QI. For two statements are given-one labelled Assertion (A) and the other labelled Reason (R).

). Select the correct answer to these 1

questions from the codes (a), (b), (c) and (d) as given below. Mark
Assertion: Significant figures for 0.200 is 3 whereas for 200 it is 1
Reason: Zero at the end or right of a number are significant provided they are not on the right side of the decimal point.
A Both A and R are true and R is the correct explanation of A. B Both A and R are true but R is not the correct explanation of
A.
C A is true but R is false. D A is false and R is also false.
Q2. For two statements are given-one labelled Assertion (A) and the other labelled Reason (R). Select the correct answer to these 1
questions from the codes (a), (b), (c) and (d) as given below. Mark
Assertion: One mole of S02 contains equal the number of molecules present in one mole of 02.
Reason: Molecular weight of S02 is half to that of 02.
A Both A and R are true and R is the correct explanation of A. B Both A and R are true but R is not the correct explanation
of A.
C A is true but R is false. D Ais false and R is also false.
Q3. Which of the following conclusions could not be derived from Rutherford's a-particle scattering experiement?
Mark
B The radius of the atom
A Most of the space in the atom is empty.
nucleus is 10 15 m.
C Electrons move in a circular path of fixed energy called D Electrons and the nucleus ar held together by
orbits. electrostatic forces of attraction.
Q4. Which of the following statement is not correct about the characteristics of cathode rays?

A They start from the cathode and move towards the anode. B They travel in straight line in the
absence of an external electrical or
magnetic field.
C Characteristics of cathode rays do not depend upon the D haracteristics of cathode rays depend upon
the nature of material of electrodes in cathode ray tube. as present in the cathode ray tube.
Q5. If the concentration of glucose (C6H1206) in blood is 0.9g El, what will be the molarity of glucose in blood? 1
A 5M B 50M C 0.005M D 0.5M Mark
Q6. A measured temperature on Fahrenheit scale is 200 0 F. What will this reading be on Celsius scale? A 1
400 C B 940 C c 93.3 0 C D 300 C Mark
Q7. The atomic number at which filling of a g-orbital is likely to begin is: 1
A 121 B 116 c 106 D 124 Mark
Q8. The only series of lines appear in the visible region of the electromagnetic spectrum of hydrogen is: 1
Mark
A Lyman series. B Balmer series. C Paschen series. D Pfund series.
Q9. Which of the following pairs of d-orbitals have electron density along the axis? 1
A dz2dxz xe yz Mark
C d z 2 dx2 y2 D dz2dxz

QIO. For two statements are given-one labelled Assertion (A) and the other labelled Reason (R). Select the correct answer to these 1
questions from the codes (a), (b), (c) and (d) as given below. Mark
Assertion: Magnetic quantum number can have the value ml = -l,
Reason: Magnetic quantum number specifies the shape or orbitals.
A Both A and R are true and R is the correct explanation of A. B Both A and R are true but R is not the correct explanation
of A.
C A is true but R is false. D A is false and R is also false.
QII. For two statements are given-one labelled Assertion (A) and the other labelled Reason (R). Select the correct answer to these 1
Q13. If EA, EB and Ec represent kinetic energies of an electron, alpha particle and proton respectively and each moving with same de- 1
Broglie wavelength, then choose the correct increasing representation, Mark

AE=E
Q14. Probability of finding an electron at a point within an atom is: 1
A Equal to the at that point. B Proportional to the at that point. Mark
2
C Inversely proportional to the IQ/J'1 at that point. D None of the above.
Q15. Which of the following options does not represent ground state electronic configuration of an atom? 1
A 1s2 2s2 2p 6 3s2 3p 6 3d 8 4s 2 B 1s 2 2p6 3s 2 3p6 3d 9 4s 2
Mark
2 2 6 2 6 10 1
C 1s 2s 2p 3s 3p 3d 4s D 1s 2 2s2 2p6 3s2 3p 6 3d 5 4s 1
Q16. The atomic number of an element is 32 and mass number 55. Calculate the number of neutrons? 1
A 23 B 32 c 21 D 25 Mark
Q17. The ionisation enthalpy of hydrogen atom is 1.312 x 106J mol -I . The energy required to excite the electron in the atoms from n 1
= Mark
1 to = 2 is:

