Iit Jee Advanced Paper 7
Iit Jee Advanced Paper 7
Kukatpally, Hyderabad.
JEE-ADVANCE-2013-P1-Model
Max.Marks:180
PHYSICS
Lenses and combination of lenses + experiments involving concave mirror, convex lens,
concave lens (including optical bench) (Reference : JEE mains syllabus) (50%) (exclude
problems involving relative motion and differential and integral calculus)
Refraction at plane surface, TIR and Prism,
Refraction at curved surface (50%) (exclude problems involving relative motion and
differential and integral calculus)
CHEMISTRY
STOICHIOMETRY-I (8×2=16): Mole, significant figures, laws of chemical combination,
Chemical calculations based upon weight, volume relations of chemical equations,
percentage composition of mixtures,empirical and molecular formula,Concept of redox
reactions - oxidation number - Types of redox reactions, Balancing Redox reactions,
Equivalent weight,(60%)
De-Broglie Equation, Heisenberg's Uncertainity principle, Schrodinger's wave equation;
Quantum numbers, Pauli's exclusion Principle; Hund's rule; Electronic configuration of the
elements, (30%)
Cumulative syllabus (10%)
MATHS
Quadratic equation (30%); Properties of AP,AM,GP,GM; Sum of ‘n’ Terms of AP & GP,
Properties of HP & HM; Sum of infinite GP & AGP, method of differences/Vn method
(60%); Cumulative (10%)
JEE-ADVANCE-2013-P1-Model
Time: 3:00 Hours IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 10) Questions with Single Correct Choice 2 0 10 20
Sec – II(Q.N : 11 – 15) Questions with Multiple Correct Choice 4 -1 5 20
Sec – III(Q.N : 16 – 20) Questions with Integer Answer Type 4 -1 5 20
Total 20 60
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 21 – 30) Questions with Single Correct Choice 2 0 10 20
Sec – II(Q.N : 31 – 35) Questions with Multiple Correct Choice 4 -1 5 20
Sec – III(Q.N : 36 – 40) Questions with Integer Answer Type 4 -1 5 20
Total 20 60
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 41 – 50) Questions with Single Correct Choice 2 0 10 20
Sec – II(Q.N : 51 – 55) Questions with Multiple Correct Choice 4 -1 5 20
Sec – III(Q.N : 56 – 60) Questions with Integer Answer Type 4 -1 5 20
Total 20 60
B C
p p
A) A is p and B is B) A is 2p and B is
4 2
p p p
C) A is p and B is D) A is and B is
2 2 4
2. A quarter cylinder of radius R and 1.4 is placed on the table. A point object P is
kept at a distance of nR from it. The value of n for which a ray from P will emerge
nR R
25 9 16 4
A) B) C) D)
14 4 5 3
3. A rectangular slab made of a material of refractive index 2 is immersed is a liquid
A B
2
P 1
D C
2 2
A) 1 1 B) 1 C) 1 1 D) 2 1
2 2 2 1
space for rough work Page 4
4. The figure shows the cross-section of a hollow glass tube of inner radius r, outer
radius R, centre O and refractive index n. ABC and ODE are two light rays emerging
from the tube into outside air as shown, where BC and DE are parallel. The separation
C B
air y A
E o
D air
glass
2 2
A) y n r B) y n 1 R C) y nr D) y n R
lens provides sharp image of the source when placed at two different positions
between the source and the screen. If the size of the image at one position of the lens
in 16 times larger than that at the other position, the focal length of the lens is
A) 18 cm B) 15 cm C) 30 cm D) 12 cm
space for rough work Page 5
6. A point object O is placed at the bottom of a beaker and it is filled with water
4
up to a height of 16 cm. A plane mirror is fixed at 50 m above the surface of
3
water. The distance of the image of O from the mirror due to reflection by the mirror
is
5 cm
16 cm
O
A) 21 cm B) 9 cm C) 17 cm D) 12.5 cm
5
7. The refractive index of the material of a prism is . This prism can have a maximum
3
refracting angle of
A) 1060 B) 370 C) 530 D) 740
space for rough work Page 6
8. A glass hemisphere 1.5 has a radius of curvature of 8 cm. A small object O is
located on its axis halfway between the plane and spherical surfaces. The distance
between the two images when viewed along the axis from the sides of the hemisphere
is
1.5
O
47 53 32 29
A) cm B) cm C) cm D) cm
18 21 15 9
9. A convex lens of focal length f is placed between an object and a screen whereby the
image produced has magnification m. The distance between the object and the screen
mx mx x mx
A) 2
B) C) D) 2
m 1 1 m2 2
m 1 m 1
space for rough work Page 7
10. A given ray of light suffers minimum deviation in an equilateral prism P. Additional
identical prisms Q and R are now placed as shown. The ray will now suffer
Q
P R
A) total internal reflection B) greater deviation
C) no deviation D) same deviation as before
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.
