22-06-2025
2001CJA101021250013 JA
PHYSICS
SECTION-I(i)
1) Two identical galvanometers are converted into voltmeter & ammeter by using two different
resistances R1 & R2. R1 >> G >> R2 where G is resistance of galvanometer. These are connected to
verify ohms law. Choose the correct circuit :-
(A)
(B)
(C)
(D)
2) A block of mass 6kg is placed on a fixed rough horizontal surface and connected by a massless
string as shown in figure. The string passes through a smooth pulley and a constant force of
magnitude 100N is acting on other end of the string. At the given instant acceleration of the block is
(A)
m/s2
(B)
m/s2
(C)
m/s2
(D)
m/s2
3) In a meter bridge circuit as shown, when one more resistance of 100 Ω is connected is parallel
with unknown resistance x, then ratio become 2. If ℓ1 is balance length of the uniform wire AB,
then the value of x must be :
(A) 50 Ω
(B) 100 Ω
(C) 200 Ω
(D) 400 Ω
4) A 115 V, 1 kW electric oven is mistakenly connected to a 230 V power line that has a 15A fuse.
The oven will :
(A) give off less than 1 kW of heat
(B) give off 1 kW of heat
(C) give off more than 1 kW of heat
(D) blow the fuse
SECTION-I(ii)
1)
Consider the circuit shown in the diagram.
(A) Current passing through wire AB is 6 ampere.
(B) Potential difference across two batteries is different.
(C) Potential difference across two batteries is same
(D) Power supplied by both batteries is same
2) A conducting wire has a non uniform cross section as shown in figure. A steady current flows
through it. Which of the following is/are true :
(A) Drift speed of electrons at A is less than at B.
(B) Drift speed of electron at A is more than at B.
(C) Magnitude of electric field at A is less than magnitude of electric field at B.
(D) Electric field is zero at every point, inside of wire.
3) Figure shows the net power dissipated in R versus the current in a simple circuit shown.
(A) The internal resistance of battery is 0.2Ω
(B) The emf of battery is 2V
(C) R at which power is 5W is 2.5 Ω
(D) At I = 2A, power through R is 3.2 W
SECTION-I(iii)
1) In the List-I some arrangement with ideal string & frictionless & light pulley are shown. In string
CD tension may be written as T = ηmg. Then match the List-II with list-I.
List-I List-II
(P) (1) η=1
(Q) (2)
(R) (3)
Acceleration of block A and B will
(S) (4)
be same
Acceleration of block A and B will
(5)
be different.
(A) P → 1;Q → 5;R → 2;S → 4
(B) P → 1;Q → 2;R → 4;S → 3
(C) P → 1;Q → 4;R → 3;S → 4
(D) P → 3;Q → 4;R → 1;S → 4
2) Five batteries whose emf and internal resistance are shown in figure. Match the following.
List - I List - II
(P) Potential of point A (1) – 5V
(Q) Potential of point B (2) 1V
(R) Potential of point C (3) – 3V
(S) Potential of point D (4) 2.5V
(5) 1.5V
(A) P → 3;Q → 4;R → 3;S → 1
(B) P → 2;Q → 4;R → 1;S → 3
(C) P → 3;Q → 1;R → 4;S → 2
(D) P → 2;Q → 3;R → 2;S → 4
3) Match the readings of the voltmeter and ammeter respectively shown in the figures.
List-I List-II
(P) (1) 0V
(Q) (2) 20A
(R) (3) 0A
(S) (4) 20 V
(A) P → 2;Q → 1;R → 3;S → 4
(B) P → 1;Q → 1;R → 3;S → 3
(C) P → 2;Q → 2;R → 4;S → 1
(D) P → 1;Q → 2;R → 3;S → 4
SECTION-II
1) The value of R so that same amount of heat is dissipated in R and rest of the circuit, is (in Ω):-
2) In the circuit shown in figure the switch S is initially open and both the capacitors are initially
uncharged. Find the ratio of current through 2Ω resistor, just after the switch S is closed and a long
time after the switch S is closed.
3)
A closely wounded circular coil of radius 5 cm produces a magnetic field of 37.68 x 10–4 T at its
center. The current through the coil is ______ A.
