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CHEM63S25S008

The document outlines various chemical reactions involving sulphites, carbonates, nitrites, and sulfides, detailing their interactions with dilute sulfuric acid and other reagents. It describes the formation of products such as SO2, CaCO3, and color changes indicating the presence of specific ions. Additionally, it includes methods for detecting nitrites and sulfides in mixtures using specific reagents and tests.

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6 views2 pages

CHEM63S25S008

The document outlines various chemical reactions involving sulphites, carbonates, nitrites, and sulfides, detailing their interactions with dilute sulfuric acid and other reagents. It describes the formation of products such as SO2, CaCO3, and color changes indicating the presence of specific ions. Additionally, it includes methods for detecting nitrites and sulfides in mixtures using specific reagents and tests.

Uploaded by

aslamsaira437
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Name: Tafshala Ashraf

Roll No: CHEM63S25S008

NOTES/EXPLANATIONS:
Sulphites reacts with dil.H2SO4 to give SO2 which reacts with K₂Cr₂O7
and
solution becomes green due to formation of Cr₂(SO₄) 3 .
Na₂SO3+H₂SO₄→Na₂SO₄+H₂O+SO₂
K2Cr₂O7+SO₂ →K₂SO₄+Cr₂(SO₄)3+H₂O
CO2 react with lime water,Ca(OH)2 to form insoluble white ppt.CaCO3.
Na₂CO3+H₂SO₄→Na₂SO₄+H₂O+CO₂
CO₂+Ca(OH)₂→CaCO₃+H₂O
8.CO3² in the presence of C₂O42-
-

Carbonates react with dil.H2SO4 to yield CO2 which turns lime water
milky.
Heat the solution to decompose the carbonate completely.Add few
drops of KMnO4 to this warm solution.Decolourization of
KMnO4 indicates the presence Mixture+dil.H,SO.
of oxalates.
→warm Flow sheet
A

Copy of m
ID card e
d
i
c
Warm solution after the a
Effervescence in cold,CO2 evolves effervescence stops. Add few
on heating:CO32- l
drops of KMnO4:colour of KMnO4
c
discharged:C2O42-
e
r
t
i
9. NO₂- in the presence of NO₃- f
Nitrite can be detected in the presence of nitrate by usual tests like i
Ring test but nitrate cannot be c
detected in the presence of nitrite. a
Therefore nitrite is decomposed by adding sulphamic acid to the t
acidified
solution of the mixture before performing tests for nitrate.
HNO3+HO.SO₂NH₂→N₂+H₂SO₄+H2O

10.S²- in the presence of SO32-


Dissolve the mixture in water or prepare Na2CO3-extract and
neutralize it with dil.H2SO4
Divide this solution into two portions. To one portion add few drops
of sodium nitroprusside solution.
A violet red colouration indicates the presence of S² -.To the second
portion add dil .HCl,solid CdCO3,shake vigorously and
filter,yellow ppt.indicate S²-.Acidify the filtrate with add dil.HCl and
add BaCl₂ and bromine water.A white
Ppt.shows the presence of SO32-
Flow sheet
Aq.Solution or neutral sodium extract+dil.H₂SO4
Divide into two portions

Solution S2- and SO₃2-.Add alkaline


solution of sodium Solution:S²-&SO3²-.Add
nitropruside solution →A violet dil.HCl+
red colouration:S²- CdCl₂(s)→Shake and filter

Filtrate:Add dil.HCl and


Yellow ppt:S²- BaCl₂→white ppt.
So3²-

NOTES/EXPLANATIONS:
Sulphide gives violet red colouration with sodium nitroprusside
solution.
NaS+Na2[Fe(CN)5NO]→Na4[Fe(CN)5NOS]
Acidified solution of sulphide gives white ppt.when treated with solid
CdCO3
CdCO3+2HCl→CdCl₂+H₂O+CO₂
CdCl₂+Na2S→CdS +2NaCl

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