11. A convex lens forms an image of an object placed in its axis on a screen. The height
of the image is 9 cm. Now the lens is displaced until an image is again obtained on the
screen. The height of the image is 4 cm. The distance between the object and the
screen is 90 cm. It follows that
A) the distance between the two positions of the lens is 30 cm
B) the focal length of the lens is 24 cm
C) the height of the object is 6 cm
D) the distance of the object from the lens in its first position is 36 cm.
space for rough work Page 8
12. A ray of light travels from a medium of refractive index to air. Its angle of
incidence in the medium is and the angle of deviation is . Let 1 be the maximum
1
A) 1 sin 1 B) 2 1
2
1 1
C) 2 21 D) C sin
13. A small plane mirror M is arranged parallel to a wall W at a distance from it. The
light produced by a point source S fixed on the wall is reflected by the mirror and
produces a light spot on the wall. The mirror is now moved with velocity towards
the wall. Then
S W
900 750
A D
A) the ray gets totally internally reflected at face CD
B) the ray emerges through face AD
C) the angle between the incident ray and the emergent ray is 1200
D) the angle of incidence of the ray with face AD is 300
depth 4 cm in a vessel . When viewed vertically through air, find the apparent distance
of the bottom of the vessel below the surface of benzene ( to the nearest cm)
5
17. An object is placed at a distance of f from a concave mirror of focal length f.
4
The mirror produces a real image______ times the size of the object
7
µ=
4
4
µ1
3
20. The focal length of a thin biconvex lens is 20cm. When an object is moved
from a distance of 25 cm to 50 cm in front of it, the magnification of its
m1
image changes from m 1 to m 2 . The ratio is ______
m2
space for rough work Page 12
CHEMISTRY Max Marks: 60
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 10 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +2 for correct answer, 0 if not attempted and 0 in all other cases.
21. In a “lead storage battery” the overall reaction (unbalanced) occurring can be
represented as
Pb(s) + PbO2(s) + H2SO4 (aq) PbSO4(s) + H2O (l)
Calculate the equivalent mass of sulphuric acid in terms of its molecular mass M.
A) M B) M/2 C) 2M D) M/4
22. Identify the species in its elemental form, which will not undergo disproportionation in
alkaline medium
A) white phosphorus B) S8 (s)
C) Cl2 (g) D) F2 (g)
23. The volume of oxygen produced from 3.0 Liters of chlorine according to the following
reactions (unbalanced) at STP is
Cl2 + NaOH NaCl + NaClO3 + H2O
NaClO3 NaCl + O2
A) 5L B) 3L C) 6L D) 1.5L
26. The equivalent weight of HCl when it reacts with K2Cr2O7 to produce Cl2 as one of the
14M M M 6M
A) B) C) D)
6 6 14 14
29. A 3L mixture of propane and butane on combustion produced 10L of CO2 at 250C.
The percentage composition of butane is?
A) 66 B) 44 C) 22 D) 11
30. Cu3P Cr2 O72 H Cu 2 H3PO4 Cr 3 the coefficient for Cu3P in balanced equation
is?
A) 2 B) 3 C) 6 D) 12
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.
31. Which among the following are true regarding the compound phosphorous(V) oxide
A) one mole of it on hydrolysis produces two moles of phosphoric acid.
B) one mole of it on hydrolysis gives a product equivalent to 12 moles of H+.
C) it is an anhydride of an acid whose equivalent mass can be 98.
D) its molecular structure contains four six membered rings.
value of “r”
C) “s” orbital has angular independence, i.e. for “s” orbital wave function is
independent of and
D) In the radial probability distribution function plots, if “n” is the number of times
the wave function changing its sign, then number of radial nodes for that orbital is
“n+1”
space for rough work Page 16
34.. Choose the correct statement(s)
A) when the number 100 is expressed in scientific notation we can have either one,
between first line of Balmer and first line of Lyman series is?
37. If the number of significant figures in 100 , 100. and 100.0 are X, Y and Z
38. The difference in the oxidation states of the two central atoms (N and Cl ) in pernitric
39. Chloride samples are prepared for analysis by using KCl, NaCl, NH4Cl separately or
precipitation of chloride in every possible case? Round off your answer to the nearest
integer.
X Y
weight of the hydride is Y; then report to the closest integer
10
A) 2 or 3 B) 1 or 4 C) 1 or 5 D) 4 or 5
44. If a, b, c are in G.P and the equations ax2 2bx c 0, dx2 2ex f 0 have a common
d e f
root then , , are in ......
a b c
A) A.P B) G.P C) H.P D) None of these
1 1
A) B) C) 1 D) 2
2 4
x2 y 2 z2
48. If x, y, z are real, then can’t lie between
xy yz zx
in
A) 3, 0 B) , 2 C) 0,3 D) 2,
p p 3
C) 4 4 3 D) 1
q q 2
1 1 1
52. The sum of the numerical series ........ up to n terms
3 7 7 11 11 15
3 4n 3 n
A) B)
4 3 4n 3
3 4n 3
C) less than ‘n’ D)
4
2 1 1 3 2 1
A) B)
bc b 2 4 c 2 ca a 2
3 2 3 2
C) 2
D)