[Given, number of turns in the coil is 100 and π = 3.14]
4) Two parallel long current carrying wire separated by a distance 2r are shown in the figure. The
ratio of magnetic field at A to the magnetic field produced at C is
5) Man A is sitting in a car moving with a speed of 12 m/s observes a man B in front of the car
crossing perpendicularly a road of width 15 m in three seconds. Then the velocity of man B (in m/s)
will be:
6)
In the following circuit, the current through the resistor R (= 2Ω) is I Amperes. The value of I is
CHEMISTRY
SECTION-I(i)
1) How many different stereoisomers are possible for the given molecule ?
(A) 3
(B) 1
(C) 2
(D) 4
2) The given compound II is respectively isomeric with I, III & IV as
I II
III IV
(A) Tautomer, functional, geometrical
(B) Metamers, tautomer, identical
(C) Functional, tautomer, identical
(D) Functional, tautomers & metamers
3) An aqueous solution has urea and glucose in mass ratio 3 : 1. If the mass ratio of water and
glucose in the solution is 10 : 1, then the mole fraction of glucose in the solution is
(A)
(B)
(C)
(D)
4) Which of the compounds will act as strongest reducing agent?
Compound NH3 PH3 AsH3 SbH3
(A) NH3
(B) PH3
(C) AsH3
(D) SbH3
SECTION-I(ii)
1) In which of the following, given tautomer is present in greater amount than its enol tautomer at
equilibrium.
(A)
(B)
(C)
(D)
2) In which of the following molecule(s) chiral carbon(s) is/are present ?
(A)
(B)
(C)
(D)
3) The pair(s) of coordination complexes/ion exhibiting the same kind of isomerism is/are
(A) [Cr(NH3)5Cl]Cl2 and [Cr(NH3)4Cl2]Cl
+ +
(B) [Co(NH3)4Cl2] and [Pt(NH3)2(H2O)Cl]
2- 2-
(C) [CoBr2Cl2] and [PtBr2Cl2]
(D) [Pt(NH3)3(NO3)]Cl and [Pt(NH3)3Cl]Br
SECTION-I(iii)
1) Match the entries given in List-I with the entries given in List-II.
List-II
List-I
(Total number of
(Compound)
stereoisomers)
(P) (1) 2
(Q) (2) 6
(R) (3) 8
(S) (4) 16
(5) 4
(A) P → 3;Q → 3;R → 4;S → 3
(B) P → 2;Q → 3;R → 1;S → 4
(C) P → 5;Q → 4;R → 3;S → 3
(D) P → 5;Q → 4;R → 3;S → 2
2) Match the complexes with their characteristics.
List-I List-II
2-
(P) [Ni(CN)4] (1) Spin only magnetic moment = BM
(Q) [Fe(CO)5] (2) sp3 hybridized state of central metal
2-
(R) [MnBr4] (3) dsp2 hybridized state of central metal
2+
(S) [Ni(NH3)6] (4) Trigonal bipyramidal complex
(A) P → 3;Q → 4;R → 1;S → 2
(B) P → 3;Q → 4;R → 2;S → 1
(C) P → 1;Q → 4;R → 3;S → 2
(D) P → 2;Q → 4;R → 3;S → 1
3) Match the formulas of oxides given in List-I with the type of oxide given in List-II and mark the
correct option.
List-I List-II
(P) As2O3 (1) Neutral oxide
(Q) N2O (2) Acidic oxide
(R) N2O5 (3) Basic oxide
(S) Bi2O3 (4) Amphoteric oxide
(A) P → 1;Q → 2;R → 3;S → 4
(B) P → 4;Q → 1;R → 2;S → 3
(C) P → 3;Q → 2;R → 4;S → 1
(D) P → 4;Q → 3;R → 1;S → 2
SECTION-II
1) The number of constitutionally different forms of C6H14 is Y. The value of Y is _____.
2) (a) How many Hydrogen atoms are replaced by D in the following tautomerization.
(b) How many total isomers are possible for the formula C2FClBrI.
(c) How many total open chain isomers are possible for C4H8.
(d) How many α-H atom are present in the most stable alkene among following.
Write answer of part (a), (b), (c) & (d) in the same order and
present the four digit numbers as answer in OMR sheet. For example: If all these answers
are 9 then fill 9999 in OMR sheet.
