – I
(SINGLE DIGIT INTEGER TYPE)
 This section contains SIX (06) questions.
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE
 For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen
virtual numeric keypad in the place designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct integer is entered;
Zero Marks : 0 If the question is unanswered;
Negative Marks : –1 In all other cases.

19. A long uniformly charged wire with linear charge density   0 Coulomb m–1 is placed in the form of a spiral of
outer radius R  1m and having a total N  160 turns as shown in figure. A dipole of dipole moment
| p | 0.1Cm is placed along x -axis at point (a,0,0) where a  3 m . Find the magnitude of force (in N)
experienced by dipole.
y
z

20. A bead of mass 5 kg is free to slide on a smooth ring of radius r = 20cm fixed in a vertical plane. The bead is
attached to one end of a massless spring whose other end is fixed to the topmost point O of the spring. Initially
the bead is held at rest at a point A of the ring such that OCA  60º ,C being the centre of the ring. The natural
length of the spring is also equal to r. After the bead is released and slides down the ring, the contact force
between the bead and the ring becomes zero when it reaches the lowest position B. If the force constant of the
spring (in N/m) equals n100 , find n .

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 XII-STU-IC-02-06-2025
21. Find the equivalent capacitance between A & C in  F if each capacitor is of 4  F .

22. A massive horizontal platform is moving horizontally with a constant acceleration of 10 m / s 2 as shown in the
figure. A particle P of mass m  1 kg is kept at rest at the smooth surface as shown in the figure. The particle is
hinged at O with the help of a massless rod OP of length 0.9 m. Hinge O is fixed on the platform and the rod can
freely rotate about point O. Now the particle P is imparted a velocity in the opposite direction of the platform's
acceleration such that it is just able to complete the circular motion about point O . Then the maximum tension
(in N) appearing in the rod during the motion is 10 n. Find the value of n.

23. In the figure shown a parallel plate capacitor has a dielectric of width d / 2 and dielectric constant K  2 . The
other dimensions of the dielectric are same as that of the plates. The plates P1 and P2 of the capacitor have area '
2 0 AV 2
A ' each. The energy of the capacitor is . The value of n is :
nd

24. A particle of mass m is released in a circular tube of radius R. If a massless spring (initially unstarched) of
constant K is placed in the tube as shown in figure and angle made by radius vector with vertical when particle
(6mg)
will come at an instantaneous rest is 60º, then the value of K is then find the value of  .
 2R

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 XII-STU-IC-02-06-2025
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
 This section contains SIX (06) questions.
 Each question has FOUR options ONE OR MORE THAN ONE of these four option(s) is(are) correct
answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which
are correct;
 Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
25. Five conducting large parallel plates each of area 'A' are arrange as shown, then find incorrect statement.

2 0 A
(A) Total charge on III rd plate is .
d
 A
(B) Total charge on V th plate is  0  .
d
0 A 2
(C) Energy stored in the space between II nd
and III rd
plate is  .
d
(D) Total charge on IV th plate is zero.
26. A weightless rigid rod AB of length connects two equal masses m. One particle is fixed at the end of point B
and the other particle is at the middle of the rod at point C as shown in the figure. The rod can rotate in the
vertical plane freely around the hinge point A. Choose the CORRECT option(s) :-
A

B
(A) The minimum horizontal velocity required to be given to the particle B so as to make the rod go around in the
24 g
complete vertical circle is
5
(B) The minimum horizontal velocity required to be given to the particle B so as to make the rod go around in the
24 g
complete vertical circle is
9
(C) The ratio of compressive force in the rods AC and BC is 2 : 1, when the masses are at highest point.

