Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Jr.Super60(incoming)_NUCLEUS BT JEE-ADV-2024_P1 Date: 11-05-2025
Time: 02.00Pm to 05.00Pm WTA-05 Max. Marks: 180

KEY SHEET
MATHEMATICS
1 B 2 A 3 C 4 A 5 ABC 6 C

7 AD 8 18 9 30 10 22 11 117 12 1

13 2 14 A 15 B 16 A 17 D

PHYSICS

18 D 19 A 20 C 21 A 22 ABD 23 BC

24 AC 25 10 26 4 27 6 28 4 29 7

30 4 31 B 32 A 33 D 34 D

CHEMISTRY
35 A 36 A 37 C 38 B 39 ABD 40 AD

41 BD 42 80 43 29 44 24 45 4 46 128

47 76 48 A 49 D 50 B 51 C
 Sri Chaitanya IIT Academy 11-05-2025_Jr.Super60(incoming)_NUCLEUS BT_Jee-Adv(2024-P1)_WTA-05_Key & Sol’s

SOLUTIONS
MATHEMATICS
1. x 2  x 1  0
S n  2023α n  2024β n
S n1  S n2  2023α n1  2024β n1  2023α n2  2024β n2
 2023α n2 1  α   2024β n2 1  β 
 2023α n2 α 2   2024β n2 β 2 
 2023α n  2024β n
S n1  S n2  S n
Put n  12
S11  S10  S12
4 1 6 1
2.     ; r  :     :   
t1 t1 t2 t2
2 2 
 ,  ,  ,  arein HP    ; 
   
1 1
   
2 3
 is a root of t2 x 2  6 x  1  0  t2  8
 r is aroot of t1 x 2  4 x  1  0  t1  3
2b  a  c & 2 ac  b 2  bc  a 2  4ac  3c 2  0
3.
 a  c or a  3c
4. One root is zero
Also 4a2 - 24b > 0  a2 > 6b
 a  3, b  1 and for a = 3, b = 1, f(x) = 0
has 3 distinct real roots.
5. 5. If roots of the equation be  ,  ,  then

 2   2   2         2        a 2  2b
2

 2  2   2 2   2 2         2      
2

 b 2  2a
    1.
2 2 2

So, the equation whose roots are  2 ,  2 ,  2 is

x 3   a 2  2b  x 2   b 2  2 a  x  1  0
It is identical to x3  ax 2  bx  1  0
 a 2  2b  a and b 2  2a  b, eliminating b, we get
a  a
2 2
a2  a
 2a 
4 2
 
a a  a  1  8  2  a  1  0
2

 a  a 3  2a 2  a  6   0
or a  a  3  a 2  a  2   0
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 a  0 or a  3 or a 2  a  2  0
Which give b  0 or b  3 or b 2  b  2  0
So, a  b  0 or a  b  3
Or a, b are roots of x 2  x  2  0
6. Given equation can be written as
xa b x b a
   0
b xa a x b
( x  a ) 2  b 2 ( x  b) 2  a 2
  0
b( x  a ) a ( x  b)
x a b xb a
 ( x  a  b)   0
 b( x  a ) a ( x  b) 
 a  x 2  bx  ax  ab  bx  b2   b  x 2  ax  bx  ab  ax  a 2  
  x  a  b      0

 ab  x  a  x  b  
  x  a  b   ax  a x  a b  ab  bx  b x  ab  a b 
2 2 2 2 2 2 2 2

 x ( x  a  b){x ( a  b )  ( a 2  b 2 )}  0
a 2  b2
 roots will be x=0, a  b,
ab
2 2
a b
Let x1  a  b , x 2  and x3  0
ab
 x1  x2  x3  c (given)
a 2  b2
 ( a  b)  0  c
ab
(a  b) 2  (a 2  b 2 ) 2ab
 c c
a b a b
i.e a, c, b are in H. P
7. We have    =  p,   q , 4   4  r and  4  4  s
Therefore,  2   2  (   )2  2  p 2  2 q, so that

r   4   4  ( 2   2 )2  2 2  2  ( p 2  2 q ) 2  2q 2
i.e., ( p 2 ) 2  4 q ( p 2 )  2 q 2  r  0
This shows that p 2 is one root of x 2  4qx  2q 2  r  0 . If its other root is  , we have
  p 2  4 q , i.e.,   4q  p 2 . Further the discriminant of this quadratic equation is

 4q 2  4  2q 2  r   8q 2  4 ( p 2  2q )2  2q 2   4( p 2  2q) 2  0
So that both roots, p 2
and  p 2  4 q are real. Since  and  are real p 2  4q  0 , i.e.,  p 2  4q  0 . Thus the roots of
x 2  4 qx  2 q 2  r  0 are positive and negative.