3) Total number of planes of symmetry present in benzene is-
4) The oxidation state of each phosphorous atom present in pyrophosphoric acid (H4P2O7) is :-
5)
Find the total number of complexes are following EAN rule.
(Atomic number : Mo ⇒ 42, Pt ⇒ 78, Ag = 47)
0
[Mo(σ – C3H5)Br(NH3)2], [Fe(η5 – C5H5)2], [Ni(DMG)2] , [Mn2(CO)10], [Fe(CO)2(NO)2] ,
0
[PtCl3(η2 – C2H4)]– , [Ag(CN)2]–1, [Fe2(CO)9]
6) During the oxidation of arsenite ion to arsenate ion in alkaline medium, the number
of moles of hydroxide ions consumed per mole of arsenite ion is
MATHEMATICS
SECTION-I(i)
1) , given that f'(2) = 6 and f'(1) = 4
(A) Does not exist
(B) Is equal to –3/2
(C) Is equal to 3/2
(D) Is equal to 3
2) If A and B are square matrices of same order and AB = A, BA = B, then (A + I)5 is equal to (where
I is unit matrix)
(A) I + 5A
(B) I + 60A
(C) I + 16A
(D) I + 31A
3) If the function ƒ(x) = 2 – e–x and g(x) = ƒ–1(x) then the value of g"(1) is equal to -
(A) –1
(B) 0
(C) 1
(D)
4) is equal to -
(A) 1
(B) 2
(C) 3
(D) 4
SECTION-I(ii)
1) If g is inverse of ƒ and ƒ (x) = x2 + 3x – 3 (x > 0) then g'(1) equals-
(A)
(B) –1
(C)
(D)
2)
Let f: ℝ ℝ, g: ℝ ℝ and h: ℝ ℝ be differentiable functions such that ,
and for all ℝ. Then
(A)
(B)
(C)
(D)
3) Let , where . Suppose is a matrix such that PQ = kI, where
, and I is the identity matrix of order 3. If and , then
(A)
(B)
(C) det(P adj(Q)) = 29
(D) det(Q adj(P)) = 213
SECTION-I(iii)
1) Given ƒ(x) =
and ƒ(x) = ℓ. If ƒ(x) is continuous at x = 0, then
Match List-I with List-II and select the correct answer using the code given below the list.
List-I List-II
(P) a is equal to (1) 4
(Q) b is equal to (2) 0
(R) (b – ℓ) is equal to (3) 2
(S) (4) 1
is equal to
(5) 3
(A) P → 1;Q → 5;R → 4;S → 2
(B) P → 2;Q → 1;R → 4;S → 3
(C) P → 2;Q → 1;R → 3;S → 4
(D) P → 1;Q → 2;R → 3;S → 5
2) Match List-I with List-II and select the correct answer :
List-I List-II
(P) If x = (1 – cot31°)(1 – cot14°), x ∈ R, then value of x is (1) 2
(Q) The least value of 3sec2x + 12cosec2x is (2) 27
(R) (3) 0
The value of equals to
Let M and m be the greatest and least values of sin2θ –
(S) (4) 1
2cosθ + 1, then equals to
(5) 3
(A) P → 5;Q → 4;R → 2;S → 1
(B) P → 4;Q → 1;R → 2;S → 5
(C) P → 1;Q → 2;R → 4;S → 4
(D) P → 1;Q → 2;R → 4;S → 3
3) Three functions, f1, f2 and f3 are given as f1(x) = sin–1 f2(x) = x – cos–1
[Note: {k} denotes fractional part function of k.]
List-I List-II
the differential coefficient of f1(x) with respect to
(P) (1) –1
f2(x) at x = tan 1, is
(Q) (2) 2
is equal to
(R) is equal to (3) 1 + sec 2
The slope of the normal to the curve y = f3(x) at x
(S) (4) tan 1
= is equal to
(5) 0
(A) P → 3;Q → 1;R → 4;S → 2
(B) P → 3;Q → 5;R → 1;S → 2
(C) P → 4;Q → 5;R → 1;S → 2
(D) P → 5;Q → 4;R → 2;S → 1
SECTION-II
1) If is differentiable function such that its left hand
derivative at x = 0 is 1,
then a + b is equal to
2) Evaluate :
3) Let f (x) = + + + .......... ∞ for x ∈ (0, 2), then is equal to
4) Let and f(x) = x3 – 2x2 – ax + b = 0.