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 XII-STU-IC-02-06-2025
(D) The ratio of compressive force in the rods AC and BC is 3 : 1, when the masses are at highest point.
27. A (Q) charge is fixed at origin. Another charged particle ( q, m) is projected parallel to X -axis with initial
speed v0 from large distance as shown. (Neglect gravity)
Choose the correct option(s).
Y

(m , +q)
V0
b O
+Q X
(fixed)

(A) The final speed of particle is v0

 2 b 0 mv0 2 
(B) The angle made by final velocity with X -axis will be 2cot 1  
 Qq 
(C) At minimum separation angular momentum about origin is zero.
  2 b 0 mv02  
(D) The total change in linear momentum of particle is 2mv0 sin cot 1  
  Qq 
28. If the given two identical charged rings lie in xy plane both having linear charge density  varies as per
  0 cos  ( 0  constant) where  is measured from  x -axis. Radius for both the rings is R

  0 cos    0 cos 
A B
 
C1 C2

C1 C2 = d >> R (C1 and C2 are centres)

(A) Dipole moment of each ring is 0 R 2

(B) Dipole moment of each ring is 20 R2

K 02 2 R 4
(C) Magnitude of work done by electric field in rotating ring B by 90º about x -axis is
2d 3
(D) Magnitude of work done by electric field in rotating ring B by 90º about x -axis is zero

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 XII-STU-IC-02-06-2025
29.

A smooth surface consists of two parts. AB is inclined at angle   30º and BC is semi-circular part of radius R.
A small ball of mass m is projected from A with initial velocity v0 . There is a fixed horizontal smooth surface
slightly above point B . The gap between point B and horizontal surface is slightly greater than diameter of ball.
The collision between ball and horizontal surface is perfectly inelastic.
Choose the correct option(s).
26
(A) The minimum value of v0 for which ball can reach at point C is gR
3
(B) For v0  10 gR , the impulse on the ball due to fixed horizontal surface is m 2 gR
(C) For v0  10 gR , the normal contact between surface and ball at C is mg
16 gR
(D) For v0  , the ball will return back to initial point A
3
30. There is a hollow cylinder of radius R and it is rotating with constant angular speed . There is a point mass
which rotates along with the cylinder and gets carried upward. Friction is enough such that the point mass does
not slip with respect to the cylinder as long as the normal force becomes zero. If the path of the particle after it
loses contact with the cylinder is as shown in the figure then,


h
O

R
(A) In Order to happen this where most the particle lose contact with the cylinder when h 
2
R
(B) In Order to happen this where most the particle lose contact with the cylinder when h 
2
g
(C) The value of  (in terms of g and R) is
2R
g
(D) The value of  (in terms of g and R) is
2R

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 XII-STU-IC-02-06-2025

SECTION-III
(Numerical Value Answer Type)
 This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter the answer. If the numerical value has more than two
decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct numerical value is entered;
Zero Marks : 0 In all other cases.

31. The circuit involves two ideal cells connected to a 1 F capacitor via a key K . Initially the key K is in position 1
and the capacitor is charged fully by 2V cell. The key is pushed to position 2. The net heat produced in circuit in
 J is after the key K is pushed from position 1 to position 2.

32. Electrostatic painting is becoming quite common now a days. Here the wall to be painted is given a uniform
positive charge on its surface. The paint drops are given a negative charge as they are sprayed from the nozzle.
The negatively charged drops are attracted to the positively charged wall.

Electrostatic painting process

The advantage of this is that the paint is attracted to the entire surface, even to the hidden regions. Very less paint
falls on the ground. To model this, let us assume that paint drops of radius 1 mm are sprayed by the nozzle. They
are charged due to friction with a charge of 50 electrons each. Neglect the interaction between the drops. The
density of the paint is 6000 /  kg / m3 . The surface to be painted is a large uniformly charged wall at a distance
of 1 m from the nozzle. The nozzle is held 80 cm above ground. The velocity of the drops is ranging from 2 m / s
to 5 m / s (all in the horizontal direction). The minimum charge/area (in C/m2) to be given to the wall so that no
drop falls to the ground?