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4a  7  49a 11  0

2
8.
a  3,20
Number of integers = 18
9. The required equation x 2  6 x  36  0
p  q  30
10. α  1β  1 γ  1  33  S1  S2  S3  32  S2  S3  26
α 3  β 3  γ 3  87  S13  3S1S 2  3S3  87
 a 3  b3  c3  a  b  c3  3a  bb  cc  a 
 
69 113 182
 S 2  ,S3  ab  26
 6 S 2  S3  43. 7 7 7
c a  b
11. Roots 1,
a b  c 
For equal roots 2ac  b a  c 
 ac  54
Then a 2  c 2  117
12.  x 2  5 x  4 x 2  5 x  6  120
Real roots of 6,1
Maximum real root is 1
1
13. Put t
x
t 2  5t  6t 2  7t  12  0
1 1 1 1
2  3, x x
x x 4 9
Number of solutions = 2
α β
α ,β roots    1  m  4  18  m  4  3 2  least  4  3 2  a  4
2

14. A) β α
1
B) x1  2 ,x2  ,k  16  k  5  11
8
C) Roots x  2 , 3 sum of squares = 5
α  β 3  k  300  k  300  sum  3
D)
15. A) x  2 is the only solution x  2  0 ,5
B) x  8,1 maximum root 8

C) Number of solution  K  2 (Reciprocal equation)

 K  4  5  4 ,10
5  41
D) Largest root =  2α  5  41  11.4  9,12
2
16. (A) Δ  0
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 Number of real roots 0
3
(B) Roots are 1,
2
Number of integral roots 1
(C) Sum of squares of roots = 1
(D) 4 x 2  5 x  5  6 x  5
x 4 x 1  0
1
x  , x  0
4
64  4    2    4   0
17. A)
    6    4   0
  6 or   4
 The least positive integral value of  is 5
(B) Roots are of opposite signs
 a 2  14a  48  0
 a  6  a  8   0
, so a can be 7
2
The equation is x  100 x  1  0
2
 discriminant = D = 100  4  0
Roots are real
f  x   ax 2  2bx  4c  16
C) Let
f  2   4a  4b  4c  16
Clearly
 4  a  b  c  4  0
 f  x   0, x  R

 f  0   0  4c  16  0
 c4
 x2  x  6  x  2
(D)
  x  3 x  2   x  2
 x 3 x  2  x  2
  x  3 x  2   x  2, x  2

  x  3 x  2   x  2, 2  x  3
  x  3 x  2   x  2, x3
 
 x  4, x  2

 x  2, 2 2  x  3
 x  4, x3
  Hence, x  2, 2, 4 N =3

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PHYSICS
18.

Let t be the time taken by bomb to hit the target.

1
h  2000  gt 2  t  20 sec
2
R  ut  100 20  2000 m
R 2000
 tan θ    1  θ  45
h 2000
8x2
19. y 2
2u
9.830
2

 20 12 
2u 2
9.8900
 u2 
8
 u  23.5 ms1
Hence, the correct answer is (A).
20. VP cos α  u cos θ
u cos θ  VP cos α u cos θ sin α
t   u cos θ 
g cos α
u sin θ  α

g cos α
21.

2 2 u2
For maximum range  R h 
g 1  sin  

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2 2 u2
R h h
g
u 2
R u  2 gh
g
22.

y0
1
0  u sin βt  g cos αt 2
2
2u sin β
t
g cos α
Vx  u x  axt
Vx  u cos β  g sin αt
 2u sin β 
Vx  u cos β  g sin α  
 g cos α 
 sin α sin β 
 u cos β  
 cos α 
 cos α  β
Vx  u  
 cos α 
Vy  u sin β  g cos αt
 2u sin β 
 u sin β  g cos α  
 g cos α 
Vy  u sin β
Vy sin β cos α
tan θ  
Vx cos α  β
θ is independent of u but depent on α and β.
Vx is always along + ve x before striking.
23. At the instant shown, we have

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u
u cos θ  u cos 60 
2
u
 υ
2 cos θ
The radius of curvature is given by
υ2 u2
R 
g cos θ 4 g cos 3 θ
u2
 Rmin  ,when θ  0
4g
8
Since R  Rmin
3 3
u2 8  u 2 
   