If f(x) = 0 is the characteristic equation of matrix A then the value of a + b + 6c is
5) Number of integral values of k for which the equation (3sinx + 4cosx + 4)2 = 9k2 has a solution, is
6) is equal to
ANSWER KEYS
PHYSICS
SECTION-I(i)
Q. 1 2 3 4
A. D A B D
SECTION-I(ii)
Q. 5 6 7
A. A,B B A,B,D
SECTION-I(iii)
Q. 8 9 10
A. A C B
SECTION-II
Q. 11 12 13 14 15 16
A. 4.00 3.00 3.00 5.00 13.00 1.00
CHEMISTRY
SECTION-I(i)
Q. 17 18 19 20
A. D C A D
SECTION-I(ii)
Q. 21 22 23
A. B,C A,D B,D
SECTION-I(iii)
Q. 24 25 26
A. D B B
SECTION-II
Q. 27 28 29 30 31 32
A. 5.00 6647.00 7.00 5.00 4.00 2.00
MATHEMATICS
SECTION-I(i)
Q. 33 34 35 36
A. D D C D
SECTION-I(ii)
Q. 37 38 39
A. A,C B,C B,C
SECTION-I(iii)
Q. 40 41 42
A. C C A
SECTION-II
Q. 43 44 45 46 47 48
A. 1.00 2.00 0.33 to 0.34 30.00 7.00 1.33
SOLUTIONS
PHYSICS
1)
Circuit diagram to verIfy ohm's law is
2)
N=0
f=0
80 = 6·a
2
m/s
3)
100 + x = 2x
x = 100Ω
4)
115 v, 1 kW oven (uses heating due to current and Resistance)
When connected with 230 V,
Oven use power
Now P = (ΔV)I
⇒ 4000W = (230V)I
⇒ I = 17.4A
But Ifuse = 15A (Max.)
∴ Fuse will blow
5)
VA – VB = 0
i1 = 2A
i2 = 4A
∴ iAB = i1 + i2 (A) correct
= 6A
ΔVP = 6v – 2i1 = 2V (B) correct
ΔVQ = 4v – 1i2 = 0V.
Power of cell = (ΔV)i
PP = (2v) × (2A) = 4W
PQ = (0v) × (4A) = 0W
(C) Incorrect
(D) Incorrect.
6) Since AA < AB
∴ vA > vB
7) Power is maximum when r = R
⇒ Pmax = I2 × (r) Pmax = 5W
⇒ r= = 0.2 Ω
8) (P) 2mg – T = m [g]
T = mg
(Q)
(R)
(S)
9)
KVL in single loop
4V + 6V + 2V + 3V – 5V =
i(4 + 6 + 2 + 3 + 5)Ω
10) In each case there will be no current in the branch containing voltmeter or ammeter.
Therefore reading instruments will be zero.
11)
Rest of Circuit For same power, R = Ω
12) Just after switch is closed, as both capacitors are uncharged, we have current flow as
Longtime after switch is closed, both capacitor reach their steady state condition. Now the
current flow is
ratio =
13)
I = 3A
14)
∴x=5
15)
Velocity of A and velocity of B relative to A are as shown.
∴
⇒ V0 =
and direction of is away from
16)
= 1A
CHEMISTRY
17)
It has 4 stereoisomers
18) (C) Functional, tautomer, identical
19)
Mole fraction glucose =
20)
Low BDE means stronger reducing agent
21) Enol of is aromatic.
22)
(AD)
(a)
(b)
(c)
(d)
23)
(B) [Co(NH3)4Cl2]+ and [Pt(NH3)2(H2O)Cl]+ → Geometrical isomerism
(D) [Pt(NH3)3(NO3)]Cl and [Pt(NH3)3Cl]Br → Ionisation isomerism
24) Question is Asking About:
Match the entries given in List-I with the entries given in List-II.
Concept:
If molecule is unsymmetrical then
Total no. of stereoisomer = 2n
where 'n' is number of chiral center.
If molecule is symmetrical then
Total no. of stereoisomer = 2n–1
Solution/Explanation/Calculation:
(P)
n=2
Total no. of stereoisomer = 2n
= 22
=4
(Q)
n=4
stereoisomer = 2n
= 24
= 16
(R)
n=3
stereoisomers = 2n
= 23
=8
(S)
n=3
→ Draw the combination
(1) R E R
(2) R Z R
(3) R E S
(4) R Z S
(5) S E S
(6) S Z S
Total = 6
Hence, option (4) is correct.