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33. A uniform rope of linear mass density  is placed on a fixed rough (   0.6) surface of shape of quarter sphere.
The upper end of the rope is attached to block of mass M0 with the help of ideal spring as shown in figure. The
block is released when the spring is in natural length. The maximum energy (in J) stored in the spring if the rope
does not slip on the surface is
[Take   1kg / m, R  1m, g  10 m / s2 , K  17.6 N / m ]

34. A particle of mass m  3 kg is moving on a straight line in a conservative force field in which the potential
energy associated with the particle is given by U ( y)  2 y 2  30 y  450 . At t  0 , particle is at y  8 m and
moving towards positive y-axis with 1 m / s . During the course of its motion the maximum speed of the particle
will be (in m/s).
35. Two large conducting plates A and B having charge 200  C and 100  C respectively. Now plates are
connected to battery having emf 100 volt.
Find heat developed (in µJ) after switch is closed. (Capacitance of arrangement is 2 F ).

36. A dipole of dipole moment p is kept at origin along x direction and fixed. A bead of mass m, charge q can slide on
fixed smooth rod kept along line x  c . Bead is given a gentle push so that it start moving along +y direction from
point P as shown. Whole arrangement is kept in gravity free space. [c is very large in comparison to length of
pq
dipole and 3  1.73 ] . Acceleration of bead where normal between rod and bead is zero is the value of
x 0 mc3
x is-
y

x
P P q,m

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CHEMISTRY Max Marks: 60
SECTION – I
(SINGLE DIGIT INTEGER TYPE)
 This section contains SIX (06) questions.
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE
 For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen
virtual numeric keypad in the place designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct integer is entered;
Zero Marks : 0 If the question is unanswered;
Negative Marks : –1 In all other cases.

37. An organic compound undergoes first-order decomposition. The time taken for its decomposition to 1/8 and 1/10
[t1/8 ]
of its initial concentration are t1/8 and t1/10 respectively. What is the value of  10 ? [Take log102 = 0.3]
[t1/10 ]

38. For the reaction 3 A( g ) 

 2B( g )  2C ( g ), starting with pure A, pressure after 9 min was 387.5 mm of Hg and
after a long time was 400 mm of Hg. Calculate half life of A in min.

39. The freezing point of an aqueous solution of KCN containing 0.189 mol/kg was –0.704ºC. on Adding 0.095 mol
of Hg(CN)2, The freezing point of the solution became –0.53ºC.
Assuming that the complex is formed according to the equation,
Hg(CN)2  xCN –  Hg(CN) xx– 2 find value of x.

40. In 103 litre sample of hard water CaSO4 and MgSO4 are present. If elevation in boiling point is 0.000052ºC.
Calculate the degree of hardness of Hard water in ppm. ( Kb , H 2O  0.5 )

41. Find the number of species which do not exist.

XeF3–, PbI4, SnCl2, SCl6, SH2, SH6, XeH4, PH3, NaBF4, NF5, SNF3, POF3

42. How many maximum Nodal plane of -bonds are present in one plane in following structure.
H H
C=C=C=C=C
H3C CH3

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SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
 This section contains SIX (06) questions.
 Each question has FOUR options ONE OR MORE THAN ONE of these four option(s) is(are) correct
answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which
are correct;
 Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
43. Identify the option(s) which are not correct w.r.t. solubility of a gas in water.
(A) Value of KH (Henry’s constant) will decrease as the temperature increases.
(B) Value of KH (Henry’s constant) at same temperature for O2 gas will be less as compared to H2 gas
(C) Soft drinks will have greater “fizz” if sealed under low pressure.
(D) Scuba divers when they move underwater will have increased solubility of gases in their blood.
44. 1 mole of a non-volatile solid is dissolved in 200 moles of water. The solution in taken to a temperature TK (lower
than freezing point of solution) to cause ice formation. After removal of ice the remaining solution is taken to 373
K where vapour pressure is observed to be 740 mm of Hg. Identify the correct options:
Given data : Kf(H2O) = 2K kg mol–1 and normal boiling point of H2O = 373K.
(A) 163 moles of ice will be formed.
2000
(B) Temperature to which original solution was cooled should be K.
37  18
10
(C) Freezing point of original solution should be  °C.
18
1
(D) Relative lowering of vapour pressure of final solution will be .
201
1 dk
45. In order to study effect of temperature on rate of reaction, another term “” is defined as   [where k is
K dT
1.25  106
rate constant and T represents temperature].If for a reaction value of   K–1
T3
[T should be in Kelvin], then identify the correct statement(s).
(A) Activation energy for the given reaction at 250 Kelvin is 10 Kcal/mol.
(B) Activation energy for the given reaction at 2000 Kelvin is 1.25 Kcal/mol.
(C) Rate of increase of rate constant with temperature is higher at lower temperature range than at higher
temperature range.
dK
(D) The value of at 2000 Kelvin is 0.625 × k.
dT

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 XII-STU-IC-02-06-2025

46. A gaseous substance ‘P’ undergoes reaction through two parallel paths as shown.
k 1, E 1 Q
P
k2 , E R
2

1 2
If rate constant k1 and k2 are min–1 and min–1 and activation energies E1 and E2 are 30 Kcal/mole and 15
3 3
Kcal/mole respectively then identify the correct statement.
[Q]t 1
(A) 
[ R]t 2
(B) Net activation energy for dissociation of P = 20 Kcal mol–1
(C) In 0.693 min ‘P’ will undergo 50% dissociation
(D) Total gaseous moles will remain constant at all instant.
47. Which of the following molecules has one unpaired electron in antibonding orbitals ?
(A) CO (B) NO (C) O2– (D) O2+
48. In which of the following, there exists a resultant dipole moment but is a non–polar solvent ?

(A) ROR (B) 2-Chlorobutane (C) HF (D)

SECTION-III
(Numerical Value Answer Type)
 This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter the answer. If the numerical value has more than two
decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct numerical value is entered;
Zero Marks : 0 In all other cases.
o o
49. In 10 moles of volatile liquid A(PA =70torr) 10 moles of volatile liquid B(PB =98torr) are added then A starts
polymerizing. After 10 min 2 moles of non-volatile solute C are added then polymerization of A stops. Polymer is
completely insoluble in ideal mixture of A and B when polymerization stops. Total vapour pressure of the volatile
liquid mixture is found to be 80 torr. If mole fraction of B in vapour phase when polymerization stops is x then
y
value of x  y is-

50. The K SP (25º C) of a sparingly soluble salt XY2 ( s ) is 3.56 105 (molL1)3 and at 30ºC, the vapour pressure of
its saturated solution in water is 31.78 mm of Hg. If enthalpy change in kJ of the reaction in scientific notation is
X 10 y , then find the value of y.
XY2 (s) X2+ (aq.)+2Y – (aq.)
Given: vapour pressure of pure water = 31.82 mm of Hg

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 XII-STU-IC-02-06-2025
1
51. For an elementary reaction A  B 
 C  D , kinetics is determined by analysis of partial pressure of gases at
5
different instants. Calculate the value of “a + b + c”. c is order of reaction.
P mm of Hg t  0 t  30 min t  60 min
PA 20 10 a
PB 10000 Not applicable Not applicable
PC 0 Not applicable 15
PD 0 b Not applicable

52. Determine i (vant-Hoff factor) for a tribasic acid H3A.

Assuming first dissociation to be 100%,
Second dissociation 50% and
Third dissociation 20%.

53. How many compound which has p-d bonds –

CO32–, ClO4–, SO3, SO42–, P4O10, NO3–, HCN, [I(CN)2]–, PO43–

54. How many number of species are planar and polar with central atom sp3d hybridized?
PCl  
4 , ClF3 , XeF2 , SOF2 , SF4 , [I2CN] , ICl2

*****
If you have any genuine question paper problems please contact the following subject concerned persons.
PAPER SETTER PHYSICS CHEMISTRY MATHEMATICS

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