A 6.56 x 105J mol-1 B 9.84 x 105J mol 1 C 7.56 x 105] mol 1 D 8.51 x 105J mol 1
Mark
questions from the codes (a), (b), (c) and (d) as given below:
Assertion: Electrons revolve in discrete orbits around the nucleus. h
Reason: Bohr postulated that only those orbits are permitted in which angular momentum is an integral multiple of

c
dnm)

Q19.
Q18. The
Howenergy of a hydrogen
many electrons can fitatom in orbital
in the the ground state is Mark
for which:1 13.6 eV.
n =The energy
3 and 1 = 1?of He + ion in the first 1
excited state will be: Mark
A 10 B 14
A -13.6 ev B -27.2 ev C -54.4
34
h = 6.63 x 10 Js):
Q20. Calculate the wavelength (in nanometer) associated with a proton moving at 1.0 x 103 ms-l (Mass of proton = 1.67 x 10 27 kg and 1
A 0.032nm B O.40nm C 2.5nmD 14.Onm
Mark
Q21. On bombarding a beam of a-particles on the atom of the gold sheet a few particles get deflected whereas most of

them go 1 Mark straight and remains undeflected. This is due to:

A The nucleus occupy much smaller volume as compared to B The force of repulsion on fast moving a-particles is
very

the volume of atom. srn%ll. 1

C The neutrons in the nucleus do not have any effect on a- D The force of attraction on a-particles by the oppositely Mark
particles. charged electron is not sufficient.
Q22
• In the line spectrum of hydrogen, the lines described by the formula v = 109.677 B)cm where, n = integer, n 2 3.
Constitutes: 1
A Balmer series. B Lyman series. C Pfund series. D Paschen series. Mark
Q23. The electronic transition from n = 2 to n = 1 will produce the shortest wavelength in (where, n = principal quantum number).
D Li2+ 1
Q24. In atom, an electron is moving with a speed of 600m/ s with an accuracy of 0.005%. Certainty with which the position of the Mark
electron can be located is:
(h = 6.6 x 10-34 kg/ m 2 s-1, mass of electron, em = 6.6 x 10-31 kg)
A 1.52 x 10-4 m B 5.10 x 10-3 m C 1.92 x 10-3 m D 3.84 x 10-3 m
17
1
Q25. The value of 'h' = 6.63 x 10-34Js. The speed of light is 3 x 10 nm/ s-1 . Which value is closer to the wavelength in nanometer of
Mark
a quantum of light with frequency 6 x 10 15 s-1
A 50 B 75 c 10 D 25
Q26. An organic compound containing C, H and O has 49.3% carbon, 6.84% hydrogen and its vapour density is 73. Molecular 1
formula of the compound is: Mark
A C3H502 B C H 4 10 O2 C C H 6 10 O4 D C 3 H O10 2
Q27. One mole of any substance contains 6.022 x 10 23 atoms/ molecules. Number of molecules of H2S04 present in 100mL of 0.02M
1
 Mark
H2S04 solution is

A 12.044 x 10 20 molecules. B 6.022 x 1023

23
C I x 10 molecules. molecules.
23
D 12.044 x 10
molecules.
Q28. 16g of oxygen has same number of molecules as in: 1
A 16g of CO B 28g of N2 C 14g of N2 D Mark
I.og of 1-12
Q29. If 500mL of a 5M solution is diluted to 1500mL, what will be the molarity of 1
the solution obtained? Mark
A 1.5M B 1.66M C 0.017M
1.59M 1
Q30. A certain metal sulphide, MS2, is used extensively as a high temperature
Mark
lubricant. If MS2 is 40.06% by mass of sulphur, metal M has atomic
mass:

A 160amu B 64amu C 40amu 1

96amu Mark
Q31. Arrange the following in the order of increasing mass (Atomic mass of O = 16,
Cu = 63 and N = 14)
1. One atom of oxygen.
2. One atom of nitrogen.
3. 1 x 10 10 mole of oxygen.
4. 1 x 10 20 mole of copper.