b ab c 2 ac
A) a 8 B) b 8
C) c 1 D) a b c 17
55. If a, b, c are in A.P and a 2 , b2 , c 2 are in H.P then which of the following can be true?
b
A) a b c B) a , , c are in G.P
2
a
C) a, b, c in G.P D) , b, c are in G.P
2
different zeros and only one of them satisfying 0 x 2 lie in the minimum possible
57. Concentric circles of radii 1,2,….100cm are drawn. The interior of the smallest circle
is coloured red and angular regions are coloured alternately green and red so that no
two adjacent regions are of the same colour. The total area of the regions coloured
x
58. If 2 log x 2 y log x log y then the numerical value of is ________
y
60. The integral solutions of the equation x 1 x x x x where . and
. denotes
PHYSICS
1 C 2 A 3 D 4 C 5 D
6 C 7 D 8 C 9 A 10 D
11 CD 12 ACD 13 BC 14 ABD 15 BC
16 7 17 4 18 6 19 3 20 6
CHEMISTRY
21 A 22 D 23 D 24 B 25 B
26 D 27 A 28 D 29 A 30 C
36 3 37 0 38 2 39 6 40 5
MATHS
41) A 42) B 43) A 44) A 45) C
51) ABCD 52) ABC 53) ABC 54) ACD 55) ACD
1 sin 2 cosC
1 2 sin C
2
22 12
sin cot C 2 1
1 1
4.
c i B
1
y r
R A
i
r
o
sin i y / R y
, n
sin r ' r / R r
y nr
m
5. m 2 16 m 4 v 4u
1/ m
u v 75 5u 75 u 15cm
1 1 1 1
f 12cm
f 60 15 12
Page 2
3 3
6. y 16 16 1 5 16 5 17cm
4 4
7.
cc
3
C sin 1 370 A 2C 740
5
4 8
8. Viewed from plane surface : app depth x cm
1.5 3
Viewed from curved surface :
1 3/ 2 1 3/ 2 1 1 3 5 16
x ' cm
x' 4 8 x' 16 8 16 5
8 16 32
distance between images 8 cm
3 5 15
1 u
1 2
m f x 2 m 1 m 1 f mx
9. 2
1 m
v f m m m 1
f
10.
11. h 9 4 6cm
v 9
u h v 9 3
u 4 u 4 2
v h
3 5
u v 90 u u u 90 u 36cm
2 2
12.
Page 3
1 C
2
1 1
sin C C sin 1
C
2
C C
2
2 2 C 21
2
13.
light spot
S
W
14.
B
600
600 C
r 1350
450
450
450
r'
90 0 750
A D
sin 60 1 1
3 sin r r 300 sin c c 35.30
sin r 2 3
0
45 C total internal reflection at face CD.
r ' = 90 – (180 – 45 – 75) = 120 – 90 = 300
1 3 3 R
tan C R / 8 sin C tan C R 6cm
5 4 8
1 7 1 3 1 1
19. 1 f 8cm
f 4 6 4 6 8
1 1 1 1
For first image due to lens : v1 12cm
v1 8 24 12
4
Apparent depth 12 16cm x 19 16 3cm
3
20.
1 u 1 25
1 1
m f m1 20 m1 50 20 30
6
1 50 m 2 25 20 5
1
m 2 20
Page 5
CHEMISTRY
21. A
22. D, fluorine canot be oxidized in alkaline medium
23. D
24. B (NCERT)
25. A
26. D
K 2Cr2O7 14HCl 2CrCl3 2KCl 7H2O 3Cl2
Page 6
MATHS
41. Let ‘D’ is the common difference
a d 3 D
b d 2 D
c a 2D
D 0 9D 2 x 4 D 4 0
D is real x 4 2 4.94 0
x 16 or x 8
1 1 1 2
42. 1 ......
2 4 8 3
1 1 1 4
1 ......
4 16 64 5
x
log10 log10
2 16 x
61
From given condition 3x 11 14 3x
2
43.
7
3x 9 and 3x 27
44. b 2 ac and ax 2 2 ac x c 0
c
x
a
1
Fn 2 3 Fn 2 10 2 n 1
9
1 1 sin10
46. 0 0
0 0 0
sin1 sin 2 sin1 sin1 sin 2
0
1 sin 2 1
sin10 sin10 sin 20
2 1
47. Tr S n Tr 2 1
r r 1 n 1
Page 7
48. When xy yz zx 0
1 2 2 2
x 2 y 2 z 2 xy yz zx x y y z z x
2
x2 y2 z2
1
xy yz zx
When xy yz zx 0
2
x y z 0
x2 y 2 z 2
2
xy yz zx
x
1
49. Let y
2
y2 2 y b 0
y 1 1 b
x log 2
1 b 1
0 1 b 1 1
r
7 4 3
p
q 2 4 p 2q p 0
p 3
1
q 2
a c 2 2a 2c 2
55. b ;b 2 2
2 a c
2 2
Eliminate ‘b’ we get a c a c 2ac 0
ac
b2
2
56. D0 9k 2 40 0 always true
f 0 f 2 0
k 3,1
5050
2
58. x 0, y 0, x 2 y and x 2 y xy
x x
4 1 0
y y
x
7 343
59. By graph
2 228
60. x 1 x x
x 1 1 x 0
Page 9