4 g cos 3 θ 3 3  4 g 
3 3  3 
3

 cos 3 θ   
8  2 
3
 cos θ 
2
 θ  30
So, from equation (1), we get
u
υ
3
dv ds bt 2
24.  ax  bt   v 
dt dt 2
3
bt
d s
6
 6d 
1/ 3

t   
 b 
s  v0t0
2
b  6d 3 2h
s   
2  b  g
2h 2  0.8
25. t   0.4 s
g 10

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120  30  10103
uMIN   0.25 ms 1
0.4
120  30 10103
and uMAX   0.35 ms1
0.4
 uMIN  25 ms and u MAX  35 ms1
1

26.

Time to reach from A to C is 1.5 s and u  12 m / s

i.e. a y  8 m / s
2

Therefore ax  6 m / s 2
3
Velocity after 1.5 s is  vx  18  6   9 m / s,v y  0
2
Velocity at B (time taken  3s ) vx  0 ,v y  12 m / s
27. Let after time t they turn back at C and D respectively.
d  200m.x   4  1.5  t
x  200   6  1.5  t
t  100s, x  250m
After turning, both boats take another 100s to meet the buoy. So in total 200s, the
distance moved by buoy u  200  1.5  200  300m
28. v1 cos αt  v2 cos β  30 3 ........1
1 1
v1 sin αt  gt 2  h  v2 sin βt  gt 2 ..........2
2 2
From (1) and (2)
h  60 m

29. RH 
 u cos 60 
2
 10m
g
2
v 400
av    40m / s 2
R 10
aH  a 2  av2  30m / s 2
30.
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  1 
s  uT  gT 2
2
1
d cos   gT 2 cot 
2 gT 2
cot    cot   cot 
d sin  2d sin 
 2cot   cot   2


4
31. Let us choose the x and y directions along OB and OA respectively. Then
u x  u  10 3 ms1 ,u y  0
ax  g sin 60  5 3 ms2 and a y  g cos 60  5 ms 2
At point Q, x-component of velocity is zero. Hence, substituting in
u x  u x  axt
 0  10 3  5 3 t
10 3
t   2s
5 3
So, A  q
At point Q,u  u y  u y  a y t
 u  0  52  10 ms1
Here, negative sign implies that velocity of particle at Q is along negative y direction,
So, u  10 ms1 , along y-direction.
Hence B  s
Displacement of particle
Dis tan ce PO   sy
along y  direction
1 1
Since, s y  u y t  a y t 2  0  52  10 m
2

2 2
 PO  10 m
1
Since, h  PO sin 30  10 
 2 
 h  5m

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So, C  p
Displacement of particle
Dis tan ceOQ   sx
along x  direction
1
Since, sx  u xt  axt 2
2
  1
 sx  10 3 2  5 3 2  10 3 m
2
2
 
 OQ  10 3 m
Since, OQ   PO   OQ 
2 2

PQ  10  10 3  
2
  400  20 m
2

32. Since range is same for complimentary angles, so

R1  R2
R
 1 1
R2
H1 u sin 30 1
2 2

 2 2 
H 2 u sin 60 3
T2 u sin 60
  3
T1 u sin 30
T1 H1 R1 TH 1 1  1
 1 1    
T2 H 2 R2 T2 H 2 3  3  3 3
33. For (A) : v'y  v y
2v y
For (B) : t AC 
g cos θ
vy
For (C) : At B, v y  0 so 0  v y   g cos θt AB  t AB 
g cos θ
vy
t BC  t AC  t AB 
g cos θ
1 2u x v y cos θ  v y2 sin θ
For (D) : x  u x t AB g sin θ t AB  
2

2 2 g cos 2 θ
1 1
x'  v'xtBC  g sin θ t BC   u x   g sin θ t AB  t BC  g sin θ t BC 
2 2

2 2
1 3
 u xt AB  g sin θt AB  g sin θt AB  u xt AB  g sin θ t AB 
2 2 2

2 2
 v y  3  v y  2u x v y cos θ  3v y2 sin θ
2

  x
 ux    g sin θ     x'  x   1
 g cos θ  2  g cos θ  2 g cos θ2
x'