C Il
Q32. For two statements are given-one labelled Assertion (A) and the other labelled Reason (R). Select the correct answer to these 1
questions from the codes (a), (b), (c) and (d) as given below. Mark
Assertion: A reactant that is entirety consumed when a reaction goes to completion is known as limiting reaction.
Reason: The amount of limiting reactant limits the amount of product formed.
A Both A and R are true and R is the correct explanation of A. B Both A and R are true but R is not the correct explanation
of A.
C A is true but R is false. D Ais false and R is also false.
Q33. What is the percentage by weight of sulphuric acid if 13g of H2S04 is dissolved to make 78g of solution?
A 13.2% B 14.28% c 20%
Q34. lg of M2C03 on treatment with excess HCI produces 0.01186 moles of C02 The molar mass of M2Cö3 in g mpr- is:
Mark
A 1186 B 84.3 c 118.6
Q35. The volume of 0.5M aqueous NaOH solution required to neutralize 10ml
of 2M aqueouS HC1solution is: 1 Mark A 20ml B 40ml D 120ml
Q36. Protons and neutrons are also called1 Mark
A Nucleons B Isotope D Elements
Q37. In the Schrodinger equation, H.1 Mark
1. A mathematical operator called Hamiltonian operator.
2. Introduced by Schrodinger from the expression for the total energy of the system. 1
3. Both (a) and (b). Mark
4. None of the above.

A A mathematical operator called Hamiltonian operator. B Introduced by Schrodinger from the expression for the total 1
energy of the system. C Both (a) and (b). D None of the above. Mark
Q38. The de Broglie wavelengths associated with a ball of mass Ikg having kinetic energy 0.5J is:

1 A (a) n = 3, I = 2, ml = -2, ms = 2

2 (b) n = 3, I = 2, ml = -1, ms = 2
 A 6.626 x 10 34 m B 13.20 x 10 34 m C 10.38 x 10 234 m D 6.626 x 10 34A
Q39. For two statements are given-one labelled Assertion (A) and the other labelled Reason (R). Select the correct answer to these
questions from the codes (a), (b), (c) and (d) as given below.
Assertion: It is impossible to determine the exact position and exact momentum of an electron simultaneously.
Reason: The path of an electron in an atom is clearly defined.

A Both A and R are true and R is the correct explanation of A. B Both A and R are true but R is not the correct explanation of
A.
C A is true but R is false. D A is false and R is also false.
Q40. Total number of orbitals associated with third shell will be

1
Mark

3 C (a) n = 4, I = 1, ml = 1, ms = 2

4 (b) n = 3, I = 2, ml = 1, ms = +
Q42. Number of angular nodes for 4d orbital is1 Mark
Q41. Out of the following pairs of electrons, identify the pairs of electrons present in degenerate orbitals: 1
Mark
1

Q43. The first line in the Balmer series in the H atom will have the frequency: 1
2
A 3.29 x 10 % 1 2
B 4.57 x 10 % 1 2
c 8.22 x 10 % 1
D 8.02 x 10 % 1 1 Mark
Q44. For two statements are given-one labelled Assertion (A) and the other labelled Reason (R). Select the correct answer to these
questions from the codes (a), (b), (c) and (d) as given below. 1
Assertion: Atomic orbital in an atom is designated by n, l, ml and ms. Mark
Reason: These play no role in designating electron present in an orbital
A Both A and R are true and R is the correct explanation of A. B Both A and R are true but R is not the correct explanation of
A.
C A is true but R is false. D A is false and R is also false.
Q45. The correct set of four quantum numbers for the valence electrons of rubidium atom (Z = 37) is:

1
Mark
1 1 1 1