25)
[Ni(CN)4]2- → dsp2 and diamagnetic
[Fe(CO)5] → T.B.P
[MnBr4]2- → SP3 tetrahedral
[Ni(NH3)6]2+ → Octahedral paramagnetic with two unpaired electron
26)
As2O3 → Amphoteric oxide
N2O → Neutral oxide
N2O5 → Acidic oxide
Bi2O3 → Basic oxide
27) C6H14 has 5 forms
CH3–CH2–CH2–CH2–CH3–CH3 → 1
→2
→3
→4
→5
28)
(a) 6 hydrogen atoms will be replaced
(b) total 6 isomers are possible
(c) 4 chain isomers are possible
(d) 7 α-h is there
29)
Concept :- Benzene in planar molecule.
30)
4 + 2x - 14 = 0
x=5
31)
EAN = Valence e– – oxidation state + 2 × lone pair from ligand.
32)
MATHEMATICS
33) Here,
[∵ f'(2) = 6 and f'(1) = 4, given]
ApplyingL' Hospital's rule,
= [using f'(2) = 6 and f'(1) = 4]
34) AB = A, BA = B A(BA) = A2
AB = A2 ⇒ A2 = A ⇒ A3 = A ⇒ A4 = A
⇒ A5 = A .....
(A + I)5 = 5C0A5 + 5C1A4I + 5C2A3I + 5C3A2I + 5C4AI + 5C5I
= I + 31A
35) y = 2 – e–x ⇒ e–x = 2 – y
⇒ –x = ℓn(2 – y)
⇒ g(x) = –ℓn(2 – x)
⇒
⇒ g''(1) = 1
36) use the result sin2A + sin2B + sin2C = 4sinAsinBsinC
where A + B + C = π
37) f(g(x)) = x
f′(g(x)) . g′(x) = 1
f(x) = x2 + 3x – 3
f′(x) = 2x + 3
f′(g(x)) = 2g(x) + 3
f′(g(1)) = 2g(1) + 3
g′(1)
g(1) = g(1) = 1
g′(1)
38)
h(g(g(x))) = x
h(g(x)) = f(x)
h(g(3)) = f(3) = 27 + 9 + 2 = 38
h(g(2)) = f(2)
h(0) = 8 + 6 + 2 = 16
= 111 × 6 = 666
39) det (P). det(Q) = k3
det (P) = 2k ; det (Q) =
(–3α + 20) + 15 α = 2k
k = 10 + 6α
Q = k . (P–1)
Q=
q23 =
4(3α + 4) = k = 10 + 6α
α = –1, k = 4
40)
∴ ƒ(x) is continuous at x = 0
⇒ a = 0, b = 4 & ℓ = 2
41) (P) 31° + 14° = 45° cot(31° + 14°) = 1
⇒ cot31° + cot14° – cot31°cot14° + 1 = 0
(Q) = 3tan2x + 12cot2x + 15
Min value = = 27
(R)
(S) 2 – 2cosθ – cos2θ
= –[(cosθ + 1)2 – 3]
42)
(A)
(B)
(C)
(D)
Slope of the normal = 2.
43) ∵ ƒ (x) is continuous at x = 0
⇒ ⇒a=0
Now ∵ ƒ (x) is differentiable and its left hand derivative is 1
∴
⇒b=1
44)
Apply L'Hospital rule
b=2
45) f (x) =
= =
f ' (x) = ⇒
46) f(x) = 0 is the characteristic equation
⇒ |A – xI| = 0 ⇒ a = 14, b = 22, c = –1
Alternative : sum of roots = sum of diagonal elements and product of roots = value of the
determinant.
47) –5 ≤ 3 sinx + 4cosx ≤ 5
⇒ –1 ≤ 3sinx + 4cosx + 4 ≤ 9
⇒ 0 ≤ (3sinx + 4cosx + 4)2 ≤ 81
0 ≤ 9k2 ≤ 81
0 ≤ k2 ≤ 9
k = ±3,±2,±1,0
48) Using
sum = 20sin9°