34. 
u  u cos 45i  sin 45j 
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 Sri Chaitanya IIT Academy 11-05-2025_Jr.Super60(incoming)_NUCLEUS BT_Jee-Adv(2024-P1)_WTA-05_Key & Sol’s
 
 u  20i  20j ms1 and a  10j
  1
Since r  ut  at 2
2

 1

 r  20i  20j t  10j t 2
2
 

 r  20t i  20  5t j

So, at t  1 s, we get

r  20i  15j
 Average velocity at t  1 s is

 r
u av   20i  15j
t

 u av  400  225  25 ms1
  
Further  υ  u  at

 
 υ  20i  15j  10j t

 υ  20i  15j  20 10t j
  
 Δ υ  υ  u  10t j

 Δ υ  20j at t  2 s
So, average acceleration at t  1 s,2s,3s and 4s

 Δυ
 a av   10j {as expected}
Δt
Radius of curvature at t  0 is
u2
r
 g cos θ
20 2 
2

 r  80 2 m
 10 
 
 2 
Radius of curvature at t  1 s is
υ2
r
g cos β
Where υ is the velocity at t  1 s and β is the angle which υat t  1s  makes with the x-
axis
10
Since υ  20i  10j, so tan β 
20

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20 20 2
 cos β   
20 2  102 10 5 5

 
2
202  102
So,  r 
 2 
10 
 5 
500 5
 r
20
 r  25 5 m
Radius of curvature at t  2 s is
u cos θ
2

r
g
  1 
 
2

 20 2  
  2  20
2

 r    40 m
10 10
CHEMISTRY
35. The percent of CaCO3 by mass in the limestone;
0.44
100
44 100  50%
2
36. In the given reaction we have;
CaBr2 , NaI
Mass = 2W , 9W
2W 9W
Moles = ,
200 150
2W 9W
 2 188   235  1786
200 150
 W  100
37.
N 2  3H 2  2 NH 3
5 12 
 LR  8
In this reaction,

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 Sri Chaitanya IIT Academy 11-05-2025_Jr.Super60(incoming)_NUCLEUS BT_Jee-Adv(2024-P1)_WTA-05_Key & Sol’s
 2
Molecules of NH 3 can be formed  12  8
 3 
38. Molecular weight,
1
M .W   3.14
0.00318
Only C21 H 30O2 satisfies the criteria.
39. The reaction takes place as,
1
CO  O2  CO2
2
V 30 100  V
V  60  60  100  V
V  60  10
 V  70 ml
VCO  30 ml
2

VCO absorbed  160  70  90 ml

2

Thus, the correct options are

The volume of CO that reacts is 60 mL.
The volume of CO that remains unreacted is 10mL.
The volume of CO2 that gets absorbed by aqueous KOH is 90 mL
40.
A  N  I
B  L
a a a
2 2 2
a  a
4 2
1 1
A  N  II
 B  C  L
2 2
a a a a
2 4 4 2
a a
2 2
117.6 1
 83.33   1
100 98
16 2 M B M B
41.  
3 3 MA MA
3/2
MB
8
MA
MB 4

MA 1
Thus, The ratio of their moles present in side the container is 8 :3.
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 Sri Chaitanya IIT Academy 11-05-2025_Jr.Super60(incoming)_NUCLEUS BT_Jee-Adv(2024-P1)_WTA-05_Key & Sol’s
6 1 56
42. The percentage of iron in the alloy is,    2   100  80
2 3 140
12
43. All Mg converts into Mg  OH 2   24  17  2  29g
24
When the products are treated with water, 1. 7 gm gaseous ammonia is generated, 29 gm
mass (in gm) of Mg  OH 2 formed simultaneously.
44. Since, 3 atoms of the metal combine with 2 atoms of nitrogen.
So, M formula n 3 N 2 m 2  N 3
14
At M mass = 14 g eq. of mass = g
3
28g N combine with = 72g metre
72
1g N combine with = g metal
28
14 72 14
gN combine with = 
3 28 3
Eq. mass of metal = 12g
At mass = eq. mass × valency
 12  2  24g
Atomic mass = 24g
45. The number of tube,
5 4
n 
10  5   16  n4
300 300
46. The molecular weight can be given as,
 2000  1500 
40 M
  M  128
 2000  1500  32
80
47. Form the given information, pressure (P) is calculated below;
800  2V  680  V
P  P  760 mm
3V
48. Conceptual
49. Conceptual
50. Conceptual
 d  PV  
51. Boyle’s law: PV  K  
dP  K P
   2   and   0
 dV T V V  dP  T
V  dV  V
Charle’s law:  K   K
T  dT  P T
V RT  dV  RT
Avogadro’s law: K   
n P  dn  P ,T P

Graham’s law: r   
dP  1

 dt